Applying carbon fiber composite honeycomb in curved sandwich shells faces challenges due to the saddle-shaped bending surface in hexagon configurations and potential damage during the shape-forming process. This study analyzes the bending deformation of honeycombs by developing large deformation theoretical model for their bending surfaces. The study introduces two novel honeycomb configurations—Boomerang-shaped with a positive Poisson's ratio and Jellyfish-shaped with a negative Poisson's ratio—achieved through curved-wall design and fabrication using a modified carbon fiber composite tape winding molding process. Experimental tests, including bending deformation and shape-forming tests, measure the three-dimensional bending surfaces and mechanical responses of carbon fiber composite honeycombs. Additionally, a developed finite element model analyzes the damage states of various carbon fiber composite honeycombs during shape-forming processes. The results reveal the bending deformation of carbon fiber composite honeycombs and present damage state cloud maps to facilitate the optimal matching of objective sandwich shells with minimal scathe.