In this paper we study the approximation algorithms for a class of discrete quadratic optimization problems in the Hermitian complex form. A special case of the problem that we study corresponds to the max-3-cut model used in a recent paper of Goemans and Williamson J. Comput. System Sci., 68 (2004), pp. 442-470]. We first develop a closed-form formula to compute the probability of a complex-valued normally distributed bivariate random vector to be in a given angular region. This formula allows us to compute the expected value of a randomized (with a specific rounding rule) solution based on the optimal solution of the complex semidefinite programming relaxation problem. In particular, we present an $[m^2(1-\cos\frac{2\pi}{m})/8\pi]$-approximation algorithm, and then study the limit of that model, in which the problem remains NP-hard. We show that if the objective is to maximize a positive semidefinite Hermitian form, then the randomization-rounding procedure guarantees a worst-case performance ratio of $\pi/4 \approx 0.7854$, which is better than the ratio of $2/\pi \approx 0.6366$ for its counterpart in the real case due to Nesterov. Furthermore, if the objective matrix is real-valued positive semidefinite with nonpositive off-diagonal elements, then the performance ratio improves to 0.9349.