The use of multi-materials such as composites of carbon fiber reinforced thermoplastic (CFRTP) and high-strength steel or CFRTP and aluminum alloy is one of the main strategies for weight reduction in automotive body. When multi-materials are used outdoors, however, they are subject to galvanic corrosion, which increases the risk of failure and shortens their service life. On winter roads in cold regions, automotive bodies suffer significant corrosion due to the large amount of salt particles sprayed as an anti-freeze agent. If the corrosion products of the multi-material are relatively protective, the progression of corrosion can be prevented. Therefore, wet-and-dry cycle test was conducted on a coated multi-material joint consisting of CFRTP/high-strength steel or CFRTP/aluminum alloy plates to simulate winter road conditions in Northern Europe, and corrosion products formed in the crevice of multi-materials joint were investigated using a membrane potential measurement as well as Raman spectroscopy and X-ray fluorescence microscopy.The wet-and-dry cycle test, in which a sample was immersed in a 5:1 mixture of NaCl and CaCl2 solutions for 0.25 h and then repeatedly subjected to a wet atmosphere of 90%RH, 283 K for 4 h and a dry atmosphere of 10%RH, 308 K for 4 h more than a dozen times, was performed according to Kozaki [1]. After several weeks or more of exposure under the wet-and-dry cycle test conditions, corrosion products filled the crevice of the multi-material sample and did not to allow air leakage through the crevice gap. Ion selectivity of the corrosion products in the crevice obtained by the membrane potential measurement was found to be anionic rather than cationic selective in all tests. The products formed in the test using dilute mixture solution were relatively porous hydroxides and oxides and showed larger fixed charge concentrations than those formed in the test using concentrated solution. It was suggested that the density and composition of corrosion products play important roles in preventing atmospheric, galvanic corrosion in the gap of CFRTP/high-strength steel or CFRTP/aluminum alloy joints.[1] T. Kozaki, M. Umeta, J. Surf. Finish. Soc. Jpn. 73 (2022) 384-389.
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