To improve the tribological properties of the 7N21 aluminum alloy under dry sliding wear conditions, three E44-PI-PAI composite coatings filled with varying contents of MoS2, h-BN and VN were designed. The mechanical and tribological performances of these coatings were evaluated using scratch experiments, nanoindentation, and sliding wear experiments. After identifying the optimal coating, the engineering constants of the coating were determined using tensile experiments. Finally, a simulation analysis of the reciprocating wear life was performed using ABAQUS and a custom-developed UMESHMOTION subroutine. The results indicate that the optimal ratio of MoS2, h-BN and VN in the designed polymer coating is 4:3:4. The coefficient of friction (CoF) and wear rate of the optimal coating are 0.189 and 0.444×10−14 m3/Nm, representing a 67 % reduction in CoF compared to the 7N21 aluminum alloy. The L2 coating demonstrates excellent compatibility, featuring a surface roughness (Ra) of 0.630 μm, a uniform thickness of 10±2 μm, an optimal bonding strength at level 0, and a nanohardness of 0.391 GPa, meeting the requirements for engine bearings. The maximum deviation between the simulated wear life prediction and experimental results is only 8.11 %.