A novel photonic scheme for generating multi-band dual-chirp waveforms with linear or nonlinear chirp rates is proposed via two cascaded polarization modulators (PolMs) paralleled with a phase modulator (PM). The cascaded PolMs produce a flat optical frequency comb (OFC) as a multi-frequency reference light, while the PM is driven by the power-function-type baseband signals to obtain the lightwave with different order phase chirp. The phase-chirped lightwave and the multi-frequency reference lightwave are orthogonally coupled by a polarization beam combiner (PBC) and then recombined via a polarization beam splitter (PBS) to make them in-phase in one output port of the PBS and anti-phase in the other. The two recombined lightwaves are detected by a balanced photodetector (BPD), and the different order dual-chirp signals, covering six bands, can be generated in their differential photocurrent without interference components. Compared with the single-chirp signal of the knife-edge-type ambiguity function, the dual-chirp signal with the peak-saliency-type ambiguity function significantly suppresses sidelobe and shows better range-Doppler resolution performance. With the 1GHz-bandwidth and 102.4ns-duration quadratic baseband driving signal, six-band linear dual-chirp signal, centered at 10, 30, 50, 70, 90 and 110GHz, are generated by simulation, and each linear dual-chirp signal has a bandwidth of 4.1GHz, the pulse compression ratio of 465.45 and the peak-to-sidelobe ratio (PSLR) of 12.8dB. As baseband driving signal has higher (3rd) order power, the six-band nonlinear dual-chirp signals with the same central frequencies can also be generated but with increased bandwidth (6.3GHz) and the improved PSLR (15.51dB). Their autocorrelation functions show that compared with the linear chirp signal, the nonlinear chirp signal has better sidelobe suppression capability, which is improve as the degree of nonlinearity increase.