Microwave staring correlated imaging (MSCI) is a staring high-resolution microwave imaging technique, employing the temporal–spatial stochastic radiation field (TSSRF). The imaging capability of MSCI depends on the spatial correlation of the TSSRF, which is equivalent to the incoherence of the sensing matrix in discrete form. A waveform design method for MSCI using multifrequency signals to reduce the spatial correlation of the TSSRF is proposed. The amplitude of each frequency component in the multifrequency signals serves as the design variable. Considering the power and the amplitude constraints in the practical radar system, we first form the waveform design as a constrained optimization problem. Then, it is reformulated as a nonsmooth unconstrained optimization problem by the penalty function method. With the smoothing approximation, the reformulated problem is solved by alternating minimization. Numerical experiments show that the proposed method can decrease the spatial correlation of the TSSRF and improve the imaging performance of MSCI as a result.