With the advent of the information age, electromagnetic hazards are becoming more serious. In view of environmental protection, green electromagnetic interference (EMI) shielding materials with little or no secondary reflection have become the ideal choice. In this paper, by freeze-drying, high-temperature carbonization, coating and impregnation backfilling, we prepared carbonized Ni-MOF/reduced graphene oxide/silver nanowire-polyimide@polyethylene glycol composites (Ni@C/r-GO/AgNW-PI@PEG) with gradient conductivity based on impedance matching. The impedance matching layer Ni@C/r-GO-300 reduces the reflection of electromagnetic waves from the surface of the material, the dissipation layer Ni@C/r-GO-600 provides excellent electromagnetic wave dissipation capability, and the reflection layer AgNW-PI ensures that the electromagnetic waves are reflected back into the material. Meanwhile, the EMI shielding performance value of Ni@C/r-GO/AgNW-PI@PEG reaches 62.3 dB with an ultra-low reflectivity (R) of 0.04. In CST simulations, the intrinsic mechanism of electromagnetic energy loss within the material is revealed by energy loss density cloud maps. In addition, heat from high-temperature objects is transferred through the highly thermally conductive AgNW-PI membrane to the long-channel Ni@C/r-GO backbone. Therefore, the composites prepared on the basis of impedance matching will accelerate the use of EMI shielding materials for the thermal management of portable electronic devices and battery heat dissipation packaging.
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