Water Retention Properties Research Articles

Characterization of Chitosan Hydrogels Obtained through Phenol and Tripolyphosphate Anionic Crosslinking.

Chitosan is a deacetylated polymer of chitin that is extracted mainly from the exoskeleton of crustaceans and is the second-most abundant polymer in nature. Chitosan hydrogels are preferred for a variety of applications in bio-related fields due to their functional properties, such as antimicrobial activity and wound healing effects; however, the existing hydrogelation methods require toxic reagents and exhibit slow gelation times, which limit their application in biological fields. Therefore, a mild and rapid gelation method is necessary. We previously demonstrated that the visible light-induced gelation of chitosan obtained through phenol crosslinking (ChPh) is a rapid gelation method. To further advance this method (<10 s), we propose a dual-crosslinked chitosan hydrogel obtained by crosslinking phenol groups and crosslinking sodium tripolyphosphate (TPP) and the amino groups of chitosan. The chitosan hydrogel was prepared by immersing the ChPh hydrogel in a TPP solution after phenol crosslinking via exposure to visible light. The physicochemical properties of the dual-crosslinked hydrogels, including Young's moduli and water retentions, were subsequently investigated. Young's moduli of the dual-crosslinked hydrogels were 20 times higher than those of the hydrogels without TPP ion crosslinking. The stiffness could be manipulated by varying the immersion time, and the water retention properties of the ChPh hydrogel were improved by TPP crosslinking. Ion crosslinking could be reversed using an iron chloride solution. This method facilitates chitosan hydrogel use for various applications, particularly tissue engineering and drug delivery.

A novel NO-releasing composite hydrogel for infected wound healing

Infection and inflammation are key factors affecting wound healing. Hydrogels are excellent wound dressings that provide a moist healing environment and serve as carriers for drugs or functional components. This work proposes a composite hydrogel, APLCE, composed of methyl methacrylate L-arginine (M-L-Arg) as an NO donor, synthesized through free radical polymerization with acrylamide (AM) and polyethylene glycol (PEG). The hydrogel matrix exhibits good water retention and mechanical properties. CaO2 and ε-poly-L-arginine (EPL) are embedded in the hydrogel to form APLCE, where the hydrolysis of CaO2 releases H2O2, triggering the release of arginine to release NO, inhibiting wound inflammation and bacterial growth. EPL added to the hydrogel synergistically with NO exhibits an antibacterial effect, with a bacterial inhibition rate exceeding 99 %. Animal experiments show that APLCE can completely eradicate bacteria in infected wounds, promote new skin formation, and achieve a wound closure rate of 94 % within 14 days. These findings emphasize the potential clinical application of APLCE as an innovative wound dressing material.

Effect of volumetric deformation on saturation of unsaturated soils under constant suction

The soil–water retention curve (SWRC) represents a fundamental relationship in the study of unsaturated soils, where volumetric deformation plays a crucial role in shaping the water retention characteristics by impacting the pore size distribution. This study conducted a thermodynamic analysis to derive a relationship between the effective stress parameter and the water retention properties of unsaturated soils. Consequently, a streamlined formula was introduced to forecast the impact of volumetric deformation on saturation at constant suction. This formula, incorporating a singular parameter from the effective stress parameters equations, can be seamlessly integrated with any prevailing SWRC model to characterize the influence of volume deformation on the SWRC. The effectiveness of the proposed model was corroborated through seven sets of experimental data spanning various soils, affirming its capability to precisely describe the water retention behavior of deformable soils under deformation.

Construction a quasi-solid-state photoelectrochemical type photodetector based on WO3/PVA/ZnSO4 and its application in near ultraviolet light detection

Low carrier mobility of WO3 material limited its application and development in the field of optoelectronic devices, especially used in photodetectors. Herein, a quasi-solid-state photoelectrochemical photodetector based on WO3 film and solid-state electrolyte (PVA/ZnSO4) was constructed. The WO3 film was prepared by a hydrothermal method. The obtained WO3/PVA/ZnSO4 quasi-solid-state photoelectrochemical photodetector exhibits superior near ultraviolet light detection performance and better stability compared with the traditional WO3/ZnSO4 photoelectrochemical detector. Considered the volatility of water in the electrolyte, a small amount of NaCl was added into the electrolyte to increase the water retention property of the electrolyte. The obtained results demonstrate that NaCl has some water retention property and can improve the stability of the device effectively. These obtained results provide the data foundation for the research and development of photodetectors based on WO3 materials.

Slow-Release Urea Fertilizer with Water Retention and Photosensitivity Properties Based on Sodium Alginate/Carboxymethyl Starch Sodium/Polydopamine

Using slow-release fertilizer is one of the sustainable strategies to improve the effectiveness of fertilizers and mitigate the environmental pollution caused by excess usage of fertilizer. In this study, a slow-release urea fertilizer with water retention and photosensitivity properties was prepared by a two-step method. It was characterized by Fourier transform infrared spectroscopy, thermogravimetric analysis, scanning electron microscopy and an infrared camera. This fertilizer can prolong the release period of urea, improve water-retention capacity of soil, and carry out photothermal conversion under illumination. Comparing four release kinetics models, the Ritger–Peppas model was the best fitting model for releasing behavior in soil, and diffusion followed the Fickian mechanism. The application of fertilizer on winter wheat was carried out to intuitively evaluate the fertilizer’s effects on promoting plant growth and resisting water stress. Thus, this study provides a new strategy for improving fertilizer utilization rate and maintaining soil moisture, which will be beneficial for sustainable agriculture.

Preparation and Properties of Attapulgite/Brucite Fiber-Based Highly Absorbent Polymer Composite.

The ATP-BF-P(HEC-AA-AMPS) composite highly absorbent polymer was copolymerized with acrylic acid (AA) and 2-acrylamido-2-methylpropane sulfonic acid (AMPS) using an aqueous solution method with attapulgite (ATP) and attapulgite (ATP) as a matrix. The prepared ATP-BF-P(HEC-AA-AMPS) was characterized in terms of microstructure and tested for its water absorption capacity, water retention properties, and pH dynamic sensing ability. The results showed that the synthesized ATP-BF-P(HEC-AA-AMPS) had a rough and porous surface and a high water absorption capacity and rate, almost reaching the maximum water absorption around 20 min, and demonstrated excellent water retention performance at low and medium temperatures. ATP-BF-P(HEC-AA-AMPS) has a sensitive dynamic sensing ability in different pH solutions, with a high swelling capacity between pH 6.0 and 10.0. When the pH value exceeded 10.0, the swelling rate decreased rapidly. Additionally, the thermal stability and mechanical strength of the highly absorbent polymers were significantly improved after blending with ATP and BF.

Uncovering the Molecular Composition and Architecture of the Bacillus subtilis Biofilm via Solid-State NMR Spectroscopy.

The complex and dynamic compositions of biofilms, along with their sophisticated structural assembly mechanisms, endow them with exceptional capabilities to thrive in diverse conditions that are typically unfavorable for individual cells. Characterizing biofilms in their native state is significantly challenging due to their intrinsic complexities and the limited availability of noninvasive techniques. Here, we utilized solid-state nuclear magnetic resonance (NMR) spectroscopy to analyze Bacillus subtilis biofilms in-depth. Our data uncover a dynamically distinct organization within the biofilm: a dominant, hydrophilic, and mobile framework interspersed with minor, rigid cores of limited water accessibility. In these heterogeneous rigid cores, the major components are largely self-assembled. TasA fibers, the most robust elements, further provide a degree of mechanical support for the cell aggregates and some lipid vesicles. Notably, rigid cell aggregates can persist even without the major extracellular polymeric substance (EPS) polymers, although this leads to slight variations in their rigidity and water accessibility. Exopolysaccharides are exclusively present in the mobile domain, playing a pivotal role in its water retention property. Specifically, all water molecules are tightly bound within the biofilm matrix. These findings reveal a dual-layered defensive strategy within the biofilm: a diffusion barrier through limited water mobility in the mobile phase and a physical barrier posed by limited water accessibility in the rigid phase. Complementing these discoveries, our comprehensive, in situ compositional analysis is not only essential for delineating the sophisticated biofilm architecture but also reveals the presence of alternative genetic mechanisms for synthesizing exopolysaccharides beyond the known pathway.

Highly efficient antifouling and toughening hydrogel for ship coatings

Hydrogels possess characteristics of anti-protein adsorption, which have attracted significant attention in the field of ship antifouling. Traditional hydrogels often exhibit poor mechanical properties and lack long-term application value. Herein, a PEGp hydrogel for underwater antifouling applications was prepared. PEGp hydrogel demonstrates excellent water retention, elasticity, and antifouling properties. It can effectively resist the adsorption of proteins and bacteria. The long-term antifouling test shows that PEGp hydrogel has application prospects in the marine environment. Additionally, molecular dynamics (MD) simulations show that water molecules interact with the PEGp to form a hydration layer, endowing PEGp hydrogel with hydrophilicity. These studies offer a novel approach to developing ship antifouling materials and exploring new directions for environmental protection and antifouling.

Restart performance of prolonged stopped down-flow hanging sponge reactor for treating of low-strength domestic sewage

The down-flow hanging sponge (DHS) reactor, a type of trickling filter used as a sponge, is a promising treatment system for low-cost sewage treatment. However, the performance of dried sponges that have been non-operational for 8 months has not been evaluated. Accordingly, herein, the re-startup process performance of a DHS reactor treating low-strength domestic sewage in Thailand that had stopped operation for over eight months was investigated. The dried sponge carrier immediately retained water in the sponge biomass-retained carrier and absorbed organic compounds. High nitrification activity of the DHS reactor was observed after 13 d, which was the same as that of the pure sponge biomass-retained carrier start-up. The tracer test results showed that the restarted DHS reactor had a high hydraulic retention time (HRT)/theoretical HRT ratio of 134.2 % at the beginning of the operation from the water retention property of the sponge carrier. Microbial community analysis showed that nitrifying microorganisms were effectively recovered in the biomass-retained sponge carrier. These results demonstrate that the sponge carriers in the DHS reactor that were left into dry condition are available for reuse and has high potential for rapid re-startup.

Oral Lubrication, Xerostomia, and Advanced Macromolecular Lubricants for Treatment of Dry Mouth

Dry mouth, also known as xerostomia, is a condition in which insufficient or ineffective saliva does not provide sufficient oral lubrication. The severity of this condition can vary from a mild discomfort to a debilitating condition that greatly impairs patients’ lives. Xerostomia arises as a side effect of various medications, diseases, radiation therapy, chemotherapy, or nerve damage. Various aqueous dispersions of macromolecules have been proposed to assist or replace the saliva in these patients. It is vital that these macromolecules have ample lubricity and water retention properties while showing long-lasting efficacy. The emphasis of this review is to provide a general overview on lubricating macromolecules that have been clinically used or reported in the literature as potential replacements for saliva. These include various natural or synthetic polymers, proteins, peptides, and lipids that are used in the form of solutions, gels, emulsions, and colloids. Perspectives into the future of macromolecular oral lubricants in the treatment of xerostomia are also provided.

Unsaturated hydraulic property measurements of subtropical anthropogenic (purple) soils in China

AbstractMany anthropogenic soils, often referred to as red bed or purple soils, are distributed in various areas of southern China. Purple soils typically are highly weathered and often lead to natural and engineering hazards because of their relatively poor water retention properties. Knowledge of the unsaturated soil hydraulic properties of purple soils is crucial for their optimal management and various assessment studies. In this work, the hydraulic properties of purple soils from southern China were measured in the laboratory over the full moisture range using a combination of evaporation (HYPROP) and psychrometer (WP4C) approaches. Measured data were analyzed in terms of four different unimodal and bimodal soil hydraulic models. The measurements and analyses showed that bimodality was not overly significant for most samples. The good fit of the Peters–Durner–Iden models furthermore suggested that corner and film flows were important under relative dry conditions. Existing soil pedotransfer functions were found to provide a fairly close match for the slope of water retention curves with the exception of near saturated water contents and the saturated conductivity. To the best of our knowledge, this is the first time that unsaturated hydraulic data of purple soils are provided over the full moisture range.

Exploring the integration of orange peel for sustainable gluten-free flatbread making

In response to the growing demand for sustainable and nutritious gluten-free (GF) products, this study explore orange peel by-products as a breadmaking ingredient of GF rice or corn flatbreads. The orange peel powder exhibited remarkable water retention properties attributed to its high dietary fiber content. Partial pre-gelatinization of rice (64 g/100 g) and corn (67 g/100 g) flour allowed obtaining doughs with sufficient consistency and extensibility to obtain GF flatbreads. The inclusion of orange peel powder (0–9 g/100 g) influenced the consistency and thermal behavior of the dough. Modifying hydration levels mitigated the hardness resulting from orange peel powder substitution, leading to improved folding properties. Final products exhibited enhanced nutritional profiles, including higher ash and dietary fiber content. The optimum nutritional and technological outcomes were observed when employing the maximum substitution rate of 9 g/100 g, along with adjusted hydration (164 g/100 g for corn and 169 g/100 g for rice), with notable emphasis on the improved extensibility of the final products. Compared to rice-based flatbreads, corn-based flatbreads displayed more uniform dough consistency, lower gelatinization enthalpy, higher yellowness, and decreased extensibility due to the stiffer dough texture. This study suggests that orange peel residue holds significant promise as a nutritional and technological enhancer for gluten-free flatbreads.

Nitrogen Deposition Modulates Litter Decomposition and Enhances Water Retention in Subtropical Forests

Nitrogen (N) deposition influences litter decomposition and its water-holding capacity in forest ecosystems. Water conservation remains a priority, so understanding these interactions is vital for managing forests, especially in the Yunnan Plateau region. This study aimed to investigate the effects of simulated N deposition on litter decomposition and water-holding capacity in the Evergreen broad-leaf and Quercus aquifolioides forest in the central Yunnan Plateau. Indoor flooding experiments were performed alongside varied nitrogen deposition treatments. Litter decomposition rates under these treatments were evaluated using the Olson model. In the decomposition study, the N treatments in the Evergreen broad-leaved forest increased the remaining mass by 4.75%–17.50% and 2.09%–16.36% compared with the control (20.97 ± 0.44% and 42.43 ± 0.47%), while in the Quercus aquifolioides forest, the remaining mass of leaves and twigs decreased by 5.00% and 0.70% in the LN treatment compared with the control (35.47 ± 0.39% and 44.10 ± 1.18%) and the MN and HN treatments increased by 2.55%–8.13% and 5.61%–11.28%, respectively. Effects of increased N deposition on litter decomposition changed from promoting to inhibiting, as low N sped up decomposition but higher levels inhibited it. Additionally, N boosted the water-holding capacity of litter, especially in leaves. The litter from both forests displayed a notable ability to absorb water. Nitrogen deposition modulates litter decomposition and water retention properties. Specifically, high nitrogen deposition increases litter water-holding capacity by inhibiting the rate of litter decomposition, which in turn alters its mass remaining rate, lignin, and cellulose remaining rates. Efficient management of the studied forests leveraging nitrogen deposition can boost their water conservation potential, aiding in atmospheric precipitation absorption and surface runoff regulation.

One-pot co-crystallized hexanal-loaded ZIF-8/quaternized chitosan film for temperature-responsive ethylene inhibition and climacteric fruit preservation

Controlling ethylene production and microbial infection are key factors to prolong the shelf life of climacteric fruit. Herein, a nanocomposite film, hexanal-loaded ZIF-8/CS (HZCF) with “nano-barrier” structure, was developed by a one-pot co-crystallized of ZIF-8 in situ growth on quaternized chitosan (CS) and encapsulation of hexanal into ZIF-8 via microporous adsorption. The resultant film realized the temperature responsive release of hexanal via the steric hindrance and hierarchical pore structure as “nano-barrier”, which can inhibit ethylene production in climacteric fruit on demand. Based on this, the maximum ethylene inhibition rate of HZCF was up to 52.6 %. Meanwhile, the film exhibits excellent antibacterial, mechanical, UV resistance and water retention properties, by virtue of the functional synergy between ZIF-8 and CS. Contributed to the multifunctional features, HZCF prolonged the shelf life of banana and mango for at least 16 days, which is 8 days longer than that of control fruit. More strikingly, HZCF is washable and biodegradable, which is expected to replace non-degradable plastic film. Thus, this study provides a convenient novel approach to simplify the encapsulation of active molecule on metal-organic frameworks (MOFs), develops a packaging material for high-efficient freshness preservation, and helps to alleviate the survival crisis caused by food waste.

Multi-season Evaluation of Substrates for Optimized Arugula and Lettuce Production in Hydroponics

Rockwool and peatmoss are commonly used substrates in the greenhouse industry due to their quality, stable pH, exceptional water retention properties and air porosity that is important for plant root development. Although rockwool is commonly used in deep water culture (DWC) hydroponic systems as the base support, there is a lack of studies comparing different types of substrates that could be used in DWC systems, especially considering the increasing market value and awareness of sustainable production in controlled environment agriculture. We identified 13 commercial substrate mixes with different compositions and conducted a series of studies in a DWC system in a greenhouse for three seasons to evaluate their effects on arugula ‘Slow Bolt’ (Eruca sativa L.) and lettuce ‘Summer Crisp’ (Lactuca sativa L.) growth, yield, and quality. The substrates tested significantly influenced the growth, yield, and quality of both arugula and lettuce. The average leaf fresh weight per plant could range from 44 to 190 g for arugula and 89 to 265 g for lettuce. The peat-based products outperformed the coir and other inorganic substrates (phenolic foam, rockwool). The substrate with 75% peat + 25% fine coir produced the greatest plant height, width, and biomass for arugula and lettuce over three growing seasons. Examining arugula and lettuce growth, the fall season produced plants with higher water and nutrient use efficiency, while plants grown during the winter had lower resource use efficiency. Further research is needed to engineer hydroponic substrates suitable for various seasons of leafy green production that results in comparable yield and quality.

ДОСЛІДЖЕННЯ СТАНУ ҐРУНТІВ РЕКУЛЬТИВОВАНИХ ТЕРИТОРІЙ ПІСЛЯ ВИДОБУВАННЯ ІЛЬМЕНІТУ НА ЖИТОМИРСЬКОМУ ПОЛІССІ

The article investigates the physical and mechanical composition of the soils of reclaimed areas after ilmenite mining in Zhytomyr Polissia, in particular, the granulometric composition and moisture content of the soils of the reclaimed areas of the Irshansk Mining and Processing Plant. It also identifies soil types by their fractional composition. To carry out the research, 7 test areas were laid out: a control area undisturbed by mining, a dump of topsoil, a site after technical reclamation, and 4 sites after biological reclamation. In order to study the dynamics of reclaimed soil restoration, we selected sites reclaimed at different times. To determine the influence of tree species on the effectiveness of reclamation, we studied sites with plantations of Pinus sylvestris and plantations of Pinus sylvestris and Betula pendula reclaimed at the same time. For all the studied areas, we determined the granulometric composition of the soil by wet and sieve methods, and soil moisture content. The results of the study showed that the soils of the reclaimed areas are mostly sandy, sandy loam and clay loam. These soils are characterized by low water retention properties and low nutrient content. The study also indicated a correlation between the topography of the studied plots and moisture levels as well as the content of fine fractions in the soil. The research revealed that soils in the areas disturbed by open-pit mining are undergoing significant transformations, which has a negative impact on their forest vegetation potential. To restore this potential, it is necessary to carry out high-quality technical and biological reclamation using modern advanced methods. To improve the effectiveness of reclamation of disturbed areas, it is beneficial to apply mineral and organic fertilizers, plant nitrogen-fixing plants, and add biochar to the soil fertile layer at the stage of levelling of the area.

Effect of Ultrasonic Treatment on the Physicochemical Properties of Bovine Plasma Protein-Carboxymethyl Cellulose Composite Gel.

In order to improve the stability of bovine plasma protein-carboxymethyl cellulose composite gels and to expand the utilization of animal by-product resources, this study investigated the impact of different ultrasound powers (300, 400, 500, 600, and 700 W) and ultrasound times (0, 10, 20, 30, and 40 min) on the functional properties, secondary structure and intermolecular forces of bovine plasma protein-carboxymethyl cellulose composite gel. The results showed that moderate ultrasonication resulted in the enhancement of gel strength, water holding capacity and thermal stability of the composite gels, the disruption of hydrogen bonding and hydrophobic interactions between gel molecules, the alteration and unfolding of the internal structure of the gels, and the stabilization of the dispersion state by electrostatic repulsive forces between the protein particles. The content of α-helices, β-turns, and β-sheets increased and the content of random curls decreased after sonication (p < 0.05). In summary, appropriate ultrasound power and time can significantly improve the functional and structural properties of composite gels. It was found that controlling the thermal aggregation behavior of composite gels by adjusting the ultrasonic power and time is an effective strategy to enable the optimization of composite gel texture and water retention properties.

Using ultrasonic-assisted sodium bicarbonate treatment to improve the gel and rheological properties of reduced-salt pork myofibrillar protein

To study the impact of ultrasonic duration (0, 30, and 60 min) and sodium bicarbonate concentration (0% and 0.2%) on the gel properties of reduced-salt pork myofibrillar protein, the changes in cooking yield, colour, water retention, texture properties, and dynamic rheology were investigated. The findings revealed that added sodium bicarbonate significantly increased (P < 0.05) cooking yield, hardness, springiness, and strength of myofibrillar protein while reducing centrifugal loss. Furthermore, the incorporation of sodium bicarbonate led to a significant decrease in L⁎, a⁎, b⁎, and white values of cooked myofibrillar protein; these effects were further amplified with increasing ultrasonic duration (P < 0.05). Additionally, storage modulus (G') significantly increased for myofibrillar protein treated with ultrasonic-assisted sodium bicarbonate treatment resulting in a more compact gel structure post-cooking. In summary, the results demonstrated that ultrasonic-assisted sodium bicarbonate treatment could enhance the tightness of reduced-salt myofibrillar protein gel structure while improving the water retention and texture properties.

High-conductivity and long-term stability strain sensor based on silk fibroin and polyvinyl alcohol hydrogels

Conductive hydrogels as promising candidates of wearable electronic have attracted considerable interest in health monitoring, multifunctional electronic skins, and human-machine interfaces. However, to simultaneously achieve excellent electrical properties, long-term stability, and water vapor permeability of conductive hydrogels remains a challenge. Herein, a highly conductive hydrogel (MPRS) with high breathability (5.90 mg∙cm−2∙h−1), excellent electrical conductivity (6.67 S/m), high elongation (315%), and remarkable water retention properties was prepared adopting cold freeze-thawing method. MXene, poly (3, 4-ethylenedioxythiophene): poly (styrenesulfonate) (PEDOT: PSS), and reduced graphene oxide were used as conductive materials, while silk fibroin (SF) and polyvinyl alcohol (PVA) were used as the gel matrix. Lithium chloride solution was used as a solvent during the preparation process. The strain sensor based on this hydrogel demonstrates rapid response (0.33 s) and recovery ability (0.31 s) to strain stimuli. Upon 250 cycles of stretching at 35% strain, the output signal remains stable and highly repeatable, ensuring accurate detection of human joint movements and facial expressions. The fabrication of flexible electrodes using the hydrogel enabled real-time monitoring of human electromyography and electrocardiogram signals. The applications in a 2D sensor array and human-machine interaction interfaces also proved the excellent performance of this conductive hydrogels in wearable sensor.

Synergizing date palm seeds-derived oxidized activated carbon: Sustainable innovation for enhanced water retention, efficient wastewater treatment, and synthetic dye removal

Herein, this study explores the efficacy of oxidized activated carbon from date palm seeds (OACDS) as a multifaceted solution for sustainable wastewater treatment and water retention improvement. Through oxidation synthesis, OACDS demonstrates exceptional capability in adsorbing contaminants from water sources, offering a promising eco-friendly option for environmental remediation. Batch adsorption experiments highlight the rapid and efficient removal of Rh-6 G dyes, achieving an impressive 88.06% adsorption rate under optimized conditions of pH 6 and a 70-minute contact time. Moreover, OACDS exhibits remarkable adsorption capacities, reaching 91.3% at a 60 mg adsorbent dose and 94.23% at 55°C. Kinetic and adsorption analyses align with PSO and Langmuir models, indicating chemisorption and mono-layered adsorption of Rh-6 G on OACDS. Thermodynamic evaluation suggests the process's spontaneity and endothermic nature. The regeneration experiment revealed a notable 10.9% decrease in the adsorption capacity of OACDS towards Rh-6 G after five cycles. These findings substantiate the reusability and cost-effectiveness of OACDS, underscoring its potential economic advantages. Beyond wastewater treatment, OACDS showcases notable water retention properties, promising for agricultural applications. Its integration into clay and sandy soil enhances water retention capacities, with the clay soil-OACDS mixture displaying a peak of 16.8 mL. The material's rough and porous surface positively impacts water retention in crops, benefiting agricultural yields. Comprehensive characterization analyses using SEM, FTIR, and XRD support OACDS's effectiveness in adsorption, highlighting its amorphous structure and suitability for environmental applications. This study positions OACDS as a comprehensive solution addressing wastewater treatment and water conservation challenges, encouraging further exploration of agricultural byproducts for sustainable environmental solutions.