Water Content Ratio Research Articles

Simultaneous Purification of Human Interferon Alpha-2b and Serum Albumin Using Bioprivileged Fluorinated Ionic Liquid-Based Aqueous Biphasic Systems.

Interferon alpha-2b (IFN-α2b) is an essential cytokine widely used in the treatment of chronic hepatitis C and hairy cell leukemia, and serum albumin is the most abundant plasma protein with numerous physiological functions. Effective single-step aqueous biphasic system (ABS) extraction for the simultaneous purification of IFN-α2b and BSA (serum albumin protein) was developed in this work. Effects of the ionic liquid (IL)-based ABS functionalization, fluorinated ILs (FILs; [C​2C​1Im][C​4F​9SO​3] and [N​1112(OH)][C​4F​9SO​3]) vs. mere fluoro-containing IL ([C​4C​1Im][CF​3SO​3]), in combination with sucrose or [N​1112(OH)][H​2PO​4] (well-known globular protein stabilizers), or high-charge-density salt K​3PO​4 were investigated. The effects of phase pH, phase water content (%wt), phase composition (%wt), and phase volume ratio were investigated. The phase pH was found to have a significant effect on IFN-α2b and BSA partition. Experimental results show that simultaneous single-step purification was achieved with a high yield (extraction efficiency up to 100%) for both proteins and a purification factor of IFN-α2b high in the enriched IFN-α2b phase (up to 23.22) and low in the BSA-enriched phase (down to 0.00). SDS-PAGE analysis confirmed the purity of both recovered proteins. The stability and structure of IFN-α2b and BSA were preserved or even improved (FIL-rich phase) during the purification step, as evaluated by CD spectroscopy and DSC. Binding studies of IFN-α2b and BSA with the ABS phase-forming components were assessed by MST, showing the strong interaction between FILs aggregates and both proteins. In view of their biocompatibility, customizable properties, and selectivity, FIL-based ABSs are suggested as an improved purification step that could facilitate the development of biologics.

Determining Liquid Limit and Plastic Limit of Clay Soils by Electrical Surface Conduction and Diffuse Double Layer Thickness

The aim of this study was to propose a new approach to determine the liquid limit and plastic limit of clay soils by considering electrical conductivity (EC) measurements. The proposed method included incorporating a new parameter, F, which is the ratio of the volumetric water contents of diffuse double layer (DDL) water and free water. In addition, the EC parameter, σ, was considered as the ratio of electrical surface conductivity and electrical conductivity of water. The changes in the thickness of DDL (χ) were also assessed to obtain corresponding equations to establish a connection with clay mineralogy, water content, and specific gravity in the final prediction. Three-dimensional surface analyses were conducted to find a correlation among F, σ, and χ to identify an appropriate method to predict liquid limit and plastic limit. The study was conducted with 39 different types of samples, and the outcomes from the EC approach were validated against the conventional methods. Overall, the coefficient of determination, R2 = 0.90, and Lin’s concordance correlation coefficient, (LCCC) = 0.91, were obtained for liquid limit prediction, whereas R2 = 0.64 and LCCC = 0.80 were obtained for plastic limit determination.

Study on the impact of physical characteristics of soil-rock composite medium on its relative permittivity based on laboratory experiments

The permittivity of soil-rock composite media is crucial for interpreting data originating from geophysical surveys such as ground-penetrating radar (GPR) imaging. At present, relevant theoretical research on the correlation analysis between the electrical and physical parameters of soil-rock composite media has not yet resulted in a complete reference system. This makes it difficult to characterize soil-rock composite media using the electromagnetic characteristic parameters of rock and soil media. In this study, the indoor electromagnetic testing method was used to extract electrical parameters such as the relative permittivity of soil-rock composite, and the influence of water content, density, soil-rock ratio, and other factors on the electrical parameters of soil-rock composite medium was analyzed. Furthermore, an artificial neural network prediction model was established, and the accuracy of the model was evaluated. The results showed that the relative permittivity tends to decrease with an increase in saturation when the moisture content of the mixture is high. The rock has a lower permittivity value than the surrounding soil particles. When the rock content increases, the average permittivity and conductive permittivity of the composite medium decreases. The main factors affecting the electrical properties of soil-rock composite media (in order of their influence, from most to least) are water content, compaction degree, and soil-rock ratio. These results provide a reliable reference for field geophysical exploration.

The Influence of Hibiscus tiliaceus Leaf Extract as Capping Agent on the Zinc Oxide Properties and its Photo-simultaneous Performance

Polyol method, as one alternative in ZnO synthetic methods, have been developed and generated a nano-ZnO. However, the produced nano-ZnO is unstable due to its small particle size. To overcome the problems, we added Hibiscus tiliaceus leaves’ extract during the ZnO (EZnO) synthesis to change the water content and hydrolysis ratio of Zn2+/water. The addition of H. tiliaceus extract resulted in a shifting peak at (101) plane compared to ZnO synthesized without extract addition (WZnO). The use of H. tiliaceus extracts leads to the formation of large and non-uniform particles compared to the one prepared without the extract, which is in agreement with the intensity of diffraction pattern. The use of H. tiliaceus extracts shifted the bandgap energy to visible range. The performance of WZnO and EZnO samples was tested for simultaneous photo-oxidation of methylene blue and photo-reduction of Cr(VI) ions under UV-C irradiation. The EZnO is equally active as WZnO for Cr(VI) ion photo-reduction but less active for photo-oxidation of methylene blue. The presence of retained organic material in EZnO is plausibly affected by the adsorption and subsequent photo-oxidation of the bulky MB leading to a lower photo-oxidation performance. However, the activity of EZnO was a little bit lower than that of WZnO, revealing that the synergistic of particle size and band gap energy is a crucial factor in photo-removal process. In addition, the presence of phenolic compounds on the EZnO surface might change the nature properties of WZnO, which influence its performance.

Characterizing early postoperative changes in body composition in patients with secondary lymphedema after breast cancer surgery: potential screening indicators for preventive intervention.

[Purpose] To characterize changes in the body composition of individuals with secondary lymphedema that developed in the early postoperative period after breast cancer surgery, before the manifestation of volume increase in the affected limb, and to test its potential as a screening indicator for preventive intervention. [Participants and Methods] A total of 219 patients with breast cancer who underwent axillary lymph node dissection and sentinel lymph node biopsy were included in this study. Body composition (extracellular water content, extracellular water content ratio, low-frequency impedance value, and phase angle) was evaluated using bioelectrical impedance analysis before surgery and three and six months after surgery. Changes in the body composition of the affected limb over time were compared between the lymphedema- and non-lymphedema-affected groups. [Results] Sixteen patients who developed lymphedema six months after breast cancer treatment showed significant changes in all body composition parameters at three months postoperatively, compared to those who did not develop lymphedema. [Conclusion] In patients with upper extremity lymphedema that develops within six months after breast cancer surgery, increases in extracellular water content, extracellular water content ratio, low-frequency impedance, and phase angle may precede apparent volume increases. Our findings suggest the usefulness of these parameters as screening indicators for early treatment triaging.

Economical Measures against Soft Ground at High Embankment on Peaty Ground

Peat, which is considered a special soil, is widely distributed over approximately 2,000 km2 in Hokkaido, Japan. In terms of engineering properties, peat is extremely high in water content, ignition loss, and void ratio and extremely in low shear strength. Ground improvement methods using cement are effective for the rapid construction of embankments on peaty ground. However, to avoid differential settlement and lateral flow, most of such construction is carried out with an improvement ratio of ap=50%. In this case, the improvement can certainly be expected to be effective. However, it is less economical than other soft ground improvement methods. The challenge is to reduce the cost of improving the ground. Our institution (the Civil Engineering Research Institute for Cold Region, PWRI) has developed an economical measure against soft ground that uses cement with a reduced improvement ratio in combination with a crushed-stone mat (gravel foundation reinforcement), and we conducted the test construction of a 16-meter-high embankment to verify effectiveness of the method. The crushed-stone mat consists of a 50-cm layer of crushed stone covered with a geo-synthetic material. The test construction achieved the following results. (1) Settlement of the embankment was significantly reduced. (2) Slip failure did not occur. (3) Displacement to the surrounding ground did not occur. (4) The geotextile in the crushed-stone mat exhibited less strain than that which would cause the geo-synthetic to exceed its design strength. These results show that this economical measure against soft ground was effective at stabilizing the high embankment constructed on peaty ground.

Investigation of the mechanical properties of magnesium chloride on magnesium oxide improved kaolin clay

In our study, samples were prepared by mixing 2%, 4%, and 6% MgO doses with the dry weight of kaolin-type low-plastic clay. In each MgO dose, 1% and 2% of the soil weight, respectively, MgCl2 chemicals were added, and all samples were mixed at the optimum water content ratio (16.2%). All components were mixed with a planetary mixer for 10 minutes until homogeneous, and then the mixture was poured to have 25 blows for 5 layers. All samples were cured under room conditions for 3–10 days to be tested on the Unconfined Compression Test. From the results, it was observed that the undrained shear strength of the sample increased as the percentages of MgCl2 and MgO rose. It can be said that the interaction between MgO and MgCl2 contributes to the cementation of the clay, and sorel cement plays a role in the mechanical strengthening of kaolin clay based on its effect on strength development. Extending the curing time also developed the mechanical properties of kaolin clay and improved the hardness of the samples by increasing the elastic modulus. In this way, early failures were attained at early strains, and the ductility of the samples increased. We finally saw that the mixture of MgO and MgCl2 worked well as a building material for kaolin clay. The study also tried to get rid of some of the problems that come up with filling materials used in geotechnical engineering and shoring projects, like swelling, shrinkage, and low mechanical properties.

Sustainable and efficient extraction of lignin from wood meal using a deep eutectic system and adsorption of neutral red dye with the extraction residue

In this study, the efficient extraction of lignin from wood meal using a deep eutectic system (DESys) was explored, and the obtained lignin was characterized. The impact of various factors, such as the type of DESys components, extraction time, temperature, water content, and solid-liquid ratio, on the lignin extraction process was systematically investigated. The results indicated that a DESys with a carboxylic acid as the HBD provided the highest lignin extraction efficiency. The obtained lignin was characterized in terms of its molecular weight distribution, elemental composition, functional groups, crystalline structure, and thermal stability. The results showed that the lignin obtained by DESys-based extraction had similar properties to lignin extracted using traditional method. Additionally, the study examined the utilization of the residue left after lignin extraction for the adsorption of cationic pollutants, such as the cationic dye neutral red (NR). The residue was found to contain carboxyl groups, which enabled it to adsorb NR efficiently. The kinetic and thermodynamic models suggested that the adsorption was a chemisorption process. Furthermore, the residue showed selective adsorption for cationic dye over anionic dye. This selectivity was attributed to interactions between the residue's functional groups and the cationic dye molecule. Overall, this study provided a sustainable and comprehensive approach to lignin extraction from lignocellulosic biomass using DESys. It also demonstrated the potential of using the residue from the extraction process for the removal of cationic pollutants from wastewater, showcasing a multi-faceted approach to the valorization of lignocellulosic materials.

Boiling combustion behaviors and heat feedback of pool fire of diesel fuel–water emulsification

AbstractIn the process of submarine oil exploitation and crude oil shipping, the offshore oil leakage accidents occur frequently. In the process of oil spill weathering on the sea, the oil is potentially mixed with water to form oil–water emulsification. The in situ burning is a low‐pollution and high‐efficiency method to eliminate the spilled oil. Meanwhile, as an alternative fuel, the emulsified diesel fuel has the advantage of energy saving and emission reduction. The combustion behaviors of pool fire of diesel fuel–water emulsifications are experimentally studied using three circular fuel reservoirs (10, 15, 20 cm) and five mass proportions of water (0%, 5%, 10%, 15%, 20%). The unsteady combustion process of emulsified diesel fuel is appreciated based on combustion phenomenon, mass burning rate, and flame length. The effects of pool diameter, ratio of water content, and initial fuel thickness on burning rate and flame length are revealed. The primary heat transfer mode in controlling the combustion behavior is explored according to the coupling factors of physical boundary of fuel reservoir, flame, and wall temperatures. This work is of great significance for understanding the combustion behavior of oil spill on the sea and optimizing the removal scheme of oil spill pollutants.

Water Content and Hydrogen Isotopes of Olivine‐Hosted Melt Inclusions in the Dali Picrites, SW China: Reassessing the Role of Water in the Formation of the Emeishan Large Igneous Province

AbstractThe contribution of water to the formation of large igneous provinces (LIPs) remains controversial. We report the first measurement of water content and hydrogen isotope ratios in olivine‐hosted melt inclusions from the Dali picrites, which belong to the Emeishan LIP (ELIP). The inclusions have a wide range of H2O content (0.01–1.73 wt %) and H isotope ratios (δD = 87 ± 11‰ to −267 ± 14‰). The lowest H isotope ratio is below that of the average mantle but comparable to that of the dehydrated slab. These results suggest that most of the Dali melt inclusions have undergone H+ diffusion and H2O degassing. However, some melt inclusions have higher H2O content and lower δD value, which may have undergone rapid cooling and thereby preserved their magmatic H isotope and water content signatures. The reconstructed H2O content of the primary magma for the Dali picrites is ∼1.35 wt %, much lower than the previous estimate for the ELIP primary magma (3.44 ± 0.89 wt % or 4.0–5.6 wt %). Our results support a moderately hydrous (OIB‐type) magma for the ELIP, instead of a highly hydrous one (arc‐type). The mantle source of the picrites is calculated to contain 0.28–0.52 wt % H2O, and recycled oceanic crust that underwent seawater alteration and subsequent slab dehydration during subduction, causing the low δD value of the melt inclusions. We suggest that the Dali picrites may have formed by partial melting of the recycled oceanic crust and metasomatized mantle peridotite.

Impacts of Drop Clustering and Entrainment‐Mixing on Mixed Phase Shallow Cloud Properties Over the Southern Ocean: Results From SOCRATES

AbstractEntrainment and associated mixing (i.e., entrainment‐mixing) have been shown to impact drop size distributions. However, most past studies have focused on warm clouds and have not considered the impacts on mixed phase clouds (i.e., those containing liquid and ice particles). This study characterizes the impacts of entrainment‐mixing on mixed phase cloud properties over the Southern Ocean using in situ observations. By taking advantage of strong correlations between droplet clustering and entrainment‐mixing, a clustering metric is used as a proxy to assess the degree of mixing. This maximizes the available sample size for a statistical analysis of entrainment‐mixing impacts on mixed phase properties. A positive relationship is found between the magnitude of droplet clustering and large ice concentrations (those with maximum dimensions greater than ∼300 μm), suggesting entrainment‐mixing enhances the Wegener‐Bergeron‐Findeisen (WBF) process. Particle size distributions are averaged over different ranges of liquid (liquid water content (LWC)) to total water content (TWC) ratio. Since the ratio is expected to transition from 1 to 0 during glaciation, differences in the distributions provide insight into the relation of entrainment‐mixing to mixed phase cloud evolution. Mixed phase samples with the greatest large ice concentrations occur at LWC/TWC < 0.4 in low clustering regions. However, these samples are relatively few, whereas high clustering regions have a greater frequency of samples with LWC/TWC < 0.4. This suggests sublimation/vapor sinks associated with entrainment can counteract the enhanced WBF. In high clustering regions, distributions of small droplets are relatively constant and large droplets (>30 μm) are preferentially removed as LWC/TWC transitions from 1 to 0.

Experimental Investigation on Shear Behavior of Partially Saturated Silty Soil under Constant Water Content and Constant Void Ratio Conditions

Abstract Matric suction is a crucial parameter that affects how unsaturated soils behave in terms of shear strength. Understanding it is essential for solving geotechnical problems like the stability of unsaturated soil slopes, foundations, embankments, and retaining walls. To investigate the shear behavior in unsaturated soil, a double cell triaxial test apparatus is used in the current research to carry out a series of triaxial compression tests under constant water content and constant void ratio conditions. Samples of silty soil, named DL-clay, were prepared with three different degrees of compaction: 80 %, 83 %, and 86 %, and water contents of 20 % (optimum water content) and 25 %. The soil samples were consolidated isotropically under net confining pressures of 300 kPa and 500 kPa before being sheared with constant volume. In another series of tests, water was infiltrated into the sample at 0 kPa deviatoric stress before the start of shearing with constant volume. Some specimens were also sheared with constant confining pressure for comparison purposes. From the test results, it is ascertained that maintaining a constant volume, i.e., constant void ratio during shearing, gives contour-like trajectories that can aid in defining the state boundary surface of unsaturated soil. It was also observed that within the axial strain range of 0–2 %, there was unusual behavior of a temporary sudden dip in the axial stress, which was more perceivable for samples having a high value of initial matric suction.

Monitoring Water Balance to Predict Hospitalization in Patients with Chronic Heart Failure: A Retrospective Study

Background: Patients with chronic heart failure often experience repeated acute exacerbations leading to high rates of rehospitalization. Therefore, the management of patients to prevent rehospitalization and retain their physical function is important. Brain natriuretic peptide (BNP) and N-terminal-pro BNP are used to estimate the conditions of patients with chronic heart failure, but some hospitals cannot measure these levels in real time. To overcome this, we used bioelectrical impedance analysis as an alternative. Methods and results: Between April 2017 and December 2019, we measured water balance in the outpatient department of Hirose Hospital in three groups: those who had been hospitalized for chronic heart failure (257 patients), those with chronic heart failure who had not been hospitalized (224 patients), and controls with other chronic diseases (275 patients). We found that water balance was significantly correlated to the history of hospitalization, and age was a confounding bias in this correlation, regardless of whether patients have been hospitalized with chronic heart failure. Moreover, patients who have high extracellular water content/total body water content ratios, even in a stable period, are at risk of becoming unstable and experiencing rehospitalization. Conclusion: Water balance monitoring could be a useful indicator to estimate patient condition in real time and predict improvement in chronic heart failure. This easy-to-use indicator may enable timely management of exacerbation of patient condition and reduce hospitalization events.

Field Test Verification and Consolidation Model of a Sand-Doped Soft Soil Foundation with Vacuum Pressure

In this study, a field test on the consolidation of sand-doped improved soft soil under surcharge-vacuum preloading is carried out. By analyzing the vacuum pressure transmission efficiency, the settlement rate, and the dissipation rule of excess pore-water pressure of sand-doped and original soft soil foundation in the consolidation process and comparing the indices of vane shear strength, water content, and void ratio before and after consolidation, the technical superiority and reinforcement effect of the sand mixing method for improving soft soil are comprehensively evaluated. Considering the fact that the vacuum pressure decreases linearly along the depth and the surcharge preloading is applied linearly, an assumption of equal volumetric strain is introduced to reflect the lateral deformation, and an axisymmetric nonlinear radial consolidation model of sand-doped soft soil is established. The model accuracy is verified by model degradation research and a field test. The results show that the sand-doped method (20% sand content) can improve the transmission efficiency of vacuum pressure, reduce the loss of vacuum pressure along the prefabricated vertical drains, accelerate the dissipation rate of excess pore-water pressure, increase the final settlement and shear strength, reduce the final void ratio and water content, and improve the reinforcement effect of deep soil. A nonlinear consolidation solution of the sand-doped soil with linear surcharge preloading considering the actual negative boundary conditions can reflect the consolidation behavior more accurately. If lateral deformation and linear surcharge preloading are not considered, the consolidation rate of soil will be overestimated.

PEMBUATAN DAN UJI PADA PAPAN PARTIKEL BERBAHAN BAKU TANDAN KOSONG KELAPA SAWIT DENGAN KOMPOSISI BAHAN YANG BERBEDA

This research was conducted to determine the quality of particle board using the raw material of empty palm oil bunches with different compositions. Oil palm is a plantation crop that has an important role in Indonesia today. This plant is a plant that produces vegetable oil and its derivative products. The processing of Empty Palm Oil Bunches (EFB) into particle board as a strategy for utilizing solid waste from palm oil processing was carried out in March - June 2020. Quality tests were carried out to determine the water content, bulk density, and composition ratio of the best OPEFB-polyurethane resin for producing high-quality particle boards. The moisture content of the OPEFB fiber was obtained at 43.34%, while the maximum density and hardness of the Hardness Rockwell Scale B (HRB) can be obtained with a ratio of OPEFB fiber to resin (50: 50) 50% OPEFB and 50% resin with a bulk density of 186.70 gr/cm3 and hardness of 60 HRB. The water content affects the resistance and weight of the contents so it needs to be dried. While the high bulk density affects the particle density thereby increasing the hardness of the material. This research was conducted at the STIPAP Medan Soil and Fertilizer Laboratory and the Medan Industrial Chemical Technology Polytechnic Lab. This research was conducted in March - June 2020. This research was a descriptive study. The parameters observed were moisture content, hardness, and bulk density. The data obtained were analyzed descriptively. Based on research conducted, the greater the mass of the board, the higher the weight of the particle board. Meanwhile, the hardness of particle board is influenced by bulk density and moisture content of particle board.

Оценка состава водных масс восточной части Баренцева моря с использованием современных данных о параметрах δ18O и δ2Н

This paper presents the results of measurements of δ18O and δ2H stable isotope values in the waters of the Barents Sea, which were carried out in March–April 2021. Based on the data presented, the ratio of base water content – atlantic (fa), river (fr) and melt water (fi), as well as the volume of water withdrawn for ice formation in the studied water area was assessed. The comparative estimation of base water content, calculated on values “δ18O–salinity” and “δ2H–salinity” is presented and obtained values do not exceed limits of mean value ±sd. However, average values of Atlantic and ice water content calculated using δ2H parameter are higher than those using δ18O, and river water content is lower. The use of δ18O and δ2H parameters in oceanographic studies in the calculation of balance characteristics is preferable to temperature and salinity because of their greater conservativity.

Effect of salt vertical distribution on sulfate-affected soils deformation

Sulfate heave caused by salt swelling behavior poses a threat to engineering safety. The salt vertical distribution has a significant impact on the salt swelling behavior of sulfate-affected soils. A series of laboratory tests were conducted to explore the law of salt swelling and deformation of sulfate-affected soils under different salt vertical distributions. The results indicated that the salt swelling deformation mainly occurred in the initial rising and falling temperature stage. Residual accumulation formed as the salt swelling deformation increased over cyclic times. Salt swelling deformation increased with the increase in water content and salt-water ratio. The salt swelling deformation of sulfate-affected soils with a decreasing salt vertical distribution was larger than the other two forms. The maximum salt swelling also decreased as the water content and salt-water ratio reduced. In the 15 % water content samples with the vertical distribution of salt decreasing with depth, the maximum decrements were 34.78 %, 70.43 %, and 85.10 % as the salt-water ratio reduced, respectively. The sulfate-affected soils with the gradually decreasing salt distribution formed a great radial expansible strain. However, the soil with uniform salt distribution had a larger contractive strain. While the contractible strain increased with the reduction in water content, the expansible strain dropped. This work reveals the law of salt swelling deformation under the effect of salt vertical distribution, providing an important reference for subgrade engineering in sulfate-affected soils.

Improving structural build-up of limestone-calcined clay-cement pastes by using inorganic additives

In 3D concrete printing, fast structuration is a prerequisite for ideal buildability. This paper aims to study the impact of inorganic additives, i.e., CaCl2 and gypsum, on structural build-up and very early-age hydration of limestone-calcined clay-cement (LC3) pastes within the first 70–80 min. Results show that, increasing the dosage of CaCl2 or gypsum can accelerate storage modulus G' and static yield stress evolution with time, as well as increase chemically bound water (H) content and total specific surface area (SSAtotal). Furthermore, good correlations were found between G' and H content, as well as static yield stress and the ratio of free water content to SSAtotal. The acceleration by CaCl2 can be attributed to stimulating C3S and C3A hydration and promoting crystal formation, i.e., ettringite, portlandite, and Friedel’s salt. Additionally, the increase in gypsum percentage led to a large amount of unreacted gypsum in the system, resulting in an increase in SSAtotal.

Re-evaluating cloud chamber constraints on depositional ice growth in cirrus clouds – Part 1: Model description and sensitivity tests

Abstract. Ice growth from vapor deposition is an important process for the evolution of cirrus clouds, but the physics of depositional ice growth at the low temperatures (<235 K) characteristic of the upper troposphere and lower stratosphere is not well understood. Surface attachment kinetics, generally parameterized as a deposition coefficient αD, control ice crystal habit and also may limit growth rates in certain cases, but significant discrepancies between experimental measurements have not been satisfactorily explained. Experiments on single ice crystals have previously indicated the deposition coefficient is a function of temperature and supersaturation, consistent with growth mechanisms controlled by the crystal's surface characteristics. Here we use observations from cloud chamber experiments in the Aerosol Interactions and Dynamics in the Atmosphere (AIDA) aerosol and cloud chamber to evaluate surface kinetic models in realistic cirrus conditions. These experiments have rapidly changing temperature, pressure, and ice supersaturation such that depositional ice growth may evolve from diffusion limited to surface kinetics limited over the course of a single experiment. In Part 1, we describe the adaptation of a Lagrangian parcel model with the Diffusion Surface Kinetics Ice Crystal Evolution (DiSKICE) model (Zhang and Harrington, 2014) to the AIDA chamber experiments. We compare the observed ice water content and saturation ratios to that derived under varying assumptions for ice surface growth mechanisms for experiments simulating ice clouds between 180 and 235 K and pressures between 150 and 300 hPa. We found that both heterogeneous and homogeneous nucleation experiments at higher temperatures (>205 K) could generally be modeled consistently with either a constant deposition coefficient or the DiSKICE model assuming growth on isometric crystals via abundant surface dislocations. Lower-temperature experiments showed more significant deviations from any depositional growth model, with different ice growth rates for heterogeneous and homogeneous nucleation experiments.

Combined removal experiment of multiple impurities from W/O emulsions under high frequency pulsed electric field: Study on laws of desalination, decalcification, and deacidification

AbstractElectrocoalescence is widely used to dehydrate crude oil, but impurities in crude oil are extremely complex, which greatly weaken the effect of dehydration. To understand the coupling law of various impurities, a static demulsification experiment was conducted under a high frequency and high voltage pulsed electric field to investigate the effects of electric field parameters (voltage, frequency, pulse width ratio), emulsification strength, electrocoalescence time, water content, acid value, injection alkali ratio, calcium content, decalcification agent concentration and removal process on desalination, decalcification, and deacidification. The results showed that the desalination and decalcification rates varied synchronously with the electric field parameters and water content. Additionally, the desalination and decalcification rates decreased with the emulsification strength, alkali injection ratio, acid value, and calcium content. Further, they increased first and then decreased with decalcifier concentration. The deacidification rate did not vary with the electric field parameters, but it strengthened with the water content and alkali injection ratio. Conversely, it decreased with the acid value, calcium content, and decalcifier concentration. Additionally, it increased first and then decreased with the emulsification intensity. The best removal procedure is deacidification followed by decalcification. These findings are helpful to achieve the combined removal of various impurities in crude oil.