Water Anomalies Research Articles

Mechanisms responsible for interdecadal variation of the thermodynamic component of East Asian summer monsoon moisture transport

AbstractIn this study, the East Asian summer (June–July–August) monsoon (EASM) atmospheric moisture transport variability under global warming are examined using ERA‐Interim reanalysis data from 1979 to 2019. The total EASM atmospheric moisture transport is decomposed into the thermodynamic (δTH) and dynamic (δMCD) components, which are related to specific humidity and wind velocity, respectively. Based on empirical orthogonal function (EOF) analysis, both the second and the fourth modes of δTH are linked to δMCD, indicating that δMCD can impact the moisture distribution and consequently influence δTH indirectly. Both the first (δTH_EOF1) and the third (δTH_EOF3) modes of δTH show considerable interdecadal changes. It is noted that their principal components exhibit significant increasing trends in recent decades. The response of EASM moisture transport to global warming is probably reflected in these two modes. δTH_EOF1 is associated with negative phases of the Interdecadal Pacific Oscillation (IPO)/Pacific Decadal Oscillation (PDO). This causes the western North Pacific subtropical high (WNPSH) to extend westward and the strengthening of Pacific trade winds. As a result, positive precipitable water anomalies dominate East Asia and δTH_EOF1 is characterized by anomalous southwesterly moisture transport along the East China Sea to southern Japan. δTH_EOF3 corresponds to anomalous moisture transport over the Indochina Peninsula and Japan. The precipitable water associated with δTH_EOF3 in general represents a meridional dipole. Anomalous southward wind induced by the eastward extension of the WNPSH is the main reason for positive (negative) precipitable water anomalies in southern (northern) East Asian. The anomalous circulation associated with the anomalous east–west sea surface temperature gradient over the Indian Ocean affects atmospheric moisture in southern East Asian and can dramatically impact δTH_EOF3.

Confining deep eutectic solvents in nanopores: Insight into thermodynamics and chemical activity

We have established the detailed phase diagram of the prototypical deep eutectic solvent ethaline (ethylene glycol / choline chloride 2:1) as a function of the hydration level, in the bulk state and confined in the nanochannels of mesostructured porous silica matrices MCM-41 and SBA-15, with pore radii RP = 1.8 nm and 4.15 nm. For neat and moderately hydrated DESs, freezing was avoided and glassforming solutions were formed in all cases. For mass fraction of water above a threshold value Wg’ ≈ 30%, crystallization occurred and led to the formation of a maximally-freeze-concentrated DES solution. In this case, extremely deep melting depressions were attained in the confined states, due to the combination of confinement and cryoscopic effects. These phenomena were analyzed quantitatively, based on an extended version of the classical Gibbs-Thomson and Raoult thermodynamic approaches. In this framework, the predicted values of the water chemical activity in the confined systems were shown to systematically deviate from those of the bulk counterparts. The origin of this striking observation is discussed with respect to thermodynamic anomalies of water in the ‘no-man’s land’ and to the probable existence of specific nanostructures in DES solutions when manipulated in nanochannels or at interfaces with solids.

Comparison of the phase transitions of high-pressure phases of ammonium fluoride and ice at ambient pressure

The phase diagrams of water and ammonium fluoride (NH4F) display some interesting parallels. Several crystalline NH4F phases have isostructural ice counterparts and one of the famous anomalies of water, the fact that the liquid is denser than ice Ih, is also found for NH4F. Here, we investigate the phase transitions of the pressure-quenched high-pressure phases of NH4F upon heating at ambient pressure with x-ray diffraction and calorimetry, and we compare the results with the corresponding ices. NH4F II transforms to NH4F Isd, which is a stacking-disordered variant of the stable hexagonal NH4F Ih polymorph. Heating NH4F III gives a complex mixture of NH4F II and NH4F Isd, while some NH4F III remains initially. Complete conversion to NH4F Isd is achieved above ∼220 K. The NH4F II obtained from NH4F III persists to much higher temperatures compared to the corresponding pressure-quenched NH4F II. Quantification of the stacking disorder in NH4F Isd reveals a more sluggish conversion to NH4F Ih for NH4F Isd from NH4F III. In general, the presence of stress and strain in the samples appears to have pronounced effects on the phase transition temperatures. NH4F shows a complete lack of amorphous forms at low temperatures either upon low-temperature compression of NH4F Ih or heating NH4F III at ambient pressure. The amorphous forms of ice are often used to explain the anomalies of water. It will, therefore, be interesting to explore if liquid NH4F displays more water-like anomalies despite the apparent lack of amorphous forms at low temperatures.

Investigating the thermal physiology of Critically Endangered North Atlantic right whales Eubalaena glacialis via aerial infrared thermography

The Critically Endangered status of North Atlantic right whalesEubalaena glacialis(NARWs) warrants the development of new, less invasive technology to monitor the health of individuals. Combined with advancements in remotely piloted aircraft systems (RPAS, commonly ‘drones’), infrared thermography (IRT) is being increasingly used to detect and count marine mammals and study their physiology. We conducted RPAS-based IRT over NARWs in Cape Cod Bay, MA, USA, in 2017 and 2018. Observations demonstrated 3 particularly useful applications of RPAS-based IRT to study large whales: (1) exploring patterns of cranial heat loss and providing insight into the physiological mechanisms that produce these patterns; (2) tracking subsurface individuals in real-time (depending on the thermal stratification of the water column) using cold surface water anomalies resulting from fluke upstrokes; and (3) detecting natural changes in superficial blood circulation or diagnosing pathology based on heat anomalies on post-cranial body surfaces. These qualitative applications present a new, important opportunity to study, monitor, and conserve large whales, particularly rare and at-risk species such as NARWs. Despite the challenges of using this technology in aquatic environments, the applications of RPAS-based IRT for monitoring the health and behavior of endangered marine mammals, including the collection of quantitative data on thermal physiology, will continue to diversify.

Potential impacts of concurrent and recurrent climate extremes on the global food system by 2030

The risk of food-supply instability is expected to increase along with the frequency and intensity of extreme agro-climatic events in many regions. Assessing the sensitivity of the global agricultural system to evolving extremes requires the probability of occurrence of such events to be estimated and their links with potential food supply and demand culminations to be established. From this perspective, in this article we implement a novel approach that can be used as a tool to inform decision-makers about the resilience of agricultural markets to climate extremes. By incorporating simulated climate-stress events into a partial-equilibrium model of interconnected agricultural commodity markets, we examine the complex manifestations of grain supply, demand and prices attributable to hazardous extremes. Market outcomes are further synthesized into coherently defined vulnerability and risk indicators. The proposed framework currently covers compound heat and water anomalies at the country level, potentially concurrent and recurrent, that impact annual crop yields and market balances in a recursive-dynamic manner until 2030. Our findings indicate that extreme-climate anomalies significantly distort expected market equilibria in the medium term. Moreover, extreme global prices may result either from climate anomalies in single key countries or from simultaneous events in many regions. Last but not least, trade and storage come forth as important alleviative mechanisms of the market uncertainty provoked by recurrent extremes.

Exomorpholithogenesis of the Selenga River delta at the present stage of the hydroclimatic cycle

The materials of complex interdisciplinary studies of the relief forming in different periods of water availability in the Selenga River delta are presented since the technogenic level rise of Lake Baikal. Four water and sediment runoff anomalies, synchronous with water level fluctuations in the Lake are identified. The current boundaries of the Selenga River mouth area (RMA), floodplain complex, flooding territories in the maximum water ability conditions are identified. The RMA covers the territory from the main channel bifurcation nod to Lake Baikal, includes subaerial and subaqueous parts of the protruding delta, the interaction zone fluvial processes and different-aged terraces deposits and adjacent lagoons Proval and Cherkalov Sor. Semi-empirical models and data on the water runoff and sediment yield are presented.

From Critical Point to Critical Point: The Two-States Model Describes Liquid Water Self-Diffusion from 623 to 126 K.

Liquid’s behaviour, when close to critical points, is of extreme importance both for fundamental research and industrial applications. A detailed knowledge of the structural–dynamical correlations in their proximity is still today a target to reach. Liquid water anomalies are ascribed to the presence of a second liquid–liquid critical point, which seems to be located in the very deep supercooled regime, even below 200 K and at pressure around 2 kbar. In this work, the thermal behaviour of the self-diffusion coefficient for liquid water is analyzed, in terms of a two-states model, for the first time in a very wide thermal region (126 K < T < 623 K), including those of the two critical points. Further, the corresponding configurational entropy and isobaric-specific heat have been evaluated within the same interval. The two liquid states correspond to high and low-density water local structures that play a primary role on water dynamical behavior over 500 K.

Hydrogeochemical Characteristics of Hot Springs and Their Short-Term Seismic Precursor Anomalies along the Xiaojiang Fault Zone, Southeast Tibet Plateau

Significant hydrogeochemical changes may occur prior- and post-earthquakes. The Xiaojiang fault zone (XJF), situated in a highly deformed area of the southeastern margin of the Tibetan Plateau, is one of the active seismic areas. In this study, major and trace elements, and hydrogen and oxygen isotopes of 28 sites in hot springs along the XJF were investigated from June 2015 to April 2019. The meteoric water acts as the primary water source of the hot spring in the XJF and recharged elevations ranged from 1.8 to 4.5 km. Most of the hot spring water in the study area was immature water and the water–rock reaction degree was weak. The temperature range was inferred from an equation based on the SiO2 concentration and chemical geothermal modeling: 24.3~96.0 °C. The circulation depth for the springs was estimated from 0.45 to 4.04 km. We speculated the meteoric water firstly infiltrated underground and became heated by heat sources, and later circulated to the earth’s surface along the fault and fracture and finally constituted hot spring recharge. Additionally, a continuous monitoring was conducted every three days in the Xundian hot spring since April 2019, and in Panxi and Qujiang hot springs since June 2019. There were short-term (4–35 d) seismic precursor anomalies of the hydrochemical compositions prior to the Xundian ML4.2, Dongchuan ML4.2, and Shuangbai ML5.1 earthquakes. The epicentral distance of anomalous sites ranged from 19.1 to 192.8 km. The anomalous amplitudes were all over 2 times the anomaly threshold. The concentrations of Na+, Cl−, and SO42− are sensitive to the increase of stress in the XJF. Modeling on hydrology cycles of hot springs can provide a plausible physicochemical basis to explain geochemical anomalies in water and the hydrogeochemical anomaly may be useful in future earthquake prediction research of the study area.

Analytical Modeling of Thermodynamic and Transport Anomalies of Water

The structures and properties of biomolecules like proteins, nucleic acids, and membranes depend on water. Water is also very important in industry. Overall, water is an unusual substance with more than 70 anomalous properties. The understanding of water is advancing significantly due to the theoretical and computational modeling. There are different kinds of models, models with fine-scale properties and increasing structural detail with increasing computational expense, and simple models, which focus on global properties of water like thermodynamics, phase diagram and are less computationally expensive. Simplified models give a better understanding of water in ways that complement more complex models. Here, we review analytical modelling of properties of water on different levels, the two- and three-dimensional Mercedes- Benz (MB) models of water and experimental water.

Segregation on the nanoscale coupled to liquid water polyamorphism in supercooled aqueous ionic-liquid solution.

The most intriguing hypothesis explaining many water anomalies is a metastable liquid-liquid phase transition (LLPT) at high pressure and low temperatures, experimentally hidden by homogeneous nucleation. Recent infrared spectroscopic experiments showed that upon addition of hydrazinium trifluoroacetate to water, the supercooled ionic solution undergoes a sharp, reversible LLPT at ambient pressure, possible offspring of that in pure water. Here, we calculate the temperature-dependent signature of the OH-stretching band, reporting on the low/high density phase of water, in neat water and in the same experimentally investigated ionic solution. The comparison between the infrared signature of the pure liquid and that of the ionic solution can be achieved only computationally, providing insight into the nature of the experimentally observed phase transition and allowing us to investigate the effects of ionic compounds on the high to low density supercooled liquid water transition. We show that the experimentally observed crossover behavior in the ionic solution can be reproduced only if the phase transition between the low- and high-density liquid states of water is coupled to a mixing-unmixing transition between the water component and the ions: at low temperatures, water and ions are separated and the water component is a low density liquid. At high temperatures, water and ions get mixed and the water component is a high-density liquid. The separation at low temperatures into ion-rich and ion-poor regions allows unveiling the polyamorphic nature of liquid water, leading to a crossover behavior resembling that observed in supercooled neat water under high pressure.

REY Patterns and Their Natural Anomalies in Waters and Brines: The Correlation of Gd and Y Anomalies

Rare earths and yttrium (REY) distribution patterns of the hydrosphere reveal systematic correlations of Gd and Y anomalies besides the non-correlated redox-dependent Ce and Eu anomalies. Eu anomalies are inherited by dissolution of feldspars in igneous rocks, whereas Ce, Gd and Y anomalies develop in aqueous systems in contact with minerals and amorphous matter. Natural, positive Gd and Y anomalies in REY patterns characterize high-salinity fluids from the Dead Sea, Israel/Jordan, the Great Salt Lake, USA, the Aral Sea, Kazakhstan/Uzbekistan, ground- and surface water worldwide. Extreme Gd anomalies mostly originate from anthropogenic sources. The correlation of Gd and Y anomalies at low temperature in water bodies differ from geothermal ones. In nature, dynamic systems prevail in which either solids settle in water columns or water moves through permeable sediments or sedimentary rocks. In both cases, the anomalies in water develop due to repeated equilibration with solid matter. Thus, these anomalies provide information about the hydrological history of seawater, fresh groundwater and continental brines. When migrating, the interaction of aqueous phases with mineral surfaces leads to increasing anomalies because the more hydrophillic Gd and Y preferentially remain in the aqueous phase compared to their nearest neighbors. The correlation coefficients between Gd and Y anomalies in groundwater is 0.5–0.9. In lakes and oceans, it is about 0.1–0.8, under anomalous conditions it can increase to 1.

Computer simulations and integral equation study of a two length scale core-softened fluid

Monte Carlo simulations, molecular dynamics and integral equation theory were used to study the thermodynamics and structure of particles interacting through the core softened interaction. Core-softened disks have two length scales of interaction, a hard core with one diameter and a soft corona with a larger diameter. We checked the possibility that a fluid with a core-softened potential reproduces anomalies of liquid water and attempted to determine the critical points which we did not observe nor with computer simulations nor with integral equations. We showed that some versions of the integral equation theory completely fail to predict structure and thermodynamics of such system, while others predict it quite well depending on the position in phase space.

Two States of Water Converge to One State below 215 K.

Anomalies of water have been explained by the two-state water model. In the model, water becomes one state upon supercooling. However, water crystallizes completely below 235 K ("no man's land"). The structural origin of the anomalous of the water is hidden in the "no man's land". To understand the properties of water, the spectroscopic experiment in "Norman's land" is inevitable. Hence, we proposed a new soft-confinement method for standard nuclear magnetic resonance spectroscopy to explore the "no man's land". We found the singularity temperature (215 K) at ambient pressure. Water exists in one state below 215 K. Above 215 K, the two states of water are supercritical states of the liquid-liquid critical point. The current study provides a perspective to determine the liquid-liquid critical point of water existing in a high-pressure condition.

SOME PROTECTIONS ON THE ROLE OF GEOCHEMICAL PROPERTIES OF CHEMICAL ELEMENTS IN THE PROBLEMS OF ENVIRONMENTAL POLLUTION AND PROTECTION

The article discusses various limited considerations and assumptions on the positive or negative impact of geochemical features chemical elements found in rocks, ores, soil, plants, water and in the air of the territories of populated areas, factories, the mining and agro-industrial complexes to the environment and the role of analytical geochemistry in this process. According to the author, one of the main points on which the light should be shed is the role of finding elements (independent, combination or isomorphic mixture) rather than their existence in different amounts in the environment. Thus, the chemical elements can be more or less hazardous to environment regardless its amount, but the finding methods. Chemical and natural combinations can be either very hazardous or very useful to all living creatures depending on their characteristics, so it’s better to determine their environmental hazardousness via their impact to a particular human or animal organ which in turn facilitates the solution of the problem. Moreover, it should be noted that the most environmentally dangerous and active chemical elements are the ones with fluctuating valence. Some elements are not so hazardous when they are independent or in solid form since they change weakly. But they are very dangerous when they turn into liquid or gas forms and create mineral compounds with other elements such as halkofil group of elements which in turn can easily decompose and dissolve in water by causing dangers to all living creatures in the nature. Approximately any chemical element can either react negatively or in most cases stimulate the life functions of the organs of animals and plants depending on its finding forms. The study of geochemical parameters in different natural objects such as surface and subsoil water, air, rocks and ores can be very helpful in organizing the protection of environmetal and the solution of its problems. X-ray Spectral analysis is particularly highlighted in this article for identifying various chemical elements in geological and ecological objects. There are several advantages of X-ray Spectral analysis such as its productiveness and low cost, the expressiveness and simplicity of analysis operations, having slightly high sensitivity, universality, high range of elements identification features, etc. To conclude some authors claim that the following problems can be solved with the help of analytic geochemistry: Identifying the main source of pollution and the evaluation of its impact on the environment; Identification of quantitative and qualitative parameters of sources of natural, techno and agro genic pollution in the settlements, industrial objects and in the regions of developed mining complexes; Eco-geochemical and biochemical evaluation of the negative impact of water, weather and harmful geochemical anomalies on live organisms. We hope the elimination of this type of problems can pave the way to the ecologically clean environment. Keywords: ore, soil, plant, water, weather.

Spiciness Anomalies of Subantarctic Mode Water in the South Indian Ocean

AbstractThis study investigates spreading and generation of spiciness anomalies of the Subantarctic Mode Water (SAMW) located on 26.6 to 26.8 σθ in the south Indian Ocean, using in situ hydrographic observations, satellite measurements, reanalysis datasets, and numerical model output. The amplitude of spiciness anomalies is about 0.03 psu or 0.13°C and tends to be large along the streamline of the subtropical gyre, whose upstream end is the outcrop region south of Australia. The speed of spreading is comparable to that of the mean current, and it takes about a decade for a spiciness anomaly in the outcrop region to spread into the interior up to Madagascar. In the outcrop region, interannual variability in mixed layer temperature and salinity tends to be density compensating, which indicates that Eulerian temperature or salinity changes account for the generation of isopycnal spiciness anomalies. It is known that wintertime temperature and salinity in the surface mixed layer determine the temperature and salinity relationship of a subducted water mass. Considering this, the mixed layer heat budget in the outcrop region is estimated based on the concept of effective mixed layer depth, the result of which shows the primary contribution from horizontal advection. The contributions from Ekman and geostrophic currents are comparable. Ekman flow advection is caused by zonal wind stress anomalies and the resulting meridional Ekman current anomalies, as is pointed out by a previous study. Geostrophic velocity is decomposed into large-scale and mesoscale variability, both of which significantly contribute to horizontal advection.

The Seasonality of Global Land and Ocean Mass and the Changing Water Cycle

AbstractThe global water cycle is generally viewed as the cycling of water masses among the land, ocean, and atmosphere. This cycling predominantly occurs at the annual time scale and between land and ocean, constituting the seasonal global water cycle. NASA’s Gravity Recovery and Climate Experiment (GRACE) and GRACE‐Follow On missions can directly observe the seasonal global water cycle and describe the changes in its intensity. We present seasonal amplitudes of the global land water and ocean mass anomalies between 04/2002 and 11/2020. We find that the average seasonal amplitude is 17.0 ± 0.6 mm sea level equivalent (SLE), and its interannual variability (σ = 1.1 mm SLE) is comparable to the long‐term trends in the land and ocean masses. We investigate two periods of rapid amplification and deamplification during which the amplitude changed as much as 29%, and find that changes in hydroclimatology in certain land regions modulate the seasonal global water cycle.

Radon and magnetic anomalies in the territory of the city Kyiv: environmental aspect

Magnetic and radon anomalous fields are essential geophysical entities of environment which determine to a considerable degree its ecological state. Revelation of magnetic and radon anomalous zones is an urgent task for the studies of geo-environmental state of the territory and appraisal of its ecological safety. The greatest danger is produced by the areas where the faults are localized with radon anomalies related in the upper part of the Earth crust. For the territory of Kyiv geological characteristics of the studied area has been reviewd, schemes of regional and accompanying faults have been adjusted and completed, maps of module and anomalies of module of geomagnetic field induction as well as a scheme of radon anomalies in water and subsoil air have been elaborated. Connection between radon anomalies with faults and natural magnetic fields has been shown which consisted in correlation of radon anomalies with negative and small positive values of anomalous magnetic field and related to thick zones of fracturing with active fluidal-dynamic activity and the faults of diagonal and orthogonal systems being the zones of radon emanation into atmosphere. Radon anomalies in subsoil air are mainly controlled by Irpin-Borshchagivka, Pushcha-Vodytsya, Kyiv and Darnytsya faults of northwestern-northern strike and Petrivka-Pukhivka and Glevakha-Brovary faults of northwestern strike. For some stations of Kyiv metro the excess of environmental norms of magnetic field and radon anomalies has been determined which can be explained by constructive features of metro compartments and their location in fault zones. It has been shown that radon anomalies are spatially and temporally stabile and magnetic anomalies, especially in metro, are characterized by considerable changes of magnetic field in both low-frequency and high-frequency spectra of their variation. Combined analysis of the fault tectonic scheme, magnetic and radon anomalies will permit to find out environmentally hazardous zones in the territory of Kyiv and out of it more reasonably.

Combined influence of oceanic and atmospheric circulations on Greenland sea ice concentration

Abstract. The amount and spatial extent of Greenland Sea (GS) ice are primarily controlled by the sea ice export across the Fram Strait (FS) and by local seasonal sea ice formation, melting, and sea ice dynamics. In this study, using satellite passive microwave sea ice observations, atmospheric and a coupled ocean-sea ice reanalysis system, TOPAZ4, we show that both the atmospheric and oceanic circulation in the Nordic Seas (NS) act in tandem to explain the SIC variability in the south-western GS. Northerly wind anomalies associated with anomalously low sea level pressure (SLP) over the NS reduce the sea ice export in the south-western GS due to westward Ekman drift of sea ice. On the other hand, the positive wind stress curl strengthens the cyclonic Greenland Sea Gyre (GSG) circulation in the central GS. An intensified GSG circulation may result in stronger Ekman divergence of surface cold and fresh waters away from the south-western GS. Both of these processes can reduce the freshwater content and weaken the upper-ocean stratification in the south-western GS. At the same time, warm and saline Atlantic Water (AW) anomalies are recirculated from the FS region to the south-western GS by a stronger GSG circulation. Under weakly stratified conditions, enhanced vertical mixing of these subsurface AW anomalies can warm the surface waters and inhibit new sea ice formation, further reducing the SIC in the south-western GS.

Heatwave-induced synchrony within forage fish portfolio disrupts energy flow to top pelagic predators.

During the Pacific marine heatwave of 2014–2016, abundance and quality of several key forage fish species in the Gulf of Alaska were simultaneously reduced throughout the system. Capelin (Mallotus catervarius), sand lance (Ammodytes personatus), and herring (Clupea pallasii) populations were at historically low levels, and within this community abrupt declines in portfolio effects identify trophic instability at the onset of the heatwave. Although compensatory changes in age structure, size, growth or energy content of forage fish were observed to varying degrees among all these forage fish, none were able to fully mitigate adverse impacts of the heatwave, which likely included both top‐down and bottom‐up forcing. Notably, changes to the demographic structure of forage fish suggested size‐selective removals typical of top‐down regulation. At the same time, changes in zooplankton communities may have driven bottom‐up regulation as copepod community structure shifted toward smaller, warm water species, and euphausiid biomass was reduced owing to the loss of cold‐water species. Mediated by these impacts on the forage fish community, an unprecedented disruption of the normal pelagic food web was signaled by higher trophic level disruptions during 2015–2016, when seabirds, marine mammals, and groundfish experienced shifts in distribution, mass mortalities, and reproductive failures. Unlike decadal‐scale variability underlying ecosystem regime shifts, the heatwave appeared to temporarily overwhelm the ability of the forage fish community to buffer against changes imposed by warm water anomalies, thereby eliminating any ecological advantages that may have accrued from having a suite of coexisting forage species with differing life‐history compensations.

Quantitative relationship between the resistivity distribution of the by-product plume and the hydrocarbon degradation in an aged hydrocarbon contaminated site

During the investigation of aged hydrocarbon contaminated sites using electrical resistivity tomography (ERT), the low-resistivity anomalies in the detection profile have been widely considered to be caused by the hydrocarbon degradation by-products. However, these low-resistivity anomalies are a comprehensive reflection of the formation’s electrical characteristics. In this study, we used ERT and geochemical methods to investigate a hydrocarbon-contaminated site that has been abandoned for more than 30 years. There are several obvious low resistivity anomalies in the site, which are related to hydrocarbon mineralization. Based on the law of Waxman and Smits, a petrophysical relationship formula suitable for this specific site was fitted, and the true resistivity after inversion was input into the formula to calculate the pore water resistivity. The electrolytic conduction contribution of the pore water was isolated, and the distribution of the by-product plume was determined based on the electrolytic conduction contribution of the pore water. Based on mineralogical identification and geochemical data analysis, the biogeochemical model of hydrocarbon mineralization was clarified. The degradation by-products (Fe2+ and H+) are the controlling factors that lead to changes in the groundwater resistivity. Based on electrochemical experiments and titration analysis experiments, the quantitative relationship between the low resistivity anomalies of the pore water and the degradation by-products (Fe2+ and H+) was established, and the biodegradation model was used to calculate the hydrocarbon degradation corresponding to the by-product plume. The results show that the hydrocarbon degradation corresponding to the by-product plume determined from the ERT detection results in the selected study area is approximately 2.8% of the total hydrocarbon content. Although this is a rough estimate based on a small amount of discrete geochemical data and ERT detection results, it improves our understanding of the natural attenuation state of hydrocarbon-contaminated sites and provides convincing data to support future estimations of the site's natural attenuation time.