Washing Time Research Articles

Melting and removing wax deposition by thermal washing in oil well

Wax precipitation has proven to be a serious problem when extracting the crude oil from current oilfields. Thermal washing is one of the common methods to remove wax deposition in oil wells. Mastering the melting process and the melting time of the wax layer in thermal washing is essential to optimize operating parameters and further improve the efficiency of thermal washing. In this paper, the scouring model and the melting model are carried out to simulate wax melting behaviour during the thermal washing process in a vertical oil well. Furthermore, with the melting model, the effects of five factors on the melting time have been studied. The results reveal that the melting time is mainly influenced by the thickness of the wax layer and the water flow rate, while the initial temperature of the wax layer, water temperature and inner wall temperature of tubing these three temperatures have a relatively slight influence on the melting time. Finally, with the numerical simulation results, a correlation is developed to predict wax melting time and verified with thermal washing time of the Cha well. It indicates that the melting model is applicable for most of the waxing section, while the scouring model is only applicable when the water initially reaches the bottom of the waxing section, so the melting model is more practical for thermal washing in the oil well.

Ultrasound Technology in Carpet Cleaning

Carpets are widely used in living spaces for beautiful appearance, heat, and sound insulation. Cleaning carpets is essential for both their lifespan and health and hygiene. Washing operations are carried out at regular intervals in carpet-washing factories. Industrial carpet washing operations must be done consciously because a significant amount of water and time is consumed during these processes. In addition, problems such as discoloration and strength losses may be encountered in delicate carpets. In this study, stained carpets were washed at mediums with and without ultrasound at room temperature at different times. Mud stain was used as an example of particle dirt. The original unwashed carpet without stain was taken as a reference and compared with the washed carpet by evaluating the color differences and changes in the yellowness index to check the amount of stain removal. The color differences (Da*, Db*, DL*, DC*, Dh*, DE*) were close to zero, and the differences in the yellowness index were low, so it was concluded that the stained carpet was cleaned and turned to the original form after washing. The washing process was evaluated as successful because the color and yellowness index of the washed carpet were close to the unwashed carpet. Effects of washing type (with and without ultrasound), washing agent (with and without detergent), and washing time (30, 60, and 90 minutes) are significant for α=0,05 in washed carpets according to the original carpet. Interactions between parameters are also significant. If the washing conditions are consciously adjusted, ultrasonic washing can be an alternative to the soaking process in carpet washing. With ultrasonic washing, it can be possible to shorten the duration of the wetting step and effectively clean sensitive carpets in softer conditions without damaging them. It would be useful to carry out studies that reduce water usage by optimizing the amount of washing baths in the future.

Design and construction of equipment for the elimination of saponin in Quinoa (Chenopodium quinoa Willd): Performance tests with Amarillo Marangani variety

Quinoa is a very important grain for human nutrition; In recent years, several research studies have addressed its nutritional use; However, one of its main weaknesses is its saponin content, which is an anti-nutrient and has a bitter taste. The debittering process involves the principle of recirculation of large quantities of water, with the purpose of reducing the consumption of this substance, it is important to develop methodologies and equipment that improve the efficiency of these traditional washing methods and reduce the work of operators and processors with the intention of making it less costly. The objective of the present research work was to design and build a quinoa de- saponifier , Amarillo Maranganí variety, to evaluate the effect of washing time (5, 10 and 15 min) and the flow of water recirculated by pumping (15, 30 and 45 L/min), on the elimination of saponin to acceptable commercial levels. The results indicated that the highest saponin extraction was achieved when using washing times of 5 min with water flow rates of 15 L/min, and 51.75 % of the initial saponin content was eliminated. In general, it is stated that increasing the flow rate of the washing water reduces the extraction efficiency, but performing a second washing significantly reduces the extraction, the equipment developed presents promising characteristics for application in the industry.

Preparation and Properties of Cotton Fabric Photocatalyzed by Ag-Doped Madder-Sensitized TiO2

In this study silver nanoparticles (NP) were grown in-situ on the surface of madder-sensitized TiO2 by an in-situ reduction method using silver nitrate as a silver source and a honeysuckle extract as a reducing agent. Silver doped madder-sensitized TiO2 nanoparticles were then prepared, supported on the surface of cotton fabrics to prepare photocatalytic cotton fabrics with high-efficiency self-cleaning properties and excellent antibacterial properties. transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) analyses showed that elemental Ag NPs were deposited on the surface of the madder-sensitized TiO2, and that Ag-doped madder-sensitized TiO2 NPs were successfully loaded on the cotton fabric surface. The results of UV-Visible diffuse reflectance spectroscopy (UV-Vis-DRS) and Photoluminescence Spectroscopy (PL) showed that Ag-doping could further reduce the band gap of madder-sensitized TiO2 than pure TiO2. The absorption of light in the photocatalytic system was increased, and the recombination of electron-hole pairs was effectively inhibited. Compared with madder-sensitized TiO2 photocatalyzed cotton fabric, the degradation rate of nano-Ag-doped madder-sensitized TiO2 photocatalytic cotton fabric for methylene blue (MB) was increased by 10.66% within 2 h, and the degradation process was in line with the first-order reaction kinetic model. After 5 times of washing, the photocatalytic cotton fabric still had excellent photocatalytic performance. Its antibacterial rates against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) reached 100 and 99.99%, respectively. In addition, it had good wrinkle resistance and UV protection properties, but the cross-linking modification reduced the breaking strength by about 14%.

Abstract 6879: Development of a rapid multiplex immunohistochemistry for characterizing tumor-immune microenvironment

Abstract Intratumoral immune profiles have been related to prognosis and therapeutic efficacy; this could result in personalized treatment based on biomarkers. Although techniques for multifactorial evaluation of different tumor-immune microenvironments have been established, their practical implementation in clinical settings still requires further improvement, where the time required for testing needs to be reduced and the technology needs to be clinically validated. To develop a multiplex, quantitative, and rapid tissue evaluation method based on clinically established standard immunohistochemistry (IHC), we attempted to develop 6-marker rapid multiplex IHC based on our previously reported 14-marker multiplex IHC via the reduction of the number of labels and speeding up the staining procedure (Tsujikawa et al. Cell Reports, 2017). First, we confirmed whether immunological features that were found to be associated with prognosis in 14-marker multiplex IHC analyses could be identified with fewer labels. Quantitative results by selected six markers exhibited significant correlation with those by 14 markers in terms of immune classifications based on the balance of lymphoid and myeloid cells. Next, we developed a rapid staining protocol by optimizing the reaction temperature, chromogen, and washing time, allowing the completion of 6-marker analysis in 5 hours and 49 minutes as opposed to several days required for the conventional multiplex IHC. By using six markers, validation in benign tonsil tissue and head and neck cancer tissue exhibited significant correlation between rapid and standard multiplex IHC in terms of staining intensities, densities of T cells, macrophages, lymphoid/myeloid immune cells ratios, and spatial profiles of intratumoral immune infiltrates. This method may enable a quantitative assessment of tumor-immune microenvironment on a clinically feasible time scale, which promote the development of tissue biomarker-guided therapeutic strategies. Citation Format: Alisa Kimura, Takahiro Tsujikawa, Hiroki Morimoto, Junichi Mitsuda, Sumiyo Saburi, Shigeyuki Mukudai, Hikaru Nagao, Nana Sakurai, Nanako Murakami, Aya Miyagawa-Hayashino, Hiroshi Ogi, Saya Shibata, Eiichi Konishi, Kyoko Itoh, Shigeru Hirano. Development of a rapid multiplex immunohistochemistry for characterizing tumor-immune microenvironment [abstract]. In: Proceedings of the American Association for Cancer Research Annual Meeting 2024; Part 1 (Regular Abstracts); 2024 Apr 5-10; San Diego, CA. Philadelphia (PA): AACR; Cancer Res 2024;84(6_Suppl):Abstract nr 6879.

"Water or not water: That is the question." Analysis of costs and consumption of the operating theaters in a greener perspective.

To compare the amounts of water and plastic used in surgical hand washing with medicated soaps and with alcohol-based products and to compare costs and consumption in a year, based on scheduled surgical activity. This retrospective study was carried out at Udine's Gynecology Operating Block from October to November 2022. We estimated the average amount of water with a graduated cylinder and the total cost of water usage based on euros/m3 indicated by the supplier; for each antiseptic agent we collected the data relevant to wash time, amount of water and product used per scrub, number of handscrubs made with every 500 mL bottle and cost of a single bottle. We put data into two hypothetical contexts, namely WHO guidelines and manufacturers' recommendations. Data were subjected to statistical analysis. The daily amount of water using povidone-iodine, chlorhexidine-gluconate and alcohol-based antiseptic agents was 187.6, 140.7 and 0 L/day (P value = 0.001), respectively; A total of 69 000 L/year of water would be saved if alcohol-based products were routinely used. A single unit of an alcohol-based product allows three times as many handscrubs as any other product (P value = 0.001) with consequent reduction in plastic packaging. Despite the cost saving being negligible, choosing alcohol-based handrub over medicated soap handrub - on equal antiseptic efficacy grounds - could lead to a significant saving of water and plastic, thus making our operating theaters more environmentally friendly.

Application of aqueous extracts of <i>Alternanthera brasiliana, Chromolaena odorata</i> and <i>Tridax procumbens</i> plants in remediating lead contaminated soils

Soil washing is an effective method of removing lead from contaminated soils. However, great limitations abound in the choice of washing solution that is ecologically sustainable for agricultural soils. In this study, applications of plant soluble extracts in remediating of Pb contaminated soils for ecological sustainability were carried out. Batch laboratory experiments were done using aqueous extracts of Alternanthera brasiliana, Chromolaena odorata, Tridax procumbens and water as control at varying soil-pulp-densities (SPD) of 3, 6, 9, 12, 15%, and washing time of 1, 3, 6, 12 h. For contaminated soil, percentage removal efficiency followed the order: Alternanthera brasiliana (38.1±0.28%) > Chromolaena odorata (21.8±0.12%) > Tridax procumbens (21.3±0.18%). The most appropriate ratio for contaminated soil was 3% SPD at 12 h washing time. Removal efficiency was found to be substantially depended on geochemical phase of Pb (exchangeable-4.04%) in contaminated soil and washing solution pH (5.68). Lead removal efficiency was observed to increased proportionally with increasing washing time, but decreased with increasing SPD. Spike soil with high exchangeable Pb-78.9% recorded significant Pb removal of 63.4±0.24% with Alternanthera brasiliana, 47.8±0.22% with Chromolaena odorata, 38.3±0.38% with Tridax procumbens and 52.0±0.26% with water. Analysis of variance at p=0.05 indicated a significant difference inpercentage Pb removal efficiency across all the four washing solutions. However, the statistical T-test indicated no significant difference at p=0.05 in percentage Pb removal efficiency between both soils. Also, moderately positive correlations were observed between contaminated and spiked soils for Alternanthera brasiliana (0.676), Chromolaena odorata (0.570) and Tridax procumbens (0.517) while negative correlation observed for water (0.485) which served as the control. The three plant extracts exhibited good potential characteristics as washing solutions for the treatment of Pb contaminated soils. Chemical modifications are recommended to enhance and improve their efficiencies when considering the geochemical phase of Pb in soil.

The value of contrast-enhanced ultrasound combined with microflow imaging in predicting microvascular invasion of hepatocellular carcinoma before operation.

To evaluate the preoperative predictive value of contrast-enhanced ultrasound (CEUS) combined with microflow imaging (MFI) in microvascular invasion (MVI) of hepatocellular carcinoma (HCC). In our study, 80 patients with HCC were analyzed retrospectively. According to the gold standard of postoperative pathology, the patients were divided into MVI positive group (n = 39) and MVI negative group (n = 41). we were to analyze the correlation between CEUS and MVI in combination with MFI, to identify independent risk factors for the occurrence of MVI positive, and to analyze the predictive efficacy of every independent risk factor and their combination in preoperative prediction of MVI. In our study, 80 patients were enrolled, including 39 patients in the MVI-positive group and 41 patients in the MVI-negative group, with a MVI-positive rate of 48.8%. By univariate analysis and multivariate analysis, it was found that there were statistically significant differences in enhancement range extension, start time of wash out and CEUS-MFI between the two groups, which were independent risk factors for MVI-positive. The combination of three independent risk factors is more effective than single one in predicting MVI of HCC. CEUS combined with MFI is feasible for the preoperative prediction of MVI in HCC, and can provides meaningful help for individualized clinical treatment.

Pengaruh Media Edukasi Cuci Tangan Terhadap Perilaku Cuci Tangan pada Anak Usia Pra Sekolah di TK ABA Gedongkiwo Yogyakarta

Background: Hand washing is cleaning hands using soap and running water if hands are visibly dirty or using an alcohol-based liquid if hands are not visibly dirty. Pre-school-aged children have less awareness about hand washing behavior. Audio visual media is one of the media used to provide hand washing education. Objective: The purpose of this study is to analyze the effect of providing hand washing education using audio-visual media on hand washing behavior in pre-school children Method: The research design was a one group pretest-posttest design. The population of this study were all students at the TK ABA Gedongkiwo, Yogyakarta, 52 students in total using a total sampling technique. The independent variable was education with audio-visual media and the dependent variable was hand washing behavior. Data collection used an observation sheet according to the six steps of hand washing and four minimum hand washing time at school. Data management techniques by means of editing, coding, scoring, tabulation, data entry and data cleaning. Statistical test used the Paired Sample T-Test. Result: The results of the study from 52 respondents before being given hand washing education using audio visual media, most of the respondents behaved badly, 48 children (92.3%), after being given hand washing education using audio visual media, most of the respondents behaved well, 41 children (78.8 %). The Paired Sample T Test statistical test obtained a Sig value. (2 tailed) = 0.001 where the Sig. value (2 tailed) was less than 0.005 therefore H0 is rejected and H1 is accepted Conclusion: The conclusion is that there is an effect of providing hand washing education using audio visual media on hand washing behavior in pre-school aged children at TK ABA Gedongkiwo, Yogyakarta.

Substantial removal of four pesticide residues in three fruits with ozone microbubbles

Developing a straightforward method to remove pesticide residues from fruits is essential for food safety. In this study, ozone microbubble treatment was performed on three fruits (strawberry, cherry, and apricot) to remove four pesticide residues (emamectin benzoate, azoxystrobin, boscalid, and difenoconazole) while comparing removal efficiency. The concentration of hydroxyl radicals in different washing orientations was homogeneous at a concentration ranging between 8.9 and 10.2 μmol·L-1. Under long washing time (18 min), strawberry, cherry, and apricot obtained higher removal rates of 51 %∼65 %, 51 %∼59 % and 24 %∼70 %, respectively. Moreover, scanning electron microscopy (SEM) and contact angle (CA) revealed that apricot has better hydrophobicity, leading to a higher pesticide removal of 45 ∼ 84 % with less water and more vigorous washing. Notably, vitamin C content in fruits remain largely unchanged following ozone microbubble treatment. This study demonstrated the effectiveness of ozone microbubble treatment as pollution-free method for enhancing food safety by removing pesticide residues on fruits.

Aplikasi Surfaktan Alami dan Sintetis untuk Meningkatkan Penghilangan Total Petroleum Hidrokarbon dari Tanah Tercemar

Environmental pollution by petroleum hydrocarbons (total petroleum hydrocarbons) is an environmental problem affecting human health and the environment. Innovative and sustainable treatment methods are needed to solve this problem. One remediation technique that can be used is soil washing. Soil washing is a remediation technique using surfactants as a contaminant washing solution. This research study investigated the washing of soil contaminated by used motor oil using green and synthetic surfactants. The type of natural surfactant used was saponin at a concentration of 10,000 mg/L and synthetic surfactant Linear Alkylbenzene Sulfonate (LAS) at 800 mg/L. The effect of washing time and stirring speed on TPH reduction efficiency was also tested through a series of laboratory tests. Based on the statistical results, the three factors, namely surfactant type, washing time, and stirring speed, significantly influenced TPH removal. Optimum removal efficiency with LAS surfactant was obtained under washing time between 70 - 90 minutes and stirring speed between 40 - 50 rpm. Meanwhile, saponin surfactant at washing time is 60 - 80 minutes, and stirring speed is 48 - 50 rpm.

Preparation of landscape gardening soil using undersized fraction from aged MSW by EDTA or citric acid coupled with humic acid: Effect assessment, properties, and optimization

ABSTRACT Undersized fraction from aged municipal solid waste (UFAMSW), as a kind of soil-like material, has been proved effective in providing a large amount of organic matter and nutrients for soil and plants. The characteristics and effectiveness of heavy metal pollution removal in UFAMSW attracted tremendous research interest from scientists recently. In this study, the heavy metal removal efficiencies and bioavailability of washing on contaminated UFAMSW were evaluated with three washing reagents including ethylene diamine tetra acetic acid (EDTA), citric acid (CA), and humic acid (HA). The effects of chelating agent concentration, pH, and washing time on metal removal were investigated and response surface methodology (RSM) was employed to optimize the washing conditions. The results indicated that the removal efficiencies of Cu, Zn, and Mn could be 53.68%, 52.12%, and 30.63% by EDTA/HA washing and 42.36%, 39.67% and 28.49% by CA/HA washing, respectively. The European Community Bureau of Reference (BCR) sequential extraction was applied to analyze the fraction change of heavy metals in UFAMSW before and after washing, and it was found that chelating agent combined with HA could contribute to the removal of the exchangeable fraction. Physical and chemical properties of UFAMSW were improved to some extent after washing with mixed HA and chelating agent and could achieve the quality standard of landscape gardening soil. Accordingly, the mixture of HA and other chelating agents could be a promising washing process for preparation of landscape gardening soil using UFAMSW. Implications: Our manuscript studies the removal of heavy metals from the contaminated undersized fraction from aged municipal solid waste (UFAMSW). UFAMSW, as a kind of soil-like material, has been proved effective in providing a large amount of organic matter and nutrients for soil and plants however often limited by heavy metal pollution. The UFAMSW used in this experiment was collected after the excavation and screening-sorting of aged refuse from Changshankou Domestic Waste Sanitary Landfill in Wuhan City, Hubei Province, Southern China. This study investigated the effects of EDTA, CA, HA, mixed EDTA/HA, and mixed CA/HA washing on heavy metal removal (Cu, Zn, and Mn), bioavailability of residual heavy metal and properties. The effects of chelating agent concentration, pH, and washing time on metal removal were investigated and then response surface methodology was employed to optimize the washing conditions. The results showed that washing by CA/HA and EDTA/HA, had a higher removal efficiency of heavy metals (Cu, Zn, and Mn) in UFAMSW compared to single HA. Meanwhile, HA has a higher removal for exchangeable fraction of heavy metals, the exchangeable concentration of Cu, Zn, and Mn in CA/HA and EDTA/HA washed UFAMSW were lower compared with UFAMSW washed by single CA and EDTA. Thus, mixing HA with EDTA or CA makes a less risk to environmental and the removal efficiency is acceptable. Additionally, CA/HA and EDTA/HA washing tend to improve soil physicochemical properties and soil fertility. Thus, mixing HA with different washing agent are potential methods for preparation of landscape gardening soil using UFAMSW.

Biomechanical and Biological Assessment of Polyglycelrolsebacate-Coupled Implant with Shape Memory Effect for Treating Osteoporotic Fractures.

Poly(glycerol sebacate) is a biocompatible elastomer that has gained increasing attention as a potential biomaterial for tissue engineering applications. In particular, PGS is capable of providing shape memory effects and allows for a free form, which can remember the original shape and obtain a temporary shape under melting point and then can recover its original shape at body temperature. Because these properties can easily produce customized shapes, PGS is being coupled with implants to offer improved fixation and maintenance of implants for fractures of osteoporosis bone. Herein, this study fabricated the OP implant with a PGS membrane and investigated the potential of this coupling. Material properties were characterized and compared with various PGS membranes to assess features such as control of curing temperature, curing time, and washing time. Based on the ISO 10993-5 standard, in vitro cell culture studies with C2C12 cells confirmed that the OP implant coupled with PGS membrane showed biocompatibility and biomechanical experiments indicated significantly increased pullout strength and maintenance. It is believed that this multifunctional OP implant will be useful for bone tissue engineering applications.

Study on the simultaneous release of microfiber and indigo dye in denim fabric home washing

In recent years, with the increasing global focus on environmental protection, the issue of microfiber release from denim during the washing process has gained attention. In this study, a programmable washing device simulating household drum washing was designed and developed, microfibers and indigo dyes released from denim washing were quantitatively detected, and we have also developed a novel method for estimating the release of microfibers during washing. The effects of washing time, washing temperature, and washing load on microfiber and indigo dye release from denim were explored. The results showed that the effect of washing load on microfiber and indigo dye release was greater than washing temperature and washing time. The research findings indicate that with an increase in washing time (35–95 min) and washing load (100–250 g), the shedding of microfibers and indigo dye significantly increases, reaching peak release levels of 343.6 μg/g fabric and 0.027 mg/L, respectively. However, there is a decreasing trend in the release of microfibers and indigo dye when the washing temperature exceeds 50 °C. Furthermore, our data suggests that an increase in washing load leads to a significant change in the number of microfibers (from 978 items/g fabric to 1997 items/g fabric) and their mass (from 156.87 μg/g fabric to 343.56 μg/g fabric). The influence of washing time, washing temperature, and washing load on microfiber length shows relatively small fluctuations within the range of 600–900 µm. This study provides new ideas and methods for estimating the release of microfiber and indigo dye in denim washing around the world.

Adsorption characteristics of SO2 onto novel activated carbon fixed bed: kinetics, isotherms, thermodynamics and washing regeneration

ABSTRACT The problem of SO2 pollution in industrial flue gas has brought great pressure to environmental governance. In this study, a new type of activated carbon fixed bed device was designed and built for flue gas desulfurization. The results showed that activated carbons (AC1-AC5) were microporous activated carbons with abundant functional groups on the surface, and the desulfurization performance was ranked as AC1 > AC2 > AC3 > AC4 > AC5. The specific surface area of AC1 was as high as 624.98 m2/g, and the maximum adsorption capacity was 29.03 mg·g−1 under the optimum reaction conditions. The Freundlich adsorption isotherm model and Bangham pore diffusion model are more suitable for describing the dynamic adsorption process of SO2 on AC1. Combined with thermodynamic research, it is shown that the adsorption process of SO2 is a spontaneous, exothermic, and chaotic reduction process, which is mainly a physical adsorption between single-layer adsorption and multi-layer adsorption. Finally, the desulfurization-washing regeneration cycle experiment results showed that the regeneration rate of AC1 increases with the washing time and washing temperature, up to 95%, which provides data reference for industrial application.

Remediation of diesel-oil contaminated soils using an innovative nanobubble and electrolyzed catalytic system

Soil contamination resulting from petroleum hydrocarbons poses a significant environmental challenge. In this research, an innovative electrolyzed catalytic system was devised to produce nanobubble-enriched catalytic water, which was employed for remediating soils contaminated with diesel oil. This novel system harnessed high voltage (220 V) via direct current, utilizing titanium electrodes coated with iridium dioxide. The inclusion of iron-copper hybrid oxide catalysts between the electrodes was instrumental in enhancing the efficiency of radical generation. The study employed the electron paramagnetic resonance (EPR) technique and the Rhodamine B (RhB) method to analyze the species and concentration of the generated radicals. EPR is a versatile tool for investigating materials with unpaired electrons and is capable of quantifying reaction kinetics for transition metals. RhB can be used as a probe for hydroxyl radical concentration determination. The addition of an electrolyte (NaCl or K2SO4) could enhance the electrolytic reaction and improve radical production rate. By incorporating 20 mM of K2SO4 and utilizing 75 g of catalyst per 500 mL batch of nanobubble-contained electrolyzed catalytic water (NECW) production, with a current density of 20 mA/cm2, a highly oxidized nanobubble-infused electrolyzed catalytic water was successfully generated. This water exhibited an oxidation-reduction potential of 887 mV and contained a radical concentration of 7.6 × 10−13 M, encompassing hydroxyl, superoxide, and sulfate radicals. Furthermore, it displayed a negative zeta potential of −39.8 mV, along with nanobubbles averaging 28 nm in diameter and a nanobubble density of 3.7 × 109 particles per milliliter. The presence of nanobubbles in electrolyzed catalytic water, owing to their negative zeta potential and nano-scale attributes, imparts a repulsive force that hinders bubble aggregation and prolongs their existence. When these nanobubbles burst, the resulting radicals contribute to an augmented radical concentration, which, in turn, facilitates the oxidation of petroleum hydrocarbons. Approximately 72.4% of the total petroleum hydrocarbon in soils could be removed (dropped from 3230 mg/kg to 892 mg/kg) after five batches of NECW washing (10 min of each washing time) via the desorption and extended chemical oxidation mechanisms. The total petroleum hydrocarbons in the water phase could be removed entirely after pumping the polluted water into the electrolyzed catalytic system for immediate treatment, indicating that the electrolyzed catalytic system could oxidize the desorbed total petroleum hydrocarbon effectively. The findings demonstrate that the nanobubble-infused catalytic water generated by the innovative electrolyzed system effectively and efficiently remediates petroleum-hydrocarbon-contaminated soils and water, all while minimizing the risk of secondary pollution.

One-step, low-cost and environmentally friendly method to prepare superhydrophilic polyester fabric for oil-water separation

Polyester (PET) fabric is currently the world's most produced and widely used synthetic fiber due to its excellent mechanical properties, thermal stability and corrosion resistance. However, the poor hydrophilicity and hygroscopicity of PET fabric limit its application. In this paper, based on tannic acid (TA) and 3-aminopropyltriethoxysilane (APTES), a simple and efficient one-step method was used to construct TA-APTES nanoparticle coating on the surface of PET fabric to obtain superhydrophilicity. The surface morphology, microstructure and coating durability of the modified PET fabric were investigated. The results showed that under the optimal reaction conditions, the water contact angle (CA) of the modified fabric surface was 0°, which remained superhydrophilic after 800 times of rubbing or 20 times of washing. The modified PET fabric exhibited exceptional breathability, dyeing properties, and ultraviolet (UV) resistance, suggesting its high potential in the apparel industry. It could separate the oil-water mixture with high separation efficiency (98.98 %) and water flux (6705.53 L·m−2·h−1). The separation efficiency (97.64 %) and water flux (5968.45 L·m−2·h−1) for separating oil-in-water emulsions were satisfactory. Moreover, the modified PET fabric exhibited excellent chemical stability and can perform efficiently in harsh environment.

A LABORATORY MODEL FOR THE TWO-PHASE FLOW CONTAMINANT TRANSIENT IN MULTI-POROUS MEDIA

The environmental behavior of rock and oil pollutants in soil has long been a focus of environmental protection research. In this research, a laboratory model was established to study the oil pollutant transfer process in two stages. Two samples from porous media of sandy soil and agricultural soil (organic) were used with oil as a pollutant. The oil is pumped through a system consisting of two pipes with a length of 4 m and a diameter of 0.07 m. Each pipe is assigned to a specific type of soil. The results showed that the organic soil needs a long time for the pollutants to travel over greater distances, while the sandy soil showed its ability to absorb and drain the pollutants and get rid of them faster. However, it was also found that both soils contain a small percentage of the pollutant after the water washing process, which lasts for more than (5 hours). The remaining oil percentage is estimated at about (0.1 ml), which is a very small percentage, and it is possible to get rid of it by increasing the washing time. It was found that the physical properties of the soil such as permeability and porosity have a significant effect on slowing down the speed of the pollutant and its transmission through the porous medium.

Remediation of cadmium-contaminated soil: GLDA-assisted extraction and sequential FeCl3–CaO-based post-stabilization

Cadmium (Cd) contamination of farmland soils is a growing concern because of its highly toxic impact on ecosystems and human health. Chelator-assisted washing and chemical immobilization are effective remediation strategies for Cd-contaminated soils. Ethylenediaminetetraacetic acid (EDTA) has traditionally been used for soil washing, but its persistence in the environment and subsequent toxicity have raised significant ecological concerns. Consequently, biodegradable chelators have gained increasing attention as eco-friendly alternatives to the persistent chelator, EDTA. Therefore, this study evaluated the performance and efficacy of three biodegradable chelators: L-glutamate-N,N′-diacetic acid (GLDA), methylglycine-diacetic acid (MGDA), and 3-hydroxy-2,2′-iminodisuccinic acid (HIDS) in comparison to EDTA for remediating a real Cd-contaminated agricultural soil. The influence of treatment parameters, including chelator variants, washing time, chelator concentration, solution pH, and liquid-to-soil ratio (L/S) on Cd extraction was studied and optimized to attain the maximum removal rate. Following chelator-assisted washing, the efficacy of a stabilization preference combining FeCl3 and CaO in reducing the leaching potential of residual Cd in chelator-washed soil residues was also investigated. GLDA demonstrated comparable Cd extraction efficiency to EDTA, and the Cd extraction efficiency was found to be positively correlated with the soil washing parameters. However, under the optimized conditions (chelator concentration: 10 mmol L−1; washing time: 3 h; solution pH: 3; L/S ratio: 10:1), GLDA exhibited a higher Cd extraction rate than EDTA or the other chelators. Furthermore, a post-treatment process incorporating FeCl3 and CaO substantially diminished the water-leachable Cd content in the resultant soil residues. The proposed remediation strategy, which combines chemically assisted washing and stabilization, could be a practical option for extracting bulk Cd from soil and reducing the leaching potential of residual Cd.

Single Ultrasonic-Assisted Washing for Eco-Efficient Production of Mackerel (Auxis thazard) Surimi.

This study highlights a promising single washing method for producing dark-fleshed mackerel surimi aided by ultrasonication in conjunction with cold carbonated water containing 0.6% NaCl and mixed antioxidants (0.5% EDTA/0.2% sodium erythorbate/0.2% sodium tripolyphosphate) (CSA). Different washing periods (5, 10, and 15 min) with and without ultrasound were tested. Unwashed mince (A1) and conventional water-washed surimi (10 min/cycle, 3 cycles) (A2) were used as controls. A3, A4, and A5 were subjected to ultrasound-assisted washing for 5, 10, and 15 min, respectively, whereas A6, A7, and A8 had non-ultrasound-assisted washing for 5, 10, and 15 min. Results showed that the surimi yield decreased as the ultrasonic treatment time increased from 5 to 15 min (p < 0.05). Increased ultrasonic time resulted in greater protein denaturation, protein oxidation, myoglobin removal, and lipid oxidation in surimi (p < 0.05). Surimi produced by CSA ultrasonication for 5 min (A3), on the other hand, had a comparable overall quality to A2 surimi (p > 0.05). The correspondence gel (A3) outperformed the control gel (A2) in terms of gel strength, whiteness, and water-holding capacity (p < 0.05). The formation of regularly continuous, more organized, and smooth network structures in surimi gel was observed in A2 and A3 gels, whereas sparse and larger pore sizes were noticed in surimi gels produced by longer ultrasonic treatment. All of the surimi gels had identical FTIR spectra, indicating that the functional groups of the protein gel were consistent throughout. As a result, a single 5 min CSA-ultrasonic washing could potentially yield surimi of comparable quality to conventional washing. This could pave the way for the development of dark-fleshed fish surimi, which would require less washing time and produce less waste water.