Chlorotrifluoroethylene (CTFE) is a vital fluorinated olefinic monomer produced through the catalytic hydrodechlorination of trichlorotrifluoroethane (CFC-113), an eco-friendly process. However, hydrodechlorination catalysts for olefin production often suffer from poor stability. The Pd/AC catalyst and Pd-Cu/AC catalyst prepared by co-impregnation method exhibited poor stability, Pd-Cu/AC catalyst with CFC-113 conversion dropping to around 37% after 50 h of hydrodechlorination reaction. BET, TEM, XPS and XRD of fresh and deactivated Pd /AC catalysts indicate that the deactivation of Pd /AC catalysts is due to high-temperature agglomeration of Pd. Comparative analysis of fresh and deactivated Pd-Cu/AC catalysts using BET, TEM, and TG techniques revealed decreased dispersion of active sites, reduced surface area, catalyst aggregation deactivation, and a significant decrease in Cu content. Furthermore, the results of NH3-TPD revealed that the acid sites of the catalyst increased significantly. XRD spectra indicated the formation of new species, basic copper chloride (Cu2(OH)3Cl), during the reaction. As the reaction progressed, these new species agglomerated, leading to a gradual loss of catalyst activity. Moreover, the deactivated catalyst was successfully reactivated using a simple alkaline washing method.
Read full abstract