In this paper, a novel high-efficiency bidirectional isolated DC–DC converter that can be applied to an energy storage system for battery charging and discharging is proposed. By integrating a coupled inductor and switched-capacitor voltage doubler, the proposed converter can achieve isolation and bidirectional power flow. The proposed topology comprises five switches and a common core coupled inductor that uses only a set of complementary pulse-width-modulated signals to control and achieve high voltage gain without requiring high turn ratios or excessive duty cycles. Moreover, the proposed topology can recover the leakage inductance energy to improve the conversion efficiency. The main switches exhibit zero-voltage switching, which reduces the switching losses. A 500-W bidirectional converter is used to verify the feasibility of the proposed bidirectional converter through theoretical analysis and experiments. The experimental results indicate that the highest efficiency of the proposed converter in the step-up and step-down modes is 97.59% and 96.5%, respectively.