Bioelectric energy is a weak electric current generated by the human body itself, and the change in its value can indicate human injury, which can be used as a competitive physical injury judgment information. However, in the past, bioelectric energy measurement was mainly based on the standard voltage of 220 V, and it was not possible to conduct follow-up tests, so the scope of application was limited. Photovoltaic equipment in new energy has the characteristics of being easy to carry and can meet the needs of bioelectric energy testing at the theoretical level. In order to improve the application depth of new energy equipment and improve the safety of volleyball competition. Therefore, from the perspective of new energy, this paper tests the human bioelectric energy, collects current, voltage and power flow signals, combines the different functions to reduce the data dimensionality, calculates the abnormal changes of bioelectricity, and forms an abnormal data set. Finally, according to the injury characteristics of the human body, the volleyball economy is given an early warning. The results show that photovoltaic cells can meet the measurement requirements of human bioenergy, and the detection accuracy rate of joint injury, negative emotion, muscle strain and respiratory system injury reaches 80~83%, the abnormal electrical energy recognition rate reaches 90~95%, and the athlete satisfaction rate reaches 98%, and the wearing time is 1~3 months. Therefore, photovoltaic equipment can meet the identification requirements of human bioelectricity and has practical value in assisting competitive training and injury early warning.
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