Stages Of Volcanism Research Articles

Gravity and magnetic geophysical surveys for exploration of low sulphidation epithermal mining project. Marifil Complex, Chon Aike Igneous Province, Argentina

The Marifil Complex constitutes the early stage of the Chon Aike Igneous Province along eastern North Patagonia, Argentina. Geological, geochronological, and geochemical data indicate that this magmatism consists of two characteristic Lower Jurassic volcanic events (V0 and V1). The epithermal activity takes place in V1 as Au-Ag veins (Pavón Pivetta et al., 2024). Particularly, base metal veins are covered and masked by the important explosive volcanic activity related to the V1 volcanic stage. This makes geophysical exploration a highly recommended tool for interpreting subsurface geological features.With this in mind, we have carried out the acquisition and processing of gravity and magnetic data that is supported with drill holes and geochronological data. A series of gravity and magnetic highs and lows were recognized, together with major lineaments. Using Euler deconvolution, the depth of the sources that generate the anomalies was calculated. The analysis of these results allowed us to construct two perpendicular gravity 2D models for the calculation of thicknesses and depth of the rhyolitic coulée. The gravity lows were associated with the major thickness of rhyolitic coulée, reaching 290 m in the drill holes, and interpreted geophysically to have a deeper root. The gravity highs were interpreted in two possible ways: a basement depth decrease and/or the absence of the rhyolitic coulée. The minimum depth estimated for the basement highs is approximately 20 m. These interpretations are consistent with outcrop, drill hole and geochronologic data, and magnetic maps. The RMSE between the calculated and the observed anomalies of the models are about 0.316 and 0.519 mGal. Due to the shape of the anomalies obtained from the gravimetric maps, the structures that generate the anomalies were considered as generated by three-dimensional bodies. For this purpose, we created a 3D model that provides interesting data about the possible location of these non-outcropping gravity lows that are located in the first 200 m depth.These results demonstrate that the use of the gravity and magnetic method constitutes a useful, fast, economical, robust, and reliable tool for the identification of these volcanic structures.

A revised stratigraphic model for the ∼ 1910–1835 Ma Tanami Group, the Northern Territory, Australia: Implications for exploration targeting

The Paleoproterozoic Tanami Group of the Granites—Tanami Orogen hosts a known endowment of > 20 Moz of gold mineralization across numerous deposits. Throughout the region, host lithologies impart a first-order control on the style, grade and endowment of mineralization. However, the genetic relationship and regional distribution of three regionally correlative formations (the Dead Bullock, Mount Charles and Stubbins formations) remains enigmatic. Here, we combine lithostratigraphic analysis, lithogeochemistry, detrital zircon geochronology and geophysical observations to propose a new evolutionary model for the Tanami Group. We find that the Tanami Group was deposited in a continental back-arc basin setting and developed in four stages. Package A marked the onset of the rifting of the continental Archean basement. Sedimentary rocks within Package A are dominantly felsic in composition and display a unimodal detrital zircon age population at ∼ 2530 Ma. Package B marks the onset of mafic volcanism; consequently, volcaniclastic and sedimentary rocks within Package B display a distinct mafic geochemical signature. Detritus shed from an Archean basement persisted throughout this period, and a unimodal detrital age component at ∼ 2530 Ma persists. Package C marked the waning stages of voluminous mafic volcanism across the Tanami Basin. Sedimentary volcaniclastic rocks within Package C display a mixed mafic and felsic composition. Detrital zircon age spectra record multiple peaks at ∼ 2500, 3000 and 3350 Ma, which may reflect erosion of older Archean basement domains or changes in paleo-drainage. Package D marked a significant change in the source of detritus entering the basin from dominantly Archean to Paleoproterozoic, with dominant detrital age peaks at ∼ 1860 Ma. Despite significant lithofacies variations, the presented model highlights multiple correlations between the Dead Bullock and Mount Charles formations. The Mount Charles Formation likely represents a volcanic source-proximal, high-energy depocenter. In contrast, the Dead Bullock Formation was deposited in a lower energy setting, distal to volcanic centers. These observations are important to mineral exploration. Notably, the Mount Charles Formation is distributed over a significantly greater area than previously thought, and the under-represented Hangingwall and Footwall sequences of this formation are interpreted to host significant gold mineralization at the Oberon and Groundrush deposits.

Geology of the Kebasen Paleovolcano in Banyumas Regency, Central Java Province, Indonesia

Abstract The new interpretation on geology of Kebasen district in Central Java, Indonesia which is located in the middle parts of Sunda Arc indicates the existence of a paleovolcano. This conclusion is achieved through 1:25,000 geological mapping with a focus on volcanic facies, characterization of lithology types, mineralogy, and fossil analysis, to clarify its volcanic history and paleo-environment. Laboratory analysis works on representative rock samples are done using petrography and fossil identification on calcareous sedimentary members. Our research results conclude that Kebasen paleovolcano was a composite volcano with a diameter of about 8 km, elongated in NW-SE orientation, with Kebasen city located at the SW rim of the old volcanic edifice. The volcanic history and resulting volcanic rocks consisted of two contrasting volcanic stages. The first one was explosive caldera-forming eruptions that produced thick and partly welded pyroclastic rocks, dominated by pyroclastic breccia at the lower parts and finer tuff members at the upper parts. After caldera-forming eruptions, volcanic activity was followed by effusive eruptions of basaltic to andesitic lavas that covered the caldera floor. The lavas have abundant pillow structures indicating a submarine environment, intermediate to basaltic composition, and porphyritic texture, with plagioclase and pyroxene as the most abundant phenocryst minerals. Available rock geochemistry data demonstrate that lavas have mafic to intermediate compositions, with magma affinity at the transition of calc-alkaline to tholeiitic series. Results of geomorphological and lithology association analysis conclude that the research area was part of the central to distal facies of a paleovolcano complex, with the paleo depositional environment in the open marine environment. The results of fossil analysis on calcareous sedimentary rocks between volcanic layers indicate that the age of volcanism was Early Pliocene (N18) with the paleobathymetry transitioning from upper-middle bathyal to outer–middle neritic, which were parts of the continental margin. It is concluded that Kebasen paleovolcano is a newly identified submarine caldera-type Pliocene volcano within the middle parts of the Sunda Arc in Central Java, Indonesia.

High-precision U[sbnd]Pb geochronology of an ignimbrite flare-up in a silicic large igneous province (Chon Aike, Patagonia)

Silicic large igneous provinces (SLIPs) are periods of particularly voluminous felsic volcanism in the geologic record. Previous work has suggested an overall long lifespan for SLIPs of 20 to 40 Myr, commonly punctuated by shorter-lived ‘flare-ups’ of higher volcanic productivity (1–5 Myr), but detailed studies of individual flare-up events are lacking. The Jurassic Chon Aike SLIP (CASP) is the product of an exceptional geological event wherein voluminous felsic volcanism (ca. 219,000 km3) was generated predominately via crustal anatexis over 45 Myr. We focus on the Late Jurassic El Quemado Complex (EQC), which marked the final stages of felsic volcanism for the CASP. In-situ U-Pb ages for the EQC previously suggested a duration of ∼5 Myr; however, new high-precision CA-ID-TIMS ages indicate the total durations of ignimbrite successions were shorter than 350 kyr. A compilation of zircon U-Pb ages for the eight CASP formations in Patagonia and the Antarctic Peninsula reveals changes in volcanic duration between formations deposited in the intraplate relative to the continental margin, suggesting a spatial control over the magmatic lifespans of geographically restricted systems. We suggest that the rate of magmatism in the CASP was primarily controlled by heterogeneities in the crust, largely between Proterozoic igneous crust and younger, metasedimentary crust that was recently accreted relative to the timing of Jurassic volcanism. The observed duration of volcanism was modulated by these differences in crustal properties from the injection of mafic magmas into the lower crust during extension and mantle upwelling, following rollback of the subducting oceanic slab towards the Paleo-Pacific margin of Gondwana. The short duration in the EQC is the product of unique overlapping conditions that favored crustal melting and resulted in the voluminous ignimbrite flareup (104 km3) of some of the Earth's highest δ18O magmas measured.

Magmatic Origins of Extensional Structures in Tempe Terra, Mars

AbstractNumerous graben features transect the Tempe Terra plateau in the northeastern Tharsis Rise, Mars, making it one of the most heavily structured regions of Tharsis. The origin of the complex fault geometries, generated over three distinct stages of tectonic activity, is poorly understood. This work distinguishes between Tempe Terra structures of local and regional origin, to isolate regional deformation patterns related to the general development of the Tharsis Rise from the patterns due to effects of local stress mechanisms. Comparison of structural observations to predicted deformation patterns from different drivers of graben formation in the Martian crust demonstrates the important role of magmatic activity at a variety of scales in driving tectonism in Tempe Terra. Noachian (Stage 1) faulting resulted from local magmatic underplating and associated heating and uplift, which formed part of an incipient stage of widespread Tharsis volcanism that predated development of the main Tharsis Rise. Early Hesperian (Stage 2) faults reflect the interaction of regional stresses from growth of Tharsis with magmatic activity highly localized along the Tharsis Montes Axial Trend—a linear volcanotectonic trendline including the alignment of the Tharsis Montes volcanoes. Early–Late Hesperian (Stage 3) faulting resulted from a series of dyke swarms from a Tharsis‐centered plume, which propagated in a regional stress field generated by growth of the Tharsis Rise. As only Stage 2 NNE faults and Stage 3 ENE faults are linked to regional, Tharsis‐related stresses, other observed Tempe Terra fault trends can be excluded when evaluating models of Tharsis's tectonic evolution.

Volcano-sedimentary interactions – A key to understand Cretaceous paleoenvironments in the Paraná basin (southern Brazil)

The Lower Cretaceous in the Paraná Basin record a large volcanic event (Serra Geral Formation) that covered an active sedimentary system (Botucatu Formation), before the fragmentation of the southern Gondwana. Therefore, the fluvial-aeolian deposits underlying aeolian deposits of residual dunes, were gradually covered by volcanic flows. Intense basic and minor acidic magmatism covered an extensive continental aeolian environment. The interface between the two units shows an aeolian environment during the early stages of volcanism forming deposits and volcano-sedimentary features overlying and underlying the flows. In six outcrops on the southern portion of the current border of Paraná Basin, in Rio Grande do Sul state, these deposits and features were recognized, showing the complexity of the environment and the processes associated with lava flows and sediments. They were formed by the interaction of consolidated or unconsolidated sediments, saturated or not in the water, with basaltic or dacitic flows. Interaction features and deposits synchronous to volcanism (volcanoclastic), later or in intervals between volcanic events (epiclastic) and only cover, with absence of interactions, were identified. Through the distinctive characteristics of the interaction processes between the volcanic rocks and the sediments analyzed in the volcanic-sedimentary features and deposits, the morphology of the aeolian environment of Botucatu Formation could be, by analogy, compared to the current aeolian environments. The proposed paleoenvironment indicates a sedimentary environment with different domains, categorized by their water saturation. The different siliciclastic components found in each domain allowed the generation of different features and volcanic-sedimentary deposits evidencing aspects related to the presence or absence of water among the proposed domains.

An Approach to Determine of the Formation Stages of Volcanism Using Natural Gamma-Ray Spectrometer from Geophysical Methods (Example of Gölcük Volcanism)

Gölcük Caldera is in the Isparta Angle, which is an interesting tectonic structure in Southwest Anatolia. This caldera is formed as a result of back-arc volcanism associated with the northward subduction zone of the African plate under the Eurasian Plate during the Tertiary. It attracts the attention of many researchers with its tectonic and volcanic structure. In this article, the results of in situ natural gamma radiation measurements made in the caldera are evaluated. In the study, radioactive element (Potassium (%K), Uranium (eU), and Thorium (eTh)) contents of volcanics were measured in situ with the portable gamma-ray spectrometer, which is effectively used in Geophysical Engineering. The changes in natural gamma radiation of alkaline volcanic are presented with maps. When these maps are examined, it is understood that K%, U-ppm and Th-ppm concentrations of Gölcük volcanic are higher than the world average values. The high potassium concentration draws even more attention. The high potassium content indicates that the local volcanic are ultrapotassic and contain lithospheric materials. In addition, since the radioactive element concentration will reflect the magmatic development, the volcanic stages in the region have been tried to be determined. The number of these stages was determined from the curves of the radioactive data from a purely geophysical engineering (numerical) point of view, and the study area was interpreted as consisting of three different phases. This finding is supported by the results of the articles on the aging studies of the samples taken as a result of observations. In addition to these, the ranges of radioactive elements belonging to these stages were determined.

Pre-eruption magmatic processes and magma plumbing system at Hachijo-Nishiyama volcano, Izu–Bonin arc, Japan

Nishiyama volcano on Hachijojima Island is an active basaltic volcano located in the Izu–Bonin arc. In this study, petrological and geochemical analyses were conducted on mafic lavas and pyroclastics to understand the magma plumbing system and pre-eruption magmatic processes. Whole-rock major element compositions show significant variations (49.4–54.9 wt.% SiO2), and the samples contain variable amounts of plagioclase phenocrysts (1–40 vol.%). The whole-rock Sr, Nd, and Pb isotopic compositions of samples from the youngest volcanic stage (< 0.7 ka) are homogeneous, whereas some samples from the older stage (3–1 ka) have relatively low Pb isotopic ratios. This observation suggests that the younger magmas were derived from a single parental magma, but another parental magma with distinct geochemical features was involved in the magmatic system before 1 ka. The temporal variation in the FeO*/MgO ratios of the volcanic products is complex and is considered to reflect the intermittent injection of primitive magmas into the main magma chamber in which fractional crystallization occurred. Two-pyroxene geobarometry suggests that the main magma chamber was located at a depth of 9–12 km. The core region of some plagioclase phenocrysts consists of a glass inclusion-free inner core and an inclusion-rich outer mantle, suggesting that some plagioclase crystallized in the main magma chamber, which was followed by overgrowth during magma ascent because of increasing liquidus temperatures due to decompression-induced water exsolution from the melt. The whole-rock compositions of some eruption units with different Al2O3/MgO ratios exhibit distinct plagioclase-controlled trends, which negates the possibility that plagioclase accumulation occurred in a stable magma chamber. In addition, the density of plagioclase was higher than that of the melt during the magma ascent to the surface. From these observations, it is suggested that the accumulation of plagioclase phenocrysts occurred in ascending magmas as the plagioclase settled relative to the surrounding melt. The estimated depth of 9–12 km for the main magma chamber coincides with the depth range over which earthquake swarms occurred in 2002, suggesting that the magma chamber is still active, and that the earthquake swarms may reflect the injection of primitive magma into the magma chamber.Graphical

Petrogenesis and tectonic significance of two bimodal volcanic stages from the Ediacaran Campo Alegre-Corupá Basin (Brazil): Record of metacratonization during the consolidation of Western Gondwana

The Ediacaran Campo Alegre-Corupá Basin in South Brazil developed in two stages, the synorogenic passive rift (Basin Stage ∼605–590 Ma) and the post-collisional caldera volcano (Caldera Stage ∼583–577 Ma), respectively. Volcanic rocks from the Basin Stage show a bimodal compositional spectrum with dominant basalt and subordinate silicic rocks. The basaltic rocks are transitional to mildly alkaline, exhibiting Ocean Island Basalt-like (OIB-like) trace element enrichment patterns, with depletion in Nb and Ta, however, and crustal-like Sr-Nd isotopic signatures, suggesting that they were derived from low degrees (∼5%) of partial melting of an enriched lithospheric mantle source. The silicic rocks are transitional to mildly alkaline trachydacites associated with subordinate rhyolites, exhibiting trace element compositions typical of A2-type granitoids, produced by fractional crystallization of the coeval basalts in the Moho. Volcanic rocks from the Caldera Stage are constituted mainly by alkaline trachytes and rhyolites, occurring primarily as pyroclastic sequences coupled to minor effusive lava flows and domes, also exhibiting trace element compositions typical of A2-type granitoids. They are associated with subordinated effusive transitional to mildly alkaline basalts with Island Arc Basalt-like (IAB-like) trace element signatures. Compared to the Basin Stage, the basalts from the Caldera Stage result from higher degrees (∼15 %) of partial melting of possibly the same enriched lithospheric-mantle sources during the lithospheric root collapse of a cratonic terrane. The silicic rocks from the Caldera Stage are also derived from the coeval basalts by fractional crystallization in the Moho. However, an additional stage of differentiation in the upper crust is required to explain their silica-enriched compositions and eruptive styles. Results from this study support a connection between the silicic volcanic rocks from the Caldera Stage and the plutonic bodies from the nearby A-type Graciosa Province. Lu-Hf isotopes from detrital zircon suggest an Andean arc-type tectonic setting during the Paleoproterozoic (∼2,185 Ma) history of the Luis Alves Terrane (LAT) basement. This tectonic setting was responsible for the arc-like signatures of the intraplate lithospheric-derived rocks of both bimodal volcanic sequences. Crustal-like Sr-Nd-Hf isotopic characteristics result from a protracted isotope evolution of their enriched mantle sources, and each tectono-magmatic stage results from a different extensional setting, which has implications for the metacratonization of the LAT.

Evolution of magma supply system beneath a submarine lava dome after the 7.3-ka caldera-forming Kikai-Akahoya eruption

Kikai caldera in SW Japan, which is a submarine volcano, has undergone repeated caldera-forming eruptions. After the 7.3-ka caldera-forming Kika-Akahoya eruption, basaltic and rhyolitic subaerial eruptions occurred at Inamura-dake, Iwo-dake and Showa-Iwojima volcanic centers on the caldera rim. Fumarole activity still continues at Iwo-dake. Recent submarine surveys have revealed that a 600 m high central lava dome grew inside the Kikai caldera, with a volume of 32 km3. In addition, several satellite volcanic cones formed to the east and the west of this central lava dome. These features inside the submarine caldera would postdate the 7.3-ka Akahoya eruption. However, the formation mechanism of these submarine volcanic edifices is yet to be well understood. Here we present the whole-rock and mineral chemistry of dredged rocks from the central lava dome and satellite volcanic cones inside the submarine caldera. The results are used to constrain magmatic conditions that formed these submarine volcanic edifices. Most rhyolites from the central lava dome and the western satellite volcanic cones are compositionally distinct from those of the Akahoya eruption and the old Iwo-dake volcanic stage (5.2–3.9 ka) rhyolites. Instead, the chemical compositions of these submarine rhyolites overlap with those of the volcanic products of the young Iwo-dake, which is active since 2.2 ka. The compositional similarity suggests that the central lava dome tapped the same magma supplying the young Iwo-dake volcanism. By contrast, the dredge samples from the eastern satellite volcanic cones exhibit binary chemical trends: one group having chemical composition that overlaps with those of the young Iwo-dake rhyolites; the other group being chemically similar to the rhyolites from the old Iwo-dake and the Akahoya eruption. The magma temperature estimated from Fe-Ti oxide thermometry (922 °C on average) is almost equal to those estimated for subaerially erupted rhyolites at Iwo-dake during the young Iwo-dake volcanic stage and the Showa-Iwojima eruption in 1934–1935. The oxygen fugacity estimated from Fe-Ti oxygen barometry is 0.8 log unit higher than Ni-NiO buffer (NNO + 0.8), on average, which is lower than that estimated for the subaerially erupted rhyolites. A magmatic hygrometer estimated H2O content of the melt ranging 2.2–3.5 wt%. Polybaric crystallization from H2O-saturated melts may have occurred beneath the submarine lava dome at depths of 2–4 km. These results suggests that a separate magma supply system with basaltic and rhyolitic magmas may exist beneath the submarine central lava dome and that underlying basaltic magma, such as that beneath Iwo-dake and Showa-Iwojima, may have heated rhyolitic magmas stored at depths of 2–4 km. Additionally, the lack of mafic enclaves, which are by contrast commonly observed in the subaerially erupted rhyolites at Iwo-dake and Showa-Iwojima on the caldera rim, implies that direct interaction between basaltic and rhyolitic magmas is limited beneath the center of the submarine caldera.

Paleovolcanology, geochemistry, and zircon U-Pb-Hf isotopes of the volcano-sedimentary sequences from the Ediacaran Campo Alegre-Corupá Basin, southern Brazil: Linking volcanism and tectonics during Western Gondwana consolidation

The Campo Alegre-Corupá Basin (CACB) records a well-documented sequence of volcano-sedimentary episodes associated with specific periods of crustal extension during the late-convergent to post-collisional tectonic stages of the consolidation of Western Gondwana. Two main volcano-sedimentary stages were detailed through stratigraphic and lithofaciological studies, combined with whole-rock geochemistry and zircon U-Pb-Hf analysis, resulting in a more complete understanding of the tectono-magmatic cycles and volcanological evolution of the CACB. During the Basin Stage (605–590 Ma), regional collisional tectonics was responsible for initiating the basin as a syn-orogenic rift, during which the sedimentary cycle progressed from alluvial fans at the northern limit of the basin to braided rivers and into a lake to the south. U-Pb geochronology and Lu-Hf isotope signatures of detrital zircon revealed that the sediments were mainly derived from the Paleoproterozoic basement of the Luis Alves Terrane, which constitutes the direct basement of the CACB, with contributions from the nearby Piên Magmatic Arc and possibly from the Curitiba Terrane to the North. The sedimentary strata were progressively covered by transitional to mildly alkaline OIB-like basalts, occurring mostly as lava flows with structural aspects suggestive of subaqueous to subaerial environments, interbedded with trachydacites and surge-like pyroclastic deposits. Large volumes of widespread and densely-welded to rheomorphic ignimbrite sheets within the CACB attest to a second infilling period corresponding to the Caldera Stage (583–577 Ma). This stage was inaugurated by the outpouring of trachytic and very subordinated IAB-like basaltic lava flows at ∼583 Ma. The caldera eruption seems to have been initiated by the production of pumiceous fallouts during an early Plinian-like period of decompression of shallow magma chambers at ∼580 Ma, during which the rift-related structural framework of the Basin Stage probably controlled the collapse of a graben-like caldera. Compositional and isotopic signatures suggest lithospheric mantle sources for the magmas from both volcanic stages and support a connection between basic-intermediate and silicic rocks from both bimodal associations. They also suggest a cogenetic nature between the silicic rocks from the Caldera Stage and the A-type granitoids from the nearby plutonic Graciosa Province.

Imaging the Volcanic Structures Beneath Gran Canaria Island Using New Gravity Data

AbstractFrom a new gravity data set that covers homogeneously the whole surface of Gran Canaria (Canary Islands, Spain) and marine gravity data in the nearest offshore, we have obtained a Bouguer anomaly gravity map of the island which improves the previous ones. Using these gravity anomalies, we have applied a gravity inversion approach to investigate the structures beneath the surface of Gran Canaria Island and derive a 3D gravity sources model. The geometry of structures with anomalous density values is constrained up to a depth of approximately 20,000 m below the sea level. The interpretation of the density model identified structures related to the different volcanic stages of Gran Canaria. Several deep‐rooted high‐density structures represent the intrusive bodies emplaced in the early formation of Gran Canaria and the magma plumbing system of the Miocene volcanic edifices. A low‐density body in the center of the island may be associated with the syenitic core of the felsic central volcanic edifice (Tejeda Caldera). Shallow low‐density structures identified fractures which acted as feeder dikes of monogenetic volcanoes during the rejuvenated stage. Finally, the NW‐SE rift, which is the most important volcano‐tectonic structure of Gran Canaria, has a characteristic gravimetric signature and represents a long‐lived extensional fracture zone that has controlled the volcanic activity at least since the Miocene.

Genesis of the Kiruna-type Nixintage iron deposit, Chinese Western Tianshan, NW China: Constrains of ore geology, geochemistry and geochronology

The Nixintage iron deposit is located in the central segment of the Awulale metallogenic belt, Chinese Western Tianshan. Iron ores are mainly hosted by andesitic tuff and andesite of the Carboniferous Dahalajunshan Formation. The paragenetic sequence includes a magmatic magnetite-apatite stage (I); a magmatic–hydrothermal stage (II), and three substages can be divided, including magnetite-albite substage (II-1), magnetite-chlorite-pyrite substage (II-2), magnetite-quartz-calcite substage (II-3); and a late hydrothermal quartz-calcite-sulfides stage (III). Anhedral, fine-grained magnetite associated with apatite in brecciated and matrix ores formed in stage I with relatively variable compositions, most probably indicate the fast crystallization under a disequilibrium condition. The high-grade magnetite orebodies mainly formed in the stage II, are featured by widespread hydrothermal mineral assemblages associated with the ores. Magnetite formed in this stage has medium-to-high concentrations of V, low-to-medium concentrations of Ti, Cr, relative depletion of Mg, Ni, K, and these data mainly plot in the Kiruna and porphyry fields of discriminant diagrams that comparable to magnetite from typical Kiruna-type iron deposits. Both stages I and II magnetites show similar wide δ18O ranges and with peak values at 6.0–10.0 ‰, heavier than typical Kiruna-type deposits, while could be attributed to the relatively low crystallization temperature inferred by microthermometric data of a previous study. The δ34S values of pyrite formed in different stages range between 0.1 and 2.4 ‰, comparable to the sulfur isotopic composition of the mantle-derived magma. These features indicate that stage I iron mineralization was generated by the extrusion of iron phosphorous oxide melts separated from the parental silicate magma. Subsequent deuteric fluids exsolved from basaltic to andesitic melts during the late stage of volcanism, generated magmatic–hydrothermal iron mineralization in stage II, and the continuous evolution of the deuteric fluids formed stage III hydrothermal veins. In summary, integrated evidence suggests the Nixintage is a Kiruna-type iron deposit.Zircon U-Pb ages of ore-hosting andesite and andesitic tuff are 317.6–314.4 Ma, and timing for iron mineralization was inferred at the same time, i.e., ca. 315 Ma. Previously published petro-geochemical data combined with our geochronological data of these rocks, suggest the ore-related volcanism in Nixintage probably originated from the partial melting of the mantle wedge modified by subducted fluids under a Late Carboniferous continental arc setting. Consequently, a genetic model for the studied deposit could be created. Furthermore, the southeast of the Nixintage nearer to the vent might have potential for prospecting large Kiruna-type iron deposits.

Emeishan felsic volcanism lasted until the Changhsingian? New evidence from volcanic ash in the northern South China block

The main episode of volcanism in the Emeishan large igneous province (ELIP) occurred ca. 260 Ma. However, the ending period of volcanism has not been well established. We present the SHRIMP and LA-ICP-MS zircon U–Pb geochronology, zircon Hf isotopes, and geochemistry of ashes in the Shuanghe and Xintang sections, northern South China block (SCB). The results show that the Al/Ti ratio and high field strength elements content of Changsingian ashes (253.5–253.0 Ma) are consistent with those of alkaline ashes in the Wuchiapingian coal measure of the western SCB. These volcanic rocks contain zircon grains with high εHf(t) values (mean + 2.53) and low Th/Nb ratios (mostly < 10), consistent with the origin from mantle-derived magmas within the plate. These magmas are interpreted to be related to the Emeishan felsic volcanism. Furthermore, the zircon grains separated from ashes at the Permian-Triassic boundary (PTB) (ca. 252 Ma) and the upper Longtan Formation (256.8 Ma), have low εHf(t) values (mean − 7.04) and high Th/Nb ratios (mostly greater than 40). These features are consistent with a magmatic arc source, and the arc was likely related to the subduction of Paleo-Tethys in the middle Wuchiapingian. Therefore, we propose that the waning stage of the Emeishan felsic volcanism continued until the middle Changhsingian (253 Ma), which is not a previously suggested older age of 257 Ma. However, the ashes near the PTB on the SCB should have come from the magmatic arc. The Emeishan volcanism may not be the main cause of the PTB extinction.

Onset of long-lived silicic and alkaline magmatism in eastern North America preceded Central Atlantic Magmatic Province emplacement

Abstract The White Mountain magma series is the largest Mesozoic felsic igneous province on the eastern North American margin. Previous geochronology suggests that magmatism occurred over 50 m.y., with ages for the oldest units apparently coeval with the ca. 201 Ma Central Atlantic Magmatic Province, the flood basalt province associated with the end-Triassic mass extinction and the opening of the Atlantic Ocean. We use zircon U-Pb geochronology to show that emplacement of White Mountain magma series plutons was already underway at 207.5 Ma. The largest volcanic-plutonic complex, the White Mountain batholith, was emplaced episodically from ca. 198.5 Ma to ca. 180 Ma and is ~25 m.y. older than published ages suggest, and all samples we dated from the Moat Volcanics are between ca. 185 Ma and 180 Ma. The Moat Volcanics and the White Mountain batholith are broadly comagmatic, which constrains the age of a key Jurassic paleomagnetic pole. Our data indicate that a regional mantle thermal anomaly in eastern North America developed at least 5 m.y. prior to the main stage of Central Atlantic Magmatic Province flood basalt volcanism and suggest a geodynamic link between the White Mountain magma series and the Central Atlantic Magmatic Province.

ALMUS (TOKAT) YÖRESİNDEKİ AKİKLERİN JEOKİMYASAL ÖZELLİKLERİNİN DEĞERLENDİRİLMESİ

The Upper Cretaceous Artova ophiolite complex, represented by metabasic and ultrabasic rocks, overlies the Paleozoic aged Tokat metamorphites, which form the basis of the study area, by the tectonic boundary. Haydaroğlu formation, which includes Middle Eocene aged volcanogenic units, cuts and covers the older units. Agates (agates) in the Almus region are found in the form of nodules in the volcanogenic sandstones of the Haydaroğlu formation along an approximately E-W trending fault. The Lower Miocene aged Almus formation, which consists of sedimentary rocks such as sandstone, conglomerate and marine limestone, also unconformably overlies all units.&#x0D; Almus region agates contain on average 93.4% SiO2, 3.59% Fe2O3, 0.03% MgO, 0.72% CaO, 793 ppm Cr2O3, 12 ppm Ni, 13.4 ppm Cu, 4.7 ppm Pb, 35.4 ppm Zn. The high Cr and Ni in agates are associated with the Artova ophiolite complex in the region. Cu, Pb and Zn are associated with the early stages of volcanism. The high Fe2O3 content in agates is associated with hematite and goethite, and they were transported into agates before SiO2 emplacement. The CaO in the agate is the product of the last phase of the solution forming the agate, and MgO is associated with the presence of dolomite. &#x0D; Evaluation of the results of geochemical analysis shows that SiO2, which is the main component due to the hydrothermal activities that occurred after the rock formation of the Haydaroğlu formation, unlike the volcanic bedrocks of the agates according to the main oxides, trace and rare earth elements, was emplaced epigenetically as a result of the circulations in the volcanogenic sandstones.

Mineralogy and geochemistry of lavas from the submarine lower caldera walls of Santorini Volcano (Greece)

Santorini Volcano, located in the central sector of the South Aegean volcanic arc, is one of the most active and potentially dangerous volcanoes in Europe. It has hosted Plinian eruptions over the last 350 ka of which at least four eruptions were accompanied by caldera collapses. Even though Santorini Volcano is considered a major threat, the main focus of research, thus far, has been on the comparatively young and subaerial deposits, whereas older stages of volcanism have been poorly studied. Our study focusses on samples from the submarine inner caldera walls and gives new insights into the early evolutionary stages of Santorini Volcano, contributing to a better understanding of its eruptive history and thus potential risks. The submarine lava successions were sampled along the inner caldera wall by a remotely operated vehicle (ROV) during R/V POSEIDON cruise 511 in 2017.The recovered lavas comprise two magmatic series, a low-K basaltic series overlain by a medium- to high-K series, which includes basaltic andesites, andesites and occasional dacites to trachytes. Major and trace element compositions and mineral zonation patterns suggest that fractional crystallisation and periodic magma replenishment were the dominant processes controlling magma evolution of both magmatic series. In addition, repeated magma mixing events played an important role, as indicated by zonation patterns in plagioclase and clinopyroxene ante- and phenocrysts. The thickness of the submarine lava successions (≥100 m) and the occurrence of similarly zoned plagioclase throughout indicate long-lived magma plumbing systems characterised by repeated differentiation and magma mixing. Furthermore, the incompatible element and radiogenic isotope ratios indicate a heterogeneous mantle source for Santorini magmas, which reflects the relative contribution of subduction (sedimentary) input and mantle wedge influx. A lava sample from the northern submarine caldera wall probably represents a deep level of the original Peristeria volcano. 40Ar/39Ar dating of andesite lavas from the southern submarine caldera produced ages of ~255 ka, whereas one basalt lava produced an age of 309 ± 30 ka. Interestingly, the new ages of both groups fall within an age gap in the volcanic history of Santorini Volcano. Even though it was not possible to unequivocally correlate the sampled submarine lava series to known subaerial units, the major and trace element compositions, and Sr-Nd-Pb isotopic compositions of our intermediate lavas show a strong similarity to subaerial lavas of Peristeria volcano, the second oldest major stage of Santorini volcanism. It however seems more likely that we have sampled a thus far unknown stage of volcanism at Santorini Volcano.

Volcanism of the Late Silurian Eastport Formation of the Coastal Volcanic Belt, Passamaquoddy Bay, New Brunswick

This field trip is an excursion through the exquisite, nearly pristine exposures of a Silurian, felsic-dominated bimodal volcanic and sedimentary sequence exposed in the Passamaquoddy Bay area of southwestern, New Brunswick (Eastport Formation). These rocks form the northwest extension of the Coastal Volcanic Belt that extends from southwestern New Brunswick to the southern coast of Maine. The sequence is significant because it is part of a large bimodal igneous province with evidence for supervolcano-scale eruptions that began to form during the close of the Salinic Orogeny (about 424 Ma), and continued into the Acadian Orogeny (421–400 Ma). The geochemical characteristic of the rocks can be explained by extension related volcanism but the specific drivers of the extension are uncertain. The Passamaquoddy Bay sequence is 4 km thick and comprises four cycles of basaltic-rhyolitic volcanism. Basaltic volcanism typically precedes rhyolitic volcanism in Cycles 1–3. Cycle 4 represents the waning stages of volcanism and is dominated by peritidal sediments and basaltic volcanics. A spectrum of eruptive and emplacement mechanisms is represented ranging from the Hawaiian and Strombolian-type volcanism of the basaltic flows and pyroclastic scoria deposits, to highly explosive sub-Plinian to Plinian rhyolitic pyroclastic eruptions forming pyroclastic density currents (PDC) and high grade rheomorphic ignimbrites. During this field trip we will examine key exposures illustrating this spectrum of eruptive and emplacement processes, and their diagnostic characteristics, along with evidence for the interaction between mafic and felsic magmas and a variety of peperitic breccias formed as a result of emplacement of flows on wet peritidal sediments. The constraints the depositional setting and voluminous bimodal volcanism places on tectonic models will also be considered.

New zircon U–Pb age of the Didao Formation in Jixi Basin and its significance for the geology and paleogeography in Jixi and eastern Heilongjiang region in the Early Cretaceous

The coal-bearing Jixi Basin of Heilongjiang is a unique Cretaceous basin in Northeast China, depositing non-marine alternated marine strata during transgressions in the Early Cretaceous. However, the ages of the Didao-, Chengzihe- and Muling formations and their relationships to transgressions and regressions have been under debate mainly due to a lack of radiometric constraints and comprehensive study of the fossils. The authors report results of new LA-ICP-MS zircon dating from the tuff of the Didao Formation in its type section (131.5 ± 1.4 Ma), which is the oldest isotopic dating data reported for the Early Cretaceous in eastern NE China. This dating result shows the earliest known volcanic activity happened in the Hauterivian stage, which implies the initial rifting of the Jixi Basin probably in the Hauterivian and caused the first sea staged regression eastward or northeastward in Jixi Basin during the Early Cretaceous. Additionally, a comprehensive study of the plant and dinoflagellate fossils, new dating, and the regional paleogeographic characteristics, indicates a Valanginian-Hauterivian age for the Didao Formation, improving the stratigraphic study of the Didao Formation in accuracy. Moreover, according to the dating in the eastern Northeast China, the four volcanic stages in this region during the Early Cretaceous can be recognized as follows (i) the Didao volcanic stage (ca. 130–132 Ma); (ii) Early Chengzihe-Boli volcanic stage (ca. 119–126 Ma); (iii) Late Chengzihe-Muling volcanic stage (ca. 110–117 Ma); (iv) the Dongshan volcanic stage (ca. 101–108 Ma).

Holocene volcanic activity in Anjouan Island (Comoros archipelago) revealed by new Cassignol-Gillot groundmass K–Ar and 14C ages

The Comoros archipelago has attracted renewed attention since 2018 due to the submarine volcano growing east of the island of Mayotte and the associated ongoing seismic crisis. However, the origin of Comorian magmatism remains controversial, as it is either interpreted as related to a hotspot trail, to a fracture zone, or to a plate boundary. Lying in the central part of the archipelago, Anjouan is a key island to better understand the relationship between volcanism and geodynamics. Together with a careful selection of published whole-rock K–Ar ages, our new set of 13 groundmass K–Ar ages on lava flows and one radiocarbon age on a charcoal from a strombolian deposit, allow us to reassess the volcano-tectonic evolution of Anjouan Island. New groundmass K–Ar ages lie within the last 1 Ma, i.e. from 899 ± 14 to 11 ± 1 ka. They suggest that most of the subaerial volcanism in Anjouan is much younger than previously inferred, and occurred as pulses at 900–750 ka, perhaps 530 ka, 230–290 ka, and since 60 ka, with erosional periods in between. Among our new data, one 14 C age of 7513–7089 yrs calBCE (9.3 ± 0.2 ka) and five K–Ar ages younger than 60 ka show that recent volcanism occurred in Anjouan. Moreover, the concentration of eruptive vents along a N150° alignment, parallel to the maximum horizontal stress, suggests a strong link between regional tectonics and volcanism. Considering the presence of active volcanoes on both the western and eastern extremities of the Comoros archipelago, our discovery of Holocene activity on Anjouan provides strong arguments against a chronological progression of volcanism along the archipelago, and therefore contradicts the hotspot hypothesis for the origin of volcanism. Finally, this study provides a robust geochronological timeframe of the different volcanic stages of Anjouan. It demonstrates that Anjouan is an active island and suggests that volcanism and tectonics can both resume at any time. • New groundmass K–Ar ages in Anjouan are between 899 ± 14 and 11 ± 1 ka. • Volcanism in Anjouan occurred in successive pulses. • A 14 C age of 7513–7089 yrs calBCE has been obtained for strombolian deposits. • Anjouan is an active island where volcanism and tectonics can both resume. • Holocene volcanism is present all over the Comorian archipelago.