Stages Of Volcanism Research Articles

Patagonia-Antarctica Early Paleozoic conjugate margins: Cambrian synsedimentary silicic magmatism, U-Pb dating of K-bentonites, and related volcanogenic rocks

This study describes the stratigraphic features, petrology and geochemistry and geochronology constraints of K-bentonites, ignimbrites and related volcanogenic rocks interbedded in the marine sedimentary sequence of the El Jagüelito Formation from northern Patagonia basement, southwestern Gondwana margin (41°33′S-65°15′W, South America). Six SHRIMP and ICP-MS U-Pb zircon ages from pyroclastic and volcanogenic sedimentary rocks indicate two stages of synsedimentary volcanism at c. 530 and c. 515 Ma which constraint the whole volcano-sedimentary pile to Early-Middle Cambrian. Distal volcanic ash fall deposits of K-bentonites and proximal pyroclastic flows of ignimbrites were erupted from three subaerial to subaqueous eruptive centers and are associated with volcanogenic facies and sub-volcanic intrusive equivalents. The volcanic rocks were deposited synchronously with on-going dynamic siliciclastic sedimentation into an actively subsiding basin.Dacitic K-bentonites and high-silica rhyolitic ignimbrites belong to the same high-K calc-alkaline/shoshonitic magma series and have a similar peraluminous signature. Their HFSE patterns with relative depletion in Nb, Sr, P, and Ti and the LREE-enriched patterns with a negative Eu anomaly indicate characteristics of subduction-related magmas associated with active continental arc magmatism. The geochemical discrimination diagrams together with geological features suggest an extensional tectonic setting for K-rich magmas within the overall convergent-margin system. Silicic, more potassic magmas with the inherited subduction-related character of the El Jagüelito Formation erupted on a back-arc basin. Their volcanic rocks are products of a mixture of fractionated mafic magmas and partial crustal melts. The integration of the Cambrian synsedimentary explosive volcanism of the El Jagüelito Formation with coeval magmatism of northern Patagonia led the interpretation to the continental scale of the paleo-Pacific margin of Gondwana by Early Paleozoic. The El Jagüelito Formation has provided consistent lithological, stratigraphic, geochemical and geochronological arguments to assess continental comparisons and a paleogeographic reconstruction between the eastern North Patagonian Massif and East Antarctica that fit in well the hypothesis that the northern Patagonia basement once occupied a position adjacent to East Antarctica. A series of geodynamic stages is proposed that allow for providing a Cambrian framework for understanding the magmatic arc-back arc system modified by episodic pulses of extension associated with slab-roll back which terminated in detachment of northern Patagonia from the East Antarctica continental margin by Late Cambrian. The several lines of geological evidence discussed in this paper point to a parautochthonous origin of the eastern North Patagonian Massif as an outboard assemblage that represents the conjugate margin of the Pensacola-Queen Maud-Ellsworth-Whitmore Mountains of Antarctica.

The spatial distribution of Mercury's pyroclastic activity and the relation to lithospheric weaknesses

Mercury's surface preserves a rich history of volcanism, impact cratering, and tectonic deformation. Geological observations show that the earliest evidence of thrust faulting that was induced by the secular cooling and resulting global contraction of the planet coincided with the waning stages of effusive volcanism, but that explosive volcanism continued beyond this point. Stresses from global contraction, however, would have precluded efficient vertical magma ascent. Sites of pyroclastic activity—manifest as irregular depressions surrounded by diffuse, spectrally distinct halos—spatially coincide with lithospheric discontinuities, such as faults or those associated with impact craters. The vast majority of explosive vents are situated on the floors, rims, central peaks, or peak rings of impact structures. A substantial portion of such vents is also proximal to thrust faults: they are most spatially concentrated at or within 20 km of faults, with ever fewer vents progressively farther from tectonic structures. We statistically evaluated the spatial distribution of sites of pyroclastic activity with respect to faults and impact craters by generating sets of random point locations of equal count to those volcanic sites, computing their spatial relationship to the mapped faults and craters, and comparing them to our observations. We find that although the observed proximity of vents to faults is indistinguishable from a random distribution, their spatial association with impact craters is non-random. To examine the interrelatedness of several geospatial relationships of lithospheric weaknesses and pyroclastic activity, we performed a principal component analysis that tested correlations between vent size, the presence of vents within a crater, the diameters and degradation states of those craters, and vent distance from mapped faults, which help tie together interpretations of magma volumes and eruption energies, repeated utilization of magma pathways, and durations of eruptive events in the geological context of global contraction. Results reveal a predominance of small-sized vents indicative of short-lived, low-volume pyroclastic activity that are consistent with suppressed volcanism after the onset of global contraction. Greater size ranges of vents are found in large impact craters and when faults are nearby, which points to denser fracture networks facilitating magma ascent.

Geology and Scientific Significance of the Rümker Region in Northern Oceanus Procellarum: China's Chang'E‐5 Landing Region

AbstractThe Rümker region (41–45°N, 49–69°W) is located in northern Oceanus Procellarum of the Moon. Mons Rümker is the most distinctive geological feature in the area. The region is characterized by prolonged lunar volcanism (Late Imbrian Period to Eratosthenian Period), forming multiple geologic units in the area, including very low‐Ti to low‐Ti mare basalts, high‐Ti mare basalts, and volcanic complexes. Each geologic unit has distinct element composition and mineral assemblages. The Rümker region, overlying the Procellarum KREEP Terrain, was selected as the landing region for China's Chang'E‐5 lunar sample return mission. Prelanding analyses of the geologic context and scientific potential are reported in this contribution. We conducted detailed geological mapping using image, spectral, and altimetry data. Fourteen geological units were defined, a geologic map was constructed, and the geologic history was outlined. The western mare units (Im1, Im2, and Im3) are Imbrian‐aged (~3.4–3.5 Ga) representing the major stage of lunar mare eruptive volcanism. The eastern young mare units (Em3 and Em4; <2 Ga) are among the youngest mare basalts on the Moon. They have never been explored in situ or studied in the laboratory. We suggest that samples returned from the eastern mare unit (Em4) could answer many fundamental questions and that this unit should be listed as the top priority landing site for Chang'E‐5 sample return mission.

The First Results of U–Pb Dating of the Nikolka Volcano (Central Kamchatka Depression)

U–Pb dating of zircon from amphibole latite of the central stock of the Nikolka shield volcano in Kamchatka provided the first data on its age. The end of activity falls to about 0.73 Ma (10 analyses). The local U–Pb analyses were carried out at the Isotope Research Center, Schmidt Joint Institute of Physics of the Earth (St. Petersburg) (VSEGEI) using SIMS SHRIMP II. Here, brief information about the geological structure, petrography, and chemistry of the rocks of the volcano are presented. A unique feature of the volcano is the occurrence of a gabbro–anorthosite sheet intrusion with derivates of monzonite and syenite composition in its central part. The correlation of the age obtained with the paleomagnetic data, indicating the formation of the volcano during the magnetic age of Matuyama, is also discussed. The date refers to the period of the change in epochs from the Brunhes to the Matuyama. The obtained age allows dating of the Pliocene volcanic stage in Kamchatka, when large shield volcanoes and plateaus formed.

Temporal constraints on magma generation and differentiation in a continental volcano: Buckland, eastern Australia

The eastern margin of the Australian continent hosts a large number of Cenozoic intraplate volcanoes along a 2000 km long track. Here, we study mafic lavas from the Buckland volcano, Queensland, located in the northern (older) segment of this track, to assess magma generation and differentiation through time. The rocks are aphanitic to microporphyritic basalts, trachy-basalts and basanites. Incompatible element geochemistry together with Sr-Nd-Pb isotope ratios indicate that magmas formed from an enriched mantle I (EMI)-like garnet-bearing source with variable degrees of crustal contamination. Whole rock elemental variations suggest fractionation of olivine, plagioclase, clinopyroxene and/or magnetite. There is no petrographic or geochemical evidence of magma mixing in the studied rocks (e.g., lack of recycled minerals), suggesting a relatively quick ascent from the source to the surface without major storage at shallow levels.40Ar/39Ar geochronology reveals two stages of volcanism: 30.3 ± 0.1 Ma and 27.4 ± 0.2 Ma. The Old Buckland (30.3 ± 0.1 Ma) melts have negative K anomalies, and incompatible element ratios suggest the occurrence of residual hydrous minerals in a metasomatised mantle source. We therefore infer that at the onset of volcanism, deep-mantle-derived magmas interacted with metasomatised sub-continental lithospheric mantle (SCLM). Major and trace element data, clinopyroxene thermobarometry and thermodynamic modelling indicate magma evolution by assimilation and fractional crystallisation (AFC) during ascent through the crust. Following a hiatus in volcanic activity of ~2.5 Ma, eruption of Young Buckland (27.4 ± 0.2 Ma) lavas marked a shift towards more alkaline compositions. Trace element compositions indicate lower degrees of partial melting and a lack of interaction with metasomatic components. Young Buckland lavas become progressively more SiO2-saturated up stratigraphy, suggesting an increase in the degree of partial melting with time. Young Buckland lavas also have more radiogenic 87Sr/86Sr and 207Pb/204Pb ratios and less radiogenic 143Nd/144Nd ratios up stratigraphy. These isotopic variations, together with coupled increases in Pb and K and decreases in Ce/Pb (27.22 to 11.09) and Nb/U (68.30 to 29.96), suggest that crustal contamination also increased with time.By placing absolute age and stratigraphic constraints on the Buckland lavas, we have been able to ascertain differentiation signatures imposed on mantle-derived melts during ascent through the continental lithosphere over 3 Ma. Our study provides new constraints on magma generation and differentiation in continental intraplate volcanic systems.

Mg isotope systematics during magmatic processes: Inter-mineral fractionation in mafic to ultramafic Hawaiian xenoliths

Observed differences in Mg isotope ratios between bulk magmatic rocks are small, often on a sub per mill level. Inter–mineral differences in the 26Mg/24Mg ratio (expressed as δ26Mg) in plutonic rocks are on a similar scale, and have mostly been attributed to equilibrium isotope fractionation at magmatic temperatures. Here we report Mg isotope data on minerals in spinel peridotite and garnet pyroxenite xenoliths from the rejuvenated stage of volcanism on Oahu and Kauai, Hawaii. The new data are compared to literature data and to theoretical predictions to investigate the processes responsible for inter–mineral Mg isotope fractionation at magmatic temperatures. Theory predicts up to per mill level differences in δ26Mg between olivine and spinel at magmatic temperatures and a general decrease in Δ26Mgolivine-spinel (=δ26Mgolivine – δ26Mgspinel) with increasing temperature, but also with increasing Cr# in spinel. For peridotites with a simple petrogenetic history by melt depletion, where increasing depletion relates to increasing melting temperatures, Δ26Mgolivine-spinel should thus systematically decrease with increasing Cr# in spinel. However, most natural peridotites, including the Hawaiian spinel peridotites investigated in this study, are overprinted by variable extents of melt-rock reaction, which disturb the systematic primary temperature and compositionally related olivine–spinel Mg isotope systematics. Diffusion, subsolidus re-equilibration, or surface alteration may further affect the observed olivine–spinel Mg isotope fractionation in peridotites, making Δ26Mgolivine-spinel in peridotites a difficult–to–apply geothermometer. The available Mg isotope data on clinopyroxene and garnet suggest that this mineral pair is a more promising geothermometer, but its application is restricted to garnet–bearing igneous (garnet pyroxenites) and metamorphic rocks (eclogites). Although the observed δ26Mg variation is on a sub per mill range in bulk magmatic rocks, the clearly resolvable inter–mineral Mg isotope differences imply that crystallization or preferential melting of isotopically distinct minerals such garnet, spinel, and clinopyroxene should cause Mg isotope fractionation between bulk melt and residue. Calculated Mg isotope variations during partial mantle melting indeed predict differences between melt and residue, but these are analytically resolvable only for melting of mafic lithologies, that is, garnet pyroxenites. Contributions from garnet pyroxenite melts may thus account for some of the isotopically light δ26Mg observed in ocean island basalts and trace lithological mantle heterogeneity. Consequently, applications for high-temperature Mg isotope fractionations are promising and diverse, and recent advances in analytical precision may allow the full petrogenetic potential inherent in the sub per mill variations in δ26Mg in magmatic rocks to be exploited.

Late Cryogenian arc-related volcaniclastic metasediment successions at Wadi Hammuda, Central Eastern Desert, Egypt: geology and geochemistry

Wadi Hammuda is dominated by a variety of low grade regionally metamorphosed volcaniclastic metasediments pertaining to two different geotectonic settings and intruded by arc and late collision granitic rocks. Thus, the volcaniclastic metasediments which form extensive outcrops are considered as a member of island arc assemblages. This paper deals with the petrography, geochemistry, and tectonic setting of the island arc volcaniclastic metasediment rock units. The volcaniclastic metasediments consist of interbedded metagreywackes, metasiltstones, metamudstones, and schists as well as metapyroclastics. They are well foliated, crenulated and tightly folded, metamorphosed, and intruded by granitic rocks. Geochemical data support the petrographic classification and reveal that these volcaniclastic metasediments are generally low-K, essentially tholeiitic in character, with the exception of some metasediments and metapyroclastics which exhibits calc-alkaline and tholeiitic affinities and represent the first stage of island arc volcanism. The overthrusted oceanic lithosphere blocks with fragments of the fore arc and/or back-arc marginal basins volcaniclastic metasediments were incorporated among the island arc volcanics which supported by tectonically relationship between the different rock units in the study area. Contemporaneous with this deformation event, Wadi Hammuda was subjected to low grade regional metamorphism and the rocks document an early phase of shearing and/or foliation. Occasionally minor folds were developed particularly in the metasediments and schists. The subsequent emplacement of the syn-tectonic granites (tonalites and granodiorites) resulted in minor local thrusts. During the regional thrusting event which preceded the emplacement of the late-tectonic granites (alkali feldspar granites) and affected the whole region, low grade successions cover the study area similar to the Meatiq volcaniclastic metasediments.

岩手火山 (薬師岳火山ステージ)における最近 3500年間のマグマプロセスの変遷

岩手火山 (薬師岳火山ステージ)における最近 3500年間のマグマプロセスの変遷

Spatial and temporal variability in Marquesas Islands volcanism revealed by 3He/4He and the composition of olivine-hosted melt inclusions

The Marquesas Islands are a volcanic chain having an oblique orientation to Pacific plate motion. They represent the surface manifestation of a mantle hotspot having a low melt flux and a large intrinsic chemical and isotopic heterogeneity. Here we provide new helium isotope data for olivine separated from 23 basalts and one gabbroic xenolith, plus whole rock major and trace element data for the same lavas. We also carried out trace element analyses of 41 olivine-hosted melt inclusions (OHMIs) from 15 of the basalts, and 40Ar/39Ar age determinations for basalt groundmass from the islands of Fatu Hiva and Hiva Oa. 3He/4He shows a large range of values from <5 RA up to 14.5 RA. Elevated 3He/4He ratios >9 RA are found at Nuku Hiva and Hiva Oa near the center of the archipelago, in agreement with previous findings (Castillo et al., 2007). The new ages for the Hiva Oa lavas indicate that 3He/4He increases from ~8 RA to 14.5 RA during the mid-late shield stage of volcanism (2.6–2.0Ma), followed by a decrease during the post-shield stage (<1.8Ma) after collapse of the Temetiu caldera. Lavas from Fatu Hiva, Ua Huka, Ua Pou, Tahuata and Motane have 3He/4He<8.3 RA, with values typically between 5 and 7 RA. Incompatible element ratios observed in the OHMIs show more variability than what is observed in the lavas because they represent a less extensive aggregation of melts derived from small scale chemical heterogeneities within the Marquesas mantle plume. The Cl/K ratio of OHMIs ranges from 0.02 to 0.4, potentially due to both mantle source heterogeneity and assimilation of brine or seawater-altered rocks at crustal levels. The geographic distribution of 3He/4He suggests the mantle plume is concentrically zoned in He isotope composition, with high 3He/4He material concentrated near its central axis that is sourced from hot, primitive material entrained near the core-mantle boundary region.

Zircon U–Pb geochronology and geochemistry of the Cerro Colorado porphyry copper deposit, northern Chile

Porphyry Copper Deposits (PCDs) dominantly form in convergent plate margins genetically related to volcanic arcs. However, their temporal relationships with active volcanism are less clear. Active volcanic activity is often considered to impede the formation of PCDs and some workers have concluded that PCD formation must take place at times of volcanic quiescence or at a waning stage of volcanism. However, several studies have documented evidence suggesting syn-eruption PCD formation. A combination of radiometric dating, geochemistry studies and observations of rock cores from the Cerro Colorado PCD, a BHP Billiton property located in N. Chile, provides evidence compatible with syn-volcanic PCD formation within a volcanic edifice.Textural observations at both hand specimen and microscopic scales combined with new LA-ICPMS and SHRIMP dating of zircons suggest the intrusive history of the Cerro Colorado area can be separated into two main units: a porphyritic tonalite ca. 53.5 Ma and a porphyritic quartz monzonite ca. 50 Ma. There is also evidence for crystallisation at ca. 60 Ma, but a corresponding distinct lithology was not identified. A quartz porphyry unit previously identified as the youngest intrusive body is reinterpreted as an altered equivalent of the monzonite. The youngest intrusive units are represented by porphyritic granodiorite with an age 51–50 Ma. These units only show minor metal mineralisation suggesting that the main phase of mineralisation in the Cerro Colorado mine occurred over a few million years, bracketed by the two main pulses of igneous intrusion, which are consistent with documented Ar–Ar ages. Re–Os ages reported by previous studies suggest an earlier phase of mineralisation at ca. 56–54 Ma. U–Pb dating of zircon from a volcanic-related breccia that cuts the host rocks of the Cerro Colorado Mine reveals a phase of volcanic activity at ca. 57 Ma, after formation of the regional Cretaceous Cerro Empexa Formation. This age range overlaps the ages derived for the intrusive porphyry units suggesting a close temporal relationship between volcanism and the ore-forming subvolcanic intrusions in Cerro Colorado. A link between active volcanism and mineralisation is reinforced by the ultrafine-grained matrix and the presence of strong brecciation associated with the monzonite-quartz porphyry stock suggesting decompression and volatile release have taken place during emplacement.

Emplacement dynamics and hydrothermal alteration of the Atengo ignimbrite, southern Sierra Madre Occidental, northwestern Mexico

The Sierra Madre Occidental is a thick continental arc related to the subduction of the Farallon plate beneath North America resulting in a very intense and widespread Cretaceous to Cenozoic magmatic and tectonic activity. The 28 My old Atengo ignimbrite outcrops in the southern Sierra Madre Occidental, northwestern Mexico. From 12 sites that belong to various pyroclastic and lava flows emplaced during two pulses in the Oligocene (ca. 32–28 Ma) and Early Miocene (ca. 24–20 Ma), 97 rock specimens were drilled. The mineralogical and rock magnetic properties of the Atengo ignimbrite are compared with the surrounding volcanic rocks to identify the eruption mechanism, and with the El Castillo Ignimbrite, Veracruz, Mexico, to understand the depositional conditions. The comparisons reveal that the Atengo ignimbrite erupted from a single source, but less violently than the El Castillo ignimbrite, and cooled rapidly, inhibiting the formation of subhedral grains. The source of the Atengo Ignimbrite was a Plinian-type eruption, and the characteristic mineralogical and textural properties of each flow are related to different stages of the Plinian-type eruption. Further more, hydrothermal fluids were active during the last stages of volcanism, and caused moderate to intense alteration, especially in the ignimbrites, where high permeability aided the movement of hydrothermal fluids.

Cenozoic Shift From Compression to Strike‐Slip Stress Regime in the High Andes at 30°S, During the Shallowing of the Slab: Implications for the El Indio/Tambo Mineral District

AbstractIn the High Andes of central Chile, above the flat‐slab segment, analysis of more than 1,000 fault slip data from Miocene outcrops provides evidence for a change of the regional tectonic regime from compressional to strike slip. This shift in tectonic regime occurred during the waning stages of arc volcanism between 14 and 11 Ma, as a result of the shallowing of the Nazca plate, in conjunction with the migration of deformation to the Precordillera. During the early to middle Miocene, a compressive regime with horizontal σ1 axis (N86°E) was responsible for reverse slip along NNE to N‐striking faults. During the late Miocene, a shift to strike‐slip tectonics took place due to an increase in the absolute magnitude of the vertical stress component as the crust thickened and the gravitational potential energy increase. We argue that instead of the previously accepted highly compressional setting in the arc region during the slab flattening, the change to a strike‐slip regime was the main control on mineralization. Mineralization was controlled by the promotion of fluid expulsion from the magma chambers along active, subvertical strike‐slip fault systems with a high slip tendency, and focusing of fluids in localized areas undergoing extension. Under this strike‐slip regime, the El Indio, Tambo, and La Despensa fault systems formed as dextral strike‐slip systems. The tips and jogsites along these faults experienced local extensional stress fields, forming the El Indio and Tambo mineral districts.

Physicochemical models of formation of gold–silver mineralization at the Rogovik deposit (Northeastern Russia)

The T,X-parameters of the main ore-forming stages of the Rogovik epithermal gold-silver deposit (northeastern Russia) were determined using microthermometric techniques on fluid inclusion assemblages. On the basis of these data we carried out thermodynamic calculations that model the formation conditions of three types of ore mineral assemblages: gold-silver – at the early volcanic stage, silver-polymetallic and silver-gold-polymetallic – at the late volcanoplutonic stage. The silver-gold-polymetallic mineralization is located at the sites where silver-polymetallic and gold-silver zones overlap. The calculations were made using the “Selektor-C” software within a complex geochemical multicomponent system. Several scenarios of formation of gold-silver mineralization at an early volcanic stage were considered: 1) boiling of a hydrothermal solution; 2) interaction of residual aqueous solution with host rocks; 3) mixing of an ore-bearing gas phase with meteoric waters. For the late volcanoplutonic stage, we modeled formation of “silver mineralization” using an ore-forming solution genetically related to a deep-seated granite massif and its interaction with host rocks and gold-silver zones of early volcanic stage. These physicochemical models substantially improve our understanding of formation of the three types of mineral assemblages at the Rogovik deposit and can be applied to other epithermal deposits with similar mineralization styles.

Eclogite trace in evolution of Late Cenozoic alkaline basalt volcanism on the southwestern flank of the Baikal Rift Zone: Geochemical features and geodynamic consequences

Eclogitized material from the oceanic lithosphere are the most likely source of alkaline basalt magmas in the formation of Late Cenozoic volcanic areas on the southwestern flank of the Baikal Rift Zone. Basaltic trachyandesites of the early stage of volcanism (Pg32 ~ 28–23 Ma) are rich in high field strength elements (HFSE), P2O5, F, Zn, Ga, Sr, Sn, and light rare earth elements (LREE); they are characterized by high values of the following ratios: Fe/Mn = 72–77, Sm/Yb = 7.7–8.5, Sr/Y = 57–63, and Ga/Sc = 2.1–2.3. At this stage, magmas are formed under conditions with a 2–8% degree of partial melting of the mantle substrate enriched with the material of the eclogite source (50–70%) (Cpx/Grt = 1.5–1.7). Basaltoid magmas of the final stage of volcanism (N13–N21 ~ 6–4 Ma) are formed from melting (1.5–4%) of a less fertilized mantle (Cpx/Grt = 2.1–3.1, Fe/Mn = 62–71, Sm/Yb = 3.5–4.6, Sr/Y = 29–44, Ga/Sc = 1.0–1.4). The directed variations of the compositions of the successive basaltoid magmas, which were formed in the Late Cenozoic, create an “eclogite trace” in this area.

Geochemistry of obsidian from Krasnoe Lake on the Chukchi Peninsula (Northeastern Siberia)

This report considers features of the geochemical composition of obsidian from beach sediments of Krasnoe Lake along the lower course of the Anadyr River, as well as from lava–pyroclastic rocks constituting the lake coastal outcrops and the surrounding branches of Rarytkin Ridge. The two geochemical types of obsidian, for the first time distinguished and researched, correspond in their chemical composition to lavas and ignimbrite-like tuffs of rhyolites from the Rarytkin area. The distinguished types represent the final stage of acidic volcanism in the West Kamchatkan–Koryak volcanic belt. It was assumed that the accumulation of obsidian in coastal pebble beds was caused by the erosion of extrusive domes and pyroclastic flows. The geochemical studies of obsidian artifacts from archeological sites of the regions of the Sea of Okhotsk, the Kolyma River, and the Chukchi Peninsula along with the correlation of geological and archeological samples show that Krasnoe Lake was an important source of “archeological” obsidian in Northeastern Siberia.

Geology, U-Pb geochronology, and stable isotope geochemistry of the Tunca semi-massive sulfide mineralization, Black Sea region, NE Turkey: Implications for ore genesis

Upper Cretaceous volcano-sedimentary sequences of the Eastern Pontide orogenic belt, NE Turkey, are host to significant VMS mineralization, including near Tunca. The initial stages of felsic volcanism within the mineralized area are marked by the eruption of dacitic lavas and breccias of the Kızılkaya Formation. This was accompanied by the emplacement of domelike hematitic dacites. Autobrecciated and volcaniclastic rocks, both in situ and resedimented, were likely generated from extrusive portions of these dacite bodies. Basaltic volcanism is marked by the eruption of the lava flows and pillow lavas of the Çağlayan Formation. Hiatuses in basaltic activity are marked by thin horizons of volcaniclastics and mudstones. The uppermost felsic volcanic units were accompanied by resedimentation of autoclastic facies from previous volcanism and represent the latest phase of Upper Cretaceous volcanism in the area. The semi-massive sulfide mineralization is associated with a late stage of the initial felsic volcanism. U-Pb LA-ICP-MS zircon dating of a dacitic tuff breccia yielded an age of 88.1±1.2Ma (Coniacian-Upper Cretaceous), which is interpreted to be the age of the sulfide occurrences.A concentric zoned alteration pattern is observed in the footwall rocks. The alteration pattern is considered to have formed by lateral migration of hydrothermal fluids which had ascended along the discharge conduit. Fluid inclusion data indicate precipitation or mobilization processes within a relatively narrow temperature range of 152–255°C (avg. 200°C). The low-salinity fluids in the fluid inclusions, less than 5.9wt% NaCl equivalent, are consistent with typical modified seawater-dominant hydrothermal vent fluids. Sulfur isotope analysis of the Tunca sulfides yields a narrow range of 1.5–4.1per mil. These δ34S values are also typical of many VMS deposits. Most of the recorded δ18O values (+7.1 to +14.0permil) are greater than 9per mil. The most intensely hydrothermally altered rocks tend to have lower δ18O values relative to the less altered rocks. Collectively, the geologic relationships, mineralization style, and the lack of seafloor ore facies suggest that mineralization is principally of sub-seafloor origin. The most geologically reasonable interpretation of the genesis of the Tunca mineralization is the continuous interaction between the host rocks and seawater-derived fluids, without significant involvement of a magmatic fluid.

Geophysical evidence for the crustal variation and distribution of magmatism along the central coast of Mozambique

For our understanding of the timing and geometry of the initial Gondwana break-up, still a consistent image of the crustal composition of the conjugated margins of central Mozambique and Antarctica and the location of their continent-ocean boundaries is missing. In this regard, a main objective is the explanation for the source of the different magnetic signature of the conjugate margins. Based on a revised investigation of wide-angle seismic data along two profiles across the Mozambican margin by means of an amplitude modelling, this study presents the crustal composition across and along the continental margin of central Mozambique. Supported by 2D magnetic modelling, the results are compared to the conjugate margin in Antarctica and allow new conclusions about their joined tectonic evolution. An observed crustal diversity between the north-eastern and south-western parts of the central Mozambican margin, testifies to the complex break-up history of this area. Conspicuous is the equal spatial extent of the HVLCB along the margin of 190–215km. The onset of oceanic crust at the central Mozambican margin is refined to chron M38n.2n (164.1Ma). Magnetic modelling supports the presence of reversed polarized SDRs in the continent-ocean transition that were mainly emplaced between 168.5 and 166.8Ma (M42–M40). Inferred SDRs in the Riiser-Larsen Sea might be emplaced sometime between 166.8 and 164.1Ma (M39–M38), but got overprinted by normal polarized intrusions of a late stage of rift volcanism, causing the opposite magnetic signature of the conjugate margins. The distribution of the magmatic material along the central coast of Mozambique clearly indicates the eastern extension of the north-eastern branch of the Karoo triple rift along the entire margin. The main magmatic phase affecting this area lasted for at least 12Myr between 169 and 157Ma, followed by the cease of the magmatism, perhaps due to the relative southwards motion of the magmatic centre.

Iron mineralization at the Songhu deposit, Chinese Western Tianshan: a type locality with regional metallogenic implications

Hosted by volcaniclastics of the Carboniferous Dahalajunshan Formation, the Songhu iron deposit is located in the central segment of the Awulale metallogenic belt, Chinese Western Tianshan. Mineralization and alteration are structurally controlled by orogen-parallel NWW-striking faults. Integrating with mineralogical and stable isotopic analyses based on paragenetic relationships, two types of iron mineralization have been identified. The deuteric mineralization (Type I) represented by brecciated, banded, and disseminated-vein ores juxtaposed with potassic–calcic alteration in the inner zone, which was formed from a magmatic fluid generated during the late stages of regional volcanism. In contrast, the volcanic-hydrothermal mineralization (Type II) is characterized by hydrothermal features occurring in massive and agglomerated ores with abundant sulfides, and was generated from the magmatic fluid with seawater contamination. Two volcaniclastic samples from the hanging and footwall of the main orebody yield zircon U–Pb ages of 327.8 ± 3.1 and 332.0 ± 2.0 Ma, respectively, which indicate Middle Carboniferous volcanism. Timing for iron mineralization can be broadly placed in the same epoch. By reviewing geological, mineralogical, and geochemical features of the primary iron deposits in the Awulale metallogenic belt, we propose that the two types of iron mineralization in the Songhu iron deposit are representative regionally. A summary of available geochronological data reveals Middle–Late Carboniferous polycyclic ore-related volcanism, and nearly contemporaneous iron mineralization along the belt. Furthermore, petro-geochemistry of volcanic–volcaniclastic host rocks indicates that partial melting of a metasomatized mantle wedge under a continental arc setting could have triggered the continuous volcanic activities and associated metallogenesis.

Shallow crustal velocities and volcanism suggested from ambient noise studies using a dense broadband seismic network in the Tatun Volcano Group of Taiwan

The Tatun Volcano Group (TVG) is situated adjacent to the Taipei metropolis and was active predominantly around 0.8–0.2Ma (Pleistocene). Various recent lines of evidence suggest that the TVG is a potentially active volcano and that future volcanic eruptions cannot be ruled out. Geothermal activities are largely constrained to faults, but the relationship between volcanism and detailed velocity structures is not well understood. We analyzed ambient seismic noise of daily vertical components from 2014 using a dense seismic network of 40 broadband stations. We selected a 0.02° grid spacing to construct 2D and 3D shallow crustal phase velocity maps in the 0.5–3s period band. Two S-wave velocity profiles transect Chishingshan (Mt. CS) in the shallow 3km crust are further derived.The footwall of the Shanchiao Fault is dominated by low velocity, which may relate to Tertiary bedrock buried under andesitic lava flows dozens to hundreds of meters thick. The hanging wall of the Shanchiao Fault is the location of recent major volcanic activities. Low velocity zones in the southeast of Dayoukeng (DYK) may be interpreted as hydrothermal reservoirs or water-saturated Tertiary bedrock related to Cenozoic structures in the shallow crust. High velocities conspicuously dominate the east of the TVG, where the earliest stages of volcanism in the TVG are located, but where surface hydro-geothermal activities were absent in recent times. Between the Shanchiao Fault and Kanchiao Fault high velocities were detected, which converge below Mt. CS and may be related to early stages of magma conduits that gradually consolidated. These two faults may play a significant role with the TVG. The submarine volcanism adjacent to the Keelung coastline also requires further attention.

Recurrent Early Cretaceous, Indo-Madagascar (89–86 Ma) and Deccan (66 Ma) alkaline magmatism in the Sarnu-Dandali complex, Rajasthan: 40Ar/39Ar age evidence and geodynamic significance

The Sarnu-Dandali alkaline complex in Rajasthan, northwestern India, is considered to represent early, pre-flood basalt magmatism in the Deccan Traps province, based on a single 40Ar/39Ar age of 68.57Ma. Rhyolites found in the complex are considered to be 750Ma Malani basement. Our new 40Ar/39Ar ages of 88.9–86.8Ma (for syenites, nephelinite, phonolite and rhyolite) and 66.3±0.4Ma (2σ, melanephelinite) provide clear evidence that whereas the complex has Deccan-age (66Ma) components, it is dominantly an older (by ~20millionyears) alkaline complex, with rhyolites included. Basalt is also known to underlie the Early Cretaceous Sarnu Sandstone. Sarnu-Dandali is thus a periodically rejuvenated alkaline igneous centre, active twice in the Late Cretaceous and also earlier. Many such centres with recurrent continental alkaline magmatism (sometimes over hundreds of millions of years) are known worldwide. The 88.9–86.8Ma 40Ar/39Ar ages for Sarnu-Dandali rocks fully overlap with those for the Indo-Madagascar flood basalt province formed during continental breakup between India (plus Seychelles) and Madagascar. Recent 40Ar/39Ar work on the Mundwara alkaline complex in Rajasthan, 120km southeast of Sarnu-Dandali, has also shown polychronous emplacement (over ≥45millionyears), and 84–80Ma ages obtained from Mundwara also arguably represent post-breakup stages of the Indo-Madagascar flood basalt volcanism. Remnants of the Indo-Madagascar province are known from several localities in southern India but hitherto unknown from northwestern India 2000km away. Additional equivalents buried under the vast Deccan Traps are highly likely.