Visible Range Of Spectrum Research Articles

Black Jamun Fruit Peel Extract Modified Gum Acacia Biopolymer Suitable for Energy Device Applications via Charge Transfer Enhancement

The visible light absorption capabilities, along with its electrical characteristics, of a low-cost, plant-based, biopolymer, gum acacia, have been chemically modified by tailoring its defect concentrations via pH modification, where the acid solvent of fruit (peel) extracts of jamun was used to influence the chemical structure by reactive modification. Ultraviolet-visible and photoluminescence spectroscopy of the gum acacia biopolymer treated with the extracted anthocyanin from jamun peel showed a prominent, characteristic red shift in the visible spectrum range. Impedance spectroscopy analysis showed the occurrence of localized ionic conduction. The bulk conductivity of the modified specimens increased due to the profound release of conducting ions in the water-swollen network. The reactively modified biopolymer could be used in multiple fields of material science, specifically in energy device applications, viz., photovoltaics (PV), by utilizing its cost effectiveness and photolytic effectiveness. 2nd, as a polymer electrolyte and dye-sensitised solar cells (DSSCs) material by utilizing its capacity of gel formation. In our research described in this article, the underlying charge transfer mechanism for such responses was examined after crosslinking in the organic dyes extracted from the peel of jamun fruit with gum acacia.

First principles study of point defects and Li doping on the electronic structure and photovoltaic performance of single-layer GaN

The preparation of single-layer GaN by chemical vapor deposition inevitably generates H interstitials. In this study, the optical properties of single-layer Ga36N36, Ga34LiN36 and Ga34HiLiN36 (0 0 1) surfaces were investigated by using the first-principles method. In the presence of Li doping and H interstitial, the dielectric function and reflectivity red-shifted in the low-energy range and the dielectric function and reflectivity of the Ga36N36 improved. In the visible range of the absorption spectrum, the impurity-containing surfaces red-shifted, and the light absorption on the Ga36N36 improved. The Ga34HiLiN36 (0 0 1) surface performed better as a photovoltaic material than other surfaces.

Visible Light Active 0.95KNbO3‐0.05Ba(Nb1/2Sc1/2)O3 Ferroelectric for Enhanced Photocatalytic Activity

AbstractThis study reports a visible light active Ba/Sc co‐doped potassium niobate (KNbO3) ferroelectric material for enhanced photocatalytic applications. Through 5% Ba and Sc co‐doping in KNbO3 (i.e., 0.95KNbO3‐0.05Ba(Nb1/2Sc1/2)O3), the electronic band gap (Eg) is narrowed down to the visible range of the solar spectrum. The prepared samples are systematically examined by using X‐ray diffraction and Raman spectroscopy, which confirms the successful incorporation of Ba and Sc ions into the KNbO3 lattice. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) analysis reveal particle morphology and chemical homogeneity of prepared samples. The UV–vis spectroscopy and ferroelectric PE‐loop demonstrate enhanced optical absorption compared to host KNbO3 while retaining ferroelectric behavior. The photoelectrochemical (PEC) measurements under visible light irradiation demonstrate a notable enhancement in the photocurrent for 0.95KNbO3‐0.05Ba(Nb1/2Sc1/2)O3 (hereafter denoted by 5KBSNO) compared to undoped KNbO3. Additionally, the 5KBSNO sample displays enhanced RhB dye degradation efficiency, reaching ≈50% compared to parent KNbO3 (≈30%) under light irradiation. First‐principles density functional theory (DFT) calculations are employed to understand the mechanism responsible for the reduced band gap. This study presents a promising material for developing advanced ferroelectric photocatalysts with tailored band structures for efficient solar energy harvesting for energy conversion and contamination remediation applications.

Mechanoluminescence and Optically Stimulated Antistokes Luminescence of Composites Based on Epoxy Resin and Strontium Aluminate Phosphors SrAl<sub>2</sub>O<sub>4</sub>:Eu<sup>2+</sup>,Dy<sup>3+</sup> and Sr<sub>4</sub>Al<sub>14</sub>O<sub>25</sub>:Eu<sup>2+</sup>, Dy<sup>3+</sup>

Composite mechanoluminescent materials (composites) based on epoxy resin transparent in the visible range of spectrum and fine-dispersed powders of mechanoluminescent phosphors SrAl2O4:Eu2+, Dy3+ and Sr4Al14O25:Eu2+, Dy3+ were obtained. The mechanoluminescence and photoluminescence spectra of composites under the combined influence of short-wave (λ = 405 nm) and long-wave (λ = 1.06 µm) laser radiation were studied. The attenuation of optically stimulated antistokes luminescence of the composite under the influence of a sequence of pulses of longwave laser radiation was investigated. The composite was pre-irradiated with shortwave laser radiation. The obtained composite was used to visualize heat propagation and thermal deformations in metal plates arising under the action of powerful laser pulses and distribution of deformations under mechanical impact. For this purpose, a thin layer of the composite was applied to the surface of the materials under study. The composite had good adhesion to the surface of the materials and a high yield of mechanoluminescence, which allowed to visualize the distribution of temperature and surface deformations with a good spatial and temporal resolution.

Transition Metal‐Derived 2D Layered Perovskites: A Promising Alternative to Pb in Photovoltaic Systems

AbstractThe high sensitivity of 3D perovskites toward air and moisture hampers their commercialization due to material decomposition. Introducing their 2D counterparts may provide a remedy to these stability issues, as hydrophobic bulky organic cations can resist direct contact of [ sheets with moisture in the air. In addition to air and water stability, 2D perovskites offer tunable optoelectronic properties through structural modulation, similar to their 3D counterparts. In this study, six different transition metal (TM)‐based 2D hybrid halide perovskites are designed: , , , , , and as alternatives for Pb‐based perovskites. Analysis of structural and thermodynamic parameters demonstrate that these designed perovskite materials can form structurally and thermodynamically stable compounds. Additionally, optical properties analysis reveals that the intended compounds exhibit absorption maxima in the visible range of the electromagnetic spectrum. Among the designed compounds, shows a promising power conversion efficiency (PCE) of 19.63%. Thus, these designed 2D perovskite materials hold potential as substitutes for conventional 3D materials in photovoltaic applications.

A comprehensive study of laser irradiated hydrothermally synthesized 2D layered heterostructure V2O5(1−x)MoS2(x) (X = 1–5%) nanocomposites for photocatalytic application

Abstract It has been studied that both two-dimensional (2D) MoS2 and V2O5, which are classified as transition metal dichalcogenides and transition metal oxides, are good photocatalyst materials. For this purpose, the hydrothermal method was practiced to synthesize V2O5(1−x)MoS2(x) (X = 1–5% w/w) nanocomposites with different 1–5% w/w weight percent of MoS2 as a prominent photocatalyst under laser irradiation for 2, 4, 6, 8, and 10 min to tune photocatalytic degradation of industrial wastage water. The surface of the 2D molybdenum nanolayered matrix was efficaciously decorated with V2O5 nanoparticles. The crystal phase and layered structures of the V2O5(1−x)MoS2(x) (X = 1–5% w/w) nanocomposites samples were verified by X-ray diffraction and scanning electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy respectively. In the range of the UV visible spectrum, the increment in light absorption from 3.6 to 14.5 Ω−1 cm−1 with an increase of active surface from 108 to 169 μ m 2 {{\rm{\mu }}{\rm{m}}}^{2} with increased MoS2 doping percentage. Furthermore, dielectric findings like the complex dielectric function, tangent loss, electrical conductivity, quality factors, and impedance of V2O5(1−x)MoS2(x) (X = 1–5% w/w) nanocomposites are studied. According to photoluminescence studies, the intensity of peaks decreases when laser irradiation time and doping percentages of MoS2 are increased. As a result, a small peak indicates a decrement rate of electron–hole pair recombination, which increases the capacity for separation. Thermo-gravimetric analysis and differential thermal analysis results revealed that weight loss decreased from 0.69 to 0.35 mg and thermal stability increased with increased doping concentrations. Methylene blue was degraded in 150 min, proving that the prepared MoS2-doped V2O5 material was a stable and economically low-cost nanocomposite for photocatalytic activity.

Near-infrared and multifunctional fluorescent probe enabled by cyanopyridine cyanine dye for bisulfite recognition and biological imaging

SO2 derivatives, sulfite/bisulfite, are widely employed in both the food processing and drug synthesis industries. Despite their widespread application, excessive levels of sulfite/bisulfite can negatively impact human health. Most probes for detecting sulfite/bisulfite are restricted by their fluorescence within the visible spectrum range and poor solubility in aqueous solution, which limit their use in food testing and biological imaging. Herein, a near-infrared probe comprising of the cyanopyridine cyanine skeleton, 4-((Z)−2-((E)−2-chloro-3-(2-cyano-2-(1-methylpyridine-4(1H)-ylidene)ethylidene)cyclohex-1-en-1-yl)−1-cyanovinyl)−1-methylpyridin-1-ium (abbreviated as CCP), was developed. This probe enables precise quantification of bisulfite (HSO3-) in almost pure buffered solutions, showing a near-infrared fluorescence emission at 784 nm with an impressively low detection limit of 0.32 μM. The probe stands out for its exceptional selectivity, minimal susceptibility to interference, and strong adaptability. The probe CCP utilizes the CC bond to trigger a near-infrared fluorescence quenching reaction with HSO3- via nucleophilic addition, which effectively disrupts the large delocalization within the molecule for accurate HSO3- identification. Moreover, the probe has been successfully applied in detecting HSO3- in various food products and living cells, simplifying the measurement of HSO3- content in water samples. This advancement not only enhances the analytical capabilities but also contributes to ensuring food safety and environmental protection. Environmental ImplicationSO2 derivatives including sulfite/bisulfite, serving dual roles as preservatives and antioxidants, have widespread application across various sectors including food preservation, water sanitation, and the pharmaceutical industry. Despite their widespread application, excessive levels of sulfite/bisulfite can affect human health. Developing methods for precisely and sensitively detecting sulfite/bisulfite in food products and biological samples is important for ensuring food safety and environmental protection. Here, a sensitive near-infrared and multifunctional fluorescent probe in a 99.9 % buffered solution, along with water gel encapsulation, has been successfully applied for the detection of bisulfite in food, authentic water samples, and biological cells.

Green-assisted synthesis of highly defective nanostructured Fe-doped SnO2: Magnetic and photocatalytic properties evaluation

Here we present a comprehensive characterization of the properties of undoped and Fe-doped SnO2 nanoparticles prepared with Syzygium cumini leaves extract. The phytochemicals present in the leaves extract act as cation chelating and capping of the nanoparticles. It is observed a relative high concentration of tin (up to 10 %) and oxygen (up to 5%) vacancies promoted by surface adsorbed OH− and by Fe-doping, respectively. The magnetic characterization reveals a ferromagnetic with a saturation monetization up to 20×10−3 emu/g for the higher defective and Fe-doped sample. This behavior associated mainly to tin vacancies for the undoped samples, and to the formation of bound magnetic polarons between the incorporated Fe and the oxygen vacancies for the doped samples. Oxygen vacancies and incorporated Fe improve the SnO2 photocatalytic efficiency in the visible range of the electromagnetic spectrum by decreasing the SnO2 effective bandgap from 3.6 eV for the undoped SnO2 sample to only 1.9 eV for the Fe-doped SnO2 sample, and by acting as electron-trapping centers increasing the system quantum efficiency. Due to the ferromagnetic behavior of the studied samples, it was also considered the effect of spin-dependent processes in the observed photocatalytic improvement. Our results highlight the key role of defect engineering strategies to optimize the physical and chemical properties of semiconductor oxides for application in the development of spintronic and quantum information devices, and in systems devoted to wastewater purification through advanced oxidation processes.

Nitrophenol Reduction with Silver Oxide Nanostructures as a Sustainable Approach to Environmental Remediation.

We propose silver oxide as a cost-effective and sustainable alternative to noble metals for the catalytic reduction of nitroaromatics. In the present investigation, we adopt a facile and green synthetic route for the synthesis of silver oxide nanostructures. The prepared nanostructures were found to crystallize in the cuprite phase and exhibit absorbance across the entire visible range of the electromagnetic spectrum. The catalytic potential of the silver oxide was evaluated by following the kinetics of nitrophenol reduction under ambient conditions and is observed to follow pseudo-first order kinetics with the apparent rate constant s-1 at minimum concentration of the catalyst. We attribute the observed catalytic activity to the freshly generated catalytic surface featuring a partially reduced form of silver oxide during reaction. The findings highlight the efficacy of silver oxide in mitigating the environmental pollution originating from the recalcitrant nitroarenes.

Optical and electrophysical properties of nitride TiAlSiN and carbonitride TiAlSiCN coatings: influence of reactive magnetron deposition regimes

The development of thin-film thermal control coatings for small spacecraft is relevant. Coatings based on titanium nitride are capable of functioning in unfavorable conditions of near and deep space, due to their high resistance to the irradiation by high-energy particles. Using the reactive magnetron sputtering method, the nanostructured TiAlSiN and TiAlSiCN coatings were formed on the substrates of silicon oxide (SiO2), glass-ceramic CT-1 and single-crystalline silicon (Si(100)). A study of the electrophysical and optical properties of the formed coatings was carried out. The deposited coatings demonstrate a good reflectivity in the infrared range of spectrum (700–2000 nm), what is important for reducing the overheating of the spacecraft (SC) under the influence of the direct sunlight. In the visible range of spectrum (400–700 nm), a low level of total Rtotal reflection is observed. This is promising for satellites designed to observe the Earth’s surface. The values of solar absorption coefficients αs, emissivity coefficients ε0, ratios αs/ε0, as well as the equilibrium temperature Tр for the samples under study were obtained. The values of resistivity ρ and surface resistance R□, electron concentration N and electron mobility μ were determined. It has been discovered that TiAlSiN, TiAlSiCN films are electrically conductive: ρTiAlSiN = (92÷4260) ∙ 10–7 Ω ∙ m, ρTiAlSiCN = (51÷2360) ∙ 10–7 Ω ∙ m. It has been found that adding carbon to the coating composition reduces the resistance. The obtained nanostructured coatings of TiAlSiN nitride and TiAlSiCN carbonitride can be used as temperature control coatings for small spacecrafts.

Investigation of optical parameters in Ge source SELBOX tunnel FET under visible spectrum

In this work, we have implemented Ge source Selective buried oxide (SELBOX) Tunnel FET for photo sensing applications in the visible range of spectrum for wavelength (λ = 300–700) nm. The various electrical parameters are extracted under dark and illumination states considering the presence and absence of trap charges at the interface of gate oxide and semiconductor. It is seen that at illumination state, the drain current degrades at low gate voltage and presence of traps lead to reduced tunnelling rate. Further, the spectral sensitivity, responsivity, and signal to noise ratio (SNR) are extracted for this TFET based photosensor with variation in λ. Result reveals that spectral sensitivity, responsivity, and signal to noise ratio (SNR) are 20.8, 0.5, and 49.5 dB, respectively, at λ = 300 nm. Further, the presence of trap charges result in degradation of these parameters. Finally, a comparative study of optical parameters with the existing data is highlighted.

Synthesis of bismuth vanadate by laser ablation in liquid route and its structural and optical characterization

In this work, a bottom up route was developed to obtain BiVO4 by dissociation of precursors by laser ablation. The process consisted of using a laser beam focusing on a mixture of bismuth oxide in an ammonium metavanadate solution under agitation. The precipitate obtained demonstrated high crystallinity as evidenced by the narrow peaks in the x-ray diffraction pattern and 20 nm crystallite size calculated by the Scherrer equation, approximately, and the presence of monoclinic Scheelite and tetragonal zirconia-like phases mixing. Particles showed a certain degree of agglomeration with size ranging from 400-200 nm according to SEM images. The Raman spectra showed the typical vibrational modes of mixed phases, which only changed into monoclinic scheelite after being calcined at 500 °C. The band gap was determined using Tauc plot and revealed a 2.5 eV energy band gap with a well-defined band in the visible range of spectrum for monoclinic phase samples material thermally treated. Photoluminescence results demonstrated low recombination rate for electron-hole pair indicating could be suitable in photocatalysis.

Multilayer Fe3O4-doped ITO indium saving indium tin oxide thin films

Multilayer Fe3O4-doped indium saving indium-tin oxide (ITO) thin films were fabricated by sputtering method. Double-layered Fe3O4-doped indium saving indium-tin oxide (ITO) thin films consisted of 12 nm layer of conventional indium tin oxide (90 mass% In2O3 and 10 mass% SnO2) and 138 nm layer of indium saving indium-tin oxide (50 mass% In2O3, 50 mass% SnO2 and Fe3O4-doped) were grown on preheated at 523 K glass substrates. Obtained polycrystalline ITO thin films exhibit volume resistivity of 416 µΩcm, electron mobility 28 cm2/V·s, carrier density 5.3 × 1020 cm−3 and average optical transmittance above 85% in visible range of spectrum.

Copper oxide nanoparticles (CuO-NPs) as a key player in the production of oil-based paint against biofilm and other activities

Copper oxide nanoparticles are among the metal nanoparticles gaining popularity in many biotechnological fields, particularly in marine environments. Their antimicrobial and antibiofilm activities make them appealing to many researchers. Among the various methods of producing nanoparticles, biosynthesis is crucial. Thus, a large number of reports have been made about the microbiological manufacture of these nanoparticles by bacteria. Nevertheless, bio-production by means of the cell-free supernatant of marine bacteria is still in its primary phase. This is landmark research to look at how bacteria make a lot (14 g/L) of copper oxide nanoparticles (CuO-NPs) via the cell-free supernatant of Bacillus siamensis HS, their characterization, and their environmental and medical approaches. The biosynthesized nanoparticles were characterized using a UV–visible spectrum range that provides two maximum absorption peaks, one obtained at 400 nm and the other around 550–600 nm. Diffraction of X-rays (XRD) clarifies that the size of the NPs obtained was estimated to be 18 nm using Debye-Scherrer's equation. Scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDX) displays 91.93 % copper oxide purity. The Transmission Electron Microscope (TEM) image proves that the particles have a spherical form and an average diameter of 6.54–8.60 nm. At the environmental level, nanoparticles incorporated into oil-based paint can be used as antibiofilm tools to diminish the biofilm formed on the submerged surface in the marine environment. In disease management, NPs can be used as a wound healing agent to reduce the wound gap size as well as an anti-tumour agent to control liver cancer cells (hepatoma cells (HepG2)).

Anti-resonant hollow core fiber with excellent bending resistance in the visible spectral range

The development of wideband guided hollow-core anti-resonant fiber (HC-ARF) that covers the sensitive range of the human eye's visible spectrum is progressing rapidly. However, achieving low-loss wideband transmission with a small bending radius remains a challenging issue to be addressed. In light of this, we propose a novel, to our knowledge, HC-ARF with a nested double-semi-elliptical cladding structure in the visible spectral region. By employing finite element method simulations, we investigate the confinement loss, bending loss, and single-mode performance of this fiber design. The result shows that the confinement loss of this new fiber exhibits below 10−5 dB·m-1 across almost the entire visible band range, with a minimum loss of 1.55 × 10−7 dB·m-1 achieved for λ = 650 nm. Furthermore, this fiber demonstrates excellent resistance to bending and can maintain an ultra-low bending loss as low as 3 × 10−7 dB·m-1 even under extreme bending conditions with a radius of only 3 cm. Notably, its 3-dB bending radius reaches just 3.5 cm for λ = 532 nm. Additionally, it exhibits outstanding single-mode conductivity under various bending scenarios and achieves a high extinction ratio of up to 104 for higher-order modes after parameter optimization for specific wavelengths.

A Self‐Powered Photodetector Based on Graphene Enhanced WSe2/PtSe2 Heterodiode with Fast Speed and Broadband Response

AbstractNarrow bandgap 2D layered material platinum selenide (PtSe2) with good environmental stability, high carrier mobility, and high light absorption, has been widely investigated for uncooled midwave‐infrared (MWIR) photodetection. However, the phototransistor based on the PtSe2 operation at room temperature suffered from the high dark current and background noise. Here, a graphene (G)‐enhanced G‐WSe2/PtSe2 hetero‐diode placed on a metal electrode is reported. To enhance the photogain, a graphene layer placed on the WSe2/PtSe2 heterodiode as a local gating layer is designed. The device exhibits an ultra‐high light on/off ratio of up to 108 and ultra‐fast photoresponse speed with raising time τr = 0.9 µs and decay time of τd = 1.5 µs in the visible spectra range. Notably, ultrabroad band photoresponse from 405 to 3366 nm is demonstrated under the self‐power model. Notably, the device presented a competitive photovoltaic effect with a high energy conversion efficiency (PCE) of 3.45%. The results pave the way toward a new approach to tuning the performance of the atomic thin layered materials photodetector.

Monolithic Two-Terminal Tandem Solar Cells Using Sb2S3 and Solution-Processed PbS Quantum Dots Achieving an Open-Circuit Potential beyond 1.1 V.

Multijunction solar cells have the prospect of a greater theoretical efficiency limit than single-junction solar cells by minimizing the transmissive and thermalization losses a single absorber material has. In solar cell applications, Sb2S3 is considered an attractive absorber due to its elemental abundance, stability, and high absorption coefficient in the visible range of the solar spectrum, yet with a band gap of 1.7 eV, it is transmissive for near-IR and IR photons. Using it as the top cell (the cell where light is first incident) in a two-terminal tandem architecture in combination with a bottom cell (the cell where light arrives second) of PbS quantum dots (QDs), which have an adjustable band gap suitable for absorbing longer wavelengths, is a promising approach to harvest the solar spectrum more effectively. In this work, these two subcells are monolithically fabricated and connected in series by a poly(3,4-ethylene-dioxythiophene) polystyrene sulfonate (PEDOT:PSS)-ZnO tunnel junction as the recombination layer. We explore the surface morphology of ZnO QD films with different spin-coating conditions, which serve as the PbS QD cell's electron transport material. Furthermore, we examine the differences in photogenerated current upon varying the PbS QD absorber layer thickness and the electrical and optical characteristics of the tandem with respect to the stand-alone reference cells. This tandem architecture demonstrates an extended spectral response into the IR with an open-circuit potential exceeding 1.1 V and a power conversion efficiency of 5.6%, which is greater than that of each single-junction cell.

Investigation of electrothermal properties of indium-tin-oxide thin films

Transparent conductive oxide (TCO) thin films are highly sought-after for their unique characteristics of conducting electricity and transmitting visible light, making them ideal conductive coating materials for electronic devices. We carried out a comprehensive analysis of the deposition, optical, electrical, and structural properties of ITO and Ag/ITO thin films on glass substrates in this study. The weight ratio of the deposited metals was 1:10, 2:10, and 4:10[Formula: see text]wt.% (Sn:In) for ITO films and 1:1:10[Formula: see text]wt.% (Ag:Sn:In) for Ag–ITO film. The films were annealed at 300°C using a program controller furnace. We employed infrared cameras to analyze the surface temperature profiles of these thin films under external voltage supply. We also investigated the resistivity behavior of both ITO and Ag–ITO films, analyzing them with regard to Mott’s variable range hopping (VRH) model and the fluctuation-induced tunneling model. Scanning electron microscope images revealed that adding Ag increased the grain size of ITO thin films. The average grain size for ITO thin film was determined as 186[Formula: see text]nm, while it was found to be 270[Formula: see text]nm for Ag–ITO thin film. Furthermore, incorporating Ag into the ITO thin film resulted in a reduction of 21.5% in transmittance over the complete visible range of the electromagnetic spectrum when compared to the ITO thin film without Ag as measured by ultra-visible spectrophotometer. The figure of merit was obtained as [Formula: see text] for ITO and [Formula: see text] for Ag–ITO thin films. However, the resistance of the ITO thin film was calculated to be 9.58[Formula: see text]k[Formula: see text], while that of the Ag–ITO film was found to be 6.99[Formula: see text]k[Formula: see text]. The ITO thin film that included Ag exhibited a lower electrical resistivity due to the larger grain size caused by doped Ag atoms in the structure, leading to less electron scattering at the grain boundaries and a resulting decrease in resistivity as determined by four-point probe system. Thermal imaging camera measurements revealed that the surface temperature of the ITO thin film decreased with the addition of Ag under high voltage application, but not under low voltage. When a voltage of 350[Formula: see text]V and 250[Formula: see text]V was applied to the thin films, the ITO film exhibited a surface temperature of 73.9°C and 50.4°C, whereas under identical conditions, the Ag–ITO film showed a surface temperature of 62°C and 44.1°C, respectively. Furthermore, both films exhibited exponentially increasing surface temperature behavior under a certain voltage, suggesting that they have potential for transparent heaters and high-voltage/low-current applications.

Metal-organic framework photonic crystals with bidisperse particles-based brilliant structural colors and high optical transparency for elaborate anti-counterfeiting

Photonic crystals (PCs) have attracted great interest and wide applications in displays, printing, anti-counterfeiting, etc. However, two main challenges significantly hinder their applications: 1) the tradeoff between high optical transparency across the whole visible range and brilliant colors requiring a large refractive index contrast (Δn), and 2) the way of regulating structural colors by altering tens of different sizes. To address these issues, a new type of metal–organic framework (MOF)-based transparent photonic crystal (TPC) has been fabricated through self-assembling MOF particles into three-dimensional ordered structures which were then infiltrated by polydimethylsiloxane (PDMS). Compared to conventional PCs, these TPCs exhibit 1) both brilliant forward iridescent structural colors and high transmittance (>75 %) across the whole visible spectra range, and 2) conveniently adjustable colors based on bidisperse particles. The unique color-generating mechanism of the light diffraction by each plane lattice and the small Δn between MOF particles and PDMS are the keys to TPCs’ characteristics. Moreover, the prepared invisible anti-counterfeit labels can reversibly hide-reveal patterns with elaborate and exchangeable color contrast in a non-destructive way, showing potential applications in anti-counterfeiting, information encryption, and optical devices.

Аналіз наявних методів та підходів до пошуку пошкодженої автобронетанкової техніки під час технічної розвідки в сучасних арміях світу

The article proposes the definition of directions and opportunities for the use of technical means of information in the performance of the tasks of rear support of troops in armed conflicts that are taking place today.
 Possible areas of application of unmanned aerial vehicles in the technical intelligence system of the National Guard of Ukraine and the Armed Forces of Ukraine are considered. The analysis of various types of unmanned aerial vehicles revealed the peculiarities of their use. The foreign experience of the use and development of unmanned technologies in the field of search and evacuation of damaged armored vehicles was analyzed. Conclusions were obtained regarding the combination of unmanned aerial vehicles with traditional means of technical intelligence, which showed their significant advantages. Prospective areas of application of aircraft in combination with technical intelligence systems of individual units of the National Guard of Ukraine and military units of the Armed Forces of Ukraine during operations and hostilities have been identified. The possibility of combining aviation technologies and means of technical intelligence in armed conflicts of modern armies of the world is also considered.
 Technical intelligence was analyzed from the point of view of the type of intelligence by tasks, forces, means and methods; and also as an organization of intelligence activities based on the use of technical means. The dependence on the nature of signals detected by technical means is shown, one of the types of technical intelligence is photo and infrared intelligence based on the interception of light waves (species intelligence).
 Species intelligence is considered as the collection of intelligence information based on the analysis of a large number of images obtained with the help of photographic, optical-electronic and radar equipment. According to its specificity, intelligence belongs to technical intelligence and includes air and space intelligence. Species reconnaissance uses photographic images taken in the visible range of the electromagnetic spectrum, infrared photography and multispectral photography. Radar images for species reconnaissance are created by equipment of various electromagnetic ranges synthesized in radar equipment. Spectral reconnaissance should be distinguished from electronic reconnaissance using optical-electronic or radar equipment that does not form an image.
 Military experts of developed countries believe that in the modern combat environment, unmanned aerial vehicles (UAVs) for conducting reconnaissance as a means of technical intelligence can more effectively and quickly solve the tasks of technical intelligence. At the same time, the time required to deliver the received intelligence information to the relevant management bodies is reduced.