Vibrational Distribution Research Articles

Zero-dimensional simulations of DC ns-pulsed plasma jet in N2 at near atmospheric pressure: validation of the vibrational kinetics

Abstract A Direct Current (DC) nanosecond (ns)-pulsed plasma jet fed with N2 at near atmospheric pressure (20 000 Pa) is studied using a transient zero-dimensional (0-D) model coupled with a two-term Boltzmann equation solver. Good agreement is observed between the simulated and measured plasma properties: including the electron density and the ratios of the N2(v = 1, 2, 3, 4) densities to the gas density. A variety of theoretical approaches are considered to determine the Vibrational-Vibrational (V-V) and Vibrational-Translational (V-T) rate coefficients. For the V-V kinetics, the simple form of an Harmonic Oscillator (sfHO), the Schwartz–Slawsky–Herzfeld (SSH) and the Forced Harmonic Oscillator (FHO) approaches are used. The SSH approach used in this study is an improved version based on the pure SSH approach. For the V-T kinetics, the sfHO, a fit function of the Semi-Classical (ffSC) calculations and a fit function of the Quasi-Classical Trajectory (ffQCT) calculations are used. The influence of these different approaches on the calculated temporal evolution profiles of the vibrational distribution functions (VDFs) within one pulse modulation cycle is revealed. It is observed that the use of these different approaches does not strongly affect the densities of the low vibrational levels (v < 5), whereas larger influences on the higher level densities are found. In addition, it is found that the simulated evolution of the VDFs are sensitive to the probabilities of the neutral wall reaction N2(v) + wall → N2(v − 1) in the range of 1 × 10−2 to 1 × 10−4. A further analysis of the wall quenching probabilities of N2(0 < v < 58) is of importance for a more accurate prediction of the VDFs.

Imaging study of O3 photodissociation in the Huggins band.

We report a velocity-mapped ion imaging study of the photodissociation of O3 in the Huggins band. The O(3PJ) images show evidence for three electronic channels producing O2(X3Σg-), O2(a1∆g), and O2(b1Σg+) state fragments, with the latter two arising from the spin-forbidden photodissociation of O3. Forward convolution simulations of the derived total translational energy distributions permit extraction of the vibrational state distribution for each O2 electronic state. All these distributions peak near v = 0 and decrease monotonically with the vibrational state. The wavelength-dependent branching of the three electronic channels has been determined and is approximately constant over the wavelength region studied (322-328nm). We have observed that the O2 electronic state branching ratios depend on the coincident O(3PJ) spin-orbit state, and the O2(b1Σg+) state is particularly sensitive. These results are qualitatively consistent with previous calculations on the coupling of the initially excited state to dissociative states by Rosenwaks and Grebenshchikov [J. Phys. Chem. A. 114, 9809-9819 (2010)]. The spatial anisotropy of the three dissociation channels has been determined through analysis of the O(3P0) angular distributions. The results are consistent with recent calculations but differ from previous experimental reports. The experimental results provide detailed information on the dissociation dynamics and should motivate new calculations.

Measurement and analysis of vibration responses due to subway transit in residential areas

The issue of building vibrations caused by subway operations has become increasingly prominent, significantly impacting residents' daily lives. This study investigates the vibration response of a residential area when the subway passing through, which involved the vibrations of the free field, the basement, and the nearby buildings. In addition, numerical simulation of building vibration by Etabs software was discussed. The free field vibration above the shield tunnel diminishes rapidly in the vertical track direction as the horizontal distance increases. However, the influence range of subway induced vibrations significantly expands when a basement is built adjacent to the subway. Data on building vibrations revealed the distribution of vibrations along the vertical direction and the vertical vibration amplification at the slab center due to local resonance. Interestingly, isolation designed for seismic loads also offers some benefits in reducing vertical vibrations. The numerical simulation results of the vibration response at the shear wall bottom show a certain degree of consistency with the actual measured results, but the attenuation of the vibration is faster, which may underestimate the vibration response of the building. The findings of this study provide valuable insights for understanding the impact of subway operations on surrounding buildings, optimizing subway and structural spatial layouts, and designing for vertical vibration control.

Comprehensive analysis of 2,5-dimethyl-1-(naphthalen-1-yl)-1H-pyrrole: X-ray crystal structure, spectral, computational, molecular properties, docking studies, molecular dynamics, and MMPBSA

This study examines the features of 2,5-dimethyl-1-(naphthalen-1-yl)-1H-pyrrole (DN1HP) in terms of its structure, vibrations, electronic transition properties, biological activity, and thermodynamic characteristics. X-ray single crystal structure solved and analysed. With the use of spectroscopic methods like FT-IR and UV–vis, the compound has been described. These experimental findings were contrasted with information derived from DFT (B3LYP) computations with the basis set 6–311++G(d,p). Vibrational allocations and Potential energy distribution(PED) were computed after optimizing the DN1PH compound's shape. The outcome of every experiment matched the values predicted by theory. To further investigate the reactivity, stability and biological activity of the titular molecule, calculations were made for the electrophilicity index (3.053), energy gap (3.789 eV), EH (−5.2962 eV), and EL (−1.5069 eV). To determine the compound's electrophilic and nucleophilic locations, a Molecular electrostatic potential (MEP) diagram was established. Molecular docking experiments have demonstrated the potential of the molecule in question as an anti-HIV medication. The binding energies of the drug to the proteins 3MLU, 3QEG, 5DHZ, and 3MLY are −5.86, −5.04, −5.01 and −4.97 kcal/mol, respectively. To further investigate the relationship and reliability of the protein (3MLU) with DN1HP, molecular dynamics (MD) simulators were utilized

Comparative computational analysis of orthoconic antiferroelectric liquid crystals: DFT analysis.

The study undertakes a comparative analysis of four distinct semi-fluorinated chiral Organic Active Ferroelectric Liquid Crystals (OAFLCs). The comparative analysis of the compounds is done by using various parameters, including thermodynamic, non-linear optical, electrical, atomic charge distribution, and atomic orientations. We use optimization algorithms to look at chemical reactivity, electrical properties, intermolecular interactions, and static hyperpolarizability. Sample 4 is the best choice for a wide range of display applications. This research contributes to understanding the nuanced properties of semi-fluorinated chiral OAFLCs and highlights Sample 4's potential for novel applications in display technology, owing to its superior stability and optimized properties. This study helps to enhance our understanding of the comparative analysis of semi-fluorinated chiral OAFLCs for potential advancements in display technologies by incorporating findings from key studies. The simulations are performed using density functional theory (DFT) with the B3LYP functional for predicting molecular properties, and Vibrational Energy Distribution Analysis (VEDA) software is used to perform the vibrational analysis of the molecules.

Quantum Calculation of the Vibrational Excitation of Nitrogen Molecules by Fast Ions: Can It Contribute to STEVE Formation?

AbstractThe vibrational‐translational (VT) excitation of nitrogen molecules led by collisions with fast ions in subauroral ion drifts (SAID) has been conceived as a potential underlying mechanism contributing to the formation of the Strong Thermal Emission Velocity Enhancement (STEVE) phenomenon (Harding et al., 2020, https://doi.org/10.1029/2020gl087102). In this study, we perform quantum calculations of the VT excitation rates of N2 led by fast‐drifting ions, and evaluate the resulting vibrational distribution of N2 with ionospheric/thermospheric parameters expected under intense SAID condition. We conclude that, while the VT energy transfer led by SAID plays a distinguishable role in the vibrational excitation of N2, it is incapable of populating the high vibrational levels to the required concentration (Harding et al., 2020, https://doi.org/10.1029/2020gl087102) to produce adequate nitric oxide density, and in turn the nitrogen‐dioxide continuum intensity, to account for the STEVE brightness.

Investigation of spectroscopic characterization, crystal structure, and antitumor activity of a novel 2ATP molecule

In this section, the spectroscopic characteristics of 2-amino-toysl-pyridine (2ATP) are fully examined, using both experimental and computational investigations guided by density functional theory (DFT). It will facilitate our computational research using the B3LYP approach to use the basis set 6–311++G(d,p). Comprehensive assignments of vibrational modes were obtained from the vibrational spectra, which comprised FT-Raman and FT-IR spectroscopy and were recorded in the region of 3500–400 cm−1 and 4000–500 cm-1, respectively, using the Vibrational Energy Distribution Analysis (VEDA) approach. The net atomic charges inside the molecule were ascertained by using Mulliken population analysis, natural atomic charges, and electrostatic potentials (CHELPG). The structural conformations of 2ATP were determined using NMR spectroscopy in a CDCl3 solvent. The donor-acceptor interactions of the 2ATP molecule at the 6–311++G(d,p) level were studied by means of a Natural Bond Orbital (NBO) study. Studies of the ultraviolet (UV) spectrum in ethanol were used to assess the effects of the solvent. An assessment was made of the energy difference between the lowest unoccupied molecular orbital (LUMO) and the highest occupied molecular orbital (HOMO) in order to understand charge transfer processes that suggest the molecule may have biological activity. Molecular electrostatic potential (MEP) surfaces were used to predict the nucleophilic and electrophilic sites in molecules. The non-covalent interactions were evaluated using the reduced density gradient (RDG) approach. The Multiwfn software was used to analyze the topological properties of the 2ATP, including the Localized Orbital Locator (LOL) and Electron Localization Function (ELF). Further attention was drawn to the compound's exceptional pharmacological potential when its ADMET (Absorption, Distribution, Metabolism, Excretion, and Toxicity) characteristics were evaluated. Not to add, molecular docking experiments were carried out to evaluate the feasibility of 2ATP as a bioactive material with possible uses in the pharmaceutical business.

Dynamic modeling and failure mechanism study of herringbone gear planetary transmission system for wind turbine under gear cracks

The herringbone gear planetary transmission system (HGPTS) is a common component in the gearbox of wind turbines. Studying the dynamic performance of gear systems is the key to improving their stability. To reveal the influence of cracks on the dynamic characteristics of the HGPTS, using slicing method, we explore the influence of different crack factors on the time-varying meshing stiffness (TVMS) of the system. A 55-degrees of freedom bending torsion axis pendulum dynamic model was constructed using the centralized mass parameter method; in the model, factors such as TVMS of cracks as well as receding groove and errors are considered. The Runge–Kutta method was used to solve the dynamics, and the evolution diagram of the vibration and load distribution characteristics of the system under crack changes was obtained. Vibration tests were conducted on the system studied in this work. The results show that under the influence of cracks, the TVMS of the external and internal meshing pairs of the system will decrease, and as the cracks intensify, the fluctuation of the TVMS will decrease. Cracks can lead to regular impact behavior in the system. A modulation sideband centered on the meshing frequency appears in the vibration response, and the vibration trajectory of the gears will also become disordered, at the same time, under the influence of cracks, there are significant excitation factors in the load-sharing characteristics of the system. As the cracks continue to intensify, the vibration of the system becomes increasingly evident, and the load-sharing characteristics show a trend of first decreasing and then increasing. The vibration test results are in good agreement with the theoretical predictions. The correctness of the established model is verified. The research results can provide reference for the reliability research of wind turbine HGPTS.

Relationship of flow pattern, vibration, and noise in automobile refrigerant system and flow pattern identification based on convolutional neural network

In recent years, the flow-induced vibration and noise in automotive refrigerant system gradually become the main factor affecting driving comfort. However, the relationship of flow pattern, vibration, and noise is not clear, and pattern identification is not easy but necessary. In this paper, a series of experiments are conducted to investigate the relationship of flow pattern, flow-induce vibration, and noise near the thermal expansion valve in an automobile refrigerant system. The flow pattern, vibration, and noise are closely related to startup processes. Mist flow, which contains more mist two-phase mixture than transition flow and wispy-annular flow, leads to the largest amplitude of vibration and strong broadband hiss noise. Moreover, the increase in compressor speed promotes the pattern transition and the vibration amplitude in time domain but has no effect on the distribution of vibration peaks in frequency spectrum. Finally, a short-time Fourier transform and convolutional neural network combined method for flow pattern identification is developed based on the relationship of flow pattern and flow-induced noise. After using transfer learning and data augmentation, four trained network architectures show relatively high accuracy above 94% for test set. Among them, ResNet34 not only has the highest accuracy of 98.8% but also can recognize each type of flow pattern. The generalization of this method can help engineers to recognize flow patterns in air conditioning without flow visualization but only need to measure sound signals.

Unveiling the Mechanism of Plasmon Photocatalysis via Multiquantum Vibrational Excitation.

Plasmon photocatalysis reactions are thought to occur through vibrationally activated reactants, driven by nonthermal energy transfer from plasmon-induced hot carriers. However, a detailed quantum-state-level understanding and quantification of the activation have been lacking. Using anti-Stokes surface-enhanced Raman scattering (SERS) spectroscopy, we mapped the vibrational population distributions of reactants on plasmon-excited nanostructures. Our results reveal a highly nonthermal distribution with an anomalously enhanced population of multiquantum excited states (v ≥ 2). The shape of the distribution and its dependence on local field intensity and excitation wavelength cannot be explained by photothermal heating or vibronic optical transitions of the metal-molecule complex. Instead, it can be modeled by hot electron-molecule energy transfer mediated by the transient negative ions, establishing direct links among nonthermal reactant activation, plasmon-induced hot electrons, and negative ion resonances. Moreover, the presence of multiquantum excited reactants, which are far more reactive than those in the ground state or first excited state, presents opportunities for vibrationally controlling chemical selectivities.

Energy and spectroscopic parameters of neutral and cations isomers of the CnH2 (n = 2-6) families using high-level ab-initio approaches.

Cationic species, previously detected from ion-induced desorption of solid methane by plasma desorption mass spectrometry (PDMS), and neutral species, are investigated using high-level ab-initio approaches. From a set of 25 cationic and 26 neutral structures belonging to CnH2 (n = 2-6) families, it was obtained the energy, rotational constants, harmonic vibrational frequency, charge distribution and excitation energies. The ZPVE-corrected energies, at CCSD(T)-F12; CCSD(T)-F12/RI/(cc-pVTZ-F12, cc-pVTZ-F12-CABS, cc-pVQZ/C) (n = 2-5) and CCSD(T)/cc-pVTZ (n = 6) levels, reveal that the topology of the most stable isomer vary with n and the charge. Out of 674 harmonic frequencies, those with maximum intensity are generally in the 3000-3500 cm-1 range. Analysis of 169 vertical transition energies calculated with the EOM-CCSD approach, suggest three C6H2 species as potential carriers of the diffuse interstellar bands (DIB). Systematic comparison of properties between neutral and cationic species can assist in the structural description of complex matrices.

Accurate and Efficient Schemes for Mapping Out Two Isolated Seams of Conical Intersections with Neural Networks Solely Based on Adiabatic Energies: A Case Study of H+ + NO(X2Π) → H + NO+(X1Σ+).

A new scheme in the neural network (NN) diabatization approach that solely utilizes the adiabatic energies for constructing the global diabatic potential energy matrices (PEMs) of the molecular systems with two isolated seams of conical intersections (CIs) is proposed. Taking a prototype charge transfer reaction H+ + NO(X2Π) → H + NO+(X1Σ+), where two seams of CIs are located at the different linear geometries N-O-H and O-N-H, for example, the diabatization with the new scheme including a diabatic state constraint is shown to map out the topographies of both two linear CIs with 100% of the success rate in 10 different trainings, while the diabatization without such constraint hardly represents CIs, in which the avoided crossings appear instead. Simultaneously, we propose a scheme to separate the whole reactive space into three different regions and define the minimal Euclidean distances for each region to efficiently sample the energy points for the NN trainings. Through adjusting the minimal Euclidean distances, the number of the adiabatic energy data needed in the construction of diabatic PEM can be heavily decreased, lowered from ∼2000 to ∼280 energy points, which is much less than the number (>22 000) of ab initio energy points used in earlier spline diabatic PEM. Further quantum dynamic calculations show that the reaction probabilities, vibrational state distributions, and vibrational state resolved differential cross sections are well reproduced on the new NN diabatic PEM, validating these schemes for constructing the diabatic PEM.

Design and implementation of shear-horizontal mode surface acoustic wave formaldehyde gas sensor

Surface acoustic wave (SAW) sensors have garnered significant attention due to high performance in gas detection. Love wave as the special mode of SAW has greater attractiveness for molecules detection in gas or liquid. To investigate the detection performance of Love wave SAW (Love-SAW) devices towards toxic gases, the influence of interdigitated electrodes on the propagating performance of Rayleigh and shear horizontal (SH) waves along ST-X and ST-90°X quartz substrates was analyzed by finite element method (FEM). The effect of the guiding layer based on different substrates of SAW devices has been discussed by changing the thickness of the zinc oxide (ZnO) layer. The results indicate that the SH wave excited on ST-90°X quartz substrate couples into the Love wave mode through the ZnO guiding layer, and Rayleigh waves in ST-X quartz do not exhibit mode coupling. The Love-SAW sensor covering the ZnO guiding layer (0.5 µm) has shown high mass sensitivity. The vibration distribution of SH wave excited by different thicknesses of electrodes is different, indicating that the mass-loading is one of the reasons for the transformation of SH wave into Love wave. Furthermore, the 50 ppm, 95 ppm and 110 formaldehyde-load leads the short-circuit resonance frequency of the polyetherimide (PEI) covered Love-SAW devices to drop by 100.1 kHz, 200.2 kHz and 300.3 kHz, respectively. The maximum detection sensitivity reached about 2.73 kHz/ppm. This work can provide valuable insights for designing and investigating the SAW formaldehyde gas sensors.

Spectroscopic and computational methods in the characterization of deep eutectic solvent, Gallic acid, and Glycerol

Several researchers have shown experimentally that Gallic acid has antioxidant, anti-inflammatory, and anti-aging properties, signifying its value in skin care. Glycerol has properties, such as increasing skin hydration, softening skin, and reducing skin dryness. The present work aims to understand the vibrational and spectroscopic study of the interacting mechanism of Deep Eutectic solvent mixture of Gallic acid and Glycerol. The theoretical analysis is performed using the Density Functional Theory with B3LYP/6-311 + g(d,p) level of theory. The optimized structure and frequency of the monomers and their biomolecular complex are obtained using Gauss view 6.0 and Gaussian16. The vibrational analysis is carried out using Vibrational Energy Distribution Analysis. The Natural Bond Orbital, molecular docking of the Glycerol-Gallic acid complex, and the molecular dynamics simulation of the docked protein-ligand system are carried out to understand the mechanism better. The theoretical and experimental frequencies are found to agree with each other. The Molecular Dynamic simulation analysis predicts that the protein-ligand complexation is relatively stable.

Vibrational relaxation of HOD by collisions with Ar atoms.

Vibrational relaxation of HOD(v12, v3) molecules by collisions with Ar was studied at 298K (v12 denotes coupled bending, v2, and OD stretching, v1, vibrational modes and v3 denotes OH stretching mode). The vibrationally excited HOD molecules were generated by exothermic abstraction reactions of OD radicals with 13 different RH reactants and observed by infrared emission from a fast-flow reactor as a function of Ar pressure and reaction time. State-specific relaxation rate constants were obtained by comparison of the time evolution of the experimental vibrational distributions with numerical kinetic calculations for vibrational populations. The relaxation mechanism was based on the relaxation scheme of H2O studied earlier with the addition of specific channels for HOD(v12, v3). Unlike H2O, energy in stretching and bending vibrations of HOD cannot be separated due to close ν1 and 2ν2 energies, which leads to fast collisional equilibration between these Fermi-resonant levels. For relaxation of the only pure bending state (10), a rate constant of (1.5 ± 0.3) × 10-13cm3molecule-1s-1 was obtained. The relaxation rate of higher v12 states linearly increases with quantum number and very likely includes transfer of population from OD stretch levels, v1, to a lower energy bend level. The average rate constants for the loss of population from (01), (02), and (03) stretching states are (1.1 ± 0.3) × 10-14, (3.2 ± 1.0) × 10-14, and (5.6 ± 1.2) × 10-14cm3molecule-1s-1, respectively.

Density functional theory and spectroscopic analysis of stigmasterol from Garcinia wightii: Deciphering its inhibitory potential against drug-resistant tuberculosis via insilico molecular docking and molecular dynamics simulations

This study investigates the molecular structure and electronic properties of stigmasterol, isolated from Garcinia wightii, using density functional theory (DFT) alongside experimental techniques including FT-IR, FT-Raman, UV–Vis, 1H and 13C NMR spectroscopy. Theoretical predictions are compared with experimental results, facilitated by vibrational energy distribution analysis for unambiguous vibrational wavenumber assignments. Natural bond orbitalanalyzes reveal donor-acceptor bond energies and electron densities, while Fukui functions identify reactive sites susceptible to electrophilic and nucleophilic attacks. Electronic properties are further explored through various analyzes, unveiling reactive surface sites. Non-covalent interactions are examined using reduced density gradient analysis. Assessment of absorption, distribution, metabolism, and excretion attributes aids in drug discovery efforts. Molecular docking studies against 20 target proteins for antitubercular screening show a stable glide score of -9.52 kcal/mol for the protein 4FDO (Mycobacterium tuberculosis DprE1 in complex with CT319). Molecular dynamics simulations over 100 ns indicate the stability of the ligand-protein complex, suggesting its potential as an antituberculosis agent. Stigmasterol's structural, vibrational, electronic, and topological properties are thoroughly investigated, revealing its ring skeleton with a flexible isooctyl side chain, adhering to C1 point group symmetry. Steric and stereo electronic interactions play crucial roles in conformation and binding to target proteins. Theoretical and experimental analyzes align, confirming the compound's bioactive properties. This comprehensive investigation underscores stigmasterol's potential as a tuberculosis treatment option, providing valuable insights into its structural characteristics and therapeutic possibilities.

GPCR Signaling: A Study of the Interplay Between Structure, Energy, and Function.

G protein-coupled receptors (GPCRs) exemplify sophisticated allosteric communication, transducing extracellular signals through ligand-induced structural rearrangements that resonate through the molecular scaffold. Despite extensive study, the biophysical underpinnings of how conformational changes spread remain unclear. This work employs a novel physics-based framework to characterize the role of energy dissipation in directing intramolecular signaling pathways. By modeling each residue as a network of coupled oscillators, we generate a localization landscape depicting the vibrational energy distribution throughout the protein scaffold. Quantifying directional energy flux between residues reveals distinct pathways for energy and information transfer, illuminating sequences of allosteric communication. Our analysis of CB1 and CCR5 crystal structures unveils an anisotropic pattern of energy dissipation aligning with key functional dynamics, such as activation-related conformational changes. These anisotropic patterns of vibrational energy flow constitute pre-configured channels for allosteric signaling. Elucidating the relationship between structural topology and energy dissipation patterns provides key insights into the thermodynamic drivers of conformational signaling. This methodology significantly advances our mechanistic understanding of allostery in GPCRs and presents a broadly applicable approach for rationally dissecting allosteric communication pathways, with potential implications for structure-based drug design targeting these critical receptors.

Noise reduction mechanism of high-speed railway box-girder bridges installed with MTMDs on top plate

The issue of low-frequency structural noise radiated from high-speed railway (HSR) box-girder bridges (BGBs) is a significant challenge worldwide. Although it is known that vibrations in BGBs caused by moving trains can be reduced by installing multiple tuned mass dampers (MTMDs) on the top plate, there is limited research on the noise reduction achieved by this method. This study aims to investigate the noise reduction mechanism of BGBs installed with MTMDs on the top plate. A sound radiation prediction model for the BGB installed with MTMDs is developed, based on the vehicle–track–bridge coupled dynamics and acoustics boundary element method. After being verified by field tested results, the prediction model is employed to study the reduction of vibration and noise of BGBs caused by the MTMDs. It is found that installing MTMDs on top plate can significantly affect the vibration distribution and sound radiation law of BGBs. However, its impact on the sound radiation caused by vibrations dominated by the global modes of BGBs is minimal. The noise reduction achieved by MTMDs is mainly through changing the acoustic radiation contributions of each plate of the bridge. In the lower frequency range, the noise reduction of BGB caused by MTMDs can be more effective if the installation of MTMDs can modify the vibration frequency and distribution of the BGB to avoid the influence of small vibrations and disperse the sound radiation from each plate.

Characteristic Extraction and Assessment Methods for Transformers DC Bias Caused by Metro Stray Currents.

Metro stray currents flowing into transformer-neutral points cause the high neutral DC and a transformer to operate in the DC bias state.Because neutral DC caused by stray current varies with time, the neutral DC value cannot be used as the only characteristic indicator to evaluate the DC bias risk level. Thus, unified characteristic extraction and assessment methods are proposed to evaluate the DC bias risk of a transformer caused by stray current, considering the signals of transformer-neutral DC and vibration. In the characteristic extraction method, the primary characteristics are obtained by comparing the magnitude and frequency distributions of transformer-neutral DC and vibration with and without metro stray current invasion. By analyzing the correlation coefficients, the final characteristics are obtained by clustering the primary characteristics with high correlation. Then, the magnitude and frequency characteristics are extracted and used as indicators to evaluate the DC bias risk. Moreover, to avoid the influence of manual experience on indicator weights, the entropy weight method (EWM) is used to establish the assessment model. Finally, the proposed methods are applied based on the neutral DC and vibration test data of a certain transformer. The results show that the characteristic indicators can be extracted, and the transformer DC bias risk can be evaluated by using the proposed methods.

Ultrasonic liquid crystal tunable light diffuser

Conventional light diffusers have periodic surface profiles, periodic refractive index distributions, or light scattering layers containing colloids. In all such structures the optical directivity of the light diffuser is cannot typically be controlled. Here we propose an electrically tunable light diffuser based on the application of ultrasound to a nematic liquid crystal (LC) material. The ultrasonic LC diffuser consists of an LC layer sandwiched by two glass discs and an ultrasonic transducer. The electrodes of the transducer are divided in a circumferential direction so that a resonant non-coaxial flexural vibration mode can be generated on the diffuser by controlling the electrical input signals. A continuous reversed-phase sinusoidal electric signal to the transducer generates the non-coaxial resonant flexural vibration mode on the glass disc, inducing an acoustic radiation force acting on the boundary between the LC layer and glass discs. This effect changes the molecular orientation of the LC and the transmitted light distribution. The diffusion angle of the transmitted light depends on the input voltage amplitude, and the diffusion angle was maximized at 16.0 V. The vibrational distribution and the diffusion directivity could be rotated by adjusting the input voltages to different electrodes, meaning that an ultrasonic LC diffuser with a thin structure and no moving mechanical parts provided a tunable light-diffusing functionality with rotatable directivity.