AbstractThe movement of two nonionic surfactants (Soil Penetrant 3685, Aqua Gro) and their effect on water flow through wettable and water repellent soils was investigated. Surfactant concentrations of 0, 100, 500, 1,000, 1,600, and 3,200 ppm were applied to the top of vertical soil columns and the concentration of surfactant in the column effluent was measured. When the concentration of surfactant in the effluent did not significantly change with time, leaching of the columns with tap water was initiated. Both surfactants affected the hydraulic conductivity of the hydrophobic soil. The conductivity effects appeared to be related to aggregate destabilization, micelle formation, and particle migration, all of which caused a general decrease of flow rates with time. Adsorptive characteristics were found to affect greatly the shape of the effluent concentration versus time curve. Aqua Gro was shown to be more strongly adsorbed and less subject to leaching than was Soil Penetrant. A theoretical model was tested for its ability to qualitatively predict experimental effluent concentrations. Allowing for the spreading effects of dispersion, there was reasonable agreement between most experimental and theoretical values. The behavior and movement of surfactants in soils are a function of adsorption isotherms, mixing or dispersion due to flow velocities, solute concentration, and the physical and chemical characteristics of the porous medium.
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