Bottom Water Ventilation Research Articles

Constraining Millennial‐Scale Changes in Northern Component Water Ventilation in the Western Tropical South Atlantic

AbstractNegative excursions in the stable carbon isotopic composition (δ13C) at Atlantic intermediate to mid‐depths are common features of millennial‐scale events named Heinrich Stadials. The mechanisms behind these excursions are not yet fully understood, but most hypotheses agree on the central role played by the weakening of the Atlantic meridional overturning circulation. Marine records registering millennial‐scale negative δ13C excursions in the Atlantic are mostly restricted to the Heinrich Stadials of the last deglacial, while the Heinrich Stadials of the last glacial are poorly studied. Here, we constrain changes in bottom water ventilation in the western tropical South Atlantic mid‐depth during Heinrich Stadials of the last glacial and deglacial by investigating marine core M125‐95‐3. The concurrent decreases in benthic foraminifera δ13C and increases in bulk sediment sulfur indicate an increased Northern Component Water (NCW) residence time in the western tropical South Atlantic mid‐depth during Heinrich Stadials. Furthermore, a coherent meridional pattern emerges from the comparison of our new data to previously published mid‐depth records from the western South Atlantic. While our record shows the largest negative δ13C excursions during almost all Heinrich Stadials, the western equatorialAtlantic showed medium and the subtropical South Atlantic showed the smallest negative excursions. This meridional pattern supports the notion that during Heinrich Stadials, a reduction in the NCW δ13C source signal together with the accumulation of respired carbon at NCW depths drove the negative δ13C excursions. We suggest that the negative δ13C excursions progressively increase along the NCW southwards pathway until the signal dissipates/dilutes by mixing with Southern Component Water.

Characterizing ventilation events in an anoxic coastal basin: Observed dynamics and the role of climatic drivers

AbstractRestricted horizontal exchange and vertical stratification restrict ventilation of bottom waters in many coastal systems, leading to stagnant basin water conditions. Dense inflows from oceanic sources can lead to dramatic changes in basin‐scale properties over very short timescales. Here, we used a semi‐enclosed coastal basin with deep‐anoxia (Lough Furnace) as a test bed, in order to discern estuary‐ocean exchange dynamics that lead to irregular and ephemeral deep‐water ventilations. Measured densities and current profiler‐based estimates of volume fluxes were used to compute typical renewal times of individual water masses in the stratified inner basin. Renewal timescales were primarily determined by freshwater flux and the spring‐neap tidal cycle. The deployment period culminated with observations of a ventilation of the basin water which had been stagnant for over 2.5 yr. Entrainment of ambient resident water doubled the volume of the dense plume and diluted its oxygen content. Following ventilation, the volumetric extent of anoxia expanded by 20% within several months, owing to uplifting of old basin water and oxygen consumption in the new basin water. Founded on these observations, a predictive model was constructed relying only on freshwater, atmospheric pressure, and wind data and successfully recreated ventilation events over the past decade. Hindcasting the model back multiple decades implied contrasting periods of higher and lower frequency variability in ventilation occurrence. This model offers a diagnostic tool for assessing how climatic change may influence the oxygen climate in systems that experience contrasting regimes of suboxia and ventilation.

Is ‘deep-water formation’ in the Baltic Sea a key to understanding seabed dynamics and ventilation changes over the past 7,000 years?

Numerous hydro-acoustic studies of the seabed of the Baltic Sea have revealed the unusual occurrence of sediment contourite drifts and re-suspension at greater water depths. In addition, radiocarbon dating of bulk sediments indicates significant age reversals. We present new geophysical, sediment proxy data (including extensive radiocarbon dating) and hydrographic measurements, which are combined with results of numerous marine geological studies performed during the last decades. These data indicate that a deep-water formation process significantly affected the seabed dynamics during regional climatically cold phases during the last c. 7,000 years. We propose that, during the colder periods (e.g. the Little Ice Age), newly formed bottom waters likely caused widespread re-suspension of organic carbon-rich laminated sediments that were deposited during the preceding warm periods in shallower areas, and this material was transported to and re-deposited in the deeper parts of the Baltic Sea sub-basins. In our scenario, a topographic feature, known as the Baltic Sea Klint, acted as a hydrographic barrier for deep-water formed in the northern Baltic. Thus, during the cold periods increased lateral matter influx from the northern Baltic led to the accumulation of much thicker macroscopically homogenous clayey sediments in sub-basins north of the Klint. Moreover, deep-water formation produced bottom currents that led to the formation of sediment contourite drifts at water depths of >200 m in the Bothnian Sea, the Åland Deep and northern central Baltic Sea sub-basins. Bottom water ventilation in the Baltic Sea is generally assumed to be determined solely by the inflow of oxygen-rich, saline water from the North Sea, but we challenge this assumption and postulate that deep-water formation is a key process that ventilates the bottom waters of the Baltic Sea during climatically cold periods with substantial implications for its sedimentary archive.

Middle to Late Pleistocene Arctic paleoceanographic changes based on sedimentary records from Mendeleev Ridge and Makarov Basin

Three sediment cores from the Makarov Basin and Mendeleev Ridge off the Siberian margin were analyzed for a number of litho-, bio- and magnetostratigraphic proxies. Correlation to previously studied Arctic records from Mendeleev to Lomonosov ridges enables paleoceanographic reconstructions for the Middle to Late Pleistocene (estimated ∼0.8 Ma) on orbital time scales. Cyclic changes in lithology corroborated by multiple stratigraphic constraints were tuned to global climate variations based on the manganese content that increases during interglacials, while calcium and zircon were used as proxies for the Laurentide and Eurasian ice sheet inputs. The combined evaluation of glacial and interglacial proxy variabilities provides a coherent picture of the western Arctic Ocean development in the Pleistocene. We suggest that major cyclic changes were driven by summer processes, such as sea-ice retreat and enhanced biological production vs. suppressed ice melt in warmer and colder summers, respectively. A potential link to low latitudes via atmospheric moisture and heat transport is indicated by similarities in the western Arctic Ocean and East Asian monsoon records. Long-term cooling is signified by biogenic proxies related to sea-ice expansion over the western Arctic Ocean with step changes at MIS 11 and 7 (∼0.4 and 0.2–0.3 Ma). This transition also features better fossil preservation indicating less corrosive/oxidative bottom waters, probably resulting from a decrease in organic export production and/or weakening of bottom water ventilation under perennial sea ice. The latter was possibly enhanced by atmospheric cooling and increased meltwater fluxes with the growth of circum-Arctic ice sheets.

Nitrogen and carbon cycle perturbations through the Cenomanian-Turonian oceanic anoxic event 2 (~94 Ma) in the Vocontian Basin (SE France)

Oceanic Anoxic Event 2, spanning the Cenomanian-Turonian boundary, was an episode of major perturbations in global biogeochemical cycles, characterized by the widespread burial of organic carbon in both oceans and epicontinental basins. In the Vocontian Basin (SE France), this event was expressed by the deposition of the Niveau Thomel, a succession of interbedded dark shales, grey marls and bioturbated carbonates as observed in the Lambruisse section. Analyses of the total organic carbon (TOC) content, combined with the concentrations of redox-sensitive trace elements, revealed that conditions fluctuated from oxic to suboxic-anoxic during the deposition of the Niveau Thomel. Transient periods of deoxygenation were related to perturbations in nutrient cycling reflected by near-zero to negative δ15N signatures indicative of increased diazotrophy.The development of deoxygenated conditions in the Vocontian Basin was likely preconditioned by hydrographically restricted conditions, as confirmed by Mo vs. U enrichments, reducing bottom-water ventilation associated with water-column stratification. Intervals of reoxygenation were likely linked to climate-induced changes. In particular, a phase of regional or global cooling associated with a drop in pCO2, called the Plenus Cold Event (PCE) resulted in vigorous reoxygenation of the Vocontian Basin.

Mechanisms of Deep and Bottom Water Ventilation over the Antarctic Continental Slope

Actual in situ observations at the Antarctic continental slope performed with eddy-resolving spatial resolution were used. As a result, some parameterizations were verified that describe the processes of instability of density flows on a sloping bottom derived during the laboratory experiments. These processes were identified based on observational data. Any changes in the bottom slope (local or general, linked to the transition of the steep slope into the deep-sea floor) lead to changes in the regime of dense water runoff. The resulting hydraulic jumps lead to the turbulent mixing and function as one of the main mechanisms of ventilation of deep and bottom water. In the areas of local bottom rubs, disturbances like leeward waves are sometimes observed at the dense water top. They cause the intrusive layering and subsequent occurrence of turbulence centers in the slope area; the eddy lenses which also take part in the slope water ventilation are sometimes observed over bottom rubs. A strong baroclinity of the Antarctic slope front (ASF) in a steep part of the slope is another mechanism of deep water ventilation. It leads to the instability of cascading, subsequent intrusive layering and eddy formation. The baroclinic instability is amplified by the increased dynamics of dense water runoff at the bottom slope increase. However, the realization of shear instability at density interface is possible but at the smaller spatial scale than the instability scales observed in the ASF area.

The Atlantic Meridional Overturning Circulation as productivity regulator of the North Atlantic Subtropical Gyre

AbstractSpatially extensive and intense phytoplankton blooms observed off Iberia, in satellite pictures, are driven by significant nutrient supply by upper-ocean vertical mesoscale activity rather than by horizontal advection by coastal upwelling. Productivity of oligotrophic regions is still poorly depicted by discrete instrumental and model data sets. The paleoproductivity reconstructions of these areas represent the mean productivity over long periods, bringing new insights into the total biomass fluxes. Here, we present paleoproductivity records from the oceanic Tore Seamount region, covering the period from 140 to 60 ka. They show higher nutrient supplies during Termination II, Marine Oxygen Isotope Stage (MIS) 4, MIS 6, and warming transitions of the MIS 5 sub-stages. The highest nutrient content (higher productivity) in phase with tracers of bottom-water ventilation (benthic δ13C,231Pa/230Th) establishes a strong linkage with variability of Southern Ocean-sourced waters. Low productivity and ventilation over warm sub-stages of MIS 5 respond instead to North Atlantic Deep Water. Assuming that the Tore Seamount is representative of oligotrophic regions, the glacial-interglacial relationship observed between paleoproductivity and Atlantic Meridional Overturning Circulation strength opens new insights into the importance of estimating the total biomass in these regions. The subtropical gyres might play a considerable role in the carbon cycle over (sub-)glacial-interglacial time scales than previously thought.

The Optical Signature of a Bottom Boundary Layer Ventilation Event in the Northern Gulf of Mexico's Hypoxic Zone

AbstractOceanographic observations in the northern Gulf of Mexico captured an unusual combination of atmospheric forcing and shelf frontal dynamics that brought about the surface ventilation of sediment‐laden bottom waters. Colorimetric analysis of in situ optical data indicates a specific turquoise‐white color signature for turbid and low‐oxygen bottom waters that match a coincident shelf‐wide feature detected in Moderate Resolution Imaging Spectroradiometer satellite true color images. The physical processes leading to this ventilation event are simulated using the Coupled Ocean Atmosphere Mesoscale Prediction System, which includes an integrated surface wave model. The combined model‐data analysis suggests that low‐oxygen, bottom water ventilation may occur episodically during boreal spring and summer in the northern Gulf of Mexico following the passage of high‐energy atmospheric systems, and these events may be identified in the historical satellite record based on the unique bottom water optical characteristics.

Insight into deep-sea life – Cibicidoides pachyderma substrate and pH-dependent behaviour following disturbance

Most palaeo-deep-water reconstructions are based on geochemical information stored in the calcareous shells of Cibicidoides species but hardly anything is known about their life cycle, population dynamics or ecology. The number of specimens of a single Cibicidoides species can locally be very limited and species may be lacking completely during certain intervals in the geological past. As a consequence, geochemical analyses are often carried out on lumped Cibicidoides spp. assuming that they share the same epizoic to epifaunal habitat and precipitated their shell in comparable offsets to surrounding bottom water mass properties. However, there is a growing body of evidence that particularly Cibicidoides pachyderma and its morphotypes C. mundulus and C. kullenbergi, may not be reliable bottom water recorders.We have recently developed aquaria that allowed, for the first time, observations of Cibicidoides pachyderma var. C. mundulus under in situ pressure and temperature. Experiments were carried out with and without artificial sediments to simulate soft sediments and rocks, respectively. Seawater was set to pH 8 and pH 7.4 to simulate more or less particulate carbon export or more or less ventilation of bottom water. Our experiments demonstrate that C. mundulus may opt for an epifaunal or an infaunal habitat depending on elapsed time following physical disturbance, pH, current activity, the availability of sediments and growth. The specimen's initial response following transfer from atmospheric pressure into the high-pressure aquaria was to immerse into the sediment or to cover more or less parts of the test with aggregated sediments or algae. However, within 24 h a strong rheotaxis became apparent and most specimens moved to sites of increased current activity under normal pH conditions (pH 8). Only few specimens remained in algae cysts or in the sediment in the pH-8 experiment. On the contrary, all specimens under pH 7.4 agglutinated a firm sediment cyst around their test and remained infaunal throughout the experimental period of three months.Independent of pH, growth was only observed in specimens that lived within an agglutinated cyst or infaunal. A solid thick cyst covered the specimens of the pH 7.4 experiment throughout the experiment and possibly restricted water exchange between the in-cyst water and the surrounding artificial bottom water mass. We suggest that a more fragile and possibly more porous sedimentary envelope may, at least temporally, have covered the infaunal specimens under pH 8 but no evidence for this was found upon termination of the experiment.

Benthic Foraminifera and Geochemistry Across the Paleocene–eocene Thermal Maximum Interval in Jordan

AbstractThis study presents benthic foraminiferal data from two sedimentary successions across the Paleocene–Eocene Thermal Maximum (PETM) from Jordan. Calcareous nannofossil biozones NP9a, NP9b, and NP10 of latest Paleocene and earliest Eocene age were encountered in proximal (core OS–01) and distal (core OS–28) sites. Lithologically, the investigated sequence consists of marls, shales, and limestones attributed to the Muwaqqar Chalk-Marl Formation and the Um Rijam Chert Limestone Formation. The δ13Corg curve records the typical carbon isotope excursion (CIE) and shows four distinctive intervals (pre-CIE, CIE-“core”, CIE-“recovery”, post-CIE) over the entire PETM interval in both cores.In the pre-CIE interval, the more proximal site (OS–01) shows high abundances of Neoeponides duwi co-occurring with an outer neritic Midway-type fauna. The fauna indicates meso- to eutrophic conditions in a middle- to outer-neritic setting. The more distal site (OS–28) is characterized by outer-neritic to upper-bathyal taxa (e.g., Cibicides pseudoacutus, Gavelinella beccariiformis, Nuttallides truempyi) suggesting well-ventilated, oligo- to mesotrophic seafloor conditions.The earliest Eocene corresponds to the CIE-“core” interval and is marked by a negative δ13Corg signal, high TOC, low CaCO3 contents, and near absence of benthic foraminifera. Oxygen deficiency in bottom waters with increased organic flux is the most likely scenario to explain the elevated organic content at the seafloor.The subsequent CIE-“recovery” interval of early Eocene age is marked by a restoration of oxygenated seafloor conditions. The proximal site is characterized by a relatively elevated TOC content and high abundance of Lenticulina spp., Valvulineria scrobiculata and common Anomalinoides zitteli, suggesting moderate oxygen conditions and mesotrophic bottom waters. The distal site is characterized by low TOC content and the presence of Lenticulina spp., Valvulineria scrobiculata, Anomalinoides zitteli and Oridorsalis plummerae, indicating a normalization of the organic flux and moderate oxygen concentrations near the seafloor.The post-CIE interval is marked by low TOC content in both cores. Benthic foraminifera include abundant Anomalinoides zitteli and common Lenticulina spp., Valvulineria scrobiculata, Oridorsalis plummerae, Cibicidoides rigidus, Cibicidoides pharaonis, and Anomalinoides praeacutus in the proximal setting. Mesotrophic conditions and a better ventilation of bottom waters are suggested for this interval. Lenticulina spp., Valvulineria scrobiculata, and Oridorsalis plummerae are also associated with the post-CIE interval in the distal site, suggesting similar mesotrophic conditions with renewed oxygenation in bottom waters.

Seasonal and annual variability of coastal sulphur plumes in the northern Benguela upwelling system.

We investigated the seasonal and annual variability of surface sulphur plumes in the northern Benguela upwelling system off Namibia because of their significant impacts on the marine ecosystem, fishing industry, aquaculture farming and tourism due to their toxic properties. We identified the sulphur plumes in ocean colour satellite data of the medium resolution imaging spectrometer (MERIS) for the 2002–2012 time period using the differences in the spectral properties of Namibian Benguela optical water types. The sulphur events have a strong seasonal cycle with pronounced main and off-seasons forced by local and remote-driven processes. The main peak season is in late austral summer and early austral autumn at the beginning of the annual upwelling cycle caused by increasing equatorwards alongshore winds. The sulphur plume activity is high between February and April during the seasonal oxygen minimum associated with the seasonal reduction of cross-shore ventilation of the bottom waters, the seasonal southernmost position of the Angola Benguela Frontal Zone, the seasonal maximum of water mass fractions of South Atlantic and Angola Gyre Central Waters as well as the seasonal arrival of the downwelling coastal trapped waves. The off-season is in austral spring and early austral summer during increased upwelling intensity and enhanced oxygen supply. The annual variability of sulphur events is characterized by very high activities in years 2004, 2005 and 2010 interrupted by periods of lower activity in years 2002 to 2003, 2006 to 2009 and 2011 to 2012. This result can be explained by the relative contributions or adding effects of local and remote-driven forces (from the equatorial area). The probability for the occurrence of sulphur plumes is enhanced in years with a lower annual mean of upwelling intensity, decreased oxygen supply associated with decreased lateral ventilation of bottom waters, more southern position of the Angola Benguela Frontal Zone, increased mass fraction of South Atlantic Central Water and stronger downwelling coastal trapped waves. Understanding of the variability and forcing processes of the toxic sulphur events will help in the future to monitor and forecast them as well as to manage their social and economic consequences in the northern Benguela upwelling system off Namibia.

Evidence of Poor Bottom Water Ventilation during LGM in the Equatorial Indian Ocean

Multi-proxy approach for the reconstruction of paleo-redox conditions is attempted in a radiocarbon (14C) dated sediment core near the equatorial Indian Ocean. Based on behavior and distribution of redox sensitive and productivity proxies, the study demonstrates prevalence of anoxic bottom water conditions during LGM due to poorly ventilated bottom waters augmented by high surface productivity resulting in better preservation of organic carbon (OC). During early Holocene, the equatorial Indian Ocean witnessed high sedimentation rates resulting in high organic carbon (OC) with depleted redox sensitive element thereby causing better preservation of OC. The study underscores poor bottom water ventilation during LGM and preservation of OC as a result of high sedimentation rate in early Holocene.

A Synoptic View of the Ventilation and Circulation of Antarctic Bottom Water from Chlorofluorocarbons and Natural Tracers.

Antarctic Bottom Water (AABW) is the coldest, densest, most prolific water mass in the global ocean. AABW forms at several distinct regions along the Antarctic coast and feeds into the bottom limb of the meridional overturning circulation, filling most of the global deep ocean. AABW has warmed, freshened, and declined in volume around the globe in recent decades, which has implications for the global heat and sea level rise budgets. Over the past three decades, the use of tracers, especially time-varying tracers such as chlorofluorocarbons, has been essential to our understanding of the formation, circulation, and variability of AABW. Here, we review three decades of temperature, salinity, and tracer data and analysis that have led to our current knowledge of AABW and how the southern component of deep-ocean ventilation is changing with time.

Major Bottom Water Ventilation Events Do Not Significantly Reduce Basin-Wide Benthic N and P Release in the Eastern Gotland Basin (Baltic Sea)

Redox-sensitive mobilization of nutrients from sediments strongly affects the eutrophic state of the central Baltic Sea; a region associated with the spread of hypoxia and almost permanently anoxic and sulfidic conditions in the deeper basins. Ventilation of these basins depends on renewal by inflow of water enriched in oxygen (O2) from the North Sea, occurring roughly once per decade. Benthic fluxes and water column distributions of dissolved inorganic nitrogen species, phosphate (PO43-), dissolved inorganic carbon (DIC), sulfide (HS-) and total oxygen uptake (TOU) were measured along a depth gradient in the Eastern Gotland Basin (EGB). Campaigns were conducted during euxinic conditions of the deep basin in Aug./Sept. 2013 and after two inflow events in July/Aug. 2015 and March 2016 when O2 concentrations in deep waters reached 60 µM. The intrusion of O2-rich North Sea water into the EGB led to an approximate 33 % and 10 % reduction of the seabed PO43- and ammonium (NH4+) release from deep basin sediments. Post-inflow, the deep basin sediment was rapidly colonized by HS- oxidizing bacteria tentatively assigned to the family Beggiatoaceae, and HS- release was completely suppressed. The presence of a hypoxic transition zone (HTZ) between 80 and 120 m water depth was confirmed not only for euxinic deep-water conditions during 2013 but also for post-inflow conditions. Because deep-water renewal did not ventilate the HTZ, where PO43- and NH4+ fluxes were highest, high seabed nutrient release there was relatively unchanged. Extrapolation of the in situ nutrient fluxes indicated that, overall, the reduction in PO43- and NH4+ release in response to deep-water renewal can be considered as minor, reducing the internal nutrient load by 2 and 12 % only, respectively. Infrequent inflow events thus have a limited capacity to sustainably reduce internal nutrient loading in the EGB and mitigate eutrophication.

Assessing bottom water anoxia within the Late Devonian Woodford Shale in the Arkoma Basin, southern Oklahoma

Comparing the concentration of molybdenum (Mo) (ppm) and total organic carbon (TOC) (wt%) within sediments allows interpretation of the relative degrees of bottom water restriction within the geologic record. The Woodford Shale is interpreted as transgressive systems tract (TST) grading into highstand systems tract (HST). The lowermost Woodford preserves a Mo-TOC signal that is consistent with a restricted basin that periodically received influxes of water consistent with rising sea levels flowing into restricted sub-basins that became isolated by localized conditions. The middle Woodford preserves a signal that indicates an increased ventilation at the sediment-water interface persisting until the maximum flooding surface. The presence of phosphate nodules in the uppermost Woodford suggests sufficient oxygen to retain the Mo in solution and indicates active upwelling and circulation with the Paleotethys.It is also possible to document changing ventilation patterns, non-destructively, within a basin by utilizing changing trends in redox-sensitive trace metals (Mo, Ni, and Cu) and an approximation of the degree of pyritization (aDOP) based on an idealized formula for pyrite (FeS2). This chemofacies approach produces a qualitatively similar interpretation to the changing Mo-TOC signal and can evaluate lateral trends in bottom water ventilation where destructive sampling is not permitted. Distal regions preserve the greatest degree of bottom water ventilation. Proximal regions preserve highly variable conditions with more restricted conditions being common in the lowermost Woodford Shale and ventilation improving upsection.Interpreting changing levels of bottom water anoxia enable greater degrees of precision in targeting potential hydrocarbon resources. Furthermore, this information improves our understanding of the changing environmental conditions of the Woodford Shale. The Framvaren Fjord is a reasonable modern analog for bottom water restriction in the lowermost portion of the Woodford Shale. The Cariaco Basin is a good modern analog for bottom water restriction in the middle and uppermost Woodford Shale.

Complete archive of late Turonian to early Campanian sedimentary deposition in newly drilled cores from the Tarfaya Basin, SW Morocco

An expanded succession of organic-rich marlstones and limestones deposited in the Tarfaya Basin provides an outstanding opportunity to closely retrace climate evolution and sea-level changes during the Cretaceous greenhouse period. We present high-resolution X-ray fluorescence (XRF) scanning and bulk carbon- and oxygen-isotope records from two newly drilled sediment cores in the Tarfaya Atlantic coastal basin, which recovered a continuous Upper Turonian to Campanian succession of ∼290 m thickness. The XRF core scanning records reveal three long-term oscillations in the abundance of terrigenous elements (increase of Al, Ti, K, Si, and Fe normalized against Ca), which correspond to progressive transgressive phases followed by rapid regressions during the Coniacian and early Santonian. Sea-level highstands during this interval corresponding to the Coniacian−Santonian oceanic anoxic event 3 (OAE 3) are characterized by overall oxygen-depleted to anoxic conditions at the seafloor (indicated by the high organic carbon content, the presence of laminations, and low log[Mn/S], high log[V/Ca], and high log[Br/Ca]). The upper Santonian interval marks the transition from anoxic to oxic bottom-water conditions, prevalent through the early Campanian. The composite bulk carbonate δ 13 C curve exhibits strong similarities to the global stacked δ 13 C reference curve, characterized by negative excursions in the early Coniacian (Navigation and East Cliff events) and late Santonian (bracketed by the Haven Brow and Buckle events) and by positive excursions in the latest Turonian (Hitchwood event), middle Coniacian (Wight Fall event), and at the Santonian-Campanian boundary. During the early Campanian, enhanced accumulation of fine-grained carbonate and clay-rich hemipelagic sediments, increasing bulk carbonate δ 18 O, and low log(Br/Ca) and log(V/Ca) values indicate climate cooling, associated with a substantial improvement in bottom-water ventilation. Two long-term δ 13 C cycles of ∼2 m.y. duration, probably related to variations in Earth’s orbital eccentricity, are associated with the long-term cooling trend initiating the Campanian−Maastrichtian climate transition toward a cool greenhouse state.

Mediterranean circulation perturbations over the last five centuries: Relevance to past Eastern Mediterranean Transient-type events.

The Eastern Mediterranean Transient (EMT) occurred in the Aegean Sea from 1988 to 1995 and is the most significant intermediate-to-deep Mediterranean overturning perturbation reported by instrumental records. The EMT was likely caused by accumulation of high salinity waters in the Levantine and enhanced heat loss in the Aegean Sea, coupled with surface water freshening in the Sicily Channel. It is still unknown whether similar transients occurred in the past and, if so, what their forcing processes were. In this study, sediments from the Sicily Channel document surface water freshening (SCFR) at 1910 ± 12, 1812 ± 18, 1725 ± 25 and 1580 ± 30 CE. A regional ocean hindcast links SCFR to enhanced deep-water production and in turn to strengthened Mediterranean thermohaline circulation. Independent evidence collected in the Aegean Sea supports this reconstruction, showing that enhanced bottom water ventilation in the Eastern Mediterranean was associated with each SCFR event. Comparison between the records and multi-decadal atmospheric circulation patterns and climatic external forcings indicates that Mediterranean circulation destabilisation occurs during positive North Atlantic Oscillation (NAO) and negative Atlantic Multidecadal Oscillation (AMO) phases, reduced solar activity and strong tropical volcanic eruptions. They may have recurrently produced favourable deep-water formation conditions, both increasing salinity and reducing temperature on multi-decadal time scales.

Eastern-Mediterranean ventilation variability during sapropel S1 formation, evaluated at two sites influenced by deep-water formation from Adriatic and Aegean Seas

Present-day bottom-water ventilation in the Eastern Mediterranean basin occurs through deep-water convection originating from the two marginal basins, i.e. Adriatic and Aegean Seas. In the paleo record, long periods of enhanced deep-water formation have been alternating with shorter periods of reduced deep-water formation. The latter is related mainly to low-latitude humid climate conditions and the enhanced deposition and preservation of organic-rich sediment units (sapropels). This study focuses on sedimentary archives of the most-recent sapropel S1, retrieved from two sites under the direct influence of the two deep-water formation areas. Restricted oxygen conditions have developed rapidly at the beginning of S1 deposition in the Adriatic site, but bottom-water conditions have not persistently remained anoxic during the full interval of sapropel deposition. In fact, the variability in intensity and persistence of sedimentary redox conditions at the two deep-water formation sites is shown to be related to brief episodes of climate cooling. In the Adriatic site, sapropel deposition appears to have been interrupted twice. The 8.2 ka event, only recovered at the Adria site, is characterized by gradually increasing suboxic to possibly intermittently oxic conditions and decreasing Corg fluxes, followed by an abrupt re-establishment of anoxic conditions. Another important event that disrupted sapropel S1 formation, has taken place at ca. 7.4 cal ka BP. The latter event has been recovered at both sites. In the Adriatic site it is followed by a period of sedimentary conditions that gradually change from suboxic to more permanently oxic, as deduced from the Mn/Al pattern. Using the same proxy for suboxic/oxic sedimentary redox conditions, we observe that conditions in the Aegean Sea site shift to more permanently oxic from the 7.4 ka event onwards. However, at both sites the accumulation and preservation of enhanced amounts of organic matter have continued under these suboxic to intermittently oxic sedimentary conditions. It seems thus, that after 7.4 cal ka BP sapropel-like surface or deep-chlorophyll-maximum conditions including enhanced productivity continued, whereas bottom-water conditions were at least intermittently oxic. The latter is related to decreasing precipitation, i.e. run-off, and thus a progressive development and deepening of deep-water formation. The shallower Aegean site, would be affected earlier by such deepening ventilation than the slightly deeper Adriatic site. Finally, termination of sapropel S1 formation as deduced from diminished organic matter contents and Ba/Al, appears to have occurred almost simultaneously in the two areas, namely at 6.6 ± 0.3 and 6.3 ± 0.5 cal ka BP in Adriatic and Aegean sites, respectively.

Depositional conditions during the Lower Kellwasser Event (Late Frasnian) in the deep-shelf Łysogóry Basin of the Holy Cross Mountains Poland

Integrated biostratigraphical, microfacial and geochemical studies of the Lower Kellwasser Event in the Plucki succession (southern Poland) provide details about redox conditions during the deposition of this horizon in the deep-shelf Łysogory basin of the Holy Cross Mountains. The environment is characterized by calm sedimentation and soft, muddy carbonate substrate. However, microfacies changing from wackestones to grainstones, the presence of crushed or current-oriented nautiloid shells and the occurrence of redeposited material from shallow-water Dyminy Reef environments (such as calcispheroids, algae and girvanellid cyanobacteria) suggest episodes of a higher-energy regime. Uranium/thorium ratios indicate that bottom-water redox conditions changed periodically from being mainly anoxic in the middle part of the Lower Kellwasser Horizon to dysoxic in the lower and upper parts. During a short-term episode of bottom-water ventilation, the seafloor was rapidly colonized by a dense assemblage of opportunistic buchiolid bivalves, which suffered mass mortality upon the return to anoxic conditions. A very rich concentration of cephalopods and homoctenids may be regarded as reflecting a bloom of high-density populations during high-productivity events. Similarly, they suffered mass mortality when episodically increasing anoxia/euxinia reached the upper part of the water column. The Late Frasnian inorganic carbon isotope records in the Plucki section show a positive shift with a maximum amplitude of 3‰. This enrichment in δ13C can be correlated with the deposition of the Lower Kellwasser Horizon and reflects the expansion of anoxic and probably high-productivity regimes.

Geochemistry of Aegean Sea sediments: implications for surface- and bottom-water conditions during sapropel deposition since MIS 5

Piston cores collected from the Aegean Sea provide a record of sapropel sequence S1, S3-S5. Primary productivity calculations using the equations of Muller and Suess suggest surface paleoproductivities ranged from 180 to 995 g C m-2 year-1 for sapropels and from 40 to 180 g C m-2 year-1 for nonsapropel sediments with corresponding total organic carbon values of 9%-12% and 1%-3%, respectively. The higher paleoproductivities exceed those in the most fertile modern upwelling zones, so are probably overestimated. Instead, enhanced preservation, particularly for S4 and S5, likely resulted from poor bottom-water ventilation beneath a salinity-stratified water column. If the preservation factor in the equations of Howell and Thunell is increased to account for such conditions, more realistic paleoproductivity estimates ensue. The interpreted presence of a deep chlorophyll maximum layer for S3-S5 within the lower part of the photic zone may account for high marine organic carbon and increased export production. A deep chlorophyll maximum layer is not advocated for S1 because of the presence of N. Pachyderma (d) immediately below S1. The organic geochemical data show that both marine and terrestrial organic matter contributed equally to sapropels S3, S4, and S5. Sapropels S3-S5 were deposited under normal marine conditions with very limited and temporary establishment of near-euxinic bottom-water conditions. Highly depleted and somewhat uniform Δ34S values together with the absence of fully euxinic conditions during sapropel intervals suggest that bacterially mediated sulfate reduction took place consistently below the sediment-water interface. It is believed that climbing levels of primary productivity triggered the onset of sapropel deposition, but that other contemporaneous factors extended and enhanced the conditions necessary for sapropel deposition, including increased nutrient supply from riverine inflow, water column stratification and reduced oxygenation of bottom waters, and buffering of low bottom-water oxygen levels by accumulating terrestrial organic carbon.