The soliton diffusion in the temperature region $Tl{T}_{0}(\ensuremath{\equiv}2m{c}^{2})$ is analyzed theoretically within the Su, Schrieffer, and Heeger model. Here $m$ is the soliton mass and $c$ is the acoustic-phonon velocity. It is shown that the diffusion constant increases exponentially like $\mathrm{exp}(\frac{{T}_{0}}{T})$ as the temperature $T$ is decreased below ${T}_{0}$. This temperature dependence appears to be consistent with some of the recent nuclear-magnetic-resonance experiments in pristine polyacetylene.
Read full abstract