The rheological property of mortar is significantly influenced by its contained fine aggregate morphology characteristic and capable predictive models are limited. This work aims to expand the film thickness theory by developing an index that integrally represents variations in grain shape, gradation, and mix proportions, and elucidates the impact and the mechanism of these multifactorial differences on rheological performance. The quantitative analysis of the aggregate gradation and particle shape differences were performed, which was used to assess the impact of these variations and different mix ratios on the rheological performance of mortars. A correlation between aggregate differences and film thickness was established using specific surface area and void ratio. The result shows that variations in aggregates are accurately assessed by image analysis and consistently reflected in specific surface area and void ratio metrics. Since variations in rheological performance are predominantly governed by differences in film thickness, the disparities among aggregates can be quantified in terms of their impact on rheological properties by considering specific surface area and void ratio, thus translating into variations of film thickness. The differences in rheological properties due to variations in grain shape, gradation, and mix proportions can be comprehensively represented and controlled through an expansion of the film thickness model.