Variable Temperature Research Articles

Biotic and abiotic factors associated with genome size evolution in oaks.

The evolutionary processes that underlie variation in plant genome size have been much debated. Abiotic factors are thought to have played an important role, with negative and positive correlations between genome size and seasonal or stressful climatic conditions being reported in several systems. In turn, variation in genome size may influence plant traits which affect interactions with other organisms, such as herbivores. The mechanisms underlying evolutionary linkages between plant genome size and biotic and abiotic factors nonetheless remain poorly understod. To address this gap, we conducted phylogenetically controlled analyses testing for associations between genome size, climatic variables, plant traits (defenses and nutrients), and herbivory across 29 oak (Quercus) species. Genome size is significantly associated with both temperature and precipitation seasonality, whereby oak species growing in climates with lower and less variable temperatures but more variable rainfall had larger genomes. In addition, we found a negative association between genome size and leaf nutrient concentration (found to be the main predictor of herbivory), which in turn led to an indirect effect on herbivory. A follow-up test suggested that the association between genome size and leaf nutrients influencing herbivory was mediated by variation in plant growth, whereby species with larger genomes have slower growth rates, which in turn are correlated with lower nutrients. Collectively, these findings reveal novel associations between plant genome size and biotic and abiotic factors that may influence life history evolution and ecological dynamics in this widespread tree genus.

Insights into the Main Protease of SARS-CoV-2: Thermodynamic Analysis, Structural Characterization, and the Impact of Inhibitors.

The main protease (Mpro) of SARS-CoV-2 is an essential enzyme for coronaviral maturation and is the target of Paxlovid, which is currently the standard-of-care treatment for COVID-19. There remains a need to identify new inhibitors of Mpro as viral resistance to Paxlovid emerges. Here, we report the use of native mass spectrometry coupled with 193 nm ultraviolet photodissociation (UVPD) and integrated with other biophysical tools to structurally characterize Mpro and its interactions with potential covalent inhibitors. The overall energy landscape was obtained using variable temperature nanoelectrospray ionization (vT-nESI), thus providing quantitative evaluation of inhibitor binding on the stability of Mpro. Thermodynamic parameters extracted from van't Hoff plots revealed that the dimeric complexes containing each inhibitor showed enhanced stability through increased melting temperatures as well as overall lower average charge states, giving insight into the basis for inhibition mechanisms.

Preparation of Self-healing Thermoplastic Polysiloxane-Polyurea/Polyether-Polyurea Elastomer Blends with a Co-continuous Microphase Structure and In-Depth Research on Their Synergistic Effects.

Polymer blending has been an important method to create materials with specific properties that have synergistic effects. However, there are few reports on the mechanism of synergistic effects. It is well known that it is quite difficult to obtain ideal blends composed of nonpolar organosilicon polymers and polar polymers. In this paper, thermoplastic polyurea elastomer blends with a co-continuous microphase structure consisting of polysiloxane-polyurea (PDMS-PUA), polyether amine-polyurea (PEA-PUA), and compatibilizer PDMS-PUA-grafted PEA-PUA (PDMS-PUA-g-PEA-PUA) were prepared for the first time. For the first time, introduction of polysiloxane does not sacrifice mechanical properties of thermoplastic polyurea elastomers. For example, the tensile strength of the elastomer blend with 30 wt % PDMS-PUA content reached 25.7 MPa, which is higher than those of PEA-PUA and PDMS-PUA. The blends also show typical outstanding characters such as exceptional heat and water resistance. The mechanism of the synergistic effect on mechanical properties is revealed based on in-depth studies on mutual interphase interaction. In situ variable temperature infrared spectroscopic analysis (VTIR) shows that compatibilization facilitates the construction of a denser hydrogen bonding network at the blend interface, which is thought to play a key role in the co-continuous microphase structure. Microscopic morphological characterization shows that PDMS-PUA and PEA-PUA phases are deformed and oriented together during the stretching process, thus jointly resisting external forces. Moreover, the blends show an exceptional self-healing ability due to their strong and reversible hydrogen bonding network.

Effect of Meteorological Variables on Energy Demand in the Northeast and Southeast Regions of Brazil

Energy consumption demand has shown successive records during recent months, primarily associated with heat waves in almost all Brazilian states. The effects of climate change induced by global warming and the increasingly frequent occurrence of extreme events, mainly regarding temperature and precipitation, are associated with this increase in demand. In this sense, the impact of meteorological variables on load demand in some substations in the northeast and southeast of Brazil was analyzed, considering the historical series of energy injected into these substations. Fifteen substations were analyzed: three in the state of São Paulo, six in Bahia, three in Pernambuco, and three in Rio Grande do Norte. Initially, essential quality control was carried out on the energy injection data. The SAMeT data sets were used for the variable temperature, and Xavier was used for precipitation and relative humidity to obtain a homogeneous data series. Daily and monthly data were used for a detailed analysis of these variables in energy demand over the northeast and southeast regions of Brazil. Some regions were observed to be sensitive to the maximum temperature variable, while others were sensitive to the average temperature. On the other hand, few cases showed the highest correlation with the precipitation and relative humidity variables, with most cases being considered slight or close to zero. A more refined analysis was based on the type of consumers associated with each substation. These results showed that where consumption is more residential, the highest correlations were associated with maximum temperature in most stations in the northeast and average temperature in the southeast. In regions where consumption is primarily rural, the correlation observed with precipitation and relative humidity was the highest despite being negative. A more detailed analysis shows that rural production is associated with irrigation in these substations, which partly explains consumption, as when rainfall occurs, the demand for irrigation decreases, and thus energy consumption is reduced.

Anion-intercalation pseudocapacitance in oxygen vacancy-rich spinel-perovskite NiFe2O4-LaFeO3 nanocomposite for high energy density asymmetric supercapacitor application

Oxide nanomaterials have attracted significant attention as energy storage materials. The combination of spinel-perovskite oxides as nanocomposites creates dense oxygen vacancies (VO) at the hetero-interface. VO present in the complex oxides are indispensable for energy conversion applications. Herein, we demonstrated the one pot synthesis of spinel-perovskite NiFe2O4-xLaFeO3 nanocomposite and investigated the phase formation using variable temperature powder X-ray diffraction of the gel precursor. The role of oxygen-vacancy mediated tuneable redox transitions in NiFe2O4-xLaFeO3 nanocomposite has been understood. The anion-intercalation-based pseudocapacitance and the oxygen intercalation have been exploited for high-performance electrochemical energy storage. The NiFe2O4–2LaFeO3 exhibited a high specific capacity of 652 C g−1 at a current density of 2 A g−1. The fabricated NiFe2O4–2LaFeO3||NiCo2O4 asymmetric supercapacitor device (ASC) exhibited excellent cyclability over 20,000 cycles with superior capacity retention and high Coulombic efficiency (92 %) and achieved a high energy density of 42.5 Wh kg−1 at a power density of 1500 W kg−1. The presence of VO and the mixed-valence states of Fe2+/3+ were confirmed by XPS-depth profiling. The tuneable redox transition of Fe2+/3+ and VO contribute to the higher pseudocapacitance response.

Design and operational features of an active condensation system for enhanced energy efficiency in a biomass-fired district heating plant

The study addresses the design and operational features of an active condensation (AC) system aimed at improving the energy efficiency of a 3rd generation district heating (DH) plant. Several similar biomass-utilizing plants have recently been built in the Republic of Serbia. The plant is equipped with biomass-fired boilers totaling 2 MW capacity, utilizing varying qualities of wet wood chips. The goals are: (i) to determine optimal constant and variable quench temperatures; (ii) to calculate the electricity consumption of ancillary devices and assess their impact on AC system performance; (iii) to evaluate the effect of biomass moisture variations on system size and performance; (iv) to assess the economic viability of integrating the AC system; and (v) to establish selection and design criteria for the heat pump (HP). For a given commercial HP, an optimal quench temperature exists, dependent on the minimal temperature lift required by the HP. This temperature can be calculated simply by subtracting the minimal HP lift from the lowest possible temperature that the HP can supply to a DH system at the average outdoor temperature. Consequently, an optimal variable quench temperature exists that should be adjusted to enable the HP to operate with its minimal temperature lift.

Flexible AIE/PCM composite fiber with biosensing of alcohol, fluorescent anti-counterfeiting and body thermal management functions

Alcohol sensing plays a critical role in medical detection and personal health management. AIE materials with high sensitivity, selectivity and fast response have been widely used in biosensing, but their application in the field of alcohol sensing still needs further research and development. Furthermore, developing flexible phase change materials (PCMs) is significant for the research of human-body thermal management. In this study, a kind of flexible polyacrylonitrile (PAN)/polyvinylpyrrolidone (PVP)/polyethylene glycol (PEG)/Py-CH (pyrene-based AIE molecule)/SiO2@h-BN composite fiber textile (PAB) with alcohol sensing performance, writable fluorescence property, and human body thermal management function has been prepared via electrospinning technique. The PAN/PVP fiber matrix successfully integrated AIE fluorescent sensing material and PCM into a multi-functional composite with great shape stability. Owing to the introduction of novel pyrene-based Py-CH with AIE characteristic, this innovative textile exhibited wonderful fluorescent properties, including sensitive alcohol fluorescence sensing, writable fluorescence performance and variable temperature fluorescence. Furthermore, proposed PAB textile delivered a high energy storage density of 87∼90 J/g, excellent thermal reliability, great comprehensive mechanical flexibility and enhanced thermal conductivity for flexible human body thermal management. Hence, this flexible multifunctional AIE/PCM composite sensing textiles can be widely used in alcohol sensing, fluorescence anti-counterfeiting and flexible body thermal management.

Optimization for the temperature range of radiator for preventing draught risk of cold window

High surface temperature of radiator can provide thermal plume with enough momentum intensity and thus counteracts the downdraft caused by window. Meanwhile, it is necessary to avoid causing indoor temperature to exceed upper limit of thermal comfort zone. In this paper, influence of heat transfer coefficients of window and exterior wall, outdoor temperature, and average surface temperature of radiator on operative temperature (Top) and temperature difference between indoor air and window (Td) was investigated. Based on response surface method, single factor and interaction effects for the four influencing factors on Top and Td were analyzed. A framework optimizing average surface temperature of radiator for preventing draught risk of window was established. When the heat transfer coefficient of window was around 1.4 W/m2·°C and satisfied related energy-conservation standard, cold draught could be eliminated without causing indoor environment overheating. Based on the optimized temperature range, the supply water temperature was controlled, and seasonal performance using the variable temperature strategy was investigated based on TRNSYS simulation. With the variable water temperature control strategy, the output hourly indoor air temperature was within the comfortable range. In the whole heating season, hours that did not meet cold draught requirement occupied 77.22 %, as the heat transfer coefficients of window dis-satisfied the energy-saving design standard. As meeting the design standard, the proportion decreased to 12.97 %. Utilizing the optimized temperature interval can prevent discomfort caused by cold draught to the greatest extent. This study is conducive to improving thermal environment with the convective–heating system and may lead to the reduction of energy consumption for heating.

Association of canopy temperature depression and membrane relative injury with seed and biological yield in chickpea (Cicer arietinum L.) genotypes under field conditions

Twenty chickpea genotypes were screened for canopy temperature depression (CTD) and membrane relative injury (RI) at flowering, poding and grain-filling stages under natural field conditions at the Nuclear Institute for Food & Agriculture (NIFA), Peshawar, Pakistan in 2020-21 and 2021-22 crop growth seasons. Eight genotypes showed highest averaged CTD values of 4.2-5.5 °C, 3.9-4.8 °C and 4.3-4.8 °C across two seasons at flowering, poding and grain-filling stages, respectively. The same eight genotypes showed lowest average RI values ranging from 24.9-45.5%, 41.2-45.5% and 40.9-48.5% across two seasons at flowering, poding and grain-filling stages, respectively. These genotypes also produced average higher biological yield plant-1 (BYPP) ranging from 59.5 g to 70.4 g and highest seed yield plant-1 (SYPP) of 16.3 g to 20.2 g across 2020-21 and 2021-22. The CTD was significantly (P ≤ 0.01) and positively correlated with BYPP and SYPP with a strong correlation with SYPP (r = 0.9888). The RI had a negative correlation with BYPP and SYPP, being strongly negatively correlated (r = -0.9743) with SYPP. Regression analysis showed positive and negative linear relationship of CTD and RI, respectively, with BYPP and SYPP. A positive association of CTD was found with BYPP and SYPP with a strong association between CTD and SYPP (R2 = 0.977), whereas a strong negative association was found between RI and SYPP (R2 = -0.9489). Based on these results, CTD and RI may be utilized as positive indirect indicators to breed chickpea genotypes for better yield performance under natural environments with variable temperatures.

Synthesis and performance study of amphoteric polymer suspension stabilizer for cementing slurry at ultra-high temperature

As the number of ultra-deep wells increases, maintaining the suspension stability of cement slurry at ultra-high temperatures becomes increasingly challenging; the development of a suspension stabilizer suitable for ultra-high temperature environments is imperative. Therefore, this study synthesized a temperature-resistant polymer suspension stabilizer (LHAP) using 2-acrylamide-2-methylpropanesulfonic acid (AMPS), N, N-dimethyl acrylamide (DMAA), 4-acryloylmorpholine (ACMO), and quaternary ammonium cationic hydrophobic long-chain monomer hexadecyl dimethylallyl ammonium chloride (DMAAC-16) as raw materials. It was applied to maintain the suspension stability of cement slurry at ultra-high temperatures. The molecular structure and molecular weight of LHAP were characterized and tested using infrared spectroscopy, nuclear magnetic hydrogen spectroscopy, and Ubbelohde viscometer. The thermal stability and viscosity-temperature performance of LHAP were measured using thermogravimetric analysis and rheometer, respectively. Through the segmented density difference testing of cement stone columns, the suspension stability effect of LHAP on cement slurry under high temperature was evaluated. The suspension stabilization mechanism of LHAP was studied through fluorescence probe testing, variable temperature UV visible light testing, variable temperature particle size distribution testing, Zeta potential analysis, Environmental Scanning Electron Microscopy (ESEM) analysis, and scanning electron microscopy (SEM) analysis. The results indicated that the polymer suspension agent LHAP had excellent temperature resistance, and the molecules didn’t undergo significant thermal degradation below 302 ℃. At high temperatures of 220 ℃, LHAP could maintain the suspension stability of cement slurry, and the segmented density difference of cement columns was less than 0.01 g/cm3. Mechanism analysis revealed that in addition to enhancing temperature resistance by introducing sulfonic acid groups and rigid rings, LHAP also effectively maintains the stability of the slurry suspension at ultra-high temperatures by coordinating electrostatic interactions and molecular associations. LHAP can effectively solve the settlement instability problem of cement slurry under ultra-high temperature, which is beneficial for improving the safety and quality of cementing construction in ultra-deep wells.

Zero thermal expansion in KxMnxIn2-x(MoO4)3 based materials

Zero thermal expansion (ZTE) materials can solve problems such as device failure and cracking caused by mismatched coefficient of thermal expansion. However, ZTE material is rare in nature. NaZr2(PO4)3 is a framework compound with near-zero thermal expansion due to coupled rotations of rigid ZrO6 and PO4 polyhedra in the structure, and several studies have been devoted to obtaining more ZTE compounds by chemical substitution of Na or Zr. Inspired by the AAV concept we proposed, in this work, the PO4 tetrahedra with a small volume has been replaced by the large volume MoO4 tetrahedra in KxMnxIn2-x(MoO4)3 (x = 0.4, 0.6, 0.8, and 1.0) compounds to provide more space for the coupling rotation of the polyhedron, and reduce the coefficient of thermal expansion. On the other hand, the flexibility of the framework structure has been modulated by the content of K+ to achieve new ZTE materials, and the effects of K+ content on crystal structure and thermal expansion have been analyzed in detail by combining variable temperature XRD and Raman. These findings not only provide more ZTE materials, but also suggest a promising design method for ZTE materials.

Mangrove forest regeneration age map and drivers of restoration success in Gulf Cooperation Council countries from satellite imagery

Mangrove forests are found across the Gulf Cooperation Council (GCC) region despite challenging environmental extremes, including highly variable temperatures and hypersalinity. Understanding the biophysical and anthropogenic factors that influence mangrove forest growth is key to locate suitable areas for regeneration and afforestation activities. The main objectives of this study were to develop a mangrove forest regeneration age map that represents the age of all the existing secondary mangroves in the past 37 years (1986–2023). Long-term Landsat satellite imagery, the random forest classification algorithm, and logistic regression analyses were used to identify the existing secondary mangroves and determine the underlying drivers that contribute to the successful afforestation of mangroves in the region. Our results showed that only around 8.5% of secondary mangrove forests in the GCC region were older than 30 years, with mangroves younger than 5 years being the most abundant age class (41.3%). Saudi Arabia and Oman have the highest percentages of young mangroves, while relatively older secondary mangrove forests were most common in Bahrain, Qatar, and UAE. The current trends in overall mangrove area show that the UAE and Saudi Arabia have the largest total mangrove area among the GCC countries, followed by Qatar, Oman, Bahrain, and Kuwait. The results of the stepwise logistic regression show that the main drivers that influence mangrove regeneration are lower elevation, lower slope, higher available soil moisture, lower average temperatures, higher precipitation, greater proximity to freshwater sources, lower population density and greater distance from agricultural and urban areas. Our results aim to offer support to decision-making in selecting optimal areas for new planting initiatives in the region.

Macrocyclic bis-diphosphenes demonstrating bimetallic exo- and endo-cyclic binding modes.

Macrocyclic bis-diphosphenes, formally heavier derivatives of macrocyclic azobenzenes, are accessed for the first time. These are synthesised in a reproducible fashion, through the nickel-mediated homocoupling of xanthene-derived NHC-stabilised bis-phosphinidene units. This gives direct access to target macrocyclic bis-diphosphenes 2, featuring exo-cyclic coordinated Ni0 fragments. The endo-cyclic binding mode in 3 is realised by NHC-abstraction using CuCl, so demonstrating two homometallic binding modes for this system. Additionally, reaction with CuCl in acetonitrile yields small amounts of a tetra-metallic NiII/CuI complex, which establishes simultaneous exo- and endo-cyclic metal binding. Fluctional solution state behavior in these systems is explored through variable temperature NMR spectroscopy, in addition to computational bonding analyses, giving the first insights into this novel class of compounds.

Conceptual modelling on water-rock reaction and genesis of high pH fluids in a typical granitoid geothermal reservoir: A case from Indus-Tsangpo Suture Zone, India

Two novel thermal springs are investigated along ITSZ of north-west Himalayas in Demchok geothermal belt. The area consists of deep-seated faults in LGB; despite being situated in ITSZ, fluid chemistry of these low-temperature springs differs significantly, specifically in terms of low TDS (161–168 mg/l) and high alkalinity, with neighbouring springs in Puga and Chumathang (∼2100 mg/l). Thermal waters are mixed type (Na–Cl–HCO3–SO4) with elemental composition influenced through silicate rock weathering and partial carbonate dissolution. Variable temperature speciation (25 °C–200 °C) indicates that in reservoir fluid, Na+ precedes over other cations, while sulfate and carbonate complexes being prominent for Mg and Ca, respectively. Aquifer boiling modelling suggests calcite scaling and silica mineral equilibration in reservoir. Environmental stable isotopes (δ18O and δD) suggest high-altitude recharge from Jamlung La (6156 m), with altitude-effect of 0.43 ‰ isotopic depletion per 100 m elevation in altitude. As only silica minerals equilibrate with thermal waters, silica, and gas geothermometers give most conservative estimate of reservoir temperature (125°−135 °C). The steep topography enables extensive lateral flow of hot fluids in outflow zone, leading to high mixing and a high water-rock ratio, which contribute to lower TDS. Conceptual modelling reveals that geothermal system is a low-enthalpic hydrothermal system controlled by joints and permeable fractures, having deep fluid circulation of meteoric waters of ∼1275 m at sub-surface, with anomalous geothermal gradient and steam migration as reservoir heat sources. These fluids closely resemble springs of Guerrero state, Mexico, exhibiting similarities in low-TDS, high-pH, and high concentration of dissolved silica.

An economic, and environmentally benign Psidium guajava L. leaves catalyst for biodiesel production at room temperature: Process optimization, and life cycle cost analysis

Biodiesel has emerged as a popular alternative to conventional fossil fuel in transportation sector and thus producing low-cost biodiesel is a topic of interest for a large community of researchers. This study reports the preparation of an efficient and robust heterogeneous catalyst from dried Psidium guajava L. (Guava) leaves and its application towards generation of biodiesel from soybean oil at room temperature. The biomass material was calcinated at variable temperature and the efficiency of each of the catalyst prepared was studied. The catalyst generated as well as the product biodiesel was thoroughly characterized using sophisticated analytical techniques. The catalyst was found to have mesoporous structure with active basic sites which contributed towards accelerating the transesterification process. Detailed characterization unveiled the occurrence of Ca as oxide and carbonate, in addition to a certain quantity of K in oxide and carbonate form, which contribute to the catalyst’s activity. Maximum biodiesel yield of 95.8 % was observed for reaction performed under optimum experimental conditions i.e., 1:17 oil-to-methanol ratio, 6 wt% loading of GL-850 (catalyst prepared by calcination at 850°C), and 15 % n-Hexane loading for 3 h at room temperature. GL-850 demonstrated exceptional recyclability for up to the fifth cycle exhibiting a mere 3.7 % decline in yield. The calculated expense for 1 kg catalyst was found to be $0.478, whereas the production cost of 1 kg biodiesel was found to be merely $1.120, indicating a strong economic feasibility of the process.

Study of Density, Sound Velocity, And Conductance of Levocetirizine in Aqueous Sodium Chloride at Variable Temperatures

Study of Density, Sound Velocity, And Conductance of Levocetirizine in Aqueous Sodium Chloride at Variable Temperatures

High-temperature fretting wear behavior and microstructure stability of a laser-cladding Ti-Al-C-N composite coating meditated by variable cycle conditions

Ti-6Al-4 V titanium alloy is used for low-pressure compressor blades of aero-engine due to its high specific strength, excellent corrosion resistance and high-temperature stability. Low-pressure compressor blades are subject to fretting wear in service, which may lead to fracture failure of the blades. The preparation of wear-resistant coatings is currently an effective solution in solving the problem of fretting wear on Ti-6Al-4 V titanium alloy. However, the fretting wear resistance and microstructure stability of the coating under variable cycle fretting conditions require more attention. In this work, the fretting wear performance and microstructure stability of the Ti-Al-C-N composite coating under variable cycle fretting conditions are investigated. The results show that the parameters of variable cycle operating conditions have a notable effect on the coefficient of friction (COF). The variable frequency and variable temperature working conditions result in the alteration of the fretting operation mechanism. Whereas the variable stroke amplitude and the variable load conditions do not cause changes in the fretting operation mechanism, and both are in the gross slip region (GSR). The lowest wear rate occurs under variable stroke amplitude conditions. The wear rate is the maximum under the variable cycle temperature condition. According to the dissipated energy calculation, the difference between the two different stroke amplitudes is the biggest among all the conditions. EBSD and TEM analyses show that the subsurface of variable stroke amplitude worn scar has a more uniform strain distribution, and reveals a unique subsurface structure with a transformation from crystalline to amorphous, which contributes to improving the wear resistance. This work provides insights into coating microstructure stability and wear mechanisms under variable cycle conditions.

TO THE ISSUE OF SOIL VARIOUS TYPES INFLUENCE ON PIPELINE LONGITUDINAL MOVEMENT

Achieving and maintaining the required reliability of the linear part of the main gas pipelines is of great importance. Emergency destruction usually leads to large gas leaks into the atmosphere and undersupply to consumers, significant costs for the restoration of main gas pipelines. The rise in cost of repair work on main gas pipelines directly depends on the difficult conditions of the route. Special technical solutions are to be used for achieving the necessary stability and reliability of pipelines on low-bearing soils. Thus, on operating gas pipelines at variable temperatures of the transported product, their longitudinal movements occur, resulting in longitudinal forces appearance and correspondingly in increase of gas pipeline stress state and their possible destruction. The significant period of time of increase in gas pipeline movements indicates that these changes in pipeline position occur due to the rheological properties of soils. An analysis of the stress state of such sections of gas pipelines is necessary to assess their operational reliability and, as a result, the timing and methods of repair. This article discusses the maximum values of longitudinal displacements of a pipeline laid in various soils and the deflection values corresponding to these models for potentially dangerous sections.

Theoretical calculation methods of stable bearing capacity for thin-walled shells with corrosion and variable temperature

AbstractThin-wall shells (steel plates, steel cylindrical shells, steel spherical shells, etc.) are widely used in many engineering fields such as construction, machinery, chemical industry, navigation, and aviation because of their light weight and high strength. Their failure modes under static pressure or impact dynamic load are mostly buckling instability, and the failure is very sudden, often causing structural failure or even catastrophic accidents without obvious symptoms. In this framework, the significance of this paper is that it considers the influence of external environment corrosion on steel shells' bearing capacity using plate and shell classical stability theory, and investigates the stable bearing capacity of thin-wall steel shells in view of corrosion impact. By this approach, a theoretical calculating method for the time-varying stable bearing capacity of plate and shell thin-walled steel members under the simultaneous action of corrosion and temperature changes is obtained, providing a useful theory for complex engineering practices such as corrosion and temperature changes, including fire actions. Noted that for this method with no analytical solution found, its numerical solutions are given in the appendixes.

Understanding Climate Variability and Malaria Transmission in West Africa: Case Studies, Regional Insights, and Future Directions

Climate variability plays a crucial role in malaria transmission in West Africa. Variable temperature, rainfall, and humidity patterns in diverse climatic zones, such as tropical rainforests and semi-arid regions, significantly influence mosquito breeding sites and transmission rates. Tropical rainforests experience high transmission rates due to consistent rainfall and humidity, while savanna regions experience seasonal peaks. Semi-arid regions with limited rainfall and extreme temperatures show lower but variable transmission rates. Temperature fluctuations affect the development and survival of Anopheles mosquitoes and malaria parasites. Rising temperatures can extend transmission seasons and spread the disease to unaffected areas. Rainfall patterns affect breeding site availability, with heavy rains increasing breeding sites and droughts reducing mosquito populations. Humidity influences mosquito survival and parasite development. Extreme weather events, such as cyclones and floods, exacerbate malaria transmission by increasing breeding sites and damaging infrastructure. Socioeconomic factors, including urbanization, land use changes, and economic instability, also interact with climate variability to impact malaria dynamics. The review highlights the need for integrated malaria control strategies that incorporate climate considerations, including enhanced surveillance, climate-resilient infrastructure, and community engagement. Future research should address knowledge gaps regarding the interaction between climate variables and malaria transmission, and the socioeconomic impacts of climate change on malaria dynamics. By tailoring control strategies to specific climatic and socio-economic contexts, stakeholders can better manage malaria risks and improve health outcomes across West Africa. Keywords: Climate, Variability, Malaria, Transmission, West Africa, Case Studies.