A novel method involving twin-wire pulsed VPPA (P-VPPA) welding was combined with Ti–Zr microalloying to improve the mechanical properties of AA2195-T8 Al–Cu–Li alloy variable polarity plasma arc (VPPA) welded joints. This method aimed to increase the width of the equiaxial cellular grain zone (ECZ) by adding higher content of Ti–Zr and reducing heat input. The microstructure evolution process was established to understand the formation and strengthening mechanism of the ECZ. The results showed that the strength of the ECZ was higher than that of the dendrite in the weld zone (WZ). The twin-wire VPPA welding led to the formation of a wider ECZ near the fusion zone (FZ). This ECZ was continuously distributed throughout the thickness direction of the welded joint. Combined with higher Ti–Zr microalloying, the maximum width of ECZ increased to 2.5 mm and extended to the WZ. Consequently, the proportion of cracks passing through the ECZ during tensile fracture increased from 27.6% to 88.7%. Moreover, the ultimate tensile strength (UTS) of the welded joint exhibited a notable improvement, rising from 328 MPa to 370 MPa, while the elongation also increased to 5%. The UTS of the welded joint achieved 66% of the base metal. Additionally, the average grain size in the ECZ was 14 μm. The formation of the ECZ was primarily attributed to the nucleation precursors of Al3(Ti, Zr) and β′ phase, as well as less welding heat input near the FZ. The widening of the ECZ was mainly due to the presence of more Al3(Ti, Zr) phases. Moreover, the grain boundary of the ECZ exhibited the distribution of Al–Cu eutectic, θ(Al2Cu), Ω, T2(Al6CuLi3), and ω(Al7Cu2Fe) phases, while a small amount of T1(Al2CuLi) phase precipitated within the grain. The strengthening mechanism of ECZ is the result of multiple strengthening effects, including the reduction of element segregation and microcracks, the precipitation of the T1 phase, and the fine grain strengthening.
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