Atmospheric Vapor Research Articles

Photosynthetic responses of large old Zelkova serrata (Thunb.) Makino trees to different growth environments

Large old trees, which provide ecosystem services and serve as a historical and cultural heritage, are exposed to various environmental threats, such as habitat fragmentation and climate change, necessitating diagnosis of tangible and intangible stresses and their effects on tree growth for effective management. This study investigated the photosynthetic characteristics of 25 large old Zelkova serrata (Thunb.) Makino trees in Chungcheong Province, Korea, and identified the physical environmental factors affecting their physiological responses. Maximum assimilation rate (Amax) was the highest in July (summer), transpiration rate (E) and stomatal conductance (gs) increased from May (spring) to September (fall), and water use efficiency (WUE) was the highest in May (spring) and decreased until September (fall). Amax decreased as tree height increased. Ambient CO2 and vapor pressure deficit (VPD) were negatively correlated with photosynthetic parameters throughout the growth season and in July (summer) and September (fall), respectively. Physical environmental factors exhibited complex effect on physiological activities, which increased with wide growth space and decreased with deep soil covering and high impervious ground surface ratio. Physiological responses differed with surface types within the growth space, with bare land showing higher mean Amax, E, and gs than areas with mulching material or concrete. This study quantitatively determined the physiological activities of large old Z. serrata and proposes appropriate management measures for ensuring their healthy growth in abiotic stress environment.

Evapotranspiration partitioning based on underlying conductance in a complex tree-grass orchard ecosystem in the humid area of southern China

Partitioning of evapotranspiration (ET) into its components (vegetation transpiration (T), soil evaporation (ESoil) and evaporation from intercepted water (Ei)) in agroforestry systems can provide valuable assessments of plant water use. However, it is still challenging to quantify the contributions of different vegetation elements to T, especially when the underlying surface is complex, consisting of trees and heterogeneous grass. Based on the water-carbon coupling theory and flux conservation hypothesis, an ET partitioning method was proposed to partition total ET into T from the tree (TTree) and understory grass (TGrass), and ESoil in a humid region tree-grass orchard ecosystem during three growing seasons (from mid-March to end-October) of 2018–2020. The results demonstrated that the partitioned TTree and understory evapotranspiration (ETun=TGrrass+ESoil) agreed well with the values measured by the heat-pulse sap flow sensors (R2 of 0.744, and RMSE of 0.379 mm d–1) and micro-lysimeters (R2 of 0.650 and RMSE of 0.545 mm d–1). The derived underlying transpiration (TGs=TTree+TGrass) was strongly consistent with Zhou's underlying water use efficiency approach (R2 of 0.939 and RMSE of 0.382 mm d–1). The estimated TGs was 536, 433 and 383 mm during the three growing seasons, resulting in a higher TGs/ET ratio of 0.74 ± 0.03 (±standard deviation). Among them, TGrass contributed to 0.32 ± 0.05 ET, while the contribution was 0.42 ± 0.02 for TTree. Esoil and residual evaporation (including Ei and estimated error) accounted for a small ET proportion, with the value of 0.13 ± 0.02 and 0.14 ± 0.01, respectively. The partitioned ET components (TTree/ET, TGs/ET and ESoil/ET) were well controlled by variations of atmospheric evaporation demand and vegetation factors, but were little affected by soil water content. Increased tree leaf area limited TGrass due to shading effects, however, TGrass tended to contribute more transpiration water under a higher atmospheric evaporation environment. The findings of this study enhance the knowledge about the contributions of individual ET components on total ET in a complex tree-grass ecosystem, and provide further insights on plant-plant interactions in terms of water use strategies and orchard water management.

Retrievals of vertical distribution of Martian water vapor from combined day and night MGS TES nadir spectra

Vertical distribution of water vapor in the Martian lower atmosphere (0–40 km) is an important characteristic of the Martian water cycle. It reflects a complex interplay between various processes shaping the contemporary water cycle, including atmospheric transport, formation of water ice clouds, sublimation of surface frost, and possible interaction with the subsurface. Despite the growing dataset of water vapor observations, there is yet no comprehensive climatology of the vertical distribution of vapor. Limb and solar occultation observations that are typically used to retrieve vapor vertical distribution are much less numerous than nadir observations and are available for limited seasons and locations. We propose a new methodology to retrieve vertical distribution of water vapor in the Martian lower atmosphere using only nadir data. The methodology is based on the observation that infrared spectra collected over same location during different parts of day are sensitive to water vapor in different parts of the atmosphere. We validate our new methodology by applying it to infrared spectra simulated for realistic Mars environments created with Mars General Circulation Model (GCM). These tests show that vertical profiles of vapor can be recovered with accuracy ~20–40%, which is comparable to accuracy of limb and occultation observations. Importantly, the new retrieval algorithm can constrain near-surface (0–10 km) vapor abundances that cannot be observed by limb and occultation techniques. Application of this new methodology to a large dataset on Martian nadir spectra, such as the one collected by the Thermal Emission Spectrometer (TES) onboard Mars Global Surveyor (MGS) during its mission in 1999–2004, can result in the development of the detailed climatology of vapor vertical distribution on Mars. As an initial step toward this goal, we apply the new retrieval methodology to a subset of nadir spectra collected by MGS TES during one Martian year. The retrieved vapor profiles are qualitatively consistent with vapor distributions predicted by the GCM for different seasons. Differences between retrieved and simulated profiles can be interpreted as reflecting wetter Martian atmosphere and weaker atmospheric transport, during some seasons. Retrieved vapor distribution during southern summer suggests disruption of atmospheric vapor transport into southern extra-tropics following a global dust storm.

Improved Configurational Sampling Protocol for Large Atmospheric Molecular Clusters.

The nucleation process leading to the formation of new atmospheric particles plays a crucial role in aerosol research. Quantum chemical (QC) calculations can be used to model the early stages of aerosol formation, where atmospheric vapor molecules interact and form stable molecular clusters. However, QC calculations heavily depend on the chosen computational method, and when dealing with large systems, striking a balance between accuracy and computational cost becomes essential. We benchmarked the binding energies and structures and found the B97-3c method to be a good compromise between the accuracy and computational cost for studying large cluster systems. Further, we carefully assessed configurational sampling procedures for targeting large atmospheric molecular clusters containing up to 30 molecules (approximately 2 nm in diameter) and proposed a funneling approach with highly improved accuracy. We find that several parallel ABCluster explorations lead to better guesses for the cluster global energy minimum structures than one long exploration. This methodology allows us to bridge computational studies of molecular clusters, which typically reach only around 1 nm, with experimental studies that often measure particles larger than 2 nm. By employing this workflow, we searched for low-energy configurations of large sulfuric acid-ammonia and sulfuric acid-dimethylamine clusters. We find that the binding free energies of clusters containing dimethylamine are unequivocally more stable than those of the ammonia-containing clusters. Our improved configurational sampling protocol can in the future be applied to study the growth and dynamics of large clusters of arbitrary compositions.

Dryness stress weakens the sustainability of global vegetation cooling

Dryness stress can limit vegetation growth, and the cooling potential of vegetation will also be strongly influenced. However, it is still unclear how dryness stress feedback weakens the sustainability of vegetation-based cooling. Based on the long-time series of multi-source remote sensing product data for the period 2001–2020, the relative contribution rate, and the method of decoupling and boxing, we determined that greening will likely mitigate global warming by 0.065 ± 0.009 °C/a, but nearly 47 % of the area is unsustainable. This phenomenon is strongly related to dryness stress. The restricted area of soil moisture (SM: 68.35 %) to vegetation is larger than that of the atmospheric vapor pressure deficit (VPD: 34.19 %). With the decrease in SM, vegetation will decrease by an average of 14.9 %, and with the increase in VPD, vegetation will decrease by 3.8 %. With the continuous increase in the dryness stress area, the sustainability of the vegetation cooling effect will be threatened in an area of about 21.03 million km2, which is equivalent to the area of North America. Specifically, we found that with the decrease in SM and the increase in VPD, the contribution of vegetation to the cooling effect has been weakened by 10.8 %. This conclusion confirms that dryness stress will threaten the sustainability of vegetation-based climate cooling and provides further insight into the effect of dryness stress on vegetation cooling.

Energy balance closure and evapotranspiration hysteresis in central Amazon under contrasting conditions during the GoAmazon project in 2014 and 2015

The Amazon region stands out as Earth's largest and most prominent terrestrial convective center, significantly influencing precipitation patterns through the substantial net radiation at the Earth's surface (Rn). This radiation is further divided into sensible heat (H) and latent heat (LE) fluxes, underscoring the critical need to investigate the intricate exchanges of energy between ecosystems and the atmosphere while also scrutinizing the closure of the energy balance (EBC). Such studies are of paramount importance for gaining a comprehensive understanding of natural process dynamics. This research was undertaken to refine our comprehension of the temporal variability of energy fluxes, energy balance closure, and the phenomenon of evapotranspiration (ET) hysteresis in relation to key atmospheric variables, namely, Rn, air temperature, and vapor pressure deficit (VPD), within the central Amazon region. This investigation spanned a typical year (2014) and accounted for the influence of an El Niño Southern Oscillation (ENSO) event (2015). The findings illuminated that LE constituted the predominant component of the energy balance in both years, comprising approximately 70% of the total energy flux, except during the dry season of 2015 when H took precedence, accounting for 55% of the total energy exchange due to the ENSO event. The EBC exhibited an underestimation of turbulent fluxes (H + LE) of around 24% relative to the available energy (Rn - G). A more robust closure was observed during the dry period of 2015, reaching 82%, suggesting heightened uncertainty in LE estimates. In the context of ET, clockwise hysteresis loops were observed concerning air temperature and VPD. The relationship between ET and Rn displayed a linear response to solar radiation, with the intensity of ET hysteresis becoming more pronounced when correlated with air temperature and VPD.

Development of a DNN Predictive Model for the Optimal Operation of an Ambient Air Vaporizer of LNG

In this study, we conducted preliminary research with the objective of leveraging artificial intelligence to optimize the efficiency and safety of the entire Ambient Air Vaporizer (AAV) system for LNG (Liquid Natural Gas). By analyzing a year-long dataset of real operational data, we identified key variables that significantly influence the outlet temperature of Natural Gas (NG). Based on these insights, a Deep Neural Network (DNN) prediction model was developed to forecast the NG outlet temperature. The endeavor to create an effective prediction model faced specific challenges, primarily due to the narrow operational range of fan speeds and safety-focused guidelines. To surmount these obstacles, various learning algorithms were evaluated under multiple conditions. Ultimately, a DNN model exhibiting lower values of both absolute mean error (MAE) and mean square error (MSE) was successfully established.

Low-temperature homoepitaxial growth of β-Ga2O3 thin films by atmospheric pressure plasma-enhanced chemical vapor deposition technique

Low-temperature homoepitaxial growth of β-Ga2O3(-201) has been successfully demonstrated by the atmospheric pressure plasma-enhanced chemical vapor deposition technique. To search for low-temperature growth, temperature-dependent studies were carried out between 350 and 600 °C. A high N2 gas flow rate, low gallium source concentration, and high oxygen flow rate ratio played key roles in growing independent and homogeneous multiple nuclei of Ga2O3, leading to three-dimensional grain growth mode, single crystallinity, and the highest growth rate of ⁓0.17 µm/h at 350 °C. The highly reactive atmospheric pressure oxygen plasma actively led to epitaxial growth. The low thermal budget homoepitaxial growth is a record reduction reported thus far.

Water Vapor Vertical Distribution on Mars During Perihelion Season of MY 34 and MY 35 With ExoMars‐TGO/NOMAD Observations

AbstractThe water vapor in the Martian atmosphere plays a significant role in the planet's climate, being crucial in most of the chemical and radiative transfer processes. Despite its importance, the vertical distribution of H2O in the atmosphere has not still been characterized precisely enough. The recent ExoMars Trace Gas Orbiter mission, with its Nadir and Occultation for MArs Discovery instrument, has allowed us to measure the H2O vertical distribution with unprecedented resolution. Recent studies of vertical profiles have shown that high dust concentration in the atmosphere, in particular during dust storms, induces an efficient transport of the H2O to higher altitudes, from 40 km up to 80 km. We study the H2O vertical distribution in a subset of solar occultations during the perihelion of two Martian years (MYs), including the 2018 Global Dust Storm (GDS), in order to compare the same Martian season under GDS and non‐GDS conditions. We present our state‐of‐the‐art retrieval scheme, and we apply it to a combination of two diffraction orders, which permits sounding up to about 100 km. We confirm recent findings of H2O increasing at high altitudes during Ls = 190°–205° in MY 34, reaching abundances of about 150 ppmv at 80 km in both hemispheres not found during the same period of MY 35. We found a hygropause's steep rising during the GDS from 30 up to 80 km. Furthermore, strong supersaturation events have been identified at mesospheric altitudes even in presence of water ice layers retrieved by the IAA team.

Epitaxial Growth of Cobalt Oxide Thin Films on Sapphire Substrates Using Atmospheric Pressure Mist Chemical Vapor Deposition

This study demonstrated the epitaxial growth of single-phase (111) CoO and (111) Co3O4 thin films on a-plane sapphire substrates using an atmospheric pressure mist chemical vapor deposition (mist-CVD) process. The phase structure of the grown cobalt oxide films was manipulated by controlling the growth temperature and process ambient, confirmed through X-ray diffraction, Raman spectroscopy, and X-ray photoelectron spectroscopy. Furthermore, the electrical properties of Co3O4 films were significantly improved after thermal annealing in oxygen ambient, exhibiting a stable p-type conductivity with an electrical resistivity of 8.35 Ohm cm and a carrier concentration of 4.19 × 1016 cm−3. While annealing CoO in oxygen atmosphere, the Co3O4 films were found to be most readily formed on the CoO surface due to the oxidation reaction. The orientation of the atomic arrangement of formed Co3O4 was epitaxially constrained by the underlying CoO epitaxial layer. The oxidation of CoO to Co3O4 was largely driven by outward diffusion of cobalt cations, resulting in the formation of pores in the interior of formed Co3O4 films.

Inter-virus relationships in mixed infections and virus-drought relationships in plants: a quantitative review.

Inter-virus relationships in mixed infections and virus-drought relationships are important in agriculture and natural vegetation. In this quantitative review, we sampled published factorial experiments to probe for relationships against the null hypothesis of additivity. Our sample captured antagonistic, additive and synergistic inter-virus relationships in double infections. Virus-drought relationships in our sample were additive or antagonistic, reinforcing the notion that viruses have neutral or positive effects on droughted plants, or that drought enhances plant tolerance to viruses. Both inter-virus and virus-drought relationships vary with virus species, host plant to the level of cultivar or accession, timing of infection, plant age and trait and growing conditions. The trait-dependence of these relationships has implications for resource allocation in plants. Owing to lagging theories, more experimental research in these fields is bound to return phenomenological outcomes. Theoretical work can advance in two complementary directions. First, the effective theory models the behaviour of the system without specifying all the underlying causes that lead to system state change. Second, mechanistic theory based on a nuanced view of the plant phenotype that explicitly considers downward causation; the influence of the plant phenotype on inter-virus relations and vice versa; the impact of timing, intensity and duration of drought interacting with viruses to modulate the plant phenotype; both the soil (moisture) and atmospheric (vapour pressure deficit) aspects of drought. Theories should scale in time, from short term to full growing season, and in levels of organisation up to the relevant traits: crop yield in agriculture and fitness in nature.

Increasing atmospheric dryness reduces boreal forest tree growth

Rising atmospheric vapour pressure deficit (VPD) associated with climate change affects boreal forest growth via stomatal closure and soil dryness. However, the relationship between VPD and forest growth depends on the climatic context. Here we assess Canadian boreal forest responses to VPD changes from 1951-2018 using a well-replicated tree-growth increment network with approximately 5,000 species-site combinations. Of the 3,559 successful growth models, we observed a relationship between growth and concurrent summer VPD in one-third of the species-site combinations, and between growth and prior summer VPD in almost half of those combinations. The relationship between previous year VPD and current year growth was almost exclusively negative, while current year VPD also tended to reduce growth. Tree species, age, annual temperature, and soil moisture primarily determined tree VPD responses. Younger trees and species like white spruce and Douglas fir exhibited higher VPD sensitivity, as did areas with high annual temperature and low soil moisture. Since 1951, summer VPD increases in Canada have paralleled tree growth decreases, particularly in spruce species. Accelerating atmospheric dryness in the decades ahead will impair carbon storage and societal-economic services.

Assessing the variability of tissue-free water tritium and non-exchangeable organically bound tritium in pine needles in Fukushima using atmospheric titrated water vapor

When conducting environmental tritium monitoring at nuclear and fusion facilities, it is important to understand how tritium concentrations vary within the soil-plant-atmosphere continuum. Past measurements of organically bound tritium (OBT) concentrations have been conducted from the standpoint of ascertaining the persistence of tritium in terrestrial vegetation, and it has been reported that OBT concentrations fluctuate depending on the influence of atmospheric sources and meteorological conditions. The present study provides information on the variability of tritium concentrations in vegetation growing close to atmospheric sources of tritiated water (HTO) in Japan. We conducted measurements of tissue-free water tritium (TFWT) and non-exchangeable OBT (NE-OBT) in pine needles collected from locations near the Tokyo Electric Power Company's Fukushima Daiichi Nuclear Power Plant from 2018 to 2021. The results we obtained indicate that TFWT concentrations fluctuate in response to short-term changes in atmospheric HTO vapor concentrations and that NE-OBT concentrations vary primarily in response to the time-averaged TFWT concentration during the pine needle growing season, which is in turn mainly determined by atmospheric HTO vapor concentrations. Although it is difficult to ascertain the time-averaged TFWT concentration during the growing season by measuring plant materials, our results show that the measurement of atmospheric HTO vapor concentrations provides an effective alternative method of doing this. We believe our findings can lead to better understanding of the potential impact on the terrestrial environment associated with the atmospheric discharge of HTO and can contribute to improving the strategy of environmental tritium monitoring.

Controllable growth of wafer-scale two-dimensional WS2 with outstanding optoelectronic properties

As one of two-dimensional (2D) semiconductor materials, transition metal dichalcogenides (TMDs) have sparked enormous potential in next-generation electronics due to their unique and excellent physical, electronic and optical properties. Controllable growth of wafer-scale 2D TMDs is essential to realize the various high-end applications of TMDs, while it remains challenging. Herein, 2 inch 2D WS2 films were successfully synthesized by ambient pressure chemical vapor deposition based on substrate engineering and space-confined strategies. WS2 nucleation density can be effectively modulated depending on the annealing conditions of sapphire substrate. The thickness of WS2 films can be controllably fabricated by adjusting the space-confined height. Moreover, our strategies are demonstrated to be universal for the growth of other 2D TMD semiconductors. WS2-based photodetectors with different thicknesses were systematically investigated. Monolayer WS2 photodetector displays large responsivity of 0.355 A W−1 and high specific detectivity of 1.48 × 1011 Jones. Multilayer WS2 device exhibits negative self-powered photoresponse. Our work provides a new route for the synthesis of wafer-scale 2D TMD materials, paving the way for high performance integrated optoelectronic devices.

Study of the High‐Temperature Oxidation Behavior of SUS430 Ferritic Stainless Steel Under Different Content of Water Vapor Atmosphere

The oxidation behavior of SUS430 ferritic stainless steel is studied during isothermal oxidation at 1100 °C for 2 h under a mixture of 10, 30, and 50% water vapor and air, and oxidation kinetics curves are drawn. The surface morphology and phase composition of oxide scale are analyzed using X‐Ray diffractometer, scanning electron microscope, and energy dispersive spectrometer. The oxidation kinetic curves under three different humidities are S‐shaped and include three stages: induction period, acceleration period, and deceleration period. The controlling steps under 10% water vapor and air are nucleation and growth, while under 30% and 50% water vapor and air are both phase boundary control reactions. The induction period becomes shorter and the breakaway oxidation occurs earlier with increasing water vapor content. The structure of oxide scale produced is layered, with the outer layer being iron oxide and the inner layer being mainly the Fe–Cr spinel phase. The volatilization of Cr and the growth stress of the Cr2O3 layer cause the formation of nodules, and a large number of cracks are generated in oxide scale. The cracks provide diffusion paths, accelerating the diffusion of Fe ions and electrons, as well as the erosion of the substrate.

Insights into the Growth of Ternary WSSe Nanotubes in an Atmospheric CVD Reactor.

The synthesis of complex new nanostructures is challenging but also bears the potential for observing new physiochemical properties and offers unique applications in the long run. High-temperature synthesis of ternary WSe2xS2(1-x) (denoted as WSSe) nanotubes in a pure phase and in substantial quantities is particularly challenging, requiring a unique reactor design and control over several parameters, simultaneously. Here, the growth of WSSe nanotubes with the composition 0 ≤ x < 1 from W18O49 nanowhiskers in an atmospheric chemical vapor deposition (CVD) flow reactor is investigated. The oxide precursor powder is found to be heavily agglomerated, with long nanowhiskers decorating the outer surface of the agglomerates and their core being enriched with oxide microcrystallites. The reaction kinetics with respect to the chalcogen vapors varies substantially between the two kinds of oxide morphologies. Insights into the chemical reactivity and diffusion kinetics of S and Se within W18O49 nanowhishkers and the micro-oxide crystallites were gained through detailed microscopic, spectroscopic analysis of the reaction products and also through density functional theory (DFT) calculations. For safety reasons, the reaction duration was limited to half an hour each. Under these circumstances, the reaction was completed for some 50% of the nanotubes and the other half remained with thick oxide core producing new WOx@WSSe core-shell nanotubes. Furthermore, the selenium reacted rather slowly with the WOx nanowhiskers, whereas the more ionic and smaller sulfur atoms were shown to diffuse and react faster. The yield of the combined hollow and core-shell nanotubes on the periphery of the agglomerated oxide was very high, approaching 100% in parts of the reactor boat. The nanotubes were found to be very thin (∼80% with a diameter <40 nm). The optical properties of the nanotubes were studied, and almost linear bandgap modulation was observed with respect to the selenium content in the nanotubes. This investigation paves the way for further scaling up the synthesis and for a detailed study of the different properties of WSSe nanotubes.

Thermal stability, work function and Fermi level analysis of 2D multi-layered hexagonal boron nitride films

Thermal stability and Fermi level analysis of commercial multilayer (ML) and as-grown 10 nm thick hexagonal boron nitride (hBN) films on Cu foil by atmospheric chemical vapor deposition (APCVD) by heating in N2 and air at temperatures ≤900 °C are studied. For all samples, progressive surface oxidation was observed correlating with higher hBN nucleation density. Thermal stability was measured in air from 200 °C to 400 °C (relative humidity ∼65%) where commercial ML and APCVD material degraded; BN peaks begin to be replaced by BO peaks at temperatures >300 °C. It is shown that hBN thermal stability is sensitive to Tgrowth and Cu foil surface preparation methods such as electropolishing (EP). We evaluate as-grown material for different Tgrowth conditions (1000 °C, 1030 °C, 1050 °C and 1060 °C) by ultraviolet photoelectron spectroscopy (UPS) to locate and understand subsequent Fermi level and work function variation, confirming our material is in general n-type, which becomes increasingly so as thermal stability regresses. To this effect, we observe a work function increase of 0.45 eV as BO increases with in-situ anneal temperature. An average electron affinity of 2.13 eV and 1.7 eV is determined for commercial hBN and APCVD material, respectively. Further work is required by material scientists to optimize the material properties of CVD hBN.

Three young planets around the K-dwarf K2-198: high-energy environment, evaporation history, and expected future

ABSTRACT Planets orbiting young stars are thought to experience atmospheric evaporation as a result of the host stars’ high-magnetic activity. We study the evaporation history and expected future of the three known transiting exoplanets in the young multiplanet system K2-198. Based on spectroscopic and photometric measurements, we estimate an age of the K-dwarf host star between 200 and 500 Myr, and calculate the high-energy environment of these planets using eROSITA X-ray measurements. We find that the innermost planet K2-198c has likely lost its primordial envelope within the first few 10s of Myr regardless of the age at which the star drops out of the saturated X-ray regime. For the two outer planets, a range of initial envelope mass fractions is possible, depending on the not-yet-measured planetary mass and the stars’ spin-down history. Regarding the future of the system, we find that the outermost planet K2-198b is stable against photoevaporation for a wide range of planetary masses, while the middle planet K2-198d is only able to retain an atmosphere for a mass range between ∼7 and 18 M⊕. Lower mass planets are too susceptible to mass-loss, and a very thin present-day envelope for higher mass planets is easily lost with the estimated mass-loss rates. Our results support the idea that all three planets started out above the radius valley in the (sub-)Neptune regime and were then transformed into their current states by atmospheric evaporation, but also stress the importance of measuring planetary masses for (young) multiplanet systems before conducting more detailed photoevaporation simulations.

Spatial and temporal distribution of geochemical elements and their processes in different size fractions–Miri River (NW Borneo)

The toxicity, persistence, and propensity for accumulation of metals in aquatic environments have raised significant concerns globally. Expansion of urbanization with the growth of industrial and agricultural sectors in Miri City results in a high concentration of pollutants that flow directly into the Miri River. Hence, this study provides a comprehensive analysis of the Miri River water quality, focusing on spatial and temporal variations. River water samples were collected in two different time periods and analysed for physico-chemical parameters includes major ions, nutrients, metals and isotopes. Particularly, the metals were analysed in different size fractions (particulate and colloid) of the suspended solids. Geochemical plots, pollution index, geochemical modelling and factor analysis were used for the data analysis. Interpretation of data reveals that the mean concentration of metals in river water were increased from downstream to the upstream of the river irrespective of the seasons. Major ions were mostly derived from the chemical weathering of source rocks, which was supported by the Gibbs plot. Piper plot indicates the seasonal shifting of water types from Ca–Mg to Na–Cl. Isotopic signatures reveal direct atmospheric precipitation and evaporation were the major origins of river water. Fe was the dominant metal concentration in river water irrespective of the seasons (mean concentration 1.05 mg/L). Fe and Zn were the dominant metal concentration observed in all the 3 size fractions of suspended solids. Industrial activities and seawater influx dominate in the downstream, whereas weathering and agricultural inputs are significant in the upstream of the river. Particulate and colloidal fractions are the major contributors for the metal transport in the midstream and downstream of the river. The outcome of this study offer a thorough understanding of the seasonal elemental distribution at different size fractions, geochemical behaviour and the pollution status of the Miri River. With this knowledge, sustainable management strategies can be developed for this crucial water resource to the benefit of Miri community.

SI-traceable validation of a laser spectrometer for balloon-borne measurements of water vapor in the upper atmosphere

Abstract. Despite its crucial role in the Earth's radiative balance, upper-air water vapor (H2O) is still lacking accurate, in situ, and continuous monitoring. Especially in the upper troposphere–lower stratosphere (UTLS), these measurements are notoriously difficult, and significant discrepancies have been reported in the past between different measuring techniques. Here, we present a laboratory assessment of a recently developed mid-IR quantum-cascade laser absorption spectrometer, called ALBATROSS, for balloon-borne measurements of H2O in the UTLS. The validation was performed using SI-traceable reference gas mixtures generated based on the permeation method and dynamic dilution. The accuracy and precision of ALBATROSS were evaluated at a wide range of pressures (30–250 mbar) and H2O amount fractions (2.5–35 ppm), representative of the atmospheric variability in H2O in the UTLS. The best agreement was achieved by implementing a quadratic speed-dependent Voigt profile (qSDVP) line shape model in the spectroscopic retrieval algorithm. The molecular parameters required by this parameterization were determined empirically using a multi-spectrum fitting approach over different pressure conditions. In the laboratory environment, ALBATROSS achieves an accuracy better than ±1.5 % with respect to the SI-traceable reference at all investigated pressures and H2O amount fractions. The measurement precision was found to be better than 30 ppb (i.e., 0.1 % at 35 ppm H2O) at 1 s resolution for all conditions. This performance, unprecedented for a balloon-borne hygrometer, demonstrates the exceptional potential of mid-IR laser absorption spectroscopy as a new reference method for in situ measurements of H2O in the UTLS.