Valence Metal Ions Research Articles

Chitosan functionalized with pyrazolinone derivative for water treatment: Application to Hg(II) removal

Due to its high toxicity, the removal of mercury from groundwater in contaminated industrial areas is of critical importance to avoid health problems for living beings. The functionalization of chitosan with pyrazolinone derivative, allows designing a sorbent (CH-PYZ) with high efficiency and selectivity for mercury sorption at acidic pH values (1.40 mmol Hg g−1, at pH 3). The sorbent is characterized by elemental analysis, thermogravimetric and textural analyses (increase in specific surface area and decrease in pore size), Fourier transform infrared spectroscopy, and shift of the pH point of zero charge toward higher value. The sorption was mainly performed through carbonyl, thiocarbonyl, hydroxyl, and amine groups. Under selected experimental conditions, sorption equilibrium is reached in 40 min (faster than crosslinked chitosan, CH) and the kinetic profile is fitted by the pseudo-first order rate equation. The Langmuir equation finely fits sorption isotherms: the functionalization improves both the maximum sorption capacity and the affinity coefficient (by four to six folds). The benefit of the functionalization is also demonstrated by the improved stability of the sorbent at recycling (loss at the fifth cycle does not exceed 2 % for CH-PYZ, against 8 % for CH). The grafting of pyrazolinone derivative brings another advantage in terms of selectivity against other mono-, di- and tri- valent metal ions. The sorbent also preferentially sorbs mercury from groundwater collected in a contaminated area. Under selected experimental conditions, the sorbent allows decontaminating the collected sample for livestock feeding, but the treated water cannot reach the levels for human drinking water.

Salt-templated synthesis of carbon nanosheets decorated with high valence tungsten doped Co2P nanoparticles for efficient Zn-air battery

An ORR/OER bifunctional electrocatalyst, porous nitrogen-doped carbon nanosheet decorated with high valence tungsten doped Co2P nanoparticles, has been developed for efficient Zn-air battery through salt template in this work. This catalyst exhibits high ORR (half-wave potential of 0.861 V) and OER activities (overpotential of 310 mV). The results of density functional theory calculation verify that the introduction of high valence tungsten dopants is advantageous to regulate the electronic structure of Co2P, thereby has effectively optimized the adsorption energy of intermediate species for ORR/OER and density of states. Meanwhile, the energy barrier of the rate-determining step is greatly lowered. Assembled Zn-air battery (ZAB) exhibits a promising open-circuit voltage of 1.50 V, good power density (224.4 mW cm−2), excellent specific capacity (881 mAh g−1), and durability (130 h). This work elucidated that creating high-performance transition-metal based electrocatalysts for rechargeable Zn-air batteries would be feasible using 5d high valence metal ion doping.

Analysis of causes for high hydration and low drainage rate of wheat straw chemi-thermo-mechanical pulp

The wheat straw chemi-mechanical pulp has the characteristics of high yield, good mechanical performance and low production cost. However, there are significant problems in the papermaking process by such as high pulp hydration, poor drainage, and large energy consumption during the paper drying-process. It was found that during the chemical mechanical pulping of wheat straw, due to the residual alkali and temperature, the hemicellulose in the pulp was continuously dissolved, some of it entered the water phase, and some of it migrated to the fiber surface. Which reflected in the raise in cation demand for anionic substances in the aqueous phase, the increase in carboxyl content on the surface of pulp fibers, and the aggravation in hydration degree. Further research found that the high valence metal ions can combine the carboxylate radical on the hemicellulose molecule in the aqueous phase with the carboxylate radical on the pulp surface to form a covalent bond, so that the hemicellulose entering the aqueous phase can be re-adsorbed to the fiber surface, thus further increasing the degree of pulp hydration. Carboxymethyl starch was used to simulate hemicellulose, and the hemicellulose re-adsorption phenomenon verification experiments were reproduced in a calcium ion environment. The above findings indicate that during the production of wheat straw chemi-mechanical pulp process, the hemicellulose dissolved and re-adsorption not only leads to the increase of pulp hydration, but also results in poor water filtration during paper formation. Therefore, this study can provide a theoretical basis for optimizing the production process of chemi-mechanical pulp of wheat straw and controlling the technology and method of pulp hydration.

Effect of Different Valence Metal Ions on Rice Protein Fibrillation: Binding Mechanism, Structural Characterization and Rheology

Effect of Different Valence Metal Ions on Rice Protein Fibrillation: Binding Mechanism, Structural Characterization and Rheology

CuCoO2 Nanoparticles as a Nanoprotease for Selective Proteolysis with High Efficiency at Room Temperature

AbstractMany nanoproteases contain tetravalent metal ions and catalyze peptide‐bond hydrolysis only at high temperature (60 °C). Here, we report a new and effective strategy to explore nanoproteases from nanoparticles containing low valent metal ions. We found that flower‐like CuCoO2 nanoparticles (CuCoO2 NPs) containing low valent Cu+ possessed excellent catalytic activity towards selective cleavage of peptide bonds with hydrophobic residues in bovine serum albumin (BSA) at room temperature. CuCoO2 NPs exhibited excellent stability and had great reusability. CuCoO2 NPs also hydrolyzed heat‐denatured and surfactant‐denatured BSA. Mechanism analysis revealed that the high Lewis acidity of Co3+ and the low valence of Cu+ were both essential for the high protease activity of CuCoO2 NPs. The flower‐like structure of CuCoO2 NPs and the strong nucleophilicity of Cu+‐bound hydroxyl endow them with excellent catalytic performance. The findings open a new way for the design and discovery of high‐efficiency nanoproteases.

CuCoO2 Nanoparticles as a Nanoprotease for Selective Proteolysis with High Efficiency at Room Temperature.

Many nanoproteases contain tetravalent metal ions and catalyze peptide-bond hydrolysis only at high temperature (60 °C). Here, we report a new and effective strategy to explore nanoproteases from the nanoparticles containing low valent metal ions. We found that flower-like CuCoO2 nanoparticles (CuCoO2 NPs) containing low valent Cu+ possessed excellent catalytic activity towards selective cleavage of peptide bonds with hydrophobic residues in bovine serum albumin (BSA) at room temperature. CuCoO2 NPs exhibited excellent stability and had great reuse performance. CuCoO2 NPs also hydrolyzed heat-denatured and surfactant-denatured BSA. Mechanism analysis revealed that the high Lewis acidity of Co3+ and the low valence of Cu+ were both essential for the high protease activity of CuCoO2 NPs. The flower-like structure of CuCoO2 NPs and the strong nucleophilicity of Cu+-bound hydroxyl endue them with excellent catalytic performance. The findings open a new way for design and discovery of high-efficiency nanoproteases.

Construction of an enhanced built-in electric field in S-doped g-C3N4/NiCo2O4 for boosting peroxymonosulfate activation

Transition metal oxide-mediated heterogeneous peroxymonosulfate (PMS) activation on organic pollutant degradation has attracted much attention, where continuous redox cycling between high and low valence metal ions is the key step as it relates to the radical generation. Herein, a composite PMS activator of S-doped g-C3N4/NiCo2O4 (CNS_NCO) was constructed and exhibited excellent tetracycline (TC) degradation performance with 96.9% removal efficiency within 30 min. Experimental and theoretical calculations indicated that S doping not only widened the difference in the work function of CNS and NCO, but also enhanced the built-in electric field intensity of CNS_NCO heterojunctions, resulting in more electron transfer from CNS to NCO in a directional manner and accelerating the Co(III)/Co(II) and Ni(III)/Ni(II) redox cycle to form more reactive oxygen species (ROS). It was demonstrated that 1O2 (main ROS) was formed mainly through SO4•−, •OH and •O2− (minor ROS) conversion. Meanwhile, high-valent cobalt-oxo (CoIV = O) species also played an important role in TC degradation.

Influence of natural organic matters on fate of polystyrene nanoplastics in porous media

Natural organic matters (NOMs) are widely present in aqueous environments. The effect of NOMs on the fate of nanoplastics that are gradually receiving widespread attention in porous media needs to be noticed, but relevant research is lacking. To fill this gap, the present study focused on elucidating the influence of NOMs and metal cations with varying concentrations upon the transport, long-term release, and particle fracture of polystyrene nanoplastics (PS-NPs) in saturated porous media. The adsorption, transport, long-term release, and particle fracture tests were conducted. A mathematical model and the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory were used in this research. NOMs could adsorb onto PS-NPs leading to a reduction in the PS-NPs' zeta potential and an increase in the energy barrier and steric hindrance between PS-NPs and quartz sand, ultimately facilitating the transport of PS-NPs through porous media. On the other hand, an increase in concentration and valence of metal ions enhanced the PS-NPs' zeta potential, resulting in PS-NPs' aggregation and increased size when NOMs were present. This reduced the energy barrier between porous media and PS-NPs, resulting in increased blocking and straining, allowing decreased PS-NPs' transport. Long-term release tests demonstrated release ability and mobilities of PS-NPs decreased as the enhanced NOM concentration, addition of metal cations, and decreased valence of metal ions, in agreement with the transport test findings. In the research about particle fracture, NOMs were found to inhibit the fracture of PS-NPs by adsorbing on their surface to protect them from fracture. Metal cations and increased metal cation valence promoted the fracture of released PS-NPs when NOMs were present by promoting NOM aggregation and thus hindering the protection of NOMs for the nanoplastics.

Surface Reconstruction of Covellite CuS Nanocrystals for Enhanced OER Catalytic Performance in Alkaline Solution.

Oxygen evolution reaction (OER) is one of the important half-reactions in energy conversion equipment such as water-spitting devices, rechargeable metal-air batteries, and so on. It is beneficial to develop efficient and low-cost catalysts that understand the reaction mechanism of OER and analyze the reconstruction phenomenon of transition metal sulfide. Interestingly, copper sulfide and cuprous sulfide with the same components possess different reconstruction behaviors due to their different metal ion valence states and different atomic arrangement modes. Because of a unique atomic arrangement sequence and certain cationic defects, the reconstruction phenomenon of CuS nanomaterials are that S2- is firstly oxidized to SO4 2- and then Cux + is converted into CuO via Cu(OH)2 . In addition, the specific "modified hourglass structure" of CuS with excellent conductivity is easier to produce intermediates. Compared with Cu2 S, CuS exhibits excellent OER activity with a lower overpotential of 192mV at 10mA cm-2 and remarkable electrochemical stability in 1.0m KOH for 120h. Herein, this study elucidates the reconstruction modes of CuS and Cu2 S in the OER process and reveals that CuS has a stronger CuS bond and a faster electronic transmission efficiency due to "modified hourglass structure," resulting in faster reconstruction of CuS than Cu2 S.

Carbon nanotube‐supported mixed‐valence Mn3O4 electrodes for high‐performance lithium‐oxygen batteries

Lithium–oxygen batteries (LOBs) have extensive applications because of their ultra-high energy densities. However, the practical application of LOBs is limited by several factors, such as a high overpotential, poor cycle stability, and limited rate capacity. In this paper, we describe the successful uniform loading of Mn3O4 nanoparticles onto multi-walled carbon nanotubes (Mn3O4@CNT). CNTs form a conductive network and expose numerous catalytically active sites, and the one-dimensional porous structure provides a convenient channel for the transmission of Li+ and O2 in LOBs. The electronic conductivity and electrocatalytic activity of Mn3O4@CNT are significantly better than those of MnO@CNT because of the inherent driving force facilitating charge transfer between different valence metal ions. Therefore, the Mn3O4@CNT cathode obtains a low overpotential (0.76 V at a limited capacity of 1000 mAh g−1), high initial discharge capacity (16895 mAh g−1 at 200 mA g−1), and long cycle life (97 cycles at 200 mA g−1). This study provides evidence that transition metal oxides with mixed-valence states are suitable for application as efficient cathodes for LOBs.

Synthesis, optical, chemical and electrical characterizations of γ-irradiated transition metal ions reinforced borate glasses

Co2+/ Ni2+/ Fe3+ borate glasses were prepared by melting-annealing procedure and extensively characterized towards gamma irradiation (up to 8 kGy). UV–visible spectra revealed Co2+ (3d7) in octahedral and tetrahedral coordinations, while Ni2+ (3d8) and Fe2+ (3d6) favored the octahedral coordination. Optical energy gap (Eopt) appeared dependent on glass density in a direct relation. ESR spectra revealed values of g// ∼ 2.01 and g┴ ∼ 2.025 correlated to the transition metal (TM) ion valence state. Chemical durability in H2O, HCl, and NaOH revealed good behavior from 15 to 35 days. Trigonal BO3 units appeared more extensive than tetrahedral BO4 on FTIR spectra after irradiation. AC conductivity, dielectric constants and dielectric loss revealed rising with incorporating TM ions and irradiation. TM ions provide the glasses stable behavior to irradiation because of their flexible configuration to heal radiation defects affording the possible use of glasses as radiation shielding materials (up to 5 kGy).

Metallo-Supramolecular Hexagonal Wreath with Four Switchable States Based on a pH-Responsive Tridentate Ligand

In biological systems, many biomacromolecules (e.g., heme proteins) are capable of switching their states reversibly in response to external stimuli, endowing these natural architectures with a high level of diversity and functionality. Although tremendous efforts have been made to advance the complexity of artificial supramolecules, it remains a challenge to construct metallo-supramolecular systems that can carry out reversible interconversion among multiple states. Here, a pH-responsive tridentate ligand, 2,6-di(1H-imidazole-2-yl)pyridine (H2DAP), is incorporated into the multitopic building block for precise construction of giant metallo-supramolecular hexagonal wreaths with three metal ions, i.e., Fe(II), Co(II), and Ni(II), through coordination-driven self-assembly. In particular, a Co-linked wreath enables in situ reversible interconversion among four states in response to pH and oxidant/reductant with highly efficient conversion without losing structural integrity. During the state interconversion cycles, the physical properties of the assembled constructs are finely tuned, including the charge states of the backbone, valency of metal ions, and paramagnetic/diamagnetic features of complexes. Such discrete wreath structures with a charge-switchable backbone further facilitate layer-by-layer assembly of metallo-supramolecules on the substrate.

Comprehensive catalytic and biological studies on new designed oxo- and dioxo-metal (IV/VI) organic arylhydrazone frameworks

Aryl Schiff base hydrazone have strong ability to form high stable complexes with transition metals with numerous applicability in catalysis and biology. For that, mononuclear pincer complexes of oxo/dioxo high valent metal ions (MoO22+, UO22+ and VO2+ ions, as MoO2Lhz, UO2Lhz and VOLhz, respectively) with aryl Schiff base hydrazone ligand (H2Lhz) were synthesized. H2Lhz and its MOxLhz complexes were characterized within alternative considerable tools. The complexes were formed in 1: 1 M ratios of MOx2+ (X = 1 or 2) ion to H2Lhz with octahedral geometries of cis-MoO2- and cis-UO2-complexes, and a square pyramidal geometry of VO-complex. The catalytic potential of MOxIILhz was estimated in the productive redox system of benzyl alcohol using H2O2 in an aerobic homogeneous phase. High productivity was progressed affording the corresponded aldehyde (benzaldehyde) with all catalysts. VOLhz displays the highest affectivity by 95 % of benzaldehyde (at 70 °C, after 2 h), MoO2Lhz represents an excellent action with 91 % (at 80 after 2 h). However, UO2Lhz shows the less efficacy with 80 % after 4 h of benzaldehyde. Hence, the catalytic performance depends upon the metal ion type (MOx2+ in the complex catalyst) in the proposed mechanism (oxygen transfer). For the bio-chemical assays, the anticancer and antimicrobial action of H2Lhz and its MOxLhz complexes were examined versus various microbes and human tumor cell lines. Their bio-interaction was also explored with ctDNA (calf thymus DNA) spectrophotometrically and the viscometric changes. All MOxLhz complexes exhibited higher inhibiting potential against the current microorganism growth (depending on the inhibiting zone in mm and MIC in μM values) and the human cancer cells over their free ligand H2Lhz. The ctDNA interaction was evaluated within Kb, the binding constants, and also the Gibbs’ free energy values for all studied compounds, exploring their role within the type and nature of MOx2+ ion for enhancement of their ctDNA interaction mode.

Spin-Lattice and Magnetoelectric Couplings Enhanced by Orbital Degrees of Freedom in Polar Multiferroic Semiconductors.

Orbital degrees of freedom mediating an interaction between spin and lattice were predicted to raise strong magnetoelectric effect, i.e., to realize an efficient coupling between magnetic and ferroelectric orders. However, the effect of orbital fluctuations has been considered only in a few magnetoelectric materials, as orbital-degeneracy driven Jahn-Teller effect rarely couples to polarization. Here, we explore the spin-lattice coupling in multiferroic Swedenborgites with mixed valence and Jahn-Teller active transition metal ions on a stacked triangular and Kagome lattice using infrared and dielectric spectroscopy. On one hand, in CaBaM_{4}O_{7} (M=Co, Fe), we observe a strong magnetic-order-induced shift in the phonon frequencies and a corresponding large change in the dielectric response. Remarkably, as an unusual manifestation of the spin-phonon coupling, the spin fluctuations reduce the phonon lifetime by one order of magnitude at the magnetic phase transitions. On the other hand, lattice vibrations, dielectric response, and electric polarization show no variation at the Néel temperature of CaBaFe_{2}Co_{2}O_{7}, which is built up by orbital singlet ions. Our results provide a showcase for orbital degrees of freedom enhanced magnetoelectric coupling via the example of Swedenborgites.

KxCo1.5−0.5xFe(CN)6/rGO with Dual−Active Sodium Ion Storage Site as Superior Anode for Sodium Ion Battery

The unique and open large frame structures of prussian blue analogues (PBA) enables it for accommodating a large number of cations (Na+, K+, Ca2+, etc.), thus, PBA are considered as promising electrode materials for the rechargeable battery. However, due to the chemical composition, there are still many alkaline metal ions in the gap within the framework, which puts multivalent metals in PBA in a low valence state and affects the sodium storage performance. To improve the valence of metal ions in PBA materials, precursors prepared by co-precipitation method and hydrothermal method are used to synthesis KxCo1.5-0.5xFe(CN)6 through further chemical oxidation. Through the introducing of reduced graphene oxide (rGO) with excellent conductivity by a simple physical mixing method, the cycle stability and rate performance of the PBA material can be further improved. The K0.5Co1.2Fe(CN)6·2H2O/rGO anode prepared with 2 h hydrothermal time and further chemical oxidation, named as KCoHCP-H2-EK/rGO, exhibits a super electrochemical performance, delivering initial charge/discharge capacities of 846.7/1445.0 mAh·g-1, and a capacity retention of 58.2% after 100 cycles at a current density of 100 mA·g-1. The KCoHCP-H2-EK/rGO outstanding electrochemical behaviors are attributed to the unique dual-active site structure properties and the improved surface conductance of materials by rGO components.

Rational design of stable functional metal-organic frameworks.

Functional porous metal-organic frameworks (MOFs) have been explored for a number of potential applications in catalysis, chemical sensing, water capture, gas storage, and separation. MOFs are among the most promising candidates to address challenges facing our society related to energy and environment, but the successful implementation of functional porous MOF materials are contingent on their stability; therefore, the rational design of stable MOFs plays an important role towards the development of functional porous MOFs. In this Focus article, we summarize progress in the rational design and synthesis of stable MOFs with controllable pores and functionalities. The implementation of reticular chemistry allows for the rational top-down design of stable porous MOFs with targeted topological networks and pore structures from the pre-selected building blocks. We highlight the reticular synthesis and applications of stable MOFs: (1) MOFs based on high valent metal ions (e.g., Al3+, Cr3+, Fe3+, Ti4+ and Zr4+) and carboxylate ligands; (2) MOFs based on low valent metal ions (e.g., Ni2+, Cu2+, and Zn2+) and azolate linkers. We envision that the synthetic strategies, including modulated synthesis and post-synthetic modification, can potentially be extended to other more complex systems like metal-phosphonate framework materials.

The construction of hierarchical assemblies with in situ generation of chemotherapy drugs to enhance the efficacy of chemodynamic therapy for multi-modal anti-tumor treatments.

The effectiveness of chemodynamic therapy (CDT) in cancer treatment is limited by insufficient endogenous H2O2 levels in tumor tissue and an increasing ratio of high valence metal ions. To overcome these challenges, a novel nanotherapeutic approach, named GOx-CuCaP-DSF, has been proposed. This approach involves the design of nanotherapeutics that aim to self-supply H2O2 within cancer cells and provide a supplement of low valence metal ions to enhance the performance of CDT. GOx-CuCaP-DSF nanotherapeutics are engineered by incorporating glucose oxidase (GOx) into Ca2+-doped calcium phosphate (CaP) nanoparticles and loading disulfiram (DSF) through surface adsorption. Under the tumor microenvironment, GOx catalyzes the conversion of tumor-overexpressed glucose (Glu) to liberate H2O2. The degradation of CaP further lowers the pH, facilitating the release of Cu2+ ions and DSF. The rapid reaction between Cu2+ and DSF leads to the generation of Cu+, increasing the Cu+/Cu2+ ratio and promoting the Cu+-based Fenton reaction, which enhances the efficiency of CDT. Simultaneously, DSF undergoes conversion to diethyldithiocarbamate acid (ET), forming a copper(II) complex (Cu(II)ET) by strong chelation with Cu ions. This Cu(II)ET complex, a potent chemotherapeutic drug, exhibits a synergistic therapeutic effect in combination with CDT. Moreover, the elevated Cu+ species resulting from DSF reaction promotes the aggregation of toxic mitochondrial proteins, leading to cell cuproptosis. Overall, the strategy of integrating the chemodynamic therapy efficiency of the Fenton reaction with the activation of efficacious cuproptosis using a chemotherapeutic drug presents a promising avenue for enhancing the effectiveness of multi-modal anti-tumor treatments.

High Seebeck coefficient thermogalvanic cells via the solvent-sensitive charge additivity of cobalt 1,8-diaminosarcophagine.

Thermogalvanic devices can chemically convert low grade (<200 °C) waste thermal energy into electrical energy. A temperature gradient across the device drives an entropically favourable electrochemical redox reaction, resulting in continuous current production. The voltage correlates with the entropy change during the redox reaction, which favours high valence metal complexes with high charge densities. Here we investigate cobalt (II/III) sarcophagine ([Co(SAR)]2+/3+) for application in thermogalvanic cells, as a function of solvent; the two uncoordinated amine groups 1,8-diaminosarcophagine are typically protonated to form tetracationic/pentacationic [Co(SARH2)]4+/5+. In water, [Co(SARH2)]4+/5+ gave a thermogalvanic Seebeck coefficient (Se) of +0.43 mV K-1, which is entropically consistent with just the Co2+/3+ core valence, whereas DMSO and ionic liquid solvents gave Se values of +1.84 and +2.04 mV K-1, respectively, in line with the 'Co4+/5+' overall complex. This work proves how the ionic charge on pendant moieties can undergo charge-additivity with the metal core to significantly boost entropically-driven processes, but only in suitably low dielectric and bulky solvents.

Controllable synthesis of Sn0.33WO3 tungsten bronze nanocrystals and its application for upconversion luminescence enhancement

The development and utilization of novel semiconductor nanocrystals with remarkable localized surface plasmon resonance (LSPR) effect is one of the current research hotspots. Tungsten bronze nanocrystals are a class of semiconductor nanocrystals with strong LSPR effect discovered recently. The synthesis of tungsten bronze nanocrystals by introducing high valence metal ions, the regulation and application of the corresponding LSPR effect are still under further exploration. In this paper, Sn 0.33 WO 3 nanocrystals with different crystal phases and morphologies were synthesized using different types of Sn precursors and different amounts of NH 4 F. Acid radical ions provided by different types of Sn precursors is an important factor affecting the LSPR absorption characteristics of Sn 0.33 WO 3 nanocrystals. Sn 0.33 WO 3 nanosheets with strong LSPR absorption synthesized with stannous oxalate were used as a representative to enhance the upconversion luminescence of NaYF 4 :Yb 3+ , Er 3+ . Compared with Glass/NaYF 4 :Yb 3+ , Er 3+ film, the upconversion luminescence intensity of the layered Glass/Sn 0.33 WO 3 /PMMA/NaYF 4 :Yb 3+ , Er 3+ film was enhanced by 34 times. The LSPR effect of Sn 0.33 WO 3 enhances the excitation field of NaYF 4 :Yb 3+ , Er 3+ nanocrystals, resulting in significant upconversion luminescence enhancement of NaYF 4 :Yb 3+ , Er 3+ in the layered Glass/Sn 0.33 WO 3 /PMMA/NaYF 4 :Yb 3+ , Er 3+ film. The present work is helpful for people to study the development and application of semiconductor nanocrystals with LSPR effect.

Framework Dimensional Control Boosting Charge Storage in Conjugated Coordination Polymers

Conjugated coordination polymers (CCPs) with extended π-d conjugation, which can effectively promote long-range delocalization of electrons and enhance conductivity, are superior to traditional metal-organic frameworks (MOFs) and attracted great attention for potential applications in chemical sensors, electronics, energy conversion/storage devices, etc. However, the precise construction of CCPs is still challenging due to the complex and uncontrollable reactions of CCPs. Herein, two different framework dimensions of CCPs are controllably realized by employing the same ligand (2,3,5,6-tetraaminobenzoquinone (TABQ)) and the same metal (copper) as center ions. The manipulation of reaction leads to different valences of ligands and metal ions, different coordination geometries, and thereby 1D-CuTABQ and 2D-CuTABQ frameworks, respectively. High performance of charge storage is hence achieved involving the storage of both cations and anions, and therein, 2D-CuTABQ shows a high reversible capacity of ≈305mAhg-1 , good rate capability and high capacity retention (≈170mAhg-1 after 2000 cycles at 5Ag-1 with 0.01% decay per cycle), which outperforms 1D-CuTABQ and almost all of the reported MOFs as cathodes for batteries. These results highlight the delicate structural control of CCPs for high-performance batteries and other various applications.