We have studied the plasma composition of a high current short pulse vacuum arc discharge with different cathode materials: lanthanum, gadolinium, lead, silver, and tin. We find that for optimal vacuum arc discharge parameters – arc current pulse duration about 2 μs and amplitude about 3 kA – the maximum ion charge state is 11+ and mean ion charge state from 7.8+ for tin to 9.6+ for lanthanum. The mean ion charge state for different materials depends on the discharge voltage and the energy required for ionization to maximum charge state. The cathode surface heats to a temperature of 700 °C–1100 °C in the course of the arc current pulse, depending on the cathode material, and the cathode surface of low melting point metals such as lead and tin melts to a depth of 5 μm and 10 μm, respectively. Surface melting does not lead to change in plasma ion composition, since the ion flux from the cathode considerably exceeds the evaporated atom flux.