AbstractA finite volume–based unstructured inviscid flow solver has been developed for the study of nonequilibrium effects in high enthalpy flows. Four different inviscid flux computation schemes are tested for literature reported test cases like unsteady wave motion in a shock tube and high enthalpy flow over cylinder/sphere. During the present assessment, encouraging agreement has been noticed in capturing all the essential flow features in the reacting media. Here, the Rusanov scheme is noticed to be computationally cheaper among all the schemes with noticeable diffusion around strong gradients. Shock tube test case revealed the existence of various shock Mach numbers for a given driving pressure ratio in the presence of reactions. Similarly, freestream Mach number is found to have limitations in representing the shock standoff distance in case of high enthalpy flow over cylinder and sphere. In line with this, real gas effects are prominently observed for the case of the cylinder in comparison with the...