Unsafe behavior is one of the main causes limiting the improvement of on-site safety performance. Safety training is an important means of preventing unsafe behavior. With changes in the scale of operations and employee characteristics, traditional training methods have largely failed to meet the practical demands. Therefore, to improve the effectiveness of safety training, this paper analyzes the shortcomings of the current training methods, demonstrates the potential value of accident cases for improving the training effect, and the advantages of 24Model for case analysis in safety training. Subsequently, this paper constructs a systematic training system with Accident-Cause-Training (ACT) as the training relationship chain, which runs the accident cases throughout the training process, 24Model is utilized to trace the unsafe behaviors that lead to accidents from the perspectives of organizational and individual level, and the training content is established according to the analysis results. This paper also conducts a case study to verify the operability of the ACT method, specifically, a training programme for limited space operations at a national-level oil and gas storage and transportation company is designed and implemented. Finally, by comparing the similarities and differences between the ACT method and other training methods from various perspectives, the universality and participation of the ACT method are proved, and the development trend of the ACT method is also discussed. It is believed that the proposed ACT method could enrich the types of safety training methods and provide an effective and scientific tool to enhance the safety performance of field operations.