Underground Hydrogen Storage Research Articles

A preliminary investigation on the mechanical behaviour of a stiff Italian clay in the context of hydrogen storage

The large-scale use of renewable energy sources is closely linked to the ability to store excess energy generated during periods of overproduction for use when demand is at a peak. Storing green energy is therefore a key component in the move towards a carbon-neutral economy. Underground hydrogen storage in depleted oil and gas reservoirs may provide an efficient long-term solution. Cyclic injection and production of hydrogen alter the chemo-hydro-mechanical conditions of the reservoir and caprocks, and possible geomechanical consequences of such alterations must be preliminarily assessed for safe storage operations. This study aims at exploring the possible effects of cyclic mechanical loads, such as those that might be induced by hydrogen storage and production, on the mechanical behaviour of a clayey caprock. A series of triaxial tests, both monotonic and cyclic, were carried out on undisturbed samples of a stiff Italian clay cored from a caprock formation overlying a hydrocarbon reservoir. The results show that the material response is characterized by the distinctive stress-strain behaviour of stiff clays, with a rather high fragility, which was found to be highly dependent on the loading strain rate. During laboratory experiments conducted at frequencies larger than in situ ones, cyclic loading under stress control causes a gradual degradation of the material structure leading to the formation of a clear shear band followed by a reduction in shear strength. Eventually, failure occurs as the peak shear strength approaches the applied load. The progressive destructuration also implies a reduction in P- and S-wave propagation velocities and a significant change in the signal shape, which is therefore a promising parameter for monitoring the material degradation process.

Numerical modelling of the effects of permeability contrasts on underground hydrogen storage in sandstone reservoirs

Hydrogen is an energy carrier that can balance the divergent variations in seasonal energy demand and energy supply from renewables. Underground hydrogen storage in porous formations, such as depleted gas sandstone reservoirs or saline aquifers, provides the capacities needed for large-scale, long-duration energy balancing. This paper reports on the fundamental behaviour of hydrogen in a model reservoir setup, involving a two-phase (H 2 , water) system and a two well (injector, producer) setup placed at different depths in the reservoir. We specifically focus on the impact of natural heterogeneities, and associated permeability contrasts, on flow and efficacy of hydrogen injection and production. We found that positioning the wells, both injector and producer, at the top of the reservoir facilitates the highest hydrogen production. We also found that permeability contrasts of three to four orders of magnitude significantly affect hydrogen flow; however, factors affecting the pressure gradient also need to be considered. These factors include compartmentalization, the behaviour of co-existing fluids and the localized pressure gradient created by the hydrogen plume. Our research underlines the need to understand the architecture of the whole reservoir, from seismic to sub-seismic scales, not just the zones surrounding the wells and pathways in-between, as this controls capacity, pressure fluctuations and informs operational management decisions. Thematic collection: This article is part of the Hydrogen as a future energy source collection available at: https://www.lyellcollection.org/topic/collections/hydrogen

Numerical simulation of fingering in the underground hydrogen storage

Underground hydrogen storage has garnered interest in recent years owing to the considerable demand for clean energy. Hydrogen is more diffusive than air and has relatively low density and viscosity. These unique properties induce distinct hydrodynamic phenomena during hydrogen storage. Cushion gas has been proven to be a potential remedy for attenuating the adverse impacts of underground hydrogen storage. To investigate the influence of the cushion gas, a microscopic numerical simulation was performed with Fluent software using the Eulerian multi-fluid model. Carbon dioxide, nitrogen, and methane are usually used as the preferred candidates for cushion gases in underground hydrogen storage systems. In this study, nitrogen was used as the cushion gas and was injected along with hydrogen into heterogeneous porous media with volume fractions ranging from 0% to 70%. A parameterization study was then performed to elucidate the influences of the injection rate and viscosity of the fluid on the fingering pattern. Two representative types of fingering, viscous fingering and capillary fingering, were observed under different gas mixtures and boundary conditions. After the simulation, an image analysis was performed to capture the evolution of the fingering pattern. The specific fingering area, number of branches, and fractal dimensions are proposed as geometric indices to describe the shape of the fingering pattern. The results showed that there was a remarkable enhancement in saturation due to the injection of the cushion gas, depending on the concentration of the gas mixture. This study offers insight on the design of gas mixture injection in underground hydrogen storage and can be further extended to the hydrochemo–mechanical coupled numerical simulation of multiphase gas injection in porous media.

Cushion gas effects on hydrogen storage in porous rocks: Insights from reservoir simulation and deep learning

Underground hydrogen (H2) storage (UHS) is crucial for the H2 economy, offering scalable and long-term solutions vital for reliable and sustainable H2-based energy systems. Cushion gas is a common component in UHS designs, but its impact on H2 storage performance is not yet fully understood. This study bridges this research gap by systematically investigating the effects of various cushion gas scenarios on UHS performance in porous rocks, specifically saline aquifers and depleted gas reservoirs, using reservoir simulations and deep learning. Firstly, we conducted 8,000 multiphase compositional reservoir simulations for UHS operations in two types of storage formations, considering four cushion gas scenarios: no cushion gas, methane (CH4), nitrogen (N2), and carbon dioxide (CO2). These simulations cover a wide range of geological and operational parameters relevant to practical UHS projects. From these simulations, we derived key insights into the physical mechanisms governing UHS processes and proposed critical storage performance metrics, including H2 withdrawal efficiency, produced H2 purity, produced gas–water ratio, and well injectivity. Then, we developed a unified reduced-order model (ROM) using a deep neural network (DNN) based on the comprehensive simulation results. The DNN architecture, with an input layer, five hidden layers, and an output layer, takes 12 geological and operational parameters as inputs, and forecasts the four performance metrics. The ROM accurately predicts the cyclic evolution of performance metrics and is over 5,000,000 times faster than traditional physics-based simulations, allowing for thorough uncertainty quantification of UHS performance prediction under various geological and operational conditions. Key findings of this study include: (a) UHS in porous rocks is technically promising, with improving storage performance over cycles; (b) UHS in saline aquifers has higher withdrawal efficiency and purity but lower gas–water ratio and injectivity compared to depleted gas reservoirs; (c) In saline aquifers, cushion gas reduces withdrawal efficiency and purity but significantly enhances gas–water ratio and injectivity, making it particularly beneficial in scenarios with high water production risks; (d) In depleted gas reservoirs, cushion gas is less important under the current operational conditions, as it barely affects withdrawal efficiency and purity, and these reservoirs inherently exhibit high gas–water ratio and injectivity due to initial/leftover native gas (mostly CH4); (e) The cushion gas type slightly affects storage performance, with N2 slightly outperforming CH4 and CO2 in withdrawal efficiency and purity, CO2 being better for gas–water ratio, and CH4 for injectivity. The findings of this study support cushion gas designs in future UHS projects in both saline aquifers and depleted gas reservoirs. Moreover, the developed ROM offers a highly efficient tool for conducting extensive sensitivity analysis and uncertainty quantification, optimizing operational conditions, and facilitating the screening of potential field sites for future UHS projects.

Exploring the prospects and challenges of underground hydrogen storage for a sustainable energy future

Compared to fossil fuel-based energy sources, renewable energy sources are gaining momentum worldwide due to climate control agreements. The Hydrogen Energy Roadmap proposes to generate hydrogen using renewable energy sources such as hydro, biomass, and solar. However, renewable energy source like hydrogen often has an unstable flow of energy supply, which can lead to temporary underproduction of the required supply. Underground storage options like depleted gas or oil reservoirs, aquifers, and salt caverns are used to address this issue. These underground gas storage alternatives have been used for various applications, including hydrogen storage. Underground hydrogen storage is possible in two geological sites: porous media and cave storage. Salt caverns are suitable for seasonal hydrogen storage at high pressures, while aquifers have the potential for hydrogen storage due to their widespread distribution. However, it is crucial to note that adequate reservoir properties and an impermeable layer are necessary for hydrogen storage in underground structures to prevent gas migration. Microbial and geochemical activities, often overlooked but crucial in hydrogen storage, can pose challenges due to their existence.

Investigating the activity of indigenous microbial communities from Italian depleted gas reservoirs and their possible impact on underground hydrogen storage.

H2 produced from renewable energies will play a central role in both greenhouse gas reduction and decarbonization by 2050. Nonetheless, to improve H2 diffusion and utilization as a fuel, large storage capacity systems are needed. Underground storage of natural gas in depleted reservoirs, aquifers and salt caverns is a well-established technology. However, new challenges arise when it comes to storing hydrogen due to the occurrence and activity of indigenous microbial populations in deep geological formations. In a previous study, four Italian natural gas reservoirs were characterized both from a hydro-chemical and microbiological point of view, and predictive functional analyses were carried out with the perspective of underground hydrogen storage (UHS). In the present work, formation waters from the same reservoirs were used as inoculant during batch cultivation tests to characterize microbial activity and its effects on different gas mixtures. Results evidence a predominant acidogenic/acetogenic activity, whilst methanogenic and sulfate reducing activity were only marginal for all tested inoculants. Furthermore, the microbial activation of tested samples is strongly influenced by nutrient availability. Obtained results were fitted and screened in a computational model which would allow deep insights in the study of microbial activity in the context of UHS.

Assessment of the in situ biomethanation potential of a deep aquifer used for natural gas storage.

The dihydrogen (H2) sector is undergoing development and will require massive storage solutions. To minimize costs, the conversion of underground geological storage sites, such as deep aquifers, used for natural gas storage into future underground hydrogen storage sites is the favored scenario. However, these sites contain microorganisms capable of consuming H2, mainly sulfate reducers and methanogens. Methanogenesis is, therefore expected but its intensity must be evaluated. Here, in a deep aquifer used for underground geological storage, 17 sites were sampled, with low sulfate concentrations ranging from 21.9 to 197.8µM and a slow renewal of formation water. H2-selected communities mainly were composed of the families Methanobacteriaceae and Methanothermobacteriaceae and the genera Desulfovibrio, Thermodesulfovibrio, and Desulforamulus. Experiments were done under different conditions, and sulfate reduction, as well as methanogenesis, were demonstrated in the presence of a H2 or H2/CO2 (80/20) gas phase, with or without calcite/site rock. These metabolisms led to an increase in pH up to 10.2 under certain conditions (without CO2). The results suggest competition for CO2 between lithoautotrophs and carbonate mineral precipitation, which could limit microbial H2 consumption.

Solubility of H2-CH4 mixtures in brine at underground hydrogen storage thermodynamic conditions

Concerning the emerging power-to-gas technologies, which are considered the most promising technology for seasonal renewable energy storage, Underground Hydrogen Storage (UHS) has gained attention in the last few years. For safe and efficient storage, possible hydrogen losses due to dissolution into the aquifer must be estimated accurately. Due to safety concerns, experimental measurements of hydrogen solubility in brine at reservoir conditions are limited. In this study, a PVT cell is used to characterize the solubility of hydrogen and its mixtures with methane in saline water/brine. The experiments were carried out at 45, 50, and 55°C and from 1 bar up to 500 bar, mimicking a significant range of possible reservoir conditions. Two brine samples representative of two different reservoirs were tested. Two mixtures of methane and hydrogen (10 mol% H2 and 50 mol% H2, respectively) were considered, along with pure hydrogen, to account for the presence of methane in the primary phase of hydrogen storage in a depleted gas reservoir. In the current paper, a comparison of the experimental results with literature models is provided. At the experiment conditions, the impact of the differences in the composition of the two analyzed brines as well as the impact of the analyzed range of temperatures was not significant. Conversely, a non-negligible variation in terms of the slope of the solubility curve was observed as a function of the gas mixture composition: the curve increased more steeply as the percentage of hydrogen reduced.

Experimental study of geophysical and transport properties of salt rocks in the context of underground energy storage

AbstractArtificial caverns in salt rock formations play an important role in the net‐zero energy transition challenge, both for covering short‐term fluctuations in energy demand and serving as safe locations for long‐term underground gas storage both for hydrogen and natural gas. Geophysical tools can serve for monitoring geomechanical changes in the salt cavern during selection and development, and during gas storage/extraction activities, but the use of common geophysical monitoring techniques has been very limited in this area. Here, we present experimental work on physical and transport properties of halite rocks within the energy storage context and assess the potential of seismic and electromagnetic data to monitor gas storage activities in salt formations. First, we analysed the stress‐dependency of the elastic and transport properties of five halite rocks to improve our understanding on changes in the geological system during gas storage operations. Second, we conducted two dissolution tests, using cracked and intact halite samples, monitored with seismic (ultrasonic P‐ and S‐waves velocities and their attenuation factors) and electromagnetic (electrical resistivity) sources to evaluate (i) the use of these common geophysical sensing methods to remotely interpret caverning development and (ii) the effect of structural discontinuities on rock salt dissolution. Elastic properties and permeability showed an increasing trend towards rock sealing and mechanical enhancement with increasing pressure for permeabilities above 10−21 m2, with strong linear correlations up to 20 MPa. In the dissolution tests, the ultrasonic waves and electrical resistivity showed that the presence of small structural discontinuities largely impacts the dissolution patterns. Our results indicate that seismic and electromagnetic methods might help in the selection and monitoring of the caverning process and gas storage operations, contributing to the expected increase in demand of large‐scale underground hydrogen storage.

Quantification of hydrogen depletion and mineral reactivity in underground hydrogen storage reservoirs

The utilisation of renewable energy has surged over the past decades due to shifts in climate patterns and the diminishing reserves of fossil fuels. Among the renewables, hydrogen energy has emerged as a promising clean energy carrier in recent years. In the hydrogen industry, storage faces a notable hurdle due to the relatively low density of hydrogen gas (0.0813 kg/m³ at 25 °C and 1 atm) and its lower storage density (7–27 kg/m³ at 25 °C and 100–400 atm). As a potential remedy, underground hydrogen storage emerges as a viable option, even though it is not without its challenges. Among these challenges, a prominent one involves the diversity in the composition and physical properties of the reservoir due to the influence of both biological and geo-chemical reactions. In this study, an extensive modelling effort was undertaken to gain insights into the impact of both bio and geo-chemical reactions, variations in porosity, hydrogen depletion, and the effects of diffusion across various levels of salinity, pressure, and temperature. Diverse Water/Rock ratios, distinct minerals, and residual gases were also considered. The modelled conditions encompassing mineral properties and parameters led to a cumulative hydrogen loss of 8.38% over a century. From this, 2.31% was identified due to the reactivity in reservoir rock and 6.07% due to the aqueous diffusion to cap rock and its reactivity. Among these reactions, carbonate dissolution emerged as the most noteworthy, resulting in considerable hydrogen loss contingent upon the presence of methanogenesis bacteria. As per the modelled scenario, porosity was reduced in reservoir rock by 0.41%, and in carbonate cap rock, it was increased by 56%, which could increase the hydrogen leakage. Also, methane (CH4) exhibited the most favourable characteristics as a cushion gas due to its lower reactivity. However, it's crucial to acknowledge that these figures could significantly fluctuate based on variations in mineral composition, bacterial populations and their growth, and the prevailing subsurface conditions. These modelled findings can serve as a valuable tool for comprehending the mechanisms of hydrogen loss and mineral reactivity within a given underground system.

Laboratory determination of hydrogen/methane dispersion in rock cores for underground hydrogen storage

Underground hydrogen storage in saline aquifers is a promising way to store large amounts of energy. Utilization of gas cushion enhances the deliverability of the storage and increases the volume of recovery gas. The key factor for the cushion characterization is cushion gas and storage gas mixing which can be used for simulation of mixing zone evolution. In this work coreflooding setup utilizing Raman spectroscopy is built and used for dispersion coefficient determination. Berea sandstone rock core is used as a test sample for setup validation and core entry/exit effects estimation. Dispersion for hydrogen and methane as displacing fluids is determined for 4 locations perspective for hydrogen storage in Poland is found. Reservoir structures most suitable for pure hydrogen or hydrogen/methane blend storage are selected.

Assessing the Role of Hydrogen in Sustainable Energy Futures: A Comprehensive Bibliometric Analysis of Research and International Collaborations in Energy and Environmental Engineering

The main results highlighted in this article underline the critical significance of hydrogen technologies in the move towards carbon neutrality. This research focuses on several key areas including the production, storage, safety, and usage of hydrogen, alongside innovative approaches for assessing hydrogen purity and production-related technologies. This study emphasizes the vital role of hydrogen storage technology for the future utilization of hydrogen as an energy carrier and the advancement of technologies that facilitate effective, safe, and cost-efficient hydrogen storage. Furthermore, bibliometric analysis has been instrumental in identifying primary research fields such as hydrogen storage, hydrogen production, efficient electrocatalysts, rotary engines utilizing hydrogen as fuel, and underground hydrogen storage. Each domain is essential for realizing a sustainable hydrogen economy, reflecting the significant research and development efforts in hydrogen technologies. Recent trends have shown an increased interest in underground hydrogen storage as a method to enhance energy security and assist in the transition towards sustainable energy systems. This research delves into the technical, economic, and environmental facets of employing geological formations for large-scale, seasonal, and long-term hydrogen storage. Ultimately, the development of hydrogen technologies is deemed crucial for meeting sustainable development goals, particularly in terms of addressing climate change and reducing greenhouse gas emissions. Hydrogen serves as an energy carrier that could substantially lessen reliance on fossil fuels while encouraging the adoption of renewable energy sources, aiding in the decarbonization of transport, industry, and energy production sectors. This, in turn, supports worldwide efforts to curb global warming and achieve carbon neutrality.

Microbial induced wettability alteration with implications for Underground Hydrogen Storage

Characterization of the microbial activity impacts on transport and storage of hydrogen is a crucial aspect of successful Underground Hydrogen Storage (UHS). Microbes can use hydrogen for their metabolism, which can then lead to formation of biofilms. Biofilms can potentially alter the wettability of the system and, consequently, impact the flow dynamics and trapping mechanisms in the reservoir. In this study, we investigate the impact of microbial activity on wettability of the hydrogen/brine/rock system, using the captive-bubble cell experimental approach. Apparent contact angles are measured for bubbles of pure hydrogen in contact with a solid surface inside a cell filled with living brine which contains sulphate reducing microbes. To investigate the impact of surface roughness, two different solid samples are used: a “rough” Bentheimer Sandstone sample and a “smooth” pure Quartz sample. It is found that, in systems where buoyancy and interfacial forces are the main acting forces, the impact of biofilm formation on the apparent contact angle highly depends on the surface roughness. For the “rough” Bentheimer sandstone, the apparent contact angle was unchanged by biofilm formation, while for the smooth pure Quartz sample the apparent contact angle decreased significantly, making the system more water-wet. This decrease in apparent contact angle is in contrast with an earlier study present in the literature where a significant increase in contact angle due to microbial activity was reported. The wettability of the biofilm is mainly determined by the consistency of the Extracellular Polymeric Substances (EPS) which depends on the growth conditions in the system. Therefore, to determine the impact of microbial activity on the wettability during UHS will require accurate replication of the reservoir conditions including surface roughness, chemical composition of the brine, the microbial community, as well as temperature, pressure and pH-value conditions.

Impact of gas type on microfluidic drainage experiments and pore network modeling relevant for underground hydrogen storage

Underground hydrogen storage (UHS) in geological reservoirs is proposed as a technically feasible solution to balance mismatch between supply and demand in emerging markets. However, unique hydrogen properties and coupled flow mechanisms require new investigations to fully understand transport and storage of hydrogen in porous media across scales. Here we use microfluidics to investigate the effect of gas type and injection rate on flow patterns, saturation and connectivity of the gas phase. We visually observe that gas flow is characterized by capillary fingering, further confirmed by fractal dimension analysis. At lower injection rates, the gas saturation after drainage appears to increase with gas viscosity, with lower hydrogen saturation compared to methane and nitrogen. The maximum gas saturations (39–46 %) were achieved at higher injection rates, showing no clear correlation to gas type. However, the high-rate injections lead to undesired outcomes in terms of formation of disconnected gas ganglia, mostly pronounced for nitrogen. We identify an optimal injection rate to achieve maximum gas saturation with the least amount of disconnected gas. The experimental results are supported with pore network modeling to derive relative permeability and capillary pressure functions.

A parallel programming application of the A* algorithm in digital rock physics

Pore-scale analysis and characterization of reservoir rocks provide valuable information for the definition and management of underground hydrogen storage and CO2 storage or sequestration.This article presents an optimized implementation of the A* algorithm, the most popular pathfinding method in the presence of obstacles. In this context, the algorithm is applied to recognize the minimum length connected paths through each flow direction of 3D images of a porous medium representative of a reservoir rock. The identification of the main paths allows the characterization of the pore space and the calculation of fundamental petrophysical properties such as tortuosity and effective porosity, which can be used for permeability estimation. Compared to other algorithms available for pore-scale characterization, such as the pore centroid, A* provides a better approximation of the pore space available for the flow and, therefore, a reliable characterization of the petrophysical properties. On the other hand, path identification is significantly consuming in terms of time and memory. In this paper, an efficient and optimized implementation based on C++/OpenMP programming language is presented.The proposed implementation aims to the analysis of large-scale models profiting from parallelization, memory optimization, and enhanced managing of dead paths. Three test cases of increasing sizes are presented, to analyze the advantages and the disadvantages of the algorithm as the number of explored points increases. The 3D binary images analyzed are related to a synthetic domain (1 million voxels) and two actual sandstone samples (about 4 and 64 million voxels respectively). The code is validated against a Matlab serial implementation, showing a significant improvement in efficiency. Remarkable test cases of several millions of voxels were afforded, overcoming the memory and execution slowness issues. Moreover, the proposed implementation is suitable for large pore-scale models run in HPC environments.

Aboveground hydrogen storage – Assessment of the potential market relevance in a Carbon-Neutral European energy system

Hydrogen storage is expected to play a crucial role in the comprehensive defossilization of energy systems. In this context, the focus is typically on underground hydrogen storage (e.g., in salt caverns). However, aboveground storage, which is independent of geological conditions and might offer other technical advantages, could provide systemic benefits and, thereby, gain shares in the hydrogen storage market. Against this background, this paper examines the market relevance of aboveground compared to underground hydrogen storage. Using the open-source energy system model and optimization framework of Europe, PyPSA-Eur, the influence of geological independence, storage cost relations, and technical storage characteristics (i.e., efficiencies) on mentioned market relevance of aboveground hydrogen storage are investigated. Further, the expectable market relevance based on current cost projections for the future is assessed. The studies show that in terms of hydrogen capacities, aboveground hydrogen storage plays a considerably smaller role compared to underground hydrogen storage. Even when assuming comparatively low aboveground storage cost, it will not exceed 1.7% (1.9TWhH2,LHV) of total hydrogen storage capacities in a cost-optimal European energy system. Regarding the amounts of annually stored hydrogen, aboveground storage could play a larger role, reaching a maximum share of 32.5% (168TWhH2,LHVa-1) of total stored hydrogen throughout Europe. However, these shares are only achievable for low cost storage in particularly suited energy system supply configurations. For higher aboveground storage costs or lower efficiencies, shares drop below 10% sharply. The analysis identifies some especially influential factors for achieving higher market relevance. Besides storage costs, the demand-orientation of a particular aboveground storage system (e.g., hydrogen storage at demand pressure levels) plays an essential role in market relevance. Further, overall efficiency can be a beneficial factor. Still, current projections of future techno-economic characteristics show that aboveground hydrogen storage is too expensive or too inefficient compared to underground storage. Therefore, to achieve notable market relevance, rather drastic cost reductions beyond current expectations would be needed for all assessed aboveground hydrogen storage technologies.

Hydrogen Storage in Deep Saline Aquifers: Non-Recoverable Cushion Gas after Storage

Underground hydrogen storage facilities require cushion gas to operate, which is an expensive one-time investment. Only some of this gas is recoverable after the end of UHS operation. A significant percentage of the hydrogen will remain in underground storage as non-recoverable cushion gas. Efforts must be made to reduce it. This article presents the results of modeling the cushion gas withdrawal after the end of cyclical storage operation. It was found that the amount of non-recoverable cushion gas is fundamentally influenced by the duration of the initial hydrogen filling period, the hydrogen flow rate, and the timing of the upconing occurrence. Upconing is one of the main technical barriers to hydrogen storage in deep saline aquifers. The ratio of non-recoverable cushion gas to cushion gas (NRCG/CG) decreases with an increasing amount of cushion gas. The highest ratio, 0.63, was obtained in the shortest 2-year initial filling period. The lowest ratio, 0.35, was obtained when utilizing the longest initial filling period of 4 years and employing the largest amount of cushion gas. The presented cases of cushion gas recovery can help investors decide which storage option is the most advantageous based on the criteria that are important to them.

Hydrogen adsorption and diffusion behavior in kaolinite slit for underground hydrogen storage: A hybrid GCMC-MD simulation study

Underground hydrogen storage (UHS) in reservoirs offers the opportunity for large-scale and long-term storage of hydrogen. In order to understand the fundamental mechanisms of hydrogen storage and transportation, it is crucial to study the adsorption and diffusion behavior of hydrogen in reservoirs. By utilizing a hybrid GCMC and MD simulation procedure, we investigated the adsorption and diffusion behavior of hydrogen in kaolinite slit with pore sizes ranging from 1 to 20 nm at pressures up to 30 MPa and temperatures ranging from 303 to 423 K. Hydrogen distribution, excess adsorption, diffusion coefficient, and gas–solid interaction energy were analyzed in relation to pore size, temperature, pressure, and mineralogy. When pores are larger than 5 nm, most of the hydrogen is located in the bulk phase, resulting in insignificant hydrogen loss due to adsorption. Therefore, reservoirs with pores larger than 5 nm are suitable for UHS. Reservoirs with low temperatures and high hydrogen pressures are conducive to UHS, but the hydrogen mobility is reduced. The mineralogy of the formation results in pore surfaces with different charge properties, which significantly affects hydrogen storage. Although van der Waals interaction dominates the gas–solid interaction, Coulomb interaction remains important. The negatively charged pore surface mitigates the gas–solid Coulomb interaction, thereby preventing hydrogen loss through adsorption. This study enhances our understanding of hydrogen storage mechanisms in subsurface porous media and elucidates the influence of various factors. Consequently, it provides a theoretical framework for selecting UHS sites.

The ranking of geological structures in deep aquifers of the Polish Lowlands for underground hydrogen storage

Selection of the proper underground hydrogen storage (UHS) site is an essential issue for zero-emission systems based on renewables. The article presents the method for assessing storage traps in saline aquifers and the ranking of storage traps in saline aquifers from the Polish Lowlands for UHS. The ranking was based on the multi-criteria approach of the hierarchical analysis of the decision-making process. The best UHS site was determined based on geological and reservoir criteria. The criteria weights were evaluated using two methods for comparative purposes. The parameters of individual storage traps came from the database developed in the Hystories project. The highest positions in the ranking were obtained by storage traps characterized by the best sealing parameters of caprock, lack of faults within the traps, and good permeability of the reservoir layers. The presented ranking approach can support the decision-making process for selecting UHS sites in other countries.

The feasibility of hydrogen storage in aquifers: A molecular dynamics simulation

Geological hydrogen storage could be an effective method for solving energy demand and climate change challenges. We focus on hydrogen diffusion in carbonate slits via molecular dynamics under subsurface conditions. We investigate the influence of pore size, moisture content, and salinity on hydrogen diffusion process. The results demonstrate that high moisture content reduces the diffusion coefficient of hydrogen due to the form of water bridge and hydrogen cluster. The impact of salinity is observed only under high moisture content conditions. Specially, CaCl2 and MgCl2 are more suitable than NaCl for hydrogen storage. Hydrogen storage is more suitable in lower NaCl concentration while it is more suitable in a higher Na2SO4 concentration. Because interfacial tension of hydrogen-salt solution could be affected by ion concentration. These results demonstrate that hydrogen diffusion could be regulated by changing salinity for high water cut reservoir. This job could provide valuable guidance for underground hydrogen storage.