Uncertainty theory was founded by Baoding Liu for modeling belief degrees about human uncertainty. And chance theory was pioneered by Yuhan Liu based on probability theory and uncertainty theory. In many cases, imprecise risk situation in subjective or objective setting and human uncertainty simultaneously appear in a complex system. To measure uncertain random events in this system, this paper combines uncertainty space with convex non-additive probability space into a new kind of two-dimensional chance space called U-C chance space. Moreover, a new framework for uncertain random variables combining uncertainty theory with convex non-additive probability theory is provided. For applications of this new framework, it can be applied to characterize some kinds of phenomena which possess the characteristics of both imprecise risk situations and belief degrees about human uncertainty in situations of great events, such as financial crisis, major natural disaster, etc. The main contribution of this paper is to derive the types of Kolmogorov and Marcinkiewicz-Zygmund LLNs for uncertain random variables satisfying some conditions under U-C chance space, where the convex non-additive probability is totally monotone. Furthermore, several examples are stated and explained.