UV Sensitivity Research Articles

High-Performance Ga2O3 Solar-Blind Photodetector Based on Thermal Oxidized Ga Buffer-Layer.

High-performance Ga2O3 solar-blind photodetectors are critical for applications due to their selective solar-blind ultraviolet sensitivity. The quality of the Ga2O3 film has a significant impact on the performance of photodetectors. This study presents an innovative approach to enhancing the quality of Ga2O3 films through the introduction of a naturally graded buffer layer, which is formed by the oxidation of a metallic Ga film and significantly improves interface stability by accommodating lattice mismatches and reducing defects. The structural and compositional characteristics of Ga2O3 films were comprehensively analyzed using UV-vis (ultraviolet-visible) spectroscopy, AFM (Atomic Force Microscope), PL (Photoluminescence Spectroscopy), TEM (Transmission Electron Microscope), and XPS (X-ray Photoelectron Spectroscopy). The photodetectors fabricated from these films demonstrate responsivity of 99.8 mA/W and a solar-blind UV/UV ratio of 1.17 × 103, with significant improvement compared to direct deposited films. This research highlights the potential of natural buffering layers to advance the performance of Ga2O3-based solar-blind UV detectors.

AlGaN-Based Ultraviolet PIN Photodetector Grown on Silicon Substrates Using SiN Nitridation Process and Step-Graded Buffers

The integration of aluminum gallium nitride (AlGaN) with silicon substrates attracts significant attention due to the superior UV sensitivity of AlGaN and the cost-effectiveness as well as mechanical robustness of silicon. A PIN ultraviolet photodetector with a peak detection wavelength of 274 nm is presented in this paper. By employing a SiN nucleation layer and a step-graded buffer, a high-quality AlGaN-based photodetector structure with a dislocation density of 2.4 × 109/cm2 is achieved. A double-temperature annealing technique is utilized to optimize the Ohmic contact of the n-type AlGaN. The fabricated UV photodetector attains a dark current of 0.12 nA at −1 V and a peak responsivity of 0.12 A/W.

Conjugated Polymer-Based Photo-Crosslinker for Efficient Photo-Patterning of Polymer Semiconductors.

Photo-patterning of polymer semiconductors using photo-crosslinkers has shown potential for organic circuit fabrication via solution processing techniques. However, the performance of patterning, including resolution (R), UV light exposure dose, sensitivity (S), and contrast (γ), remains unsatisfactory. In this study, a novel conjugated polymer based photo-crosslinker (PN3, Figure 1a) is reported for the first time, which entails phenyl-substituted azide groups in its side chains. Due to the potential π-π interactions between the conjugated backbone of PN3 and those of polymer semiconductors, PN3 exhibits superior miscibility with polymer semiconductors compared to the commonly used small molecule photo-crosslinker 4Bx (Figure 1a). Consequently, photo-patterning of polymer semiconductors with PN3 demonstrates improved performance with much lower UV light exposure dose, higher S and higher γ compared to 4Bx. By utilizing electron beam lithography, patterned arrays of polymer semiconductors with resolutions down to 500nm and clearer edges are successfully fabricated using PN3. Furthermore, patterned arrays of PDPP4T, the p-type semiconductor (Figure 1b), after being doped, can function as source-drain electrodes for fabricating field-effect transistors (FETs) with comparable charge mobility and significantly lower sub-threshold swing value compared to those with gold electrodes.

Self-Powered Lateral Heterojunction Photodetectors: Unveiling Ultraviolet Sensitivity via the RbCu2I3 Microwire and the MAPbBr3 Film with Innovative Engineering

Self-Powered Lateral Heterojunction Photodetectors: Unveiling Ultraviolet Sensitivity via the RbCu₂I₃ Microwire and the MAPbBr₃ Film with Innovative Engineering

Evaluation of antibacterial activity on nanoline-array surfaces with different spacing

Extensive research has been conducted on anti-biofouling or antibacterial surfaces, with nanostructured surfaces that mimic cicada and dragonfly wings emerging as promising candidates for mechano-bactericidal applications. These biomimetic nanostructured surfaces are capable of exerting a bactericidal effect by directly damaging the membranes of bacteria attached to nanostructures. Although research on bactericidal effect using various nanostructures have been conducted, no specific studies have yet reported on the antibacterial efficiency of the surface having nanoline array, especially regarding the spacing between nanolines. This study details the fabrication of nanoline array via ultraviolet (UV) molding with polyurethane acrylate (PUA), noted for its UV sensitivity and rapid curing, enabling the fabrication of precise and scalable nanoscale structures. Investigation into the nanoline array’s antibacterial effects against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) reveals that nanoline spacing critically influences bacterial adherence and viability, with specific spacings enhancing antibacterial properties. Scanning electron microscopy (SEM) and confocal microscopy analyses show that surface topography significantly affects bacterial behavior, with specific spacings leading to varied bacterial responses, including membrane damage and altered attachment patterns. The study highlights the potential of nanoline array in fabricating surfaces with tailored antibacterial properties, emphasizing the importance of nanoscale design in influencing bacterial interaction and viability. We also confirm the relative mechanical rigidity of the nanoline array, which exhibits antibacterial effects, through both experimental observations and numerical analysis. This indicates our proposed nanoline-array surface could have potential future applications in mechanical anti-bacterial functions that require such structural robustness.

A review of plant phenolics and endozoochory.

Phenolic compounds (phenolics) are secondary metabolites ubiquitous across plants. The earliest phenolics are linked to plants' successful transition from an aquatic to a terrestrial environment, serving as protection against damaging ultraviolet (UV) radiation, and as antioxidants to reduce oxidative stress in an atmosphere with an increasingly high O2:CO2 ratio. In modern plants, phenolics are best known for the defense against fungal and bacterial pathogens and as antifeedants that deter herbivory. Phenolics also play a role in seed dormancy, delaying germination, and lengthening viability in the seed bank. Many plants' seeds are endozoochorous - dispersed by animals, like birds, who eat and later excrete the seeds. Plants send visual signals to attract birds with UV-sensitive (UVS) vision for pollination and seed dispersal. As fruits ripen, antioxidant activity and phenolic content decrease. The waxy cuticle of fruits increases in UV reflection as phenolic rings, which absorb UV light, degrade. The UV contrast that birds detect may act as an honest signal, indicating nutritional changes in the fruit. However, there is little evidence to support the evolution of UV coloration during ripening being driven by frugivore selection. Antioxidant properties of fruit phenolics may be dually adaptive in plants and avian frugivores.

Accumulated melanin in molds provides wavelength-dependent UV tolerance.

Fungal contamination poses a serious threat to public health and food safety because molds can grow under stressful conditions through melanin accumulation. Although ultraviolet (UV) irradiation is popular for inhibiting microorganisms, its effectiveness is limited by our insufficient knowledge about UV tolerance in melanin-accumulating molds. In this study, we first confirmed the protective effect of melanin by evaluating the UV sensitivity of young and mature spores. Additionally, we compared UV sensitivity between spores with accumulated melanin and spores prepared with melanin biosynthesis inhibitors. We found that mature spores were less UV-sensitive than young spores, and that reduced melanin accumulation by inhibitors led to reduced UV sensitivity. These results suggest that melanin protects cells against UV irradiation. To determine the most effective wavelength for inhibition, we evaluated the wavelength dependence of UV tolerance in a yeast (Rhodotorula mucilaginosa) and in molds (Aspergillus fumigatus, Cladosporium halotolerans, Cladosporium sphaerospermum, Aspergillus brasiliensis, Penicillium roqueforti, and Botrytis cinerea). We assessed UV tolerance using a UV-light emitting diode (LED) irradiation system with 13 wavelength-ranked LEDs between 250 and 365nm, a krypton chlorine (KrCl) excimer lamp device, and a low pressure (LP) Hg lamp device. The inhibition of fungi peaked at around 270nm, and most molds showed reduced UV sensitivity at shorter wavelengths as they accumulated pigment. Absorption spectra of the pigments showed greater absorption at shorter wavelengths, suggesting greater UV protection at these wavelengths. These results will assist in the development of fungal disinfection systems using UV, such as closed systems of air and water purification.

Electronic Structure, Aromaticity, and Magnetism of Minimum-Sized Regular Dodecahedral Endohedral Metallofullerenes Encapsulating Rare Earth Atoms.

A series of minimally sized regular dodecahedron-embedded metallofullerene REC20 clusters (RE = Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, and Gd) as basic units of nanoassembled materials with tunable magnetism and UV sensitivity have been explored using density functional theory (DFT). The contribution of the 4f orbital of the rare earth atom at the center of the C20 cage to the frontier molecular orbital of REC20 gives the REC20 cluster additional stability. The AdNDP orbitals of the four REC20 superatoms that conform to the spherical jellium model indicate that through natural population analysis and spin density diagrams, we observe a monotonic increase in the magnetic moment from Ce to Gd. This is attributed to the increased number of unpaired electrons in the 4f orbitals of lanthanide rare earth atoms. The UV-visible spectrum of REC20 clusters shows strong absorption in the mid-UV and near-UV bands. REC20 clusters encapsulating lanthanide rare earth atoms stand out for their tunable magnetism, UV sensitivity, and stability, making them potential new self-assembly materials.

Vanillin-based flame retardant enables polylactic acid high-efficiency fireproof, anti-UV and oxygen barrier for food packaging

Polylactic acid (PLA) is widely known for its biocompatibility, biodegradability, and high transparency. However, it still has varied limitations such as flammability, UV sensitivity, and poor oxygen barrier properties. To address these issues, a bio-based compound, hexasubstituted cyclotriphosphazene (HVP), was synthesized by using vanillin and hexachlorocyclotriphosphazene to enhance the overall performance of PLA. The resulting PLA/HVP composites demonstrated improved mechanical strength and UV resistance. Specifically, PLA/3HVP, with a 3 wt% HVP loading, achieved a UL-94 V-0 rating and a high limiting oxygen index of 26.5 %. Cone calorimeter tests revealed that PLA/3HVP possessed a significantly longer ignition time and a lower peak heat release rate compared to pure PLA. These burning testing results indicated the enhanced fire resistance. Additionally, the oxygen transmission rate of PLA/3HVP was reduced by 81.1 % compared to pure PLA. When used as food packaging, the weight loss of mangoes covered with PLA/3HVP film was 2.2 % after 7 days, compared to 2.5 % with pure PLA film, highlighting its potential for food preservation applications.

Elf1 promotes transcription-coupled repair in yeast by using its C-terminal domain to bind TFIIH

Transcription coupled-nucleotide excision repair (TC-NER) removes DNA lesions that block RNA polymerase II (Pol II) transcription. A key step in TC-NER is the recruitment of the TFIIH complex, which initiates DNA unwinding and damage verification; however, the mechanism by which TFIIH is recruited during TC-NER, particularly in yeast, remains unclear. Here, we show that the C-terminal domain (CTD) of elongation factor-1 (Elf1) plays a critical role in TC-NER in yeast by binding TFIIH. Analysis of genome-wide repair of UV-induced cyclobutane pyrimidine dimers (CPDs) using CPD-seq indicates that the Elf1 CTD in yeast is required for efficient TC-NER. We show that the Elf1 CTD binds to the pleckstrin homology (PH) domain of the p62 subunit of TFIIH in vitro, and identify a putative TFIIH-interaction region (TIR) in the Elf1 CTD that is important for PH binding and TC-NER. The Elf1 TIR shows functional, structural, and sequence similarities to a conserved TIR in the mammalian UV sensitivity syndrome A (UVSSA) protein, which recruits TFIIH during TC-NER in mammalian cells. These findings suggest that the Elf1 CTD acts as a functional counterpart to mammalian UVSSA in TC-NER by recruiting TFIIH in response to Pol II stalling at DNA lesions.

Achieving consistency of flexible surface acoustic wave sensors with artificial intelligence

Flexible surface acoustic wave technology has garnered significant attention for wearable electronics and sensing applications. However, the mechanical strains induced by random deformation of these flexible SAWs during sensing often significantly alter the specific sensing signals, causing critical issues such as inconsistency of the sensing results on a curved/flexible surface. To address this challenge, we first developed high-performance AlScN piezoelectric film-based flexible SAW sensors, investigated their response characteristics both theoretically and experimentally under various bending strains and UV illumination conditions, and achieved a high UV sensitivity of 1.71 KHz/(mW/cm²). To ensure reliable and consistent UV detection and eliminate the interference of bending strain on SAW sensors, we proposed using key features within the response signals of a single flexible SAW device to establish a regression model based on machine learning algorithms for precise UV detection under dynamic strain disturbances, successfully decoupling the interference of bending strain from target UV detection. The results indicate that under strain interferences from 0 to 1160 με the model based on the extreme gradient boosting algorithm exhibits optimal UV prediction performance. As a demonstration for practical applications, flexible SAW sensors were adhered to four different locations on spacecraft model surfaces, including flat and three curved surfaces with radii of curvature of 14.5, 11.5, and 5.8 cm. These flexible SAW sensors demonstrated high reliability and consistency in terms of UV sensing performance under random bending conditions, with results consistent with those on a flat surface.

Improved UV sensitivity in solution-processed PVDF/ZnO nanocomposites via piezo-phototronic effect

In this article, we report the enhanced UV photo-detection property of solution processed poly(vinyledene fluoride) (PVDF) membranes filled with zinc oxide (ZnO) nanoparticles at varying concentration. Microstructural analysis confirms β-crystalline phase formation. PVDF/ZnO membranes show increased photo-current compared to pristine PVDF, under UV (λ∼365 nm, 8.3 μW/cm2) irradiation, with PVDF/10% ZnO achieving 4.34 μA photo-current and 6 second response time at 10 V bias. Under mechanical stress in form of bending, UV photocurrent of the composite is enhanced significantly as a result of piezo-phototronic effect. Impedance spectra show significant variations under UV, revealing modifications in grain-boundary interfaces with ZnO and UV, and bending affecting electrical response, confirming the piezo-phototronic effect.

RAD18 O-GlcNAcylation promotes translesion DNA synthesis and homologous recombination repair

RAD18, an important ubiquitin E3 ligase, plays a dual role in translesion DNA synthesis (TLS) and homologous recombination (HR) repair. However, whether and how the regulatory mechanism of O-linked N-acetylglucosamine (O-GlcNAc) modification governing RAD18 and its function during these processes remains unknown. Here, we report that human RAD18, can undergo O-GlcNAcylation at Ser130/Ser164/Thr468, which is important for optimal RAD18 accumulation at DNA damage sites. Mechanistically, abrogation of RAD18 O-GlcNAcylation limits CDC7-dependent RAD18 Ser434 phosphorylation, which in turn significantly reduces damage-induced PCNA monoubiquitination, impairs Polη focus formation and enhances UV sensitivity. Moreover, the ubiquitin and RAD51C binding ability of RAD18 at DNA double-strand breaks (DSBs) is O-GlcNAcylation-dependent. O-GlcNAcylated RAD18 promotes the binding of RAD51 to damaged DNA during HR and decreases CPT hypersensitivity. Our findings demonstrate a novel role of RAD18 O-GlcNAcylation in TLS and HR regulation, establishing a new rationale to improve chemotherapeutic treatment.

Evaluating UV-C Sensitivity of Calonectria pseudonaviculata in Model Buffer Solution Using a UV-C Light-Emitting-Diode System.

Calonectria pseudonaviculata, responsible for boxwood blight, produces sticky conidia that pose a contamination risk in boxwood production via cross-contamination from tools, equipment, and other resources. This study evaluated UV-C light-emitting-diode (LED) irradiation (263 to 287 nm) as a disinfection method by examining its effectiveness in inactivating conidia and determining the UV-C sensitivity. Conidial suspensions were exposed to quantifiable UV-C doses under a dynamic stirring condition. Average volumetric intensity was quantified by accounting for UV gradients and UV dose was calculated as a product of average fluence rate (mW⋅cm-2) and exposure time (s). UV-C irradiation effectively inactivated the tested pathogen following log-linear + shoulder kinetics as identified by parameters of goodness of model fit (i.e., high R2 and low root mean square error [RMSE] values). The model predicted the UV sensitivity of C. pseudonaviculata conidia as 46.6 mJ⋅cm-2 per log. A total of 2.04 log reductions of the population could be obtained by an exposure of 60 mJ⋅cm-2 of UV-C dose. The calculated decimal reduction dose (D10) was 13.53 ± 0.98 mJ⋅cm-2 (R2 = 0.97, RMSE = 0.14), inactivation rate constant (Kmax) = 0.17 ± 0.01, and shoulder length = 33.06 ± 1.81 mJ⋅cm-2. These findings indicate that UV-C irradiation could be a viable option for disinfecting tools, equipment, and possibly propagation cuttings in nurseries.

Weak-scale Higgs inflation

The present measurement of the Standard Model (SM) parameters suggests that the Higgs effective potential has a maximum at the Higgs field value of approximately 1011GeV, and the electroweak (EW) vacuum is not absolutely stable. To achieve absolute EW stability, a very large Higgs-Ricci scalar non-minimal coupling can be introduced.I study cosmic inflation driven by the Higgs field in this extension of the SM and refer to it as “weak-scale Higgs inflation” because the resulting inflationary Hubble parameter is around the weak scale. The Palatini formulation of gravity with a dimension 6 term is shown to drive successful inflation. I also argue for the UV (in)sensitivity of the predictions, and phenomenological implications. In the metric formulation case, the scenario for stable EW vacuum may be probed by measuring the Higgs coupling in future colliders.

Flexible biopolymer photodetectors based Er, Tb doped BaW[formula omitted]@CS for enhanced light-sensitive coatings

Today, the electro-optics industry is one of the world's largest manufacturing sectors today, and its growth has led to an increasing reliance on electronic equipment. Simultaneously, the significance of optical wearable detection across diverse fields, from high-energy physics to nuclear medicine and optoelectronics, cannot be overstated. Barium tungstate (BWO), a remarkable and advanced compound, has consistently piqued the interest of researchers across various domains due to its unique photoenergy properties. This study presents a novel, cost-effective approach to creating flexible ionizing radiation detectors. These detectors are constructed using pure barium tungstate fillers infused with erbium and terbium within a chitosan matrix (Er: BWO-CS, Tb: BWO-CS). Initially, we synthesized pure barium tungstate nanoparticles, incorporating erbium and terbium through a co-precipitation method, and subsequently embedded them into a chitosan biopolymer substrate. Characterization through XRD, XPS, EDX-MAP, and FTIR analyses confirmed the formation of the tetragonal barium tungstate structure, bonding, compounds, and chemical elements in the prepared composites. Through SRIM calculations, we determined the optimal thickness for these flexible nanocomposites to detect alpha particles, approximating 60–80 micrometers. The optical properties of the detectors were assessed under ultraviolet light excitation, 980 nm laser irradiation, proton beam exposure, and alpha source activation. Notably, the Er: BaWO4-CS nanocomposite exhibited the best scintillation properties, highest UV sensitivity, and superior alpha particle detection efficiency (at a low activity of 643 Bq). The results underscored the stability, reproducibility, and linear response of these sensors under continuous irradiation. Photo/ionoluminescence studies revealed that the doped nanocomposite showed, in comparison to the pure BWO-CS sample, the greatest visible blue-green emission at room temperature, featuring a luminescence delay time of 243 µs. Antimicrobial and cytotoxicity tests confirmed the safety of these flexible sensors, making them suitable for applications related to human health applications. Consequently, these sensors represent a promising avenue for the development of next-generation wearable and environmentally friendly sensing technologies.

MicroRNA164 Affects Plant Responses to UV Radiation in Perennial Ryegrass.

Increasing the ultraviolet radiation (UV) level, particularly UV-B due to damage to the stratospheric ozone layer by human activities, has huge negative effects on plant and animal metabolism. As a widely grown cool-season forage grass and turfgrass in the world, perennial ryegrass (Lolium perenne) is UV-B-sensitive. To study the effects of miR164, a highly conserved microRNA in plants, on perennial ryegrass under UV stress, both OsmiR164a overexpression (OE164) and target mimicry (MIM164) transgenic perennial ryegrass plants were generated using agrobacterium-mediated transformation, and UV-B treatment (~600 μw cm-2) of 7 days was imposed. Morphological and physiological analysis showed that the miR164 gene affected perennial ryegrass UV tolerance negatively, demonstrated by the more scorching leaves, higher leaf electrolyte leakage, and lower relative water content in OE164 than the WT and MIM164 plants after UV stress. The increased UV sensitivity could be partially due to the reduction in antioxidative capacity and the accumulation of anthocyanins. This study indicated the potential of targeting miR164 and/or its targeted genes for the genetic manipulation of UV responses in forage grasses/turfgrasses; further research to reveal the molecular mechanism underlying how miR164 affects plant UV responses is needed.

Pauli–Villars Regularization of Kaluza–Klein Casimir Energy with Lorentz Symmetry

Abstract The Pauli–Villars regularization is appropriate to discuss the UV sensitivity of low-energy observables because it mimics how the contributions of new particles at high energies cancel large quantum corrections from the light particles in the effective field theory. We discuss the UV sensitivity of the Casimir energy density and pressure in an extra-dimensional model in this regularization scheme, and clarify the condition on the regulator fields to preserve the Lorentz symmetry of the vacuum state. Some of the conditions are automatically satisfied in spontaneously broken supersymmetric models, but supersymmetry is not enough to ensure the Lorentz symmetry. We show that the necessary regulators can be introduced as bulk fields. We also evaluate the Casimir energy density with such regulators, and its deviation from the result obtained in the analytic regularization.

Effect of Traps on the UV Sensitivity of Gallium Oxide-Based Structures

Resistive metal/β-Ga2O3/metal structures with different interelectrode distances and electrode topologies were investigated. The oxide films were deposited by radio-frequency magnetron sputtering of a Ga2O3 (99.999%) target onto an unheated sapphire c-plane substrate (0001) in an Ar/O2 gas mixture. The films are sensitive to ultraviolet radiation with wavelength λ = 254. Structures with interdigital electrode topology have pronounced persistent conductivity. It is shown that the magnitude of responsivity, response time τr, and recovery time τd are determined by the concentration of free holes p involved in recombination processes. For the first time, it is proposed to consider hole trapping both by surface states Nts at the metal/Ga2O3 interface and by traps in the bulk of the film.

UV and IR effects in axion quality control

Motivated by recent discussions and the absence of exact global symmetries in UV completions of gravity we re-examine the axion quality problem (and naturalness issues more generally) using antisymmetric Kalb-Ramond (KR) fields rather than their pseudoscalar duals, as suggested by string and higher dimensional theories. Two types of axions can be identified: a model independent S-type axion dual to a two form Bμν in 4D and a T-type axion coming directly as 4D scalar Kaluza-Klein (KK) components of higher-dimensional tensor fields. For T-type axions our conclusions largely agree with earlier workers for the axion quality problem, but we also reconcile why T-type axions can couple to matter localized on 3-branes with Planck suppressed strength even when the axion decay constants are of order the KK scale. For S-type axions, we review the duality between form fields and massive scalars and show how duality impacts naturalness arguments about the UV sensitivity of the scalar potential. In particular UV contributions on the KR side suppress contributions on the scalar side by powers of m/M with m the axion mass and M the UV scale. We re-examine how the axion quality problem is formulated on the dual side and compare to recent treatments. We study how axion quality is affected by the ubiquity of p-form gauge potentials (for both p = 2 and p = 3) in string vacua and identify two criteria that can potentially lead to a problem. We also show why most fields do not satisfy these criteria, but when they do the existence of multiple fields also provides mechanisms for resolving it. We conclude that the quality problem is easily evaded.