Ultrahigh Stability Research Articles

Screening transition metal and nonmetal atoms co-doped graphyne as efficient single-atom catalysts for nitrogen reduction

Despite the great potential of electrocatalytic nitrogen reduction reaction (NRR) for more sustainable and energy-efficient ammonia (NH3) production, significant challenges remain, including low activity and poor selectivity of currently available catalysts. In this study, we systematically investigate the electrocatalytic NRR performance of 43 types of single-atom catalysts (SACs) constructed by introducing single transition metal (TM) or/and nonmetal (NM) atoms in graphyne (TM-NM-GY) through first-principles calculations. It is found that Mn-, Os-, B-, Ti-B-, V-B-, Cr-B-, Ru-B-, and Os-B-GY exhibit remarkable efficiency for NRR, showcasing overpotentials lower than 0.34 V. Particularly, Os-B-GY stands out by demonstrating ultra-high catalytic activity, selectivity, and stability for NRR as well as good experimental feasibility, with an impressively low overpotential of merely 0.13 V. The co-doping of Os and B allows for adjusting moderately positive charge densities around Os, which enables strong d-2π* coupling between Os and N2. As a result, the N≡N triple bond is remarkably weakened, facilitating the subsequent NRR process. Moreover, benefiting from the cooperative doping of NM and TM, the potential limiting step is changed, which breaks the inherent linear volcanic relationship between the free energy of the critical intermediate N2H* and limiting potential (UL) on the sole TM-doped system, further enhancing the activity and selectivity. We anticipate that the insights gained from this comprehensive and systematic study can offer valuable guidance for the design and synthesis of novel and highly efficient SACs toward NRR.

Rational Construction of Bi2CuO12Se4 and VGCFs@Fe2O3 Composite Electrodes for High-Performance Semi-Solid-State Asymmetric Supercapacitors.

Recently, supercapacitors (SCs) are extensively explored as effective energy storage devices. Specifically, asymmetric SCs are being developed to enhance energy density using suitable materials with favorable nanostructures. This study describes the construction of a bismuth copper selenite (BCS-200) working electrode with an ultrathin nanosheet(UTNS) architecture. This morphology is achieved using a low-cost electrodeposition (ED) method, followed by annealing. The impact of ED time on the development of morphology is studied by synthesizing comparative electrodes simultaneously. The optimized BCS-200 electrode prepared with a deposition time of 200 s shows higher specific capacity/capacitance (Cs/Csc) values of 330.9 mAh g-1/2206.6 F g-1 than the other synthesized electrodes (BCS-100, BCS-150, BCS-250, and BCS-300). Besides, a vapor-grown carbon fiber (VGCF)-added Fe2O3 composite coated on nickel foam (NF) is developed as a negative electrode. The VGCFs@Fe2O3/NF electrode exhibits the (Cs/Csc) values of 183.5 mAh g-1/734.4 F g-1, which is associated with ultra-high cycling stability. In addition, the fabricated BCS-200 and VGCFs@Fe2O3/NF electrodes are combined to construct a wearable semi-solid-state asymmetric SC (SSASC) with an energy density (Ed) of 20.5Wh kg-1 and a cycling stability of 91.7% over 40000 charge/discharge cycles. Furthermore, the real-time applicability of the SSASC is verified by powering it in practical applications.

Electrolyte‐gated organic field‐effect transistors with high operational stability and lifetime in practical electrolytes

AbstractA key component of organic bioelectronics is electrolyte‐gated organic field‐effect transistors (EG‐OFETs), which have recently been used as sensors to demonstrate label‐free, single‐molecule detection. However, these devices exhibit limited stability when operated in direct contact with aqueous electrolytes. Ultrahigh stability is demonstrated to be achievable through the utilization of a systematic multifactorial approach in this study. EG‐OFETs with operational stability and lifetime several orders of magnitude higher than the state of the art have been fabricated by carefully controlling a set of intricate stability‐limiting factors, including contamination and corrosion. The indacenodithiophene‐co‐benzothiadiazole (IDTBT) EG‐OFETs exhibit operational stability that exceeds 900 min in a variety of widely used electrolytes, with an overall lifetime exceeding 2 months in ultrapure water and 1 month in various electrolytes. The devices were not affected by electrical stress‐induced trap states and can remain stable even in voltage ranges where electrochemical doping occurs. To validate the applicability of our stabilized device for biosensing applications, the reliable detection of the protein lysozyme in ultrapure water and in a physiological sodium phosphate buffer solution for 1500 min was demonstrated. The results show that polymer‐based EG‐OFETs are a viable architecture not only for short‐term but also for long‐term biosensing applications.

Encapsulating Mn-Fe prussian blue analog nanocuboids into the graphene framework towards fast and durable sodium storage

The exploration of high-performance sodium-ion hosts is an important issue in the field of advanced energy storage and conversions. Herein, MnFe PBA/rGO composite was prepared by simple coprecipitation and in situ synthesis, and realized the fast kinetics and superior stability for sodium storage. The rGO nanosheets were introduced as the framework to encapsulate the MnFe PBA nanocuboids with uniform particle size and well-defined configuration to further enhance their electrical conductivity and electrochemical properties. The prepared MnFe PBA/rGO composite exhibits superior charge/discharge properties than the pristine MnFe PBA nanocuboids, which show a capacity enhancement of over 30%. In addition, the PBA/rGO composite exhibits excellent cycling stability, which retains 80% of the capacity after 1000 cycles at a high rate of 1 A/g. The electrochemical impedance spectroscopy (EIS) results further demonstrate the low resistance, high durability, and ultrahigh stability of the MnFe PBA/rGO composite during high-rate long-term cycling. Therefore, this work not only provides a high-performance sodium host but also gives a new clue to the design and construction of highly efficient electrode materials for advanced electrochemical systems.

Preparation method and industrialization of Ta-based ultra high temperature ceramic Tujia jar tea baking jar materials

The production materials of traditional Tujia jar tea often face problems such as poor high-temperature performance and poor durability. To improve the temperature resistance and durability of tea baking utensils, this study proposes a new type of TaC ultra-high temperature ceramic. TaC ceramics with excellent performance were prepared through powder metallurgy technology, including high-energy ball milling to ensure uniform mixing, followed by compression molding and high-temperature sintering. The test results demonstrated excellent mechanical properties, with a maximum depth of 948.67 nm and a contact depth of 954.45 nm, proving outstanding compressive and wear resistance. The hardness reached 21.4±0.5 Gpa, and the elastic modulus was 397.2±8.7 Gpa, both of which indicate its stability under high loads. In addition, the fracture toughness was 2.8±0.2 Mpa*m1/2. At a high temperature environment of 1000 °C, the oxidation rate constant of TaC ceramics was only 0.183 mg2 *cm−4 *h, which demonstrates its excellent high-temperature stability. The development of this TaC ceramic not only strengthened the traditional production process of Tujia teapots and tea roasting teapots, thereby improving the product’s service life, but also holds potential for other industrial applications that demand ultra-high temperature stability. These contributions provide new directions for the high-temperature application of ceramic materials and bring tangible economic and technological value to related industries.

Suppressing proton-induced HER and cathode fading by an aprotic hybrid electrolyte for long-cycle stability of aqueous Na||Zn hybrid batteries

Aqueous zinc metal batteries with unique advantages of intrinsic safety and low cost are considered as one of the most promising next-generation energy-storage technologies. However, their lifespan is significantly constrained by the electrolyte, specifically due to limitations caused by proton-induced HER and dendritic growth at the anode side and dissolution phenomena at the cathode. Unlike most studies on the protic electrolyte systems, herein, a new aprotic hybrid electrolyte of Na/Zn tetrafluoroborate-trimethyl phosphate with ultralow proton activity tuned by reconstruction of hydrogen bonding network and ultrahigh interfacial stability endowed by simultaneous formation of SEI and CEI were designed for the first time. Attributed to the synergistic effect of proton activity attenuation and ZnF2-Zn3(PO4)2 SEI formation, HER-trigged corrosion current was decreased by 96.52%, which leads to an exceptionally high coulombic efficiency up to 99.63%, and operational lifespan exceeding 2000 hours at 1 mA cm−2/ 1 mAh cm−2 for Zn||Cu asymmetric cell and Zn||Zn symmetric cell, respectively. Furthermore, the suppression of excess hydrated proton co-insertion reaction and construction of inorganic-organic CEI enabled the PBAs||Zn full cell a prolonged cycling life of 6000 cycles with an ultralow decay rate of 0.004% per cycle. The special electrolyte utilizing cheap tetrafluoroborate salts in conjunction with cost-effective PBA cathode and Zn anode provides a new choice for low-cost, high-safety, non-toxic batteries for practical applications.

Over 60h of Stable Water-Operation for N-Type Organic Electrochemical Transistors with Fast Response and Ambipolarity.

Organic electrochemical transistors (OECTs) are of great interest in low-power bioelectronics and neuromorphic computing, as they utilize organic mixed ionic-electronic conductors (OMIECs) to transduce ionic signals into electrical signals. However, the poor environmental stability of OMIEC materials significantly restricts the practical application of OECTs. Therefore, the non-fused planar naphthalenediimide (NDI)-dialkoxybithiazole (2Tz) copolymers are fine-tuned through varying ethylene glycol (EG) side chain lengths from tri(ethylene glycol) to hexa(ethylene glycol) (namely P-XO, X=3-6) to achieve OECTs with high-stability and low threshold voltage. As a result, the NDI-2Tz copolymers exhibit ambipolarity, rapid response (<10ms), and ultra-high n-type stability. Notably, the P-6O copolymers display a threshold voltage as low as 0.27V. They can operate in n-type mode in an aqueous solution for over 60h, maintaining an on-off ratio of over 105. This work sheds light on the design of exceptional n-type/ambipolar materials for OECTs. It demonstrates the potential of incorporating these ambipolar polymers into water-operational integrated circuits for long-term biosensing systems and energy-efficient brain-inspired computing.

Built-in electric field and core-shell structure of the reconstructed sulfide heterojunction accelerated water splitting

The rational design of high-performance bifunctional electrocatalysts for overall water splitting (OWS) is the key to popularize hydrogen production technology. The active metal oxyhydroxide (MOOH) formed after surface self-reconfiguration of transition metal sulfide (TMS) electrocatalyst is often regarded as the "actual catalyst" in oxygen evolution reaction (OER). Herein, an Fe doped CoS2/MoS2 hollow TMS polyhedron (Fe-CoS2/MoS2) with rich Mott-Schottky heterojunction is reported and directly utilized as an OWS electrocatalyst. The spontaneous built-in electric field (BEF) at the heterogeneous interface regulates the electronic structure and D-band center of the catalyst. More importantly, the “TMS-MOOH” core-shell structure obtained in the KOH electrolyte shows enhanced OER properties. And the introduction of Fe ions activates the inert basal plane of MoS2, which greatly steps up the performance of HER. Hence, the preferable Fe-CoS2/MoS2–400 presents superior OER activity (η10 = 178 mV, η100 = 375 mV), HER activity (η10 = 92 mV) and ultra-high stability for 50 h. This work has deeply explored the catalytic mechanism of TMS and provided a new idea for the construction of efficient bifunctional catalysts.

High-Entropy CeNbO4+δ-Based Ceramics with Ultrahigh Comprehensive Thermosensitive Performances.

Next-generation advanced high-temperature sensors rely heavily on negative temperature coefficient thermosensitive ceramics with low cost, small volume, high sensitivity, and fast response. However, thus far, the enormous challenge of achieving ultrahigh stability and accuracy has become a critical bottleneck restricting the development of thermosensitive ceramics in high-temperature sensor applications. Here, we propose a high-entropy strategy to design a "cation valence self-equilibrium" system in CeNbO4+δ-based ceramics introducing redox couple compensation and ultrahigh density dislocations to solve the problem of temperature-dependent oxygen nonstoichiometry that restricts the performances of high-temperature thermosensitive ceramics. Ferroelastic domains are generated by enhancing the configurational entropy at both A and B sites, resulting in a dramatic increase of dislocation density to >1010 mm-2, which ultimately optimizes the thermosensitive performances. Extreme temperature measurement accuracy with R2 as high as 999.98‰ and RSS as low as 0.011 and high-temperature stability with ΔR/R0 as low as 0.23% after aging at 873 K for 1000 h are realized in high-entropy CeNbO4+δ-based ceramics, indicating a breakthrough in the comprehensive performances of thermosensitive ceramics. This work opens up an effective way to design thermosensitive materials with ultrahigh comprehensive performance to meet the requirements of advanced high-temperature sensors.

Hydrogen Bonds Induced Ultralong Stability of Conductive π-d Conjugated FeCo3(DDA)2 with High OER Activity.

Conductive π-d conjugated metal-organic frameworks (MOFs) have attracted wide concerns in electrocatalysis due to their intrinsic high conductivity. However, the poor electrocatalytic stability is still a major problem that hinders the practical application of MOFs. Herein, a novel approach to enhancing the stability of MOF-based electrocatalyst, namely, the introduction of hydrogen bonds (H-bonds), is reported. Impressively, the π-d conjugated MOF FeCo3(DDA)2 (DDA = 1,5-diamino-4,8-dihydroxy-9,10-anthraceneedione) exhibits ultrahigh oxygen evolution reaction (OER) stability (up to 2000h). The experimental studies demonstrate that the presence of H-bonds in FeCo3(DDA)2 is responsible for its ultrahigh OER stability. Besides that, FeCo3(DDA)2 also displays a prominent OER activity (an overpotential of 260mV vs reversible hydrogen electrode (RHE) at a current density of 10mA cm-2 and a Tafel slope of 46.86mV dec-1). Density functional theory (DFT) calculations further indicate that the synergistic effect of the Fe and Co sites in FeCo3(DDA)2 contributes to its prominent OER performance. This work provides a new avenue of boosting the electrocatalytic stability of conductive π-d conjugated MOFs.

Protein-nanoparticle co-assembly supraparticles for drug delivery: Ultrahigh drug loading and colloidal stability, and instant and complete lysosomal drug release

Two frequent problems hindering clinical translation of nanomedicine are low drug loading and low colloidal stability. Previous efforts to achieve ultrahigh drug loading (>30 %) introduce new hurdles, including lower colloidal stability and others, for clinical translation. Herein, we report a new class of drug nano-carriers based on our recent finding in protein-nanoparticle co-assembly supraparticle (PNCAS), with both ultrahigh drug loading (58 % for doxorubicin, i.e., DOX) and ultrahigh colloidal stability (no significant change in hydrodynamic size after one year). We further show that our PNCAS-based drug nano-carrier possesses a built-in environment-responsive drug release feature: once in lysosomes, the loaded drug molecules are released instantly (<1 min) and completely (∼100 %). Our PNCAS-based drug delivery system is spontaneously formed by simple mixing of hydrophobic nanoparticles, albumin and drugs. Several issues related to industrial production are studied. The ultrahigh drug loading and stability of DOX-loaded PNCAS enabled the delivery of an exceptionally high dose of DOX into a mouse model of breast cancer, yielding high efficacy and no observed toxicity. With further developments, our PNCAS-based delivery systems could serve as a platform technology to meet the multiple requirements of clinical translation of nanomedicines.

Poly(ethylene oxide)-based composite solid electrolyte for long cycle life solid-state lithium metal batteries: Improvement of interface stability through a dual mechanism

Solid-state lithium metal batteries (SSLMBs) are promising candidates for safe and high-energy-density next-generation applications. However, harmful interfacial decomposition and uneven Li deposition lead to poor ion transport, a short cycle life, and battery failure. Herein, we propose a novel poly(ethylene oxide) (PEO)-based composite solid electrolyte (CSE) containing succinonitrile (SN) and zinc oxide (ZnO) nanoparticles (NPs), which improves interface stability through a dual mechanism. (1) By anchoring bis(trifluoromethanesulfonyl)imide (TFSI) anions to ZnO, a reliable solid electrolyte interface (SEI) later with abundant LiF can be obtained to inhibit interface decomposition. (2) The immobilization of escaping SN molecules in the SEI layer by ZnO NPs promotes the self-polymerization of SN and facilitates charge transfer through the interface. As a result, the ion conductivity of the stainless steel–symmetrical battery reaches 1.1 × 10−4 S cm−1 at room temperature, and a LiFePO4 (LFP) full battery exhibits ultrahigh stability (800 cycles) at 0.5 C. Thus, the present study provides valuable insights for the development of advanced PEO-based SSLMBs.

A novel composite solid electrolyte with ultrahigh ion transference number and stability for solid-state sodium metal batteries

The combination of a Na-ion conducting filler and polymer matrix in composite solid electrolyte (CSE) presents a promising and attractive strategy for improving the energy density and safety of the sodium-metal batteries. The agglomeration and precipitation of inorganic ceramic fillers in the polymer matrix present a major challenge leading to the decreased Na ion conductivity property and transference number, increased interfacial resistance, and worsened mechanical properties of CSEs. Herein, we introduce a novel composite solid electrolyte (denoted as 3D-15PNZSPP), comprising a three-dimensional interconnected porous Na3Zr2Si2PO12 framework integrated with an asymmetric polymer electrolyte layer, which not only offers continuous conductive pathways and high mechanical strength for Na ions transfer, but also enhances the interfacial compatibility and expands the electrochemical stability window. The 3D-15PNZSPP CSE shows a high Na+ conductivity of 7.6 × 10−4 S cm−1 and an outstanding transference number of 0.82 at temperature of 30 °C. These characteristics enable the Na/3D-15PNZSPP/Na symmetric cell to cycle for over 700 h with a small overpotential. More importantly, the assembled all solid-state Na0.67Li0.24Mn0.76O2/3D-15PNZSPP/Na batteries demonstrate remarkable cycling stability and high rate capability, indicating a promising and facile strategy for designing ultra-safe and high-performance solid-state sodium metal batteries.

Turning Ultra-Low Coercivity and Ultra-High Temperature Stability Within 897 K via Continuous Crystal Ordering Fluctuations.

High-performance soft magnetic materials are important for energy conservation and emission reduction. One challenge is achieving a combination of reliable temperature stability, high resistivity, high Curie temperature, and high saturation magnetization in a single material, which often comes at the expense of intrinsic coercivity-a typical trade-off in the family of soft magnetic materials with homogeneous microstructures. Herein, a nanostructured FeCoNiSiAl complex concentrated alloy is developed through a hierarchical structure strategy. This alloy exhibits superior soft magnetic properties up to 897K, maintaining an ultra-low intrinsic coercivity (13.6 A m-1 at 297 K) over a wide temperature range, a high resistivity (138.08µΩcm-1 at 297K) and the saturation magnetization with only a 16.7% attenuation at 897 K. These unusual property combinations are attributed to the dual-magnetic-state nature with exchange softening due to continuous crystal ordering fluctuations at the atomic scale. By deliberately controlling the microstructure, the comprehensive performance of the alloy can be tuned and controlled. The research provides valuable guidance for the development of soft magnetic materials for high-temperature applications and expands the potential applications of related functional materials in the field of sustainable energy.

Eliminating the Adverse Impact of Composition Modulation in Perovskite Light-Emitting Diodes toward Ultra-High Brightness and Stability.

Excess ammonium halides as composition additives are widely employed in perovskite light-emitting diodes (PeLEDs), aiming to achieve high performance by controlling crystallinity and passivating defects. However, an in-depth understanding of whether excess organoammonium components affect the film physical/electrical properties and the resultant device instability is still lacking. Here, the trade-off between the performance and stability in high-efficiency formamidinium lead iodide (FAPbI3)-based PeLEDs with excess ammonium halides is pointed, and the underlying mechanism is explored. Systematic experimental and theoretical studies reveal that excess halide salt-induced ion-doping largely alters the PeLEDs properties (e.g., carrier injection, field-dependent ion-drifting, defect physics, and phase stability). A surface clean assisted cross-linking strategy is demonstrated to eliminate the adverse impact of composition modulation and boost the operational stability without sacrificing the efficiency, achieving a high efficiency of 23.6%, a high radiance of 964 W sr-1 m-2 (The highest value for FAPbI3 based PeLEDs), and a prolong lifetime of 106.1 h at large direct current density (100mA cm-2), concurrently. The findings uncovered an important link between excess halide salts and the device performance, providing a guideline for rational design of stable, bright, and high efficiency PeLEDs.

Interfacial modulation of hollow ZnS-SnS2 microboxs by Ti3C2Tx MXene to construct three-dimensional hybrid anodes for lithium-ion batteries with ultra high stability at low temperature

Metal sulfides exhibit obvious volume expansion due to the inherent poor conductivity and large temperature fluctuations, leading to reduced storage capacity. Herein, an electrostatic self-assembly strategy was proposed to fabricate a three-dimensional (3D) polyaniline (PANI) encapsulated hollow ZnS-SnS2 (H-ZSS) heterojunction confined on Ti3C2Tx MXene nanosheets (H-ZnS-SnS2@MXene@PANI, denoted as H-ZSSMP), which exhibits remarkable reversible capacity and cyclic stability (520.3 mAh/g at 2 A/g after 1000 cycles) at room temperature. Additionally, specific capacity can stabilized at 362.5 mAh/g for 250 cycles at −20 °C. A full cell with the configuration of H-ZSSMP//lithium iron phosphate (LiFePO4) can retain a satisfactory reversible capacity of 424.7 mAh/g after 100 cycles at 0.1 C. Theory calculations confirm heterogeneous interface can accelerate the transfer of ions through the interfacial regulation effect of MXene on H-ZSS. Our work provides a simple strategy to improve the capacity and stability of lithium-ion batteries (LIBs), as well as the new applications of MXene and bimetallic sulfides as anode materials, which will facilitate the development of MXene based composites for energy storage.

Thiazole-functionalized conjugated microporous polymers enable efficient gold recovery from e-waste

From the perspectives of environmental protection and efficiency, the use of clean and efficient photocatalytic reduction technology to recover gold from e-waste not only has a high economic value, but also reduces environmental pollution. However, it remains a challenge to construct adsorbents with simultaneously high photocatalytic activity, high stability, high capacity and high selectivity. Here, we demonstrate the application of D-π-A type thiazole-functionalized conjugated microporous polymer (termed BTD-TEA) for adsorption-photocatalytic recovery of gold from e-waste. The synthesized BTD-TEA not only have a narrow optical bandgap (1.75 eV) and excellent semiconductor properties, but also have ultra-high acid stability (stable in aqua regia). Surprisingly, BTD-TEA exhibits breakthrough gold adsorption capacity (4052.83 mg g−1), ultrafast adsorption kinetics, excellent selectivity and outstanding reusability under light conditions. This work provides a promising new adsorption-photocatalytic strategy for gold recovery from e-waste.

Silica Nanowires-Filled Glass Microporous Sensor for the Ultrasensitive Detection of Deoxyribonucleic Acid.

DNA carries genetic information and can serve as an important biomarker for the early diagnosis and assessment of the disease prognosis. Here, we propose a bottom-up assembly method for a silica nanowire-filled glass microporous (SiNWs@GMP) sensor and develop a universal sensing platform for the ultrasensitive and specific detection of DNA. The three-dimensional network structure formed by SiNWs provides them with highly abundant and accessible binding sites, allowing for the immobilization of a large amount of capture probe DNA, thereby enabling more target DNA to hybridize with the capture probe DNA to improve detection performance. Therefore, the SiNWs@GMP sensor achieves ultrasensitive detection of target DNA. In the detection range of 1 aM to 100 fM, there is a good linear relationship between the decrease rate of current signal and the concentration of target DNA, and the detection limit is as low as 1 aM. The developed SiNWs@GMP sensor can distinguish target DNA sequences that are 1-, 3-, and 5-mismatched, and specifically recognize target DNA from complex mixed solution. Furthermore, based on this excellent selectivity and specificity, we validate the universality of this sensing strategy by detecting DNA (H1N1 and H5N1) sequences associated with the avian influenza virus. By replacing the types of nucleic acid aptamers, it is expected to achieve a wide range and low detection limit sensitive detection of various biological molecules. The results indicate that the developed universal sensing platform has ultrahigh sensitivity, excellent selectivity, stability, and acceptable reproducibility, demonstrating its potential application in DNA bioanalysis.

Strongly-Confined CsPbBr3 Perovskite Quantum Dots with Ultralow Trap Density and Narrow Size Distribution for Efficient Pure-Blue Light-Emitting Diodes.

The development of pure-blue perovskite light-emitting diodes (PeLEDs) faces challenges of spectral stability and low external quantum efficiency (EQE) due to phase separation in mixed halide compositions. Perovskite quantum dots (QDs) with strong confinement effects are promising alternatives to achieve high-quality pure-blue PeLEDs, yet their performance is often hindered by the poor size distribution and high trap density. A strategy combining thermodynamic control with a polishing-driven ligand exchange process to produce high-quality QDs is developed. The strongly-confined pure-blue (≈470nm) CsPbBr3 QDs exhibit narrow size distribution (12% dispersion) and are achieved in Br-rich ion environment based on growth thermodynamic control. Subsequent polishing-driven ligand exchange process removes imperfect surface sites and replaces initial long-chain organic ligands with short-chain benzene ligands. The resulting QDs exhibit high photoluminescence quantum yield (PLQY) to near-unity. The resulting PeLEDs exhibit a pure-blue electroluminescence (EL) emission at 472nm with narrow full-width at half-maximum (FWHM) of 25nm, achieving a maximum EQE of 10.7% and a bright maximum luminance of 7697cdm-2. The pure-blue PeLEDs show ultrahigh spectral stability under high voltage, a low roll-off of EQE, and an operational half-lifetime (T50) of 127min at an initial luminance of 103cdm-2 under continuous operation.

Phytic Acid Customized Hydrogel Polymer Electrolyte and Prussian Blue Analogue Cathode Material for Rechargeable Zinc Metal Hydrogel Batteries.

Zinc anode deterioration in aqueous electrolytes, and Zn dendrite growth is a major concern in the operation of aqueous rechargeable Zn metal batteries (AZMBs). To tackle this,the replacement of aqueous electrolytes with a zinc hydrogel polymer electrolyte (ZHPE) is presented in this study. This method involves structural modifications of the ZHPE by phytic acid through an ultraviolet (UV) light-induced photopolymerization process. The high membrane flexibility, high ionic conductivity (0.085Scm-1), improved zinc corrosion overpotential, and enhanced electrochemical stability value of ≈2.3V versus Zn|Zn2+ show the great potential of ZHPE as an ideal gel electrolyte for rechargeable zinc metal hydrogel batteries (ZMHBs). This is the first time that the dominating effect of chelation of phytic acid with M2+ center over H-bonding with water is described to tune the gel electrolyte properties for battery applications. The ZHPE shows ultra-high stability over 360h with a capacity of 0.50mAhcm-2 with dendrite-free plating/stripping in Zn||Zn symmetric cell. The fabrication of the ZMHB with a high-voltage zinc hexacyanoferrate (ZHF) cathode shows a high-average voltage of ≈1.6V and a comparable capacity output of 63mAhg-1 at 0.10Ag-1 of the current rate validating the potential application of ZHPE.