Ultra-dense deuterium D(−1) with D-D bond distance 2.3 pm is the first ultra-dense material studied. It is a superfluid quantum material and may also be superconductive. Its interaction with metal and polymer surfaces is of immediate interest. D(−1) exists on organic polymer surfaces like (poly(methyl methacrylate)) PMMA even at a distance of a few millimeter from a metal in contact with the polymer. The density of D(−1) decreases from the metal surface to the open polymer surface, and is to some extent replaced by D(1) on the polymer surface. At low surface density of D(−1), the long chain-clusters appear to lie parallel the surface, while at large densities the clusters stand vertical to the surface. Various polymers give different structures of D(−1), for example fewer non-superfluid clusters D4 are observed on fluorocarbon surfaces relative to hydrogen containing polymers. Isotope exchange reactions in four-atom clusters are probably observed between deuterium in D(−1) and protium atoms in the hydrogenated polymer surface.
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