Tunable Resonance Research Articles

Demonstration of graphene-assisted tunable surface plasmonic resonance sensor using machine learning model

Demonstration of graphene-assisted tunable surface plasmonic resonance sensor using machine learning model

Coplanar superconducting resonators with nonlinear kinetic inductance bridge

We present a model and experimental realization of coplanar superconducting resonators terminated by a shunting kinetic inductance bridge made of ultra-thin Al films. The fabrication process that we propose allows us to create very homogeneous films, which makes them suitable for many applications in quantum devices. Due to the specific properties of the films, the resonators exhibit a Duffing oscillator behavior resulting in bifurcations and interactions between different power sources, which was previously observed in similar systems. Moreover, since the nonlinearity of such a system is concentrated at the bridge, while the wave propagates in a linear environment, it is possible to propose a simple model that accurately describes its behavior. We show that, when resonators are operated within a notch-port architecture, our model has a closed-form solution for the transmission coefficient and allows one to accurately extract parameters of the system, including the kinetic inductance of the bridge and its depairing current. Potential applications of such systems include tunable resonators, photon detectors, bifurcation and parametric amplifiers, as well as a measurement device for studying the properties of thin films.

Twist-tunable polaritonic nanoresonators in a van der Waals crystal

Optical nanoresonators are key building blocks in various nanotechnological applications (e.g., spectroscopy) due to their ability to effectively confine light at the nanoscale. Recently, nanoresonators based on phonon polaritons (PhPs)—light coupled to lattice vibrations—in polar crystals (e.g., SiC, or h-BN) have attracted much attention due to their strong field confinement, high quality factors, and their potential to enhance the photonic density of states at mid-infrared (mid-IR) frequencies, where numerous molecular vibrations reside. Here, we introduce a new class of mid-IR nanoresonators that not only exhibit the extraordinary properties previously reported, but also incorporate a new degree of freedom: twist tuning, i.e., the possibility of controlling their spectral response by simply rotating the constituent material. To achieve this result, we place a pristine slab of the van der Waals (vdW) α-MoO3 crystal, which supports in-plane hyperbolic PhPs, on an array of metallic ribbons. This sample design based on electromagnetic engineering, not only allows the definition of α-MoO3 nanoresonators with low losses (quality factors, Q, up to 200), but also enables a broad spectral tuning of the polaritonic resonances (up to 32 cm−1, i.e., up to ~6 times their full width at half maximum, FWHM ~5 cm−1) by a simple in-plane rotation of the same slab (from 0 to 45°). These results open the door to the development of tunable and low-loss IR nanotechnologies, fundamental requirements for their implementation in molecular sensing, emission or photodetection applications.

2D Assembly of Atomically Oriented Gold Nanodisks Leads to Tunable Plasmonic Resonance

2D Assembly of Atomically Oriented Gold Nanodisks Leads to Tunable Plasmonic Resonance

Tunable resonance Raman scattering of quantum dots in a nonlinear excitation regime.

Controllable tuning of electron-phonon coupling strength and excited state dynamics is important for the understanding of resonance Raman scattering in low-dimensional semiconductors. Here, we report a significant and reversible field-induced modulation in absolute resonance Raman intensity of quantum dots using ionic liquid gating. Meanwhile, a potential-dependent nonlinear relationship is present between Raman intensity and excitation power density. By exploring the parameter space within a time domain model, we find that the Raman intensity variation is mainly determined by the homogeneous linewidth. We further propose that the Fermi level positions and exciton species play key roles in the excited state decay rates.

Acoustical Theory of Vowel Modification Strategies in Belting

Various authors have argued that belting is to be produced by “speech-like” sounds, with the first and second supraglottic vocal tract resonances (fR1 and fR2) at frequencies of the vowels determined by the lyrics to be sung. Acoustically, the hallmark of belting has been identified as a dominant second harmonic, possibly enhanced by first resonance tuning (fR1≈2fo). It is not clear how both these concepts – (a) phonating with “speech-like,” unmodified vowels; and (b) producing a belting sound with a dominant second harmonic, typically enhanced by fR1 – can be upheld when singing across a singer’s entire musical pitch range. For instance, anecdotal reports from pedagogues suggest that vowels with a low fR1, such as [i] or [u], might have to be modified considerably (by raising fR1) in order to phonate at higher pitches. These issues were systematically addressed in silico with respect to treble singing, using a linear source-filter voice production model. The dominant harmonic of the radiated spectrum was assessed in 12987 simulations, covering a parameter space of 37 fundamental frequencies (fo) across the musical pitch range from C3 to C6; 27 voice source spectral slope settings from −4 to −30 dB/octave; computed for 13 different IPA vowels. The results suggest that, for most unmodified vowels, the stereotypical belting sound characteristics with a dominant second harmonic can only be produced over a pitch range of about a musical fifth, centered at fo≈0.5fR1. In the [ɔ] and [ɑ] vowels, that range is extended to an octave, supported by a low second resonance. Data aggregation – considering the relative prevalence of vowels in American English – suggests that, historically, belting with fR1≈2fo was derived from speech, and that songs with an extended musical pitch range likely demand considerable vowel modification. We thus argue that – on acoustical grounds – the pedagogical commandment for belting with unmodified, “speech-like” vowels can not always be fulfilled.

High-Q tunable Fano resonances in the curved waveguide resonator with mirrors with spatially variable reflectivity

High-Q Fano resonances are demonstrated, as well as effects similar to electromagnetically induced transparency arising in a curved Fabry-Perot waveguide resonator with variable-reflection mirrors. It is shown that these effects arise as a result of coupling the fundamental mode of the bent waveguide core with whispering gallery cladding modes. An influence of the main geometrical parameters of the resonator on the resonance features in its reflection and transmission spectra is studied. The results obtained can be used in the creation of new functional elements of photonics based on curved waveguides, in particular, highly sensitive portable refractometers for bio- and chemosensory systems, as well as optical sensors of mechanical effects.

Ligand-Mediated Control of the Surface Oxidation States of Copper Nanoparticles Produced by Laser Ablation

We report on studies that demonstrate how the chemical composition of the surface of copper nanoparticles (CuNPs) - in terms of percentage copper(I/II) oxides - can be varied by the presence of N-donor ligands during their formation via laser ablation. Changing the chemical composition thus allows systematic tuning of the surface plasmon resonance (SPR) transition. The trialed ligands include pyridines, tetrazoles, and alkylated tetrazoles. CuNPs formed in the presence of pyridines, and alkylated tetrazoles exhibit a SPR transition only slightly blue shifted with respect to CuNPs formed in the absence of any ligand. On the other hand, the presence of tetrazoles results in CuNPs characterized by a significant blue shift of the order of 50-70 nm. By comparing these data also with the SPR of CuNPs formed in the presence of carboxylic acids and hydrazine, this work demonstrates that the blue shift in the SPR is due to tetrazolate anions providing a reducing environment to the nascent CuNPs, thus preventing the formation of copper(II) oxides. This conclusion is further supported by the fact that both AFM and TEM data indicate only small variations in the size of the nanoparticles, which is not enough to justify a 50-70 nm blue-shift of the SPR transition. High-resolution transmission electron microscopy (HRTEM) and selected area electron diffraction (SAED) studies further confirm the absence of Cu(II)-containing CuNPs when prepared in the presence of tetrazolate anions.

Independently tunable Fano resonance from quasibound state in the continuum in hybrid graphene–dielectric metasurface for magnetic field tunability

We study an independently tunable Fano resonance from quasibound state in the continuum and polarization-independent toroidal dipole resonance in hybrid graphene–dielectric metasurface consisting of a nanoring and a cross-shaped nanobar. The unique structural properties of the proposed metasurface can support directional toroidal dipole mode, where the asymmetric magnetic field enhancement can be dynamically switched on and off while maintaining polarization-independent Fano spectral response. Through reducing or increasing inner radius of nanoring, an additional quasi-BIC dominated by magnetic dipole moment can be excited and independently tuned by altering the polarization direction of the incident wave. In addition, the quasi-BIC can be effectively modulated via adjusting the Fermi energy and layer numbers of the graphene. Our results can be of practical interest for a variety of applications including optical modulator, filter, switches, and light trapping.

Tunable Multiple Fano Resonance Plasmonic Nanosensor with an Oblique Path in a Pentagonal-Ring-Shaped Resonator

Tunable Multiple Fano Resonance Plasmonic Nanosensor with an Oblique Path in a Pentagonal-Ring-Shaped Resonator

Facile Preparation of Monodisperse Silver Nanorods with Tunable Plasmon Resonances in the Near-Infrared Region: Implications for SERS-Based Sensing

The facile synthesis of silver nanorods with uniform size and tunable localized surface plasmon resonances is of great significance for plasmon resonance-related applications, such as surface-enhanced Raman spectroscopy (SERS)-based sensing, biomedical diagnostics, and photothermal therapy. However, improving reproducibility is difficult for nonexpert researchers since general synthesis methods involve multiple steps. Addressing this issue, this work develops a facile, effective synthetic strategy for monodisperse silver nanorods with tunable plasmon resonance in the near-infrared region assisted by in situ monitoring via an optical microfiber in the seed formation stage and surfactant-assisted purification of the final product. The optical microfiber monitoring ensures the formation of monodisperse bipyramid templates, guaranteeing the synthesis of the final product. The surfactant-assisted purification of the final product ensures the monodispersity of the final Ag nanorods. This study provides a flexible and alternative approach for nonexpert researchers and may present an opportunity for solving the reproducibility problem faced by nanomaterial synthesis.

Enhancing the thermo-optic tuning performance of whispering gallery modes in a microcapillary resonator filled with nematic liquid crystal

We investigated both theoretically and experimentally, the thermo-optic tuning of whispering-gallery modes (WGMs) in a microcapillary resonator filled with nematic liquid-crystal (LC). The tuning of WGMs was realized due to the photo-thermal effect of magnetic nanoparticles (MNPs) on the surface of a fiber half-taper connected to a pump laser source, resulting in temperature-induced refractive index (RI) changes of the LC material. Based on perturbation theory, we analyzed the influence the RI and the wall thickness on the sensitivity of the proposed tuning scheme. Furthermore, we experimentally demonstrated that increasing the thickness of the MNPs coating on the fiber taper surface leads to a stronger photo-thermal effect and to a larger RI change of the LC material within the microcapillary core. Thermo-optic tuning of WGM resonances with a sensitivity of 256.63 ± 5.67 pm/mW to the laser pump power and tuning range of 10.43 nm has been achieved. The developed thermo-optic tuning scheme has many potential applications as tunable devices, optical filters and sensors.

Tunable Fabry–Pérot Resonator with Dynamic Structural Color: A Visual and Ultrasensitive Hydrogen Sensor

Hydrogen detection is crucial for the forthcoming hydrogen economy. Here, we present a visual, ultrasensitive, optical hydrogen sensor based on a tunable Fabry-Pérot (FP) resonator, which can fully release the volume expansion of palladium during hydrogenation and transfer this volume expansion into an optical signal. The FP resonator consists of a suspended polymethylmethacrylate/palladium (PMMA/Pd) bilayer on a gold (Au) square-hole array. The bottom of the gold square hole and hydrogen-sensitive PMMA/Pd bilayer form a dynamically tunable FP resonator. When hydrogen gas (H2) is loaded, the hydrogen-induced lateral expanding stress concavely deforms the suspended bilayer downward to the substrate, narrowing the metal-air-metal gap at the center of the hole, and finally leading to a spectral blue shift. Our experimental results show a giant spectral shift of 279 nm with a reflectance variation of 57% on exposure to 0.6% H2 mixed with air. Such an ultrahigh optical response results in a significant color change, enabling visual hydrogen detection. In addition, the sensor has a H2 detection limit down to 0.1% and good recyclability. These advantages indicate that the sensor has excellent potential for hydrogen sensing applications.

Tunable metasurfaces for seismic Love wave manipulation: A theoretical study

Seismic Love waves are horizontally polarized surface waves propagating within an overlying layer, which have been shown to pose potential hazards to infrastructures. In this study, we propose an original analytical formulation to investigate the interaction between seismic Love waves and a metasurface that is composed of a cluster of tunable anti-plane resonators. The formulation utilizes the Green's function of a layered half-space subjected to a surface SH source, to describe both the source-induced incident field and the resonator-excited scattered field. Based on the multiple scattering theory, we obtain the total wavefield of the layered half-space equipped with surface resonators by coupling the incident field and the scattered field. Besides, a closed-form dispersion relation governing the hybrid Love waves is derived by utilizing the effective medium approximation. We demonstrate the capabilities of our analytical formulation by modelling Love waves propagating across a pair and a cluster of resonators, evidenced by some complex phenomena (e.g., surface-to-bulk wave conversion and higher-order hybridized surface modes). The hybridization features of different Love modes and metasurface resonances are clearly revealed. We anticipate the proposed tunable metasurface and the formulation can shed light on versatile control of Love wave propagation.

Enzyme-Triggered Transforming of Assembly Peptide-Modified Magnetic Resonance-Tuned Probe for Highly Sensitive Imaging of Bacterial Infection In Vivo.

Confirming bacterial infection at an early stage and distinguishing between sterile inflammation and bacterial infection is still highly needed for efficient treatment. Here, in situhighly sensitive magnetic resonance imaging (MRI) bacterial infection in vivobased on a peptide-modified magnetic resonance tuning (MRET) probe (MPD-1) that responds to matrix metallopeptidase 2 (MMP-2) highly expressed in bacteria-infected microenvironments is achieved. MPD-1 is an assembly of magnetic nanoparticle (MNP) bearing with gadolinium ion (Gd3+ ) modified MMP-2-cleavable self-assembled peptide (P1 ) and bacteria-targeting peptide (P), and it shows T2 -weighted signal due to the assemble of MNP and MRET ON phenomenon between MNP assembly and Gd3+ . Once MPD-1 accumulates at the bacterially infected site, P1 included in MPD-1 iscleaved explicitly by MMP-2, which triggers the T2 contrast agent of MPD-1 to disassemble into the monomer of MNP, leading the recovery of T1 -weighted signal. Simultaneously, Gd3+ detaches from MNP, further enhancing the T1 -weighted signal due to MRET OFF. The sensitive MRI of Staphylococcus aureus (low to 104 CFU) at the myositis site and accurate differentiation between sterile inflammation and bacterial infection based on the proposed MPD-1 probe suggests that this novel probe would be a promising candidate for efficiently detecting bacterial infection in vivo.

Excitonic Beam Steering in an Active van der Waals Metasurface.

Two-dimensional transition metal dichalcogenides (2D TMDCs) are promising candidates for ultrathin active nanophotonic elements due to the strong tunable excitonic resonances that dominate their optical response. Here, we demonstrate dynamic beam steering by an active van der Waals metasurface that leverages large complex refractive index tunability near excitonic resonances in monolayer molybdenum diselenide (MoSe2). Through varying the radiative and nonradiative rates of the excitons, we can dynamically control both the reflection amplitude and phase profiles, resulting in an excitonic phased array metasurface. Our experiments show reflected light steering to angles between -30° and 30° at different resonant wavelengths corresponding to the A exciton and B exciton. This active van der Waals metasurface relies solely on the excitonic resonances of the monolayer MoSe2 material rather than geometric resonances of patterned nanostructures, suggesting the potential to harness the tunability of excitonic resonances for wavefront shaping in emerging photonic applications.

Hot Spot Engineering in Hierarchical Plasmonic Nanostructures

The controllable nanogap structures offer an effective way to obtain strong and tunable localized surface plasmon resonance (LSPR). A novel hierarchical plasmonic nanostructure (HPN) is created by incorporating a rotating coordinate system into colloidal lithography. In this nanostructure, the hot spot density is increased drastically by the long-range ordered morphology with discrete metal islands filled in the structural units. Based on the Volmer-Weber growth theory, the precise HPN growth model is established, which guides the hot spot engineering for improved LSPR tunability and strong field enhancement. The hot spot engineering strategy is examined by the application of HPNs as the surface-enhanced Raman spectroscopy (SERS) substrate. It is universally suitable for various SERS characterization excited at different wavelengths. Based on the HPN and hot spot engineering strategy, single-molecule level detection and long-range mapping can be realized simultaneously. In that sense, it offers a great platform and guides the future design for various LSPR applications like surface-enhanced spectra, biosensing, and photocatalysis.

Asymmetric Cross Metasurfaces with Multiple Resonances Governed by Bound States in the Continuum.

The bound state in the continuum (BIC) has paved a new way to achieve excellent localization of the resonant mode coexisting with a continuous spectrum in the metasurface. Here, we propose an all-dielectric metasurface consisting of periodic pairs of asymmetric crosses that supports multiple Fano resonances. Due to the sufficient degrees of freedom in the unit cell, we displaced the vertical bars horizontally to introduce in-plane perturbation, doubling the unit cell structure. Dimerization directly resulted in the folding of the Brillouin zone in k space and transformed the BIC modes into quasi-BIC resonances. Then, simultaneous in-plane symmetry breaking was introduced in both the x and y directions to excite two more resonances. The physical mechanisms of these BIC modes were investigated by multipole decomposition of the scattering cross section and electromagnetic near-field analysis, confirming that they are governed by toroidal dipole (TD) modes and magnetic dipole (MD) modes. We also investigated the flexible tunability and evaluated the sensing performance of our proposed metasurface. Our work is promising for different applications requiring stable and tunable resonances, such as optical switching and biomolecule sensing.

Design and Performance prediction of Liquid based Tunable Cylindrical Dielectric Resonator Antenna

In this paper, we report a liquid-based tunable Cylindrical Dielectric Resonator Antenna (CDRA), whose resonance is varied by loading the cavity installed in the CDRA with different volumes of liquid. The tunability of the CDRA is investigated by loading the cavity with two different types of liquids, one with lower permittivity (i.e.) oil and the other with higher permittivity (i.e.) water. CDRA loaded with oil is found to be tunable over a small frequency range of 32MHz (5.76GHz to 5.728GHz), whereas the change in water volume in the cavity provides a wide tuning range of 452MHz (5.76GHz to 5.308GHz). Further, the antenna gain is found to be almost constant, around 5.1 dB, for oil-based CDRA. In a water-filled cavity, the gain is observed to reduce by 1dB as the volume is increased from 0 to 100%.

Autonomous Resonant Frequency Tuner for a 6.78MHz Inductive Coupling Wireless Power Transfer System to Stably Maximize Repeater Current

Recently, the resonant inductive coupling wireless power transfer (RIC-WPT) technique is being widely used to charge small IoT devices dispersed in a wide area, e. g., an office desk and warehouse rack. In this application, the repeater is utilized to expand the chargeable area without an additional AC power source. The repeater comprises a LC resonator commonly with a high-quality factor to induce large current in the repeater coil. However, this causes the problem that the repeater performance is highly susceptible to the variation in its resonant frequency due to the manufacturing tolerance of coil inductance and resonant capacitance as well as the variation of the magnetic coupling between the transmitter and repeater coils. To solve this problem, a previous study has proposed a concept of the autonomous resonant frequency tuning circuit to stably maximize repeater coil current, although this study implemented a part of this control system as a practical circuit. This paper aims to develop a complete autonomous resonant frequency tuning circuit that implements the aforementioned concept. The proposed circuit adjusts the resonant frequencies of the transmitter and repeater by utilizing the Automatic Tuning Assist Circuits. These frequencies are optimized using the infrared wireless signal communication from the transmitter to the repeater. Along with the operating principle of the proposed circuit, this study presents detailed circuit design as well as the experimental results, which verified the stable autonomous maximization of the repeater coil current against the variation in the resonant frequency of the repeater resonator.