TRIP-aided Martensitic Steel Research Articles

Effect of Hydrogen on Fatigue Life and Fracture Morphologies of TRIP-Aided Martensitic Steels with Added Nitrogen

The effects of hydrogen on the tensile properties, fatigue life, and tensile and fatigue fracture morphologies of nitrogen-added ultrahigh-strength transformation-induced plasticity (TRIP)-aided martensitic (TM) steels were investigated. The total elongation and number of cycles to failure (Nf) of the hydrogen-charged TM steels decreased with the addition of nitrogen; in particular, adding 100 ppm of nitrogen decreased the total elongation and Nf of the TM steels. The quasi-cleavage cracking around the AlN occurred near the sample surface, which is the crack propagation region, although dimples appeared at the center of the fracture surface in the tensile samples. The initial fatigue crack initiated at the AlN precipitate or matrix/AlN interface, located at the notch root. During crack propagation, new cracks were initiated at the AlN precipitates or matrix/AlN interfaces, while quasi-cleavage crack regions were observed around the AlN precipitates. The decrease in the total elongation and Nf of the hydrogen-charged TM steel with 100 ppm of added nitrogen might be attributable to the crack initiation around the AlN precipitates formed by a large amount of hydrogen trapped at the AlN precipitates and matrix/AlN interfaces, and to the dense distribution of AlN, which promoted crack linkage.

Unstable stress-triaxiality development and contrasting weakening in two types of high-strength transformation-induced plasticity(TRIP) steels: Insights from a new compact tensile testing method

The impact of high stress triaxiality on work hardening in transformation-induced plasticity (TRIP) steel has been widely acknowledged, particularly through measurements of the austenite fraction. Understanding this TRIP behavior is crucial for predicting material fracture in press-forming processes. However, the actual flow stresses under high-stress-triaxiality conditions remain largely undetermined. To address this gap, we developed a new tensile testing method using tiny notched round bars to investigate stress-triaxiality-induced work hardening in TRIP steels. The specimens were analyzed using two-dimensional micrometry to allow finite element analyses to identify the flow stress. Additionally, we conducted in situ tensile tests in which their crystal lattice stresses were monitored using synchrotron X-ray diffraction (XRD) to realize mechanism analyses of the unexpected work-hardening behavior identified by the developed tensile testing method. Our combined approach revealed a mutual, unstable increase in the flow stress and stress triaxiality in the TRIP-aided bainitic ferrite steel, which reduced the hardening exponent coefficients and thus induced a higher stress triaxiality. In contrast, the TRIP-aided martensitic steel exhibited a weakening behavior, characterized by a significant decrease in the hardening exponent coefficients in the case of the sharpest notch. XRD analyses showed that microstructural heterogeneity led to an extraordinarily high hydrostatic stress in the austenite phase, accounting for these contrasting behaviors. This finding challenges the established consensus on TRIP steels and suggests the need for a revised framework for their application in press-forming, taking into account stress-triaxiality conditions.

Effects of Partial Replacement of Si by Al on Impact Toughness of 0.2%C-Si-Mn-Cr-B TRIP-Aided Martensitic Steel

The effects of partial replacement of Si by Al on the microstructure, tensile properties, and Charpy impact toughness were investigated using 0.2%C-Si/Al-Mn-Cr-B TRIP-aided martensitic steels to promote the application of galvanized third-generation ultrahigh- and high-strength steels. The impact toughness was related to the microstructural and mechanical properties. The partial replacement decreased the volume fraction of retained austenite and increased the mechanical stability, accompanied by softening and an increase in the volume fraction of the primary martensite. Resultantly, the partial replacement decreased strength and ductility. The impact absorbed energy (value) at 25 °C was slightly increased by the partial replacement. The increased impact absorbed energy was mainly caused by high crack/void propagation energy due to the softened primary martensite and a small contribution of the stabilized retained austenite. The 50% shear fracture ductile-to-brittle transition temperature was marginally raised by the partial replacement. The raised transition temperature was mainly associated with an increase in a unit crack path of quasi-cleavage/cleavage fracture.

Cold Formabilities of Martensite-Type Medium Mn Steel

Cold stretch-formability and stretch-flangeability of 0.2%C-1.5%Si-5.0%Mn (in mass%) martensite-type medium Mn steel were investigated for automotive applications. High stretch-formability and stretch-flangeability were obtained in the steel subjected to an isothermal transformation process at temperatures between Ms and Mf − 100 °C. Both formabilities of the steel decreased compared with those of 0.2%C-1.5%Si-1.5Mn and -3Mn steels (equivalent to TRIP-aided martensitic steels), despite a larger or the same uniform and total elongations, especially in the stretch-flangeability. The decreases were mainly caused by the presence of a large amount of martensite/austenite phase, although a large amount of metastable retained austenite made a positive contribution to the formabilities. High Mn content contributed to increasing the stretch-formability.

Effect of Hydrogen on Spot Welded Tensile Properties in Automotive Ultrahigh Strength TRIP-aided Martensitic Steel Sheet

Effect of Hydrogen on Spot Welded Tensile Properties in Automotive Ultrahigh Strength TRIP-aided Martensitic Steel Sheet

Effects of residual stress and plastic strain on hydrogen embrittlement of a stretch-formed TRIP-aided martensitic steel sheet

Hydrogen assisted cracking on hemispherically-stretch-formed specimens of transformation induced plasticity-aided martensitic steel was investigated. Hydrogen charging induced cracking around the foot of the impression formed on the steel sheet, and the cracks propagated along the radial direction toward the hillside and the plains. Distributions of stress, plastic strain and volume fraction of retained austenite were analyzed employing the energy-dispersive X-ray diffraction method utilizing the synchrotron X-ray radiation at SPring-8. It was notable that the crack initiation took place in the region where the measured tensile stress was the highest. Influences of plastic strain and resulted martensitic transformation were also suggested.

Effects of Alloying Elements Addition on Delayed Fracture Properties of Ultra High-Strength TRIP-Aided Martensitic Steels

To develop ultra high-strength cold stamping steels for automobile frame parts, the effects of alloying elements on hydrogen embrittlement properties of ultra high-strength low alloy transformation induced plasticity (TRIP)-aided steels with a martensite matrix (TM steels) were investigated using the four-point bending test and conventional strain rate tensile test (CSRT). Hydrogen embrittlement properties of the TM steels were improved by the alloying addition. Particularly, 1.0 mass% chromium added TM steel indicated excellent hydrogen embrittlement resistance. This effect was attributed to (1) the decrease in the diffusible hydrogen concentration at the uniform and fine prior austenite grain and packet, block, and lath boundaries; (2) the suppression of hydrogen trapping at martensite matrix/cementite interfaces owing to the suppression of precipitation of cementite at the coarse martensite lath matrix; and (3) the suppression of the hydrogen diffusion to the crack initiation sites owing to the high stability of retained austenite because of the existence of retained austenite in a large amount of the martensite–austenite constituent (M–A) phase in the TM steels containing 1.0 mass% chromium.

Hydrogen embrittlement properties of nitrogen added ultra-high-strength TRIP-aided martensitic steels evaluated by using conventional strain rate technique

Hydrogen embrittlement properties of nitrogen-added TRIP-aided martensitic steels for improving the fuel efficiency of vehicles due to the weight reduction and the impact safety were evaluated by using conventional strain rate tensile tests. Decrease in the total elongation due to hydrogen of a 100-ppm-nitrogen-added TRIP-aided martensitic steel was small in comparison with that of the TRIP-aided martensitic steel without nitrogen. This was attributed to refinement of martensite lath matrix. On the other hand, hydrogen charging decreased the total elongation of a 200-ppm-nitrogen-added TRIP-aided martensitic steel, and decrease in the total elongation of the 200-ppm-nitrogen-added TRIP-aided martensitic steel was more than that of the 100-ppm-nitrogen-added TRIP-aided martensitic steel. This might be caused by the promotion of crack initiation at AlN and AlN/matrix interfaces induced by trapped hydrogen.

Effects of fine particle peening on fatigue strength of a TRIP-aided martensitic steel

The effects of fine particle peening on the fatigue properties of a transformation-induced plasticity-aided martensitic steel with a chemical composition of 0.2% C, 1.5% Si, 1.5% Mn, 1.0% Cr, and 0.05% Nb (mass%) were investigated for applications in precision gears. When this steel was subjected to fine particle peening after heat treatment, higher fatigue limits and lower notch sensitivity were achieved compared with those of SNCM420 martensitic steel. The increased fatigue limits are principally associated with higher hardness and compressive residual stress on and just below the surface, as well as low surface roughness. Fine particle peening also increased the threshold stress intensity factor range in stage I, and decreased the crack propagation rate in stage II in this steel. The crack propagation behavior was mainly suppressed by (1) high hardness and high compressive residual stress, and (2) the strain-induced martensite transformation of retained austenite and high internal stress resulting from a difference in flow stress between the soft martensite matrix and the finely dispersed hard MA-like phase that developed during fatigue deformation.

Effects of Warm Working on Microstructural and Shear Deformation Properties of TRIP-Aided Martenitic Steel

The effects of warm working on microstructural, retained austenite characteristics and shear deformation properties of 0.2C–1.5Si–1.5Mn–1.0Cr–0.2Mo TRIP-aided martensitic (TM) steel for applications to automotive frame and forging parts were investigated. When warm working at 550 °C and post cooling at 1 °C/s was conducted to the TM steel, volume fractions of retained austenite and martensite-austenite constituent phase increased and mixture matrix of ultra fine granular bainitic ferrite and fine bainitic ferrite lath was obtained, whereas microstructure of TM steel warm worked at 750 °C exhibited granular bainitic ferrite matrix. These were caused by the dynamic recrystallization and the promotion of bainitic transformation of austenite due to the worm forging at 550 °C with the post cooling rate of 1 °C/s. Maximum shear stress decreased and total shear displacement increased with decreasing working temperature in TM steel. These were caused by the effective strain induced transformation of a large amount of retained austenite and the refined matrix structure.

Effects of Cooling Rate on Impact Toughness of an Ultrahigh-Strength TRIP-Aided Martensitic Steel

The effects of variations in the rate of post-austenitization cooling of a 0.2%C-1.5%Si-1.5%Mn-1.0%Cr-0.2%Mo-1.5%Ni-0.05%Nb (mass%) transformation-induced plasticity (TRIP)-aided steel with a lath martensite structure matrix on the Charpy impact toughness were investigated, with the aim of improving the material properties for automotive body applications. When cooled at 1.2°C/s after austenitization, the TRIP-aided steel showed a higher upper-shelf Charpy impact absorbed value (90 J/cm2) and a lower ductile-brittle fracture appearance transition temperature (−126°C), compared with the values determined (82 J/cm2, −98°C) for steel cooled at 53.5°C/s. The lower cooling rate yielded a higher volume fraction and carbon concentration of metastable retained austenite, finer martensite-austenite constituents, and a lower carbide fraction in the wide lath martensite structure in the TRIP-aided steel. These improved microstructural characteristics resulted in superior impact toughness.

Effects of Microalloying on the Impact Toughness of Ultrahigh-Strength TRIP-Aided Martensitic Steels

The effects of the addition of Cr, Mo, and/or Ni on the Charpy impact toughness of a 0.2 pct C-1.5 pct Si-1.5 pct Mn-0.05 pct Nb transformation-induced plasticity (TRIP)-aided steel with a lath-martensite structure matrix (i.e., a TRIP-aided martensitic steel or TM steel) were investigated with the aim of using the steel in automotive applications. In addition, the relationship between the toughness of the various alloyed steels and their metallurgical characteristics was determined. When Cr, Cr-Mo, or Cr-Mo-Ni was added to the base steel, the TM steel exhibited a high upper-shelf Charpy impact absorbed value that ranged from 100 to 120 J/cm2 and a low ductile–brittle fracture appearance transition temperature that ranged from 123 K to 143 K (−150 °C to −130 °C), while also exhibiting a tensile strength of about 1.5 GPa. This impact toughness of the alloyed steels was far superior to that of conventional martensitic steel and was caused by the presence of (i) a softened wide lath-martensite matrix, which contained only a small amount of carbide and hence had a lower carbon concentration, (ii) a large amount of finely dispersed martensite-retained austenite complex phase, and (iii) a metastable retained austenite phase of 2 to 4 vol pct in the complex phase, which led to plastic relaxation via strain-induced transformation and played an important role in the suppression of the initiation and propagation of voids and/or cleavage cracks.

Microstructure and Retained Austenite Characteristics of Ultra High-strength TRIP-aided Martensitic Steels

A new type of 0.2%C–1.5%Si–1.5%Mn ultra high-strength low alloy TRIP-aided steel consisting of lath martensite structure matrix and metastable retained austenite films, “TRIP-aided martensitic steel; TM steel”, was developed by means of quenching and partitioning process. In addition, effects of partitioning temperature and time on the microstructure and retained austenite characteristics were investigated. The matrix structure was composed of two kinds of lath martensite structures, or wide and narrow lath martensite structures. Most of the retained austenite of about 3 vol% was located along the narrow martensite lath boundary. On the other hand, a small amount of fine and needle-like carbides precipitated only in wider lath martensite structure. Partitioning at temperatures lower than 250°C for 1000 s after quenching in oil or ice brine considerably increased carbon concentration of the retained austenite phase to about 1.0 mass%, maintaining volume fractions of retained austenite and carbide. Also, the carbon-enrichment mechanism in the retained austenite was proposed through TEM observation, as well as the carbide precipitation and coarsening mechanisms.

Effects of Hot-Forging Process on Combination of Strength and Toughness in Ultra High-Strength TRIP-Aided Martensitic Steels

Recently developed ultra high-strength low alloy transformation-induced plasticity (TRIP)-aided steel with martensitic lath structure matrix or "TRIP-aided Martensitic steel; TM steel" possesses a high impact toughness. In this study, to apply the TM steel to some hot-forging parts, the effects of hot-forging on microstructure, retained austenite characteristics, tensile properties and toughness in the TM steels with chemical composition of 0.3-0.4%C, 1.5%Si, 1.5%Mn, 0.002%B, 0.02Ti, 0.05Nb (mass%) were investigated. The hot forging brought on an excellent combinations of tensile strength of 1500-2000 MPa or 0.2% offset proof stress of 1200-1560 MPa and Charpy impact absorbed value of 35-80 J/cm2 when partitioned at 250-350°C after quenching in oil. The combinations exceeded so much those of the conventional quench and tempering structural steels. From examinations of microstructure and retained austenite characteristics, it was found that the excellent combinations are mainly caused by (i) refined and uniform martensitic lath structure matrix with a small amount of carbide, (ii) increasing narrow martensite with high dislocation density and (iii) the increased stability of retained austenite, resulting from the FQP process.