This study aimed to identify the biomechanical features of backstroke to breaststroke transition techniques (open, somersault, bucket, and crossover) in age-group swimmers. Eighteen preadolescent swimmers (12.2 ± 0.4 years old and 3–4 Tanner stages) underwent 4 weeks of systematic contextual interference training, comprising 16 sessions (40 min·session−1). Soon after, experimental testing was conducted where swimmers randomly performed 12 × 15 m maximal turns (composed of 7.5 m turn-in and 7.5 m turn-out of the wall segments), three in each transition technique. Kinematical, kinetic, and hydrodynamic variables were assessed with a dual-media motion capture system (12 land and 11 underwater cameras), triaxial underwater force plates, and inverse dynamics. Variables were grouped in turn-in (approach and rotation) and turn-out (wall contact, gliding, and pull-out) phases, with factor analysis used to select the variables entering on multiple regressions. For the turn-in phase, 86, 77, 89, and 87% of the variance for open, somersault, bucket, and crossover turning techniques, respectively, was accounted by the 7.5 and 2.5 m times, mean stroke length, and rotation time. For the turn-out phase, first gliding distance and time, second gliding depth, turn-out time, and dominating peak_Z push-off force accounted for 93% in open turn, while wall contact time, first gliding distance, breakout distance and time, turn-out time, dominating peak_Y push-off force, and second gliding drag coefficient accounted for 92% in a somersault turn. The foot plant index, push-off velocity, second gliding distance, and turn-out time accounted for 92% in bucket turn while breakout and turn-out time, non-dominating peak_Y and peak_Z push-off force, first and second gliding drag force and second gliding drag coefficient accounted for 90% in crossover turn, respectively. The findings in this study were novel and provided relevant biomechanical contribution, focusing on the key kinematic–temporal determinant during turn-in, rotation, and push-off efficacy, and the kinetic and hydrodynamic during turn-out, which would lead to improved backstroke to breaststroke transition techniques in 11–13 years-old age-group swimmers.