Textile Industry Wastewater Treatment Research Articles

Industrial activated sludge model identification using hyperparameter-tuned metaheuristics

This study focuses on the parameter estimation of an industrial activated sludge model using hyperparameter-tuned metaheuristic techniques. The data used in this study were collected on-site from a textile industry wastewater treatment plant. A Modified Activated Sludge Model (M-ASM) was the 'first-principle model’ selected and implemented with suitable assumptions. Advanced metaheuristic techniques, as Adaptive Tunicate Swarm Optimization (ATSO), Whale Optimization Algorithm (WOA), Rao-3 Optimization (Rao-3) and Driving Training Based Optimization (DTBO) were implemented. The hyperparameter tuning was performed with Bayesian Optimization (BO). Optimized metaheuristic algorithms were implemented for model-parameter identification. The Bayesian optimized Rao-3(BO-Rao-3) algorithm provided the best validation results, with a Mean Absolute Percentage Error (MAPE) value of 7.0141 and Normalized Root Mean Square Error (NRMSE) value of 0.2629. It also had the least execution time. BO-Rao-3 is 0.93% to 4.7% better than the other implemented hyperparameter-tuned metaheuristic techniques.

Treatment of textile industry effluents with up‐flow anaerobic sulfidogenic reactor

AbstractBACKGROUNDDyes present in textile wastewater can pose various environmental problems, including toxicity, carcinogenicity and mutagenicity, when released into receiving environments. Sulfidogenic bacteria play a crucial role in wastewater treatment by reducing sulfate and producing sulfide through the utilization of organic compounds in water. The resulting sulfide often transfers its electrons to another electron acceptor. This study focused on the treatment of real textile wastewater using an up‐flow sulfidogenic column bioreactor.RESULTSThe reactor was acclimated to sulfate‐reducing conditions when influent chemical oxygen demand and sulfate concentrations were 1742 and 2000 mg L−1, respectively. Subsequently, a gradual transition was made from sulfate‐reducing conditions to dye‐reducing conditions. Throughout the study, the hydraulic retention time was maintained at 1 day.CONCLUSIONThe influent dye concentration was 2722 Pt‐Co, and an impressive dye removal efficiency of approximately 90 ± 2% was achieved. This corresponds to a removal rate of 2450 Pt‐Co L−1 day−1. Although the sulfide concentration in the reactor decreased in the last period, investigating the extent to which this sulfide participates in the dye removal may expand the use of sulfidogenic reactors in the treatment of real textile industry wastewater. © 2024 The Author(s). Journal of Chemical Technology and Biotechnology published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry (SCI).

Spectroscopic monitoring of polyurethane-based nanocomposite as a potential catalyst for the reduction of dyes

In this study, AgNPs-loaded polyurethane-sodium alginate (PU-S/Alg) composite polymers were prepared by precipitation polymerization and in-situ reduction method. Their catalytic potential was evaluated for the reduction of methyl orange (MO), brilliant blue (BB), Rhodamine B (RhB), 4-nitroaniline (4-NA), and 4-nitrophenol (4-NP). Successful preparation of samples was confirmed by UV–Visible spectrophotometry (UV–Visible), Fourier transform infrared (FTIR), and Scanning electron microscopy (SEM) analysis. During the catalytic study, the value of kapp for the reduction of MO in the presence of NaBH4 and catalyst was found 0.488 min−1 while, in the presence of NaBH4 and catalyst alone, were found as 0.9 × 10-4 and 0.8 × 10-5 min−1, respectively which indicates the role of catalyst in making the reaction speedy. The value of kapp for the reduction of BB, RhB, 4-NA, and 4-NP was found as 0.764, 0.475, 0.212 and 0.757 min−1, respectively. Simultaneous reduction of dyes induced a decreased reaction completion time under the same reaction conditions. A slight increase in the value of kapp for the catalytic reduction of MO was also observed when reactions were performed in the presence of ionic media of different salts such as NaCl, KCl, CaCl2, and MnCl2. The rate of reduction of MO was increased with the increase in ionic strength of the medium. However, the presence of SDS (surfactant) in the reaction mixture induced the decreased activity of the catalyst and increased reaction completion time. The same value of kapp for the reduction of MO was observed in the case of freshly prepared and several days old nanocomposite catalyst. These results illustrate the stability and maintained catalytic potential of metal NPs for a prolonged time. Our reported catalyst also showed good potential for the treatment of dyes-polluted textile industry wastewater.

Aluminum Waste as Electrode for Home Textile Industry Wastewater Treatment using Batch Electrocoagulation Process: Studies on Operating Parameters

The manufacture of the Sasirangan home textile industry involves coloring and dyeing processes using synthetic dyes in large quantities. These contaminants of dyes and organic materials would cause high color and chemical oxygen demand (COD) contaminants values. This study aims to characterize the wastewater of batik-modified Sasirangan and determine the effect of current density and length of operating time on color removal and reduction of COD in Sasirangan home textile industry wastewater through the batch electrocoagulation process. The method used in this research is an electric current flowing in the same direction to the Sasirangan home textile industry wastewater in a reactor with dimensions of 310 180 240 mm3. The electrode used is aluminum alloy type 1100. The aluminum/aluminum (Al/Al) electrode is used in this electrocoagulation (EC) process, then connected to a direct current (DC) power supply. The experiment was carried out at room temperature using an electrode distance of 2 cm with variations in the time of the electrocoagulation process for 15–120 minutes. The experiment was repeated for variations in pH (4–9) with a current density of 3.5–5.5 mA/cm2. Furthermore, an analysis of the color removal and the decrease in the concentration of COD was carried out. The results showed that the contaminant content in Sasirangan home textile industry wastewater decreased significantly, whereas the optimal conditions for the EC reaction were determined using color and COD removal efficiency parameters. The decrease in color and COD concentrations occurred at a current density of 5.5 mA/cm2 with a pH of 4 for 120 minutes, around 1110 PtCo and 90.4 mg/L of COD, respectively

Multivariate optimization of organic matter and color removal from textile dyeing industry wastewater by ultraviolet-activated oxidants

This study investigated the efficiency of ultraviolet (UV) activation of the oxidants that are used in advanced oxidation processes in textile dyeing industry wastewater treatment with high concentrations of refractory organic matter and strong color. The effect of peroxymonosulfate (PMS), peroxydisulfate (PS), hydrogen peroxide (HP), percarbonate (PC), and chlorine as oxidants in UV-based processes was first evaluated. The two processes with the greatest removal efficiency were determined as UV/PS and UV/PMS. Then the operating parameters for UV/PS and UV/PMS were optimized by the Box-Behnken Design (BBD). Process parameters for both processes were oxidant dosage, initial pH, and reaction time whereas system responses were chemical oxygen demand (COD), UV254, and color removal efficiency. Under optimum conditions in the UV/PS process (pH 5.54, PS dosage 24.4 mM, and reaction time 117 min), COD, UV254, and color removal efficiency were 83.21 %, 92.14 %, and 93.87 %, respectively. Under optimum conditions in the UV/PMS process (pH 5.83, PMS dosage 23.1 mM, and reaction time 120 min), COD, UV254, and color removal efficiency were 66.89 %, 78.45 %, and 96.89 %, respectively. The R2 of all the models that applied for the system responses of both processes was nearly one and the adj R2 values were very near to the R2 values. These findings showed that the BBD is efficient, suitable, and significant in modeling the removal of pollutants in textile dyeing industry wastewater by UV/PS and UV/PMS processes. Electrical Energy per Order (EE/O) calculations for UV/PS and UV/PMS processes were 101 and 167 kWh/m3 for optimum conditions, respectively. The results showed that both UV/PS and UV/PMS processes are effective; however, the UV/PS process is more economical and effective concerning pollutant removal efficiency and EE/O calculations.

Expression of Concern: Efficacy of Lemna minor and Typha latifolia for the treatment of textile industry wastewater in a constructed wetland under citric acid amendment: A lab scale study. (Chemosphere, Volume 283, November 2021, 131107)

Expression of Concern: Efficacy of Lemna minor and Typha latifolia for the treatment of textile industry wastewater in a constructed wetland under citric acid amendment: A lab scale study. (Chemosphere, Volume 283, November 2021, 131107)

An Integrated (Electrocoagulation and Adsorption) Approach for the Treatment of Textile Industrial Wastewater: RSM and ANN Based Optimization

An Integrated (Electrocoagulation and Adsorption) Approach for the Treatment of Textile Industrial Wastewater: RSM and ANN Based Optimization

Solar Thermal Technology Aided Membrane Distillation Process for Wastewater Treatment in Textile Industry—A Technoeconomic Feasibility Assessment

Because textile industries are intensely water-consuming and generate a huge quantity of wastewater, the present study examines the scope of using solar thermal technology to treat wastewater from textile industries. A hybrid technology, comprising a compound parabolic concentrator-based solar thermal system in conjunction with a Membrane Distillation (MD) system, is experimented with for wastewater treatment in textile industries. The MD system requires a water temperature of around 90 °C for efficient functioning. The advanced MD technology using waste heat combined with solar heat to meet the system’s thermal load is technologically evaluated for an experimental textile industry in India. Moreover, the present study critically analyses the techno economics of the proposed hybrid technology. A detailed financial analysis has revealed that, besides technological superiority, the recommended technology is also financially rewarding for wastewater treatment in the textile industry. To cope with the delayed payback period, financial incentives are recommended so that the system becomes a lucrative technological option.

Performance evaluation of a lab-scale subsurface flow-constructed wetland system for textile industry wastewater treatment.

This study compares biochar (BCW) systems' pollutant removal effectiveness to conventional subsurface flow (CCW) in constructed wetland systems to treat textile wastewater. The two systems were identical in construction, but the biochar was 0.1 m thick over gravel and sand (maximum flow rate of 0.021 m3 h-1) as the primary medium over CCW (flow rate of 0.02 m3 h-1). The results revealed that the BCW approach was more efficient than the CCW system (pebble over sand and gravels) in removing and lowering heavy metals below thresh hold limits such as Cr, Cd, Cu, Pb, Ni, and Zn. The alkaline nature of textile water achieves neutrality in both CCW and BCW. However, BCW is more efficient due to a larger active surface area and the ability to filter out more metal and organic ions. TDS reduction efficiency in BCW was 53.07%, compared to 40.04% in CCW. Heavy metal removal was 100% in BCW at 3 to 12 h, whereas it takes 6 to 24 h in CCW (82% for Cr to 93% for Cu). The quick removal of Na from textile wastewater by BCW was reversed and achieved equilibrium in 24 h in contrast to the CCW system (> 24 h). The findings obtained at the lab scale level demonstrated that the BCW system was more effective in reducing TDS, neutralizing the alkalinity of textile wastewater, and removing heavy metals. This study strongly supports the potential application of biochar-constructed wetlands for textile wastewater treatment.

Constructed "sandwich" structure to obtain recyclability and high rejection rate high-flux CA@HMSN@h-BN/PDA membrane for efficient treatment of dye wastewater

It is necessary to develop a nanofiltration membrane that can remove dye molecules efficiently and is not easily polluted for the treatment of textile industry wastewater. A novel high-flux CA@HMSN@h-BN/PDA membrane with a "sandwich" structure was obtained by assembling the support layer of the Hollow mesoporous silica nanoparticles (HMSN), and the isolation layer of the h-BN/PDA on the Cellulose acetate (CA) membrane. HMSN was synthesized using ZIF-8 as a self-sacrificial template to provide improved permeability. h-BN/PDA obtained by modifying hexagonal boron nitride (h-BN) with polydopamine (PDA) brought higher hydrophilicity, rejection rate, and stability to the membrane. The study solved the problem that the membrane separation process requires sacrificing flux and recyclability for high rejection rates. CA@HMSN@h-BN/PDA membrane has a super-hydrophilic property (water contact angle of 22.5°) and high pure water flux (4419.4 L·m−2·h−1·bar−1). Meanwhile, the CA@HMSN@h-BN/PDA membrane achieves a high rejection rate (over 99.5%) due to the special "sandwich" structure. Through cycling experiments, CA@HMSN@h-BN/PDA membranes exhibit recyclability. More importantly, CA@HMSN@h-BN/PDA membranes maintain stable performance in complex environments, such as extremely acidic/alkaline or inorganic salt interference environments. Thus the CA@HMSN@h-BN/PDA membrane has the potential for future wastewater treatment.

Sequential Treatment of Textile Industry Wastewater Using Electrocoagulation and Photo electro-Fenton Processes

Sequential Treatment of Textile Industry Wastewater Using Electrocoagulation and Photo electro-Fenton Processes

Effective treatment of textile industry wastewater by combined ultraviolet assisted and Fe2+ catalyzed percarbonate oxidation

Sustainable water management is very important for industries with high water consumption and wastewater generation, such as the textile industry. This study aims to investigate the treatment of textile wastewater with ultraviolet (UV) assisted and Fe2+ catalyzed sodium percarbonate (SPC) oxidation, which is an eco-friendly treatment method in terms of both added oxidant and activation methods. Based on the removal efficiencies and reaction rates, a sorting was made as UV/SPC/Fe2+ > SPC/Fe2+ > UV/Fe2+ > UV/SPC > SPC > UV. It was observed that the removal efficiencies increased as the SPC dose increased, and decreased due to the scavenging effect with the 5 g/L oxidant dose, and the optimum SPC dose was determined as 2.5 g/L. It was determined that the removal efficiencies were higher in acidic conditions and high UV power applications. Under optimum operating conditions (pH:3, SPC dose: 2.5 g/L, Fe2+ dose: 1 g/L, UV lamps: 4), 68% COD, 80.9% UV254, and 92% color removal were achieved. Under optimum conditions energy cost, chemical cost, and operational cost were calculated as 11.9 $/m3, 0.20 $/m3, and 12.1 $/m3, respectively. By reducing the process COD concentration to 236.2 mg/L, discharge standards have been achieved, and the applicability of the UV/SPC/Fe2+ process was proven.

Treatment of Textile Industry Wastewater by Using Solar Photocatalytic Process: Experimental Studies & Statistical Optimization

Treatment of Textile Industry Wastewater by Using Solar Photocatalytic Process: Experimental Studies & Statistical Optimization

A critical review of textile industry wastewater: green technologies for the removal of indigo dyes.

The denim textile industry represents an important productive sector. It generates wastewater with low biodegradability due to the presence of persistent pollutants, which can produce toxic and carcinogenic compounds; therefore, wastewater treatment reduces risks to aquatic life and public health. This paper presents a review of 172 papers regarding textile industry wastewater treatment for the removal of contaminants, especially indigo dyes used in the denim industry, in the context of green technologies. The physicochemical characteristics of textile wastewater, its environmental and health impacts, and the permissible limit regulations in different countries were reviewed. Biological, physicochemical and advanced oxidation processes for the removal of indigo dyes were reviewed. The goal of this study was to analyze the characteristics of green technologies; however, the research does not clearly demonstrate an effect on energy consumption savings, carbon footprint decreases, and/or waste generation. Advanced oxidation processes showed the highest color removal efficiency (95 and 97% in synthetic or real wastewater, respectively). Photocatalysis and Fenton reactions were the most efficient processes. None of the revised works presented results regarding upscaling for industrial application, and the results should be discussed in terms of the guidelines and maximum permissible limits established by international legislation. New technologies need to be developed and evaluated in a sustainable context with real wastewater.

Electrospun niobium oxide 1D nanostructures and their applications in textile industry wastewater treatment

Electrospun niobium oxide 1D nanostructures and their applications in textile industry wastewater treatment

Performance and resilience of the PolyCera® Titan membrane for industrial wastewater treatment.

This research aims to evaluate the performance of PolyCera® Titan membrane for different wastewater treatment. Membrane filtration of several cycles was conducted in understanding the fouling mechanism, fouling propensity, and defouling potential of the PolyCera® Titan which had not been studied by any other researcher before. The PolyCera® Titan membrane is effective for the treatment of textile industry wastewater, palm oil mill effluent (POME), leachate, and semiconductor-industry wastewater. Rejection of methylene blue (MB) and Congo red (CR) was in the range of 78.76-86.04% and 88.89-93.71%, respectively; 94.72-96.50% NaCl, 96.07-97.62% kaolin, and 97.26-97.73% glucose were rejected from synthetic leachate indicating the removal of TDS, TSS, and COD from the leachate, respectively. Standard blocking and complete model were the best models used to explain the PolyCera® Titan membrane fouling mechanism in all types of wastewater treatment processes with a high R2 value. Physical cleaning with the use of distilled water was able to recover the permeate flux with the flux recovery ratio (FRR) value in the range of 79.2-95.22% in the first cycle, 81.20-98.16% in the second cycle, and 86.09-95.96% in the third cycle.

Simultaneous Adsorption of Anionic Dyes onto Kail Sawdust Charcoal (KSC) from Binary Dye Solution

Charcoal prepared from Kail Sawdust (waste obtained from carpenter shop) has been used as adsorbent for the simultaneous removal of red RB (RRB) and yellow M4G (YMG) dyes from water. The interactive effect of both dyes is found as antagonistic. The experiments are performed on optimized operating parameters, which are based on individual dye adsorption. Experimental results are tested for Langmuir, Freundlich, and Temkin adsorption isotherm models but the equilibrium data fitt well with Langmuir isotherm model. Adsorption kinetics fit well pseudo second order kinetic model. FTIR, SEM, and BET analysis are used to characterize the adsorbent. Adsorption process is spontaneous, feasible, and exothermic as proved by thermodynamic parameters. From the outcomes, it is presumed that removal of dyes by KSC (bioadsorbent) can be proved as successful and green innovation for the treatment of textile industrial wastewater.

Fe-N-C-based cathode catalyst enhances redox reaction performance of microbial fuel cells: Azo dyes degradation accompanied by electricity generation

Microbial fuel cell (MFC) is a promising technology for the treatment of textile industry wastewater and energy recovering. However, insufficient power for redox reaction and costly cathode catalyst limit the application of MFCs. Herein, we proposed an environmentally friendly and convenient approach for Fe-N-C-based catalysts synthesis and confirmed their satisfactory effects. The results showed that graphitized structures, pyridine-N and graphitic-N enhanced the conductivity of pomelo peel-derived carbon (PPC). In addition, the existence of Fe3C nanocrystals, Fe-Nx active sites and the rod-like carbon nanotubes (CNTs) was favorable for the synthetic catalyst. Meanwhile, the effective removal of Congo Red (CR) (99.0%) and COD (86.6%) was achieved at the precursor mass ratio was 2 under neutral conditions, accompanied by a maximum power output of 184 mW·m-2. It was clarified that electrons preferentially break the azo bond (-N = N-) of CR and the intermediates mainly included the benzene ring and the naphthalene ring. Microbial community analysis showed that Proteobacteria (56.5%), Gammaproteobacteria (44.6%) and Acinetobacter (29.5%) dominated at the phylum, class and genus levels of the anodic biofilm, respectively. In general, this study provides an innovative substitute for cathode catalyst in MFCs and the synthesized Fe-N-C-based catalyst could be widely employed in engineering owing to its admirable intrinsic activity.

Biodiesel production from biomass by treating textile industry wastewater

Real textile industry wastewater was treated with the activated sludge process, and biodiesel was produced from activated sludge which was used for the treatment of wastewater. The sequential Batch Reactor was operated at the laboratory scale under ambient conditions that were 25oC. During the treatment, some of the sludge returned to the reactor while the remaining part was harvested and stored at +4°C. To determine the optimum hydraulic residence time in the treatment of textile industry wastewater with the activated sludge process, different hydraulic retention times of 1,2,3,4, and 5 days were compared. In the study, the SBR reactor was operated with and without UV to evaluate the effect of UV on treatment efficiency. While the highest removal efficiency in real textile industry wastewater by activated sludge at HRT-3 was 62% COD and 20% color with UV, the highest removal efficiency was 43% COD and 11% color used without UV. Bio-oil was extracted by Bling and Dyer extraction method from harvested sludge. 82 ml biodiesel and 15 ml glycerine were obtained from 1 L wet activated sludge by the transesterification method.

Highly active iron (II) oxide-zinc oxide nanocomposite synthesized Thymus vulgaris plant as bioreduction catalyst: Characterization, hydrogen evolution and photocatalytic degradation

This study aimed to synthesize an iron (II) oxide-zinc oxide (Fe2O3/ZnO) nanocomposite using eco-friendly methods and to evaluate its performance as a catalyst against textile dyes and hydrogen generation. To these means, Fe2O3/ZnO was synthesized from the Thymus vulgaris plant by biogenic methods. The resulting nanocomposite was characterized by Fourier Transmission Infrared Spectroscopy, Transmission Electron Microscopy (TEM), UV–vis spectrometry, and X-Ray diffraction patterns (XRD). According to the obtained TEM characterization results, it was observed that the nanocomposite had an average size of 3.78 nm. According to the XRD results, the nanocomposite's average crystal size was 3.884 nm. In addition, the hydrogen release was investigated by NaBH4 hydrolysis. The turnover frequency, activation energy (Ea), entropy (ΔS), and enthalpy (ΔH) values obtained from hydrogen production studies are 1942.23 h−1 and 15.68 kJ/mol, −127.29 J/mol K, and 13.14 kJ/mol, respectively. In the reusability tests, it was observed that the nanocomposite was 78% effective. The photocatalytic studies using solar energy revealed that the nanocomposite was 79% effective for methylene blue (MB) dye removal. This work demonstrated the potential of transition metals for energy production. It showed that the developed nanocomposite could be a viable solution and, with further development, can be an efficient catalyst for alternative energy production (energy generation) and textile industry wastewater treatment.