Trap Parameters Research Articles

Performance limiting inhomogeneities of defect states in ampere-class Ga2O3 power diodes

Impacts of spatial charge inhomogeneities on carrier transport fluctuations and premature breakdown were investigated in Schottky ampere-class Ga2O3 power diodes. Three prominent electron traps were detected in Ga2O3 epilayers by a combination of the depth-resolved capacitance spectroscopy profiling and gradual dry etching. The near-surface trap occurring at 1.06 eV below the conduction band minimum (EC), named E3, was found to be confined within a 180 nm surface region of the Ga2O3 epilayers. Two bulk traps at EC − 0.75 eV (E2*) and at EC − 0.82 eV (E2) were identified and interconnected with the VGa- and FeGa-type defects, respectively. In the framework of the impact ionization model, employing the experimental trap parameters, the TCAD simulated breakdown characteristics matched the experimental breakdown properties well, consistently with inverse proportionality to the total trap densities. In particular, the shallowest distributed E3 trap with the deepest level is responsible for higher leakage and premature breakdown. In contrast, Ga2O3 Schottky diodes without E3 trap exhibit enhanced breakdown voltages, and the leakage mechanism evolves from variable range hopping at medium reverse voltages, to the space-charge-limited conduction at high reverse biases. This work bridges the fundamental gap between spatial charge inhomogeneities and diode breakdown features, paving the way for more reliable defect engineering in high-performance Ga2O3 power devices.

Pore-to-field scale modeling of residual gas trapping in tight carbonate underground gas reservoirs

The deep saline aquifer and depleted gas reservoirs are suitable candidates for CO2 storage. The estimation of residual gas and corresponding flowing behavior are major parameters for successful CO2 trapping in geological formations. In this article the residual gas trapping phenomenon in pore scale has been studied using Micro-CT images. In macro scale, the results of imbibition experiments on core plug samples have been considered to determine residual gas saturation (RGS) and the corresponding water relative permeability. In the field scale, pressure transient data in water leg has been used to determine the water relative permeability at RGS in a tight carbonate reservoir in Middle East. In the proposed workflow, an artificial intelligence approach is applied to determine absolute permeability profile. Then, a numerical dynamic single well model is built to calculate the water relative permeability. The comparison of core and pressure transient data shows that the absolute permeability and water relative permeability from core imbibition test are significantly overestimated while the results of gas-water simulation in pore scale confirmed the real field transient data. The proposed method can be used by industrial reservoir simulator to define rock/fluid interaction parameters in simulation of CO2 storage in depleted underground gas reservoirs.

Effect of helium ion and gamma irradiation on the TL and OSL properties of Tb-doped LiF nanophosphors

Lithium Fluoride (LiF) stands out as a extensively researched material in Thermally Stimulated Luminescence Dosimetry (TLD). This study specifically delves into nanocrystalline Tb-doped LiF TL dosimeters, synthesized through the co-precipitation method, and evaluates their efficacy under He ion and gamma rays radiation. Morphological examination via transmission electron microscopy has revealed cubic-shaped particles. These particles were subjected to irradiation by 120 keV He ion beams ranging from 1014 to 1016 ions/cm2 and gamma rays ranging from 10 to 1000 Gy, facilitating a comprehensive comparative analysis. Deconvolution of the glow curves enabled the extraction of trapping parameters. Under gamma irradiation, the nanophosphor exhibited a distinctive, intense single TL glow peak centered at 400 K with a minor hump at 512 K, diminishing with increasing doses. Conversely, under He ion irradiation, the nanophosphor displayed a peak at 492 K, accompanied by a slight shoulder around 600 K. Additionally, gamma doses displayed a highly promising response to Optically Stimulated Luminescence (OSL). Fading studies further underscore its suitability for radiation dosimetry applications. The unique characteristics of the TL glow curve, dose-response behaviours, and OSL responses highlight the versatility and effectiveness of these nanophosphors in radiation dosimetry, making significant contributions to advancements in this field.

Investigations of swift heavy ion induced thermoluminescence effect, trapping parameter analysis, and density functional theory of MgB4O7: Eu phosphor

The present work reports swift heavy ion (SHI) induced thermoluminescence (TL) dosimetric properties and density functional theory (DFT) studies of Eu doped MgB4O7 phosphor. Comparative investigations of structural, and luminescent properties of MgB4O7:Eu phosphor upon irradiation by 100 MeV Ag7+ and Ni7+ ion beams at the varied fluence range from 1 × 1010 ion/cm2 to 5 × 1012 ion/cm2 are presented systematically. Eu doped MgB4O7 phosphor is prepared by facile hydrothermal method. X-ray diffraction pattern of the material reveals its orthorhombic structure with crystallite size of ∼30 nm. Fourier transform infrared spectroscopy (FTIR) studies demonstrate loss of crystallinity of material after the SHI irradiations. Correlation of stopping powers and projectile range calculations is performed using SRIM software. The investigated photoluminescence properties show emission bands located in the orange-red region with prominent peaks centered at ∼593 nm and ∼625 nm corresponding to 5D0→7F1 and 5D0→7F2 transitions of Eu3+ion. The influence of ion beam fluence on the photoluminescence properties has been explored. Variation in the intensity of the PL peaks without any shift in the peak positions is observed at different ion fluence. The TL glow curve of phosphor exhibits two major dosimetric peaks (a) at 185 °C and 275 °C and (b) at 172 °C and 273 °C upon Ag7+ and Ni7+ ion beam irradiation respectively. The phosphor shows fairly good linear dose response in the range of 1 × 1010 ion/cm2 to 5 × 1012 ion/cm2. Fading measurements reveal 10% and 12% fading for the irradiation of Ag7+ and Ni7+ ions respectively in two months. Trapping parameter calculations of SHI irradiated phosphors are carried out via various TL glow curve analysis methods such as, peak shape method, whole glow peak method, and glow curve deconvolution method. Efficient thermoluminescence properties of MgB4O7:Eu make it a potential phosphor material and promise to provide avenue into swift heavy ion dosimetry applications. DFT computational studies performed to obtain the electronic structure of Eu doped MgB4O7 phosphor support the experimental results of crystal structure, symmetry and electronic structure studies.

Development of Dy3+ doped lithium magnesium borate glass system for thermoluminescence based neutron dosimetry applications

Abstract The manuscript reports the synthesis of Dy3+ incorporated lithium magnesium borate glass by melt quenching technique. FTIR study revealed the presence of both BO3 as well as tetrahedral BO4 units through their characteristic frequencies. Photoluminescence (PL) study of unirradiated samples confirmed the presence of Dy dopant in the ‘+3’ oxidation states from the characteristic emissions at 482, 578, 666 and 716 nm corresponding to 4F9/2 → 6H15/2, 4F9/2 → 6H13/2 and 4F9/2 → 6H11/2, 4F9/2 → 6H9/2 transitions, respectively. Thermal neutron and gamma irradiated PL emission and lifetime characteristics were discussed in details based on the different defect centers. Thermal neutron irradiated TL study showed that the material has a broad and single dosimetry glow peak at about 450 K which showed high fading due to low temperature peak. TL based neutron sensitivity of LMB: Dy3+ was found to be about 37.4 times less than that of standard TLD-100 (LiF: Mg, Ti) powder. The net TL response from about 3 to 83 mSv of neutron dose was found to be linear (Adj. R2 = 0.9994) which is one of the most desirable properties for dosimetry applications. In addition, the TL trap parameters were evaluated using both deconvolution of TL glow curve and peak shape method as suggested by Chen which were found to be matching with each other.

Thermoluminescence characteristics of gamma-irradiated nano-alumina

The focus of this study lies in exploring the properties of thermoluminescence (TL) in nano-alumina, including the correlation between TL intensity and absorbed dose, identification of individual luminescence peaks, and investigation of trap parameters for potential dosimetry applications. The samples were irradiated by 60Co with doses ranging from 530 to 2646 Gy. Micro-sized α-Al2O3 had a prominent dosimetry peak at maximum temperature Tm = 435 K. Nano-α-Al2O3 samples with 40 and 50 nm particle sizes exhibited a TL luminescence glow curve, with the main dosimetry peak in the low-temperature region and a complex structure at higher temperatures (above 500 K). The observed maximum of the main dosimetry peak depended on the nanoparticle size and was 460 K for the sample with particle size of 40 nm and 467 K for 50 nm. The main dosimetry peak was described by the superposition of the two peaks.A computerized glow curve deconvolution method was applied to determine the parameters of the traps responsible for TL using the Microsoft Windows-operated GlowFit program, assuming first-order kinetics. The found values of the activation energies were 0.97 ± 0.01 eV for the trapping center responsible for the peak with Tm = 458 ± 3 K and, accordingly, 1.05 eV for the peak with Tm = 473 ± 3 K. The estimated values of the frequency factor were s ≈ 1.01 × 1010 and 1.3 × 1010 s−1 for the peak with Tm = 458 ± 3 K, and 2.06 × 1011 s−1 for the peak with Tm = 473 ± 3K, respectively. The lifetime for the traps in nano-α-Al2O3 was estimated as 43–56 days for the first trap and approximately 65 days for the second trap. It is assumed that these traps are responsible for TL emission at the low-temperature part of the glow curve.

Luminescence in Zinc Selenide Doped with Sn and (Sn, Dy) Phosphors

AbstractZinc selenide doped with Sn and (Sn, Dy) phosphors has been prepared by firing the samples in an atmosphere of nitrogen gas. The voltage and frequency dependence of electrolyte brightness has been studied. Voltage dependence of electroluminescence (EL) brightness reveals an acceleration collision mechanism in the Schottky barrier at the metal–semiconductor interfaces. EL and photoluminescence (PL) spectra and thermoluminescence (TL) glow curves of these phosphors have also been recorded to understand the nature and mechanism involved in the luminescence process. The trapping parameters are calculated for the glow curves of these phosphors.

TL-SDA: A designed toolkit for the deconvolution analysis of thermoluminescence glow curves

In the present study, a graphical user interface (GUI) toolkit has been developed to analyze the thermoluminescence (TL) glow-curve and evaluate the trapping parameters using TL expression based on the one-trap one-recombination model. The basic idea of the deconvolution analysis in the developed toolkit is based on performing a sequence of successful fits, where the information provided by each fit is used by the next fit until the deconvolution of the entire glow curve approaches an optimum solution. The starting values and ranges of the fitting parameters can be controlled and adjusted to improve the deconvolution analysis of complex structure glow curves. The designed toolkit is also supported by the background-subtraction option to improve the analysis at low irradiation dose levels. The expanded uncertainty at the 95 % confidence level of the fitted trapping parameters is also provided. All the evaluations performed using the designed toolkit are allowed to be extracted into an Excel spreadsheet. The TL-SDA toolkit can be freely downloaded from: TLSDA_v1 - File Exchange - MATLAB Central (https://www.mathworks.com/matlabcentral/fileexchange/154136-tlsda_v1-1)

Existence of Small-Amplitude Double Layers in Two-Temperature Non-Isothermal Plasma

In the presence of warm negative ions, ion-acoustic small-amplitude monotonic double layers are theoretically investigated in a plasma consisting of warm positive ions, warm positrons, and two-temperature non-isothermal electrons under the variation of the trapping parameters of electrons, concentration of positrons, and mass ratios of heavier negative ions to lighter positive ions by the Sagdeev pseudopotential method. The corresponding double layer solutions are also discussed for the same variation. Consequently, ion-acoustic solitary waves and double layers have been observed in auroral and magnetospheric plasmas with two-temperature electron distributions found in a laboratory, as well as in the space. This paper shows the effects of trapping parameters of electrons, positron concentration, and mass ratios of heavier negative ions to lighter positive ions on the Sagdeev potential function ψ(φ) and double layer solutions φDL for small-amplitude monotonic double layers. The results are presented graphically in Figs. 1 to 6.

Plasma antioxidant potential measured by total radical trapping antioxidant parameter in a cohort of multiple sclerosis patients.

Oxidative injury has been implicated as a mediator of demyelination, axonal damage, and neurodegeneration in multiple sclerosis (MS). There is a high demand for oxidative injury biomarkers. The aim of the study was to evaluate MS patients' plasma antioxidant potential using the total radical trapping parameter (TRAP) assay and examine its usefulness as an MS disease biomarker. A total number of 112 MS patients underwent an analysis of TRAP. In addition, plasma uric acid (UA) levels were analyzed. The neurological and radiological data were collected from patient records from Helsinki University Hospital during 2012-2013 when first-line injectables of moderate-efficacy, natalizumab (NTZ), and fingolimod (FTY) of high efficacy disease modifying therapies and in some cases azathioprine (AZT) were used to treat MS. TRAP values were negatively associated with expanded disability status scale (EDSS) score with p-value .052, β=-28. There was also a negative association in TRAP values between patients with no medication (n=22, TRAP mean 1255μmol/L (95% confidence interval [CI] 1136-1374)) and patients who received NTZ, p-value .020 (n=19, TRAP mean was 991μmol/L (95% CI 849-1133) or FTY treatment, p-value .030 (n=5, TRAP mean 982μmol/L (95% CI 55-1909). Due to a small sample size, these results were not significant after applying a false discovery rate correction at a 0.05 significance level but are worth highlighting. Men in the study had higher TRAP values, p-value=.001 (TRAP mean 1320±293μmol/L) than women (TRAP mean 1082±288μmol/L). UA was positively associated with TRAP values, p-value <.001 and UA levels in men (UA mean 334.5±62.6μmol/L) were higher compared to women (UA mean 240±55.8μmol/L), t-test p-value <.001. The significant difference in TRAP levels between genders, with men showing higher TRAP values than women, may be attributed to the variation in UA levels. Our findings suggest that lower plasma antioxidant potential is linked to more severe disability measured by EDSS scores. Patients treated with NTZ and FTY had reduced antioxidant power, which might be influenced by the active MS disease rather than the treatments themselves. The study reveals a strong positive correlation between UA levels and TRAP, particularly among women. However, men on average had better antioxidant potential than women. Neither the disease type nor the duration influences TRAP levels. While serving as a marker of antioxidant potential, plasma TRAP in MS patients does not reliably reflect overall oxidative stress (OS) and should not be solely used as an indicator of OS.

Effect exponentially distributed trapped charge jump transport on energy storage performance in polyetherimide nanocomposite dielectric

With the development of science and technology, polymer dielectric capacitors are widely used in energy, electronics, transportation, aerospace, and many other areas. For polymer dielectric energy storage capacitors to remain effective in practical applications, excellent charge and discharge performance is essential. However, the performance of the common polymer dielectric capacitors will deteriorate rapidly at high temperature, which makes them fail to work efficiently under worse working conditions. Dielectric trap energy levels and trap densities increase when nanoparticles are incorporated into the dielectric. The change in trap parameters will affect carrier transport. Therefore, the high temperature energy storage performance of polymer nanocomposite dielectric can be improved by changing the trap parameters to regulate the carrier transport process. However, the quantitative relationship between trap energy level and trap density and the energy storage properties of nanocomposite dielectric need further studying. In this paper, the energy storage and release model for exponentially distributed trapped charge jump transport in linear polymer nanocomposite dielectrics is constructed and simulated. The volume resistivity and electric displacement-electric field loops of pure polyetherimide are simulated at 150 ℃, and the simulation results match the experimental results, which demonstrates the validity of the model. Following that, under different temperatures and electric fields, the current density, electric displacement-electric field loops, discharge energy density and charge-discharge efficiency of polyetherimide nanocomposite dielectric are simulated by using different trap parameters. The results show that increasing the maximum trap energy level and the total trap density can effectively reduce the carrier mobility, current density and conductivity loss, and enhance the discharge energy density and the charge-discharge efficiency of the nanocomposite dielectric. On condition that temperature is 150 ℃ and applied electric field is 550 kV/mm, the polyetherimide nanocomposite dielectric with a maximum trap energy level of 1.0 eV and a total trap density of 1×10&lt;sup&gt;27&lt;/sup&gt; m&lt;sup&gt;–3&lt;/sup&gt;, has 4.26 Jcm&lt;sup&gt;–3&lt;/sup&gt; of discharge energy density and 98.93% of energy efficiency. These parameters in the polyetherimide nanocomposite dielectric are 91.09% and 227.58% higher than those in the pure polyetherimide, respectively. The energy storage performance under high temperature and high electric field is obviously improved. It provides theoretical and model support for the research and development of capacitors with high temperature resistance and energy storage performance.

Effect exponentially distributed trapped charge jump transport on energy storage performance in polyetherimide nanocomposite dielectric

With the development of science and technology, polymer dielectric capacitors are widely used in energy, electronics, transportation, aerospace, and many other areas. For polymer dielectric energy storage capacitors to remain effective in practical applications, excellent charge and discharge performance is essential. However, the performance of the common polymer dielectric capacitors will deteriorate rapidly at high temperature, which makes them fail to work efficiently under worse working conditions. Dielectric trap energy levels and trap densities increase when nanoparticles are incorporated into the dielectric. The change in trap parameters will affect carrier transport. Therefore, the high temperature energy storage performance of polymer nanocomposite dielectric can be improved by changing the trap parameters to regulate the carrier transport process. However, the quantitative relationship between trap energy level and trap density and the energy storage properties of nanocomposite dielectric need further studying. In this paper, the energy storage and release model for exponentially distributed trapped charge jump transport in linear polymer nanocomposite dielectrics is constructed and simulated. The volume resistivity and electric displacement-electric field loops of pure polyetherimide are simulated at 150 ℃, and the simulation results match the experimental results, which demonstrates the validity of the model. Following that, under different temperatures and electric fields, the current density, electric displacement-electric field loops, discharge energy density and charge-discharge efficiency of polyetherimide nanocomposite dielectric are simulated by using different trap parameters. The results show that increasing the maximum trap energy level and the total trap density can effectively reduce the carrier mobility, current density and conductivity loss, and enhance the discharge energy density and the charge-discharge efficiency of the nanocomposite dielectric. On condition that temperature is 150 ℃ and applied electric field is 550 kV/mm, the polyetherimide nanocomposite dielectric with a maximum trap energy level of 1.0 eV and a total trap density of 1×10&lt;sup&gt;27&lt;/sup&gt; m&lt;sup&gt;–3&lt;/sup&gt;, has 4.26 J·cm&lt;sup&gt;–3&lt;/sup&gt; of discharge energy density and 98.93% of energy efficiency. Compared with pure polyetherimide, the rate of improvement is 91.09% and 227.58%, respectively. The energy storage performance under high temperature and high electric field is obviously improved. It provides theoretical and model support for the research and development of capacitors with high temperature resistance and energy storage performance.

Differences in the Quantitative HRCT Characteristics of Patients with Asthma, COPD and Asthma-COPD Overlap and Their Relationships with Pulmonary Function.

We compared pulmonary function indices and quantitative CT parameters of airway remodeling, air trapping, and emphysema in asthmatic patients and patients with COPD and asthma-COPD overlap (ACO) and explored their relationships with airflow limitation. Patients with asthma (n=48), COPD (n=52), and ACO (n=30) and controls (n=54) who completed pulmonary function tests and HRCT scans were retrospectively enrolled in our study. Quantitative CT analysis software was used to assess emphysema (LAA%), airway wall dimensions (wall area (WA), luminal area (LA), and wall area percentage (WA%)), and air trapping ((relative volume change of -860 HU to -950 HU (RVC-860 to-950) and the expiration-to-inspiration ratio of the mean lung density (MLDE/I))). Differences in pulmonary function and HRCT parameters were compared among the groups. Spearman correlation analysis and regression analysis were utilized to explore structure‒function relationships. The LAA% in COPD and ACO patients was significantly greater than that in asthmatic patients and controls. The WA% and WA in COPD and ACO patients were greater than those in controls, whereas the WA% and LA between asthmatic patients and controls reached statistical significance. The RVC-860 to -950 levels decreased in the following order: ACO, COPD, and asthma. RVC-860 to -950 independently predicted FEV1% in asthmatic patients; LAA% and MLDE/I in COPD patients; and LAA%, WA% and RVC-860 to -950 in ACO patients. Comparable emphysema was observed in patients with COPD and ACO but not in asthmatic patients. All patients exhibited proximal airway remodeling. The bronchi were thickened outward in COPD and ACO patients but are thickened inward in asthmatic patients. Furthermore, air trapping in ACO patients was the most severe among all the groups. Indirect lung densitometry measurements might be more predictive of the degree of airflow limitation than direct airway measurements in obstructive airway diseases.

Quantum simulation and Anderson localization in vector rogue waves of Bose-Einstein condensate

We report the existence of vector rogue waves in a coupled Bose-Einstein condensate, trapped in a bichromatic optical lattice, which is an appropriate platform for quantum simulation. Such two-component Bose-Einstein condensate plays a vital role to beget hybrid mixtures and structural transition of nonlinear excitations like rogue waves and solitons. An efficient manipulation of rogue waves is embraced, where we identify the slowing down and stopping of dark rogue wave by lattice engineering. This may nurture quantum memory application and transform the rogue wave mixture immiscible. The existence of Anderson localized rogue wave at the central frustrated lattice site is confirmed by showing the exponential nature and localization length of the condensate. A merging of a dual Anderson rogue waves is manifested in their coherent control. Numerical stability analysis is also carried out for a wide range of trap parameters for experimental viability.

Improving the multi-functionality of optical tweezers with FPGA integration.

The development of optical tweezers aims to extend their operating function and pattern. However, excessive programming can lead to a decrease in the system's operating speed and introduce bugs or data transmission delays. In this study, we present a time-shared optical tweezers system that allows for parallel operation of multiple functions. To enable efficient data transmission, we employ a queue structure and a buffer. To assess the system's performance, we utilize a biological sample in conjunction with the optical tweezers system and scanning imaging technique. We quantify the trapping parameter while concurrently running power stabilization programs. As a result, the standard deviation of the measured stiffness is reduced by 60% in the x and y directions and 30% in the z direction, indicating a significant improvement in calibration precision. Throughout the program execution, the system maintains an operating rate of 110kHz, and the data are continuously updated in real time on the host. The system's performance demonstrates its potential for quantification and morphological reconstruction of biological samples.

B2O3–TeO2–ZnO–Na2O–Nd2O3 glass matrices: A comprehensive study of physical, structural, optical, and thermoluminescence properties

The present study reveals the effect of Nd3+ in sodium zinc borotellurite glasses for photonic and dosimetric applications. The melt quenching technique was employed to prepare glass samples for different Nd2O3 compositions (0.0–1.0 mol%) with the empirical chemical relation (60-x)B2O3+20TeO2+10ZnO+10Na2O+xNd2O3. The glass samples were characterized via different techniques for their physical, structural, optical and thermoluminescence behaviour. The Archimede's principle was used to analyse the physical parameters, including density (ρ), molar volume (Vm), and oxygen packing density (OPD). XRD spectra indicated the amorphous nature of fabricated glasses and Fourier transform infrared spectroscopy (FTIR) revealed ZnO, TeO3, TeO4, BO3, BO4 units and Nd–O bonds present in the glass matrix. The values for indirect (Eopt1) gap, Urbach energy (ΔE), cut-off wavelength (λc) and other optical parameters were determined from the optical absorption spectra. Thermoluminescence (TL) response of the prepared glasses was analyzed for gamma dose of 1 kGy–13 kGy, among which NBT 0.2 glass sample showed strongest TL intensity at 5 kGy with non-monotonic behaviour. With the use of Computerised Glow Curve Deconvolution (CGCD), various trap parameters, including activation energy (E), order of kinetics (b) and frequency factor (s) have been identified. Low effective atomic number of these glasses, along with their optimal TL response makes them effective for radiation monitoring, pasteurization of sea food and decomposition of drugs at high doses.

Thermo- and photoluminescent properties and gamma radiation shielding efficiency of NiO doped B2O3–Bi2O3 glass system

Nickel-doped bismuth borate glass system was synthesized via a conventional melt-quenching technique. Various characterizations such as thermoluminescence (TL), UV-VIS, and photoluminescent (PL) spectroscopy were conducted on glasses to study their thermo- and photoluminescent properties. Co-60 was used as an irradiation source to activate the thermoluminescence in the glasses. The kinetic and trapping parameters of the glasses were studied and their radiation shielding efficiency was also studied through simulation with the use of a user-friendly software called Phy-X/PSD software. Shielding parameters such as Mass attenuation Coefficient (MAC), Linear attenuation coefficient (LAC), Half Value Layer (HVL), Tenth value layer (TVL) and others were calculated for the studied glasses. The highest radiation shielding efficiency was recorded by the sample with 2% NiO concentration. The values of the glass shielding parameters were also compared with those commercially available concrete such as ordinary, serpentine, barite and chromite concretes and the result indicated great potentials of the glasses for radiation shielding application considerations.

Luminescence and dosimetry approach in terbium(III)-activated tungstate double perovskite.

A series of tungstate double perovskite Ca3 WO6 doped with Tb3+ was prepared by a combustion process using urea as a flux. The crystal structure identification of Ca3 WO6 :Tb3+ phosphors was done using X-ray diffraction patterns, and a monoclinic structure was discovered. The Fourier transform infrared spectrum of Ca3 WO6 :Tb3+ displayed characteristic vibrations of tungstate bonds. Under 278 nm excitation, Ca3 WO6 :Tb3+ exhibited intense downconversion green emission, which corresponded to the 5 D4 -7 FJ (J = 4,5) transitions of Tb3+ . The phosphor exhibited the highest photoluminescence (PL) intensity when it was doped with 1mol% of Tb3+ ; later intensity quenching appeared to be due to the multipolar interaction at higher dopant concentrations. Moreover, high-quality thermoluminescence (TL) was detected when phosphors were irradiated using beta rays. The effects of Tb3+ concentration and beta dose on TL intensity were the two major aspects studied in detail. The TL intensity demonstrated excellent linear response to the applied range of beta dose. The trap parameters of the studied phosphors were computed by the peak shape approach and glow curve deconvolution. The fading effect on TL intensity was studied by recording the TL glow curves after 1 month of beta irradiation. Obtained results from the PL and TL characterizations showed that the phosphors under study have the potential to be used in lighting displays and in thermoluminescence dosimetry.

Optimization of an experimental TL protocol for discriminating the recombination pathways

The present work investigates an altered version of an already existing protocol that was utilized to study in depth the underlying mechanisms and phenomena of stimulated luminescence based on three phenomenological models. These phenomena are related to electron recombination pathways, including de-localized, localized, or semi-localized transitions. This new experiment consists of one new protocol, that requires prior specific heating treatments. It includes sets of 5 measurements per heating cycle and uses prompt isothermal decay (PID) following certain preheats under single high doses. The materials that are under study are the MgB4O7: Dy, Na (MBO) and BeOR, both having a localized peak in their dosimetric region. The protocol enables the examination of the recombination mechanisms of the traps and their trapping parameters, while also providing the ability to observe any potential transition between the two. Generally, the work concludes that the protocol can be utilized in both cases to find the recombination pathways, although the transition is only visible in the case of BeOR. Throughout the experimental analysis, it was pre-considered that MBO possesses two distinct excited states (trap energy levels). The validation of all experimental results was conducted using different techniques, such as the peak shape methods (PSM), the initial rise (IR) and the prompt isothermal decay (PID) deconvolution.

Influence of Annealing Temperature on the Structural and Luminescence Features and Thermoluminescence Trap Parameters of Ca2Al2SiO7: Ce3+ Phosphors

Cerium-doped Ca2Al2SiO7 phosphors were synthesized via the combustion technique and annealed at 1073 K, 1173 K, and 1373 K. X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), photoluminescence (PL), and thermoluminescence (TL) studies were performed to explore the variation of structural, morphological, luminescence, and TL properties with annealing temperature. The XRD plot showed an increase in crystallinity with an increase in annealing temperature. Similarly, the enhancement of PL intensity with an increase in annealing temperature supports the increased crystallinity of the phosphor samples. Detailed analysis of traps and trap parameters was carried out using the principle of TL. Samples were irradiated with different γ-ray doses, and, on heating, luminescence was observed. Thus, TL glow curves were drawn and deconvoluted using computerized glow curve deconvolution (CGCD) and Chen’s peak shape method to study the traps and trap parameters. With increasing annealing temperature, an increase in TL intensity was observed. Regardless of annealing temperature, every sample displayed a linear dose–response for doses ranging from 3 Gy to 500 Gy. TL investigations suggested that the produced phosphors are suitable candidates for gamma dosimetry applications.