Cold chain logistics involves all aspects of food storage, transport, and sales. This study focuses on innovating cold storage disinfection within this context. Regular disinfection reduces microorganism growth, improves food quality, and ensures safety. Traditional methods lack automation, accurate monitoring, and responsive control. Conventional sensors are unsuitable for curved bottles and need frequent power changes. This paper proposes a light energy harvested flexible wireless sensing for disinfection sterilization in food storage (FLWDS). FLWDS comprises five parts: light energy harvesting and power supply node (LEPN), sensing node, control node, monitoring node, and host computer. A predictive control model improves response speed and accuracy. Bluetooth technology ensures real-time communication between nodes. FLWDS collects light energy inside the cold store as a supplementary energy source and can be used in curved structures with a response time of less than 1 s. The maximum communication distance is 40 m. The flexible level sensing system can be designed according to the induction pad’s length, with a measurement accuracy of 0.3 mm, sampling every 4.8 ms, and a resolution of 0.2 mm. FLWDS provides self-powered flexible wireless sensing, ensuring accurate liquid level measurement, improved food quality, reduced pollution, and increased sustainability.