Transport Behavior Research Articles

Transport of reduced PBAT microplastics in saturated porous media: Synergistic effects of enhanced surface energy and roughness

Microplastic (MP) pollution presents significant global environmental challenges, exacerbated by reduction aging processes in anoxic environments, thereby increasing environmental risks and potential threats to human health. However, the mechanisms underlying the transport of reduced MPs remain poorly understood. In this study, laboratory-scale column experiments were conducted to investigate the transport behavior of polybutylene adipate terephthalate (PBAT), a common biodegradable MPs, and its reduced products obtained through the aging process mediated by two typical reducing agents, NaBH4 and Na2S, under varying conditions (ionic strength (IS), divalent cations, and low molecular weight organic acids (LMWOAs)). The results indicated that reduction aging improved the hydrophilicity of PBAT by increasing the surface roughness (roughness factor increased from 1.300 to 1.642) and surface energy (from 51.80 to 107.03 mN m−1), thereby increasing the mobility of reduced PBAT (with recovery rate increased from 53.77 % to 63.18 %). Increased IS decreased the mobility of reduced PBAT by decreasing the surface negative charge density. Divalent cations inhibited the mobility of both pristine and reduced PBAT in porous media, with pristine PBAT, containing more oxygen functional groups, exhibiting stronger inhibition. Furthermore, LMWOAs promoted the retention of reduced PBAT in porous media, which was dependent on the type of LMWOAs. This study revealed the alterations in MPs properties caused by reduction aging and their effects on transport mechanisms, offering new insights into the transport behavior and environmental risks of reduced MPs.

Transitioning from gridlock to sustainability: advancing transport strategies for eco-friendly solutions in high-income countries.

The study aims to comprehend sustainable behaviors in high-income nations, where human-environment interactions are crucial. Increased transportation needs in industrialized countries highlight the importance of environmental challenges affecting human well-being. Railway passenger carrier, automobile energy efficiency, technology breakthroughs, financial incentives, and public-private partnerships (PPPs) affect congestion and sustainability, which the study analyses for sound policy inferences in a panel of 28 high-income nations from 2000 to 2022. The panel ARDL estimates reveal that railway passenger carrier increases carbon emissions in the short run while it improves them over time, highlighting the importance of urban planning. Environmental pollution, energy use, transportation behavior (including PPPs), and technical innovation have an inverse connection, demonstrating the efficacy of energy-efficient transport methods, research and development, and renewable energy sources. However, economic incentives highly correspond with carbon-intensive habits, emphasizing the need for high-income countries to phase them out.

Recovery of rare earth elements from ion-adsorption deposits using electro kinetic technology: A comparative study on leaching agents

Ion-adsorption rare earth deposits are crucial sources of heavy rare earth elements. Conventional ammonium-salt leaching techniques have resulted in severe environmental impacts. Electrokinetic mining technology has emerged as a potential solution that can enhance recovery efficiency. However, persistent issues associated with ammonium salts and the influence of electric fields on rare earth elements extraction from ion-adsorption rare earth deposits with alternative leaching agents remain unexplored. In addition, the electrokinetic behavior and mechanisms of rare earth ions and various ions in weathering crusts in an electric field have not been studied. Thus, we report a comparative study of rare earth elements recovery using electrokinetic mining technology with three leaching agents. The results demonstrate that the electrokinetic mining efficiency is enhanced by using magnesium sulfate and ammonium sulfate; however, hindered by sodium sulfate. These differences arise from the diversities in adsorption amounts, and transport characteristics of the leaching cations in soil. Surprisingly, electrokinetic mining technology exhibits superior mining efficiency in high-density soils, contrasting with conventional leaching techniques. Our findings indicate that electromigration, electroosmosis, and electrolysis mechanisms collectively influence the mining process. Remarkably, electrokinetic mining technology achieves a significant rare earth element recovery efficiency of 90 % using magnesium sulfate synergically promoted by the voltage and leaching agent concentration. The findings of this study are expected to provide valuable insights into rare earth elements transport and exchange behavior in an electric field with various leaching agents, thereby contributing to the advancement of sustainable rare earth elements mining practices.

An interprocess communication-based two-way coupling approach for implicit–explicit multiphysics lattice discrete particle model simulations

In this study, the researchers have developed a Multiphysics-Lattice Discrete Particle Model (M-LDPM) framework that deals with coupled-fracture-poroflow problems. The M-LDPM framework uses two lattice systems, the LDPM tessellation and the Flow Lattice Element (FLE) network, to represent the heterogeneous internal structure of typical quasi-brittle materials like concrete and rocks, and to simulate the material’s mechanical and transport behavior at the aggregate scale. The researchers revisited the LDPM governing equations and added the influence of fluid pore pressure. They also derived the Flow Lattice Model (FLM) governing equations for pore pressure flow through mass conservation balances for uncracked and cracked volumes. The M-LDPM framework was implemented using Abaqus user element subroutine VUEL for the explicit dynamic procedure of LDPM and user subroutine UEL for the implicit transient procedure of FLM. The coupling of the two models was achieved using Interprocess Communication (IPC) between Abaqus solvers. The M-LDPM framework can simulate the variation of permeability induced by fracturing processes by relating the transport properties of flow elements with local cracking behaviors. The researchers validated the M-LDPM framework by comparing the numerical simulation outcomes with analytical solutions of classical benchmarks in poromechanics.

Regulation of the co-transport of toluene and dichloromethane by adsorbed phase humic acid under different hydro-chemical conditions

The transport behavior of combined organic pollutants in soil and groundwater has attracted significant attention in recent years. Research on the influence of humic acid (HA) on organic pollutant transport behavior mainly focuses on the study of the mobile phase HA, with less research on the adsorbed phase HA, especially regarding its interaction with combined pollutants. To enhance understanding of the regulation of co-transport and retention of combined pollutants by adsorbed phase HA, in this study, tests were conducted to investigate how toluene (TOL) and dichloromethane (DCM) are transported in the presence of adsorbed phase HA at different pH levels and ionic strengths. As the proportions of HA-coated sand increased, so did its adsorption capacity for TOL and DCM, which can be attributed to adsorbed phase HA providing more adsorption sites compared to plain sand, thereby reducing the transport potential of the pollutants. The presence of both TOL and DCM facilitated their mutual transportation due to competitive adsorption controlled by the adsorbed phase HA content in the porous medium. Furthermore, it was observed that pH levels influenced the transport behavior of TOL and DCM when adsorbed phase HA was present since adsorbed phase HA transformation into mobile phase was regulated by pH levels. The transport patterns can be effectively simulated using the chemical nonequilibrium two-site sorption model in HYDRUS-1D, accurately reflecting the retardation coefficients and transport distances based on model parameters. This work sheds new light on the regulatory role of adsorbed phase HA in TOL and DCM transport under diverse hydrochemical conditions, with implications for accurately depicting the behavior of combined pollutants, optimizing the remediation strategies and improving remediation efficiency in contaminated sites.

The Impact of Organisational Culture on Transportation Behaviours: An Exploratory Analysis

By annually accommodating a growing number of students, higher education institutions contribute significantly to the daily flow of individuals. This flow exerts a significant impact on greenhouse gas emissions caused by transportation. Several studies have addressed promoting sustainable transportation at the individual level, while little attention has been drawn to examining the impact of organisations in this realm. This paper proposes a model of organisational influences on pro-environmental behaviours. Therefore, we thus identify a set of variables within organisations that expect to influence these behaviours. Among these variables, organisational culture appears as a major predictor. Organisational culture is a set of values, norms, beliefs, meanings and behaviours. Based on this definition, we propose to study organisational culture through measurable elements such as the organisation's values, norms and perceived practices. Additionally, we have identified variables directly influenced by organisational culture, such as leadership and organisational trust. Further variables, including personal norms and facilitating conditions, interact with the organisational culture and provide a more precise understanding of pro-environmental behaviours. This framework will be used to investigate student transportation behaviours. The results are expected to provide valuable insights for developing a culture of sustainable transportation at the organisational level.

The Effect of Fracture Wall Surface Roughness on Proppant Transport

Summary Proppant transport into created fractures is crucial in maximizing hydrocarbon recovery in unconventional reservoirs. Injected proppants keep the created fractures open, enhancing final fracture conductivity and propped and effective fracture length. The roughness and width of the created fracture are also important in proppant transport and distribution within induced fractures, affecting fracture conductivity. This study investigates the effect of fracture width on proppant transport into a complex slot system with 3D-printed rough wall surfaces. This study builds upon previous experimental work (Tatman et al. 2022), exploring different fracture roughness profiles and varying fracture widths. The effects of proppant densities, sizes, and concentrations on proppant transport within rough fracture surfaces were also investigated. A laboratory-scaled slot apparatus was used to examine the effects of various parameters. The slot consisted of a 4-ft-long primary fracture intersecting with a secondary fracture at a 90o angle. The wall surface roughness was printed using 3D printing technology and average fracture widths were set at 0.1 in. and 0.2 in. Fresh water (1 cp) with proppant concentrations of 1 ppg and 2 ppg and proppant sizes of 100-mesh sand [2.65 specific gravity (SG)], 40/70-mesh sand (2.65 SG), and 35/45-mesh ultralightweight (ULW) proppant (1.07 SG) were tested. The results show that fracture wall roughness impacts proppant transport behavior. The rough wall surface formed irregular proppant dune shapes and trapped some of the injected proppant at different locations within the slot, which is distinct from smooth wall surfaces. Decreasing the fracture width of a rough wall surface had a significant impact on proppant transport. The majority of the injected proppant was transported away from the injection point due to the increased slurry velocity. This led to improved proppant transport due to redirected flow direction and associated decreased proppant settling velocities, and a decrease in the proppant-dune-building rate near the inlet point, which carried more proppant deep into the secondary slot. Increasing the proppant concentration had a positive impact on proppant transport within both tested fracture widths by increasing the proppant-dune-buildup rate along the fracture slot and increasing the proppant-covered area inside fractures. The slurry injection rate had a great impact on low-density proppant transport. Decreasing the injection rate for lighter proppant (1.07 SG) helped to build a proppant dune near the injection point, increasing the proppant-covered area. Conversely, the higher injection rate carried the majority of the lighter proppant farther and out of the slots. Larger proppant sizes, (i.e., 40/70-mesh sand) resulted in a large proppant-covered area for both tested fracture widths, due to more particle-to-wall interaction, particle-to-particle interaction, and high density, which increased the settling velocity. However, injecting lighter and larger proppant sizes, such as 35/45-mesh ULW proppant, resulted in less settling and more particles suspended during injection due to lower density.

Numerical study for atmospheric transport of radioactive materials for hypothetical severe nuclear accident under different meteorological conditions

A study for atmospheric transport is essential for the consequence assessment of severe nuclear accidents since radionuclides could be released from the nuclear facility into the atmosphere and cause radioactive pollution in the environment. Atmospheric transport behaviors are strongly related with meteorological conditions, which can obviously influence the transport and diffusion characteristics of radioactive materials in the atmosphere; thus, it is meaningful to investigate the coupling effects between meteorological processes and transport behaviors of radioactive materials. To evaluate the influence of meteorological conditions on atmospheric transport, meteorological parameters for different seasons were first acquired by the weather research forecast model. Furthermore, atmospheric transport behaviors of radioactive materials were simulated by the meso-scale numerical model under different meteorological conditions, and numerical analyses were conducted toward transport and deposition behaviors of radioactive materials. In addition, the influence of FDDA (four-dimensional data assimilation) on meteorological parameters and atmospheric transport behaviors was researched. The present study is important for strengthening consequence assessment for severe nuclear accident and made it possible to apply the data assimilation technology in further research works.

Drying-Wetting Correlation Analysis of Chloride Transport Behavior and Mechanism in Calcium Sulphoaluminate Cement Concrete.

In response to rising CO2 emissions in the cement industry and the growing demand for durable offshore engineering materials, calcium sulphoaluminate (CSA) cement concrete, known for its lower carbon footprint and enhanced corrosion resistance compared to Ordinary Portland Cement (OPC), is increasingly important. However, the chloride transport behavior of CSA concrete in both laboratory and marine environments remains underexplored and controversial. Accordingly, the chloride ion transport behaviors and mechanisms of CSA concrete in laboratory-accelerated drying-wetting cyclic environments using NaCl solution and seawater, as well as in marine tidal environments, were characterized using the rapid chloride test (RCT), X-ray diffraction (XRD), mercury infiltration porosimetry (MIP), and thermogravimetric analysis (TGA). The results reveal that CSA concrete accumulates more chloride ions in NaCl solution than in seawater, with concentrations 2-3.5 times higher at the same water-cement ratio. Microscopic analysis indicates that calcium and sulfate ions present in seawater facilitate the regeneration of ettringite, thereby increasing the density of the surface pore structure. The hydration and repair mechanisms of CSA concrete under laboratory conditions closely resemble those in marine tidal conditions when exposed to seawater. Additionally, this study found that lower chloride ion concentrations and pH levels inhibit the formation of Friedel's salt. Therefore, laboratory experiments with seawater can effectively simulate CSA concrete's chloride transport properties in marine tidal environments, whereas NaCl solution does not accurately reflect actual marine conditions.

Thermal conductivity reduction and crystal properties evolution in iron silicides induced by doping

Understanding the thermal transport behaviors in the crystal lattice is important for designing semiconducting materials in thermal management. In this work, we investigate the mechanism of the decrease in thermal properties of β-FeSi2 when Co dopant is introduced to the host crystal. The crystallite size decreases as Co doping increases from 0 to 5 %. The micro-strain and stress increase with increasing doping levels. The decrease in crystallite size and increase in micro-strain/stress indicate the origin of phonons scattering and lattice softening, leading to the reduction in thermal conductivity. This study provides insights into the correlation between the crystal properties evolution and thermal transport in metal silicide compounds which could be useful in thermal-to-energy conversion applications.

Unraveling Molecular Diffusion Behaviors on the Acidic Sites of H‐ZSM‐5 Zeolite Using Time‐Resolved In Situ FT‐IR Technique

AbstractZeolites, renowned for their abundant crystalline structures and moderate acidities, have garnered significant attention in industrial chemical processes. Among them, the diffusion behaviors of various hydrocarbons within zeolite play a pivotal role due to their profound impact on product selectivity and separation efficiency. While acid sites are essential in determining the catalytic performance of zeolites, their effect on intra‐crystalline diffusivities has often been neglected in catalyst design. Herein, we employ a homemade time‐resolved in situ Fourier Transform Infrared (TR in situ FT‐IR) spectroscopy to investigate the intricate interplay between Brønsted acid sites and various probe molecules. Our study reveals that an augmentation in the density of Brønsted acid sites within H‐ZSM‐5 zeolites remarkably enhances the diffusivity of 1‐butene, in stark contrast to the behavior observed for iso‐butane. This contrasting effect in diffusivity is attributed to the distinct nature of interactions between alkenes and alkanes with Brønsted acid sites. Specifically, the π‐H interactions between alkenes and acid sites act as a driving force, propelling the alkene molecules forward through the zeolite pores. These findings offer valuable insights into designing tailored zeolites with specific acid site properties, controlling the transport behaviors of various probe molecules, and promising new avenues for catalysis and separation.

Numerical and experimental analysis of the effect of multi-ion electrical coupling on the sulfate convection zone in hydraulic concrete

This study centers on investigating the effects of multi-ion electrical coupling on sulfate profiles in the convection zone of hydraulic concrete under drying-wetting cycles. Considering the moisture ingress triggered by capillary negative pressure and electrical potential gradients generated due to the varying speeds of the charged solutes, a coupled numerical model framework for moisture and multi-component ions transport is established. The influence of drying and rewetting conditioning regimes, electrochemical coupling between multi-species ions, sulfate adsorption-binding mechanism, fly ash replacement and porosity of concrete on moisture and multi-ion transport behavior is numerically analyzed. Our findings reveal that more than 60 % of the sulfate ions that penetrate the concrete matrix engage in chemical reactions. After 30 cycles, the sulfate ion content differs by approximately 21 % depending on the presence of the electrical coupling effect. Moreover, the electrostatic potential in the pore solution fluctuates sharply in the ion-rich area near the concrete surface, interacting with ion distribution in the convection zone. The knowledge gleaned from this investigation offers a robust framework for the design of concrete structures that need to withstand challenging aqueous environmental conditions marked by multi-component ions and cyclic drying-wetting processes.

Tracing the electron transport behavior in quantum-dot light-emitting diodes via single photon counting technique

The electron injection and transport behavior are of vital importance to the performance of quantum-dot light-emitting diodes. By simultaneously measuring the electroluminescence-photoluminescence of the quantum-dot light-emitting diodes, we identify the presence of leakage electrons which leads to the discrepancy of the electroluminescence and the photoluminescence roll-off. To trace the transport paths of the leakage electrons, a single photon counting technique is developed. This technique enables us to detect the weak photon signals and thus provides a means to visualize the electron transport paths at different voltages. The results show that, the electrons, except those recombining within the quantum-dots, leak to the hole transport layer or recombine at the hole transport layer/quantum-dot interface, thus leading to the reduction of efficiency. By reducing the amount of leakage electrons, quantum-dot light-emitting diode with an internal power conversion efficiency of over 98% can be achieved.

Механизмы электронного транспорта в низкоразмерных полупроводниковых структурах: обзор

Background: Low-dimensional semiconductor structures such as quantum wells, wires, and dots have sparked widespread attention due to their distinct electron transport properties that differ dramatically from bulk materials. These characteristics are critical for advances in nanoscale electrical and optoelectronic devices. Objective: The article aims to summarize current knowledge of electron transport processes in low-dimensional semiconductor devices, focusing on the impact of reduced dimensionality on electron behaviour. Methods: A thorough literature analysis was carried out, emphasizing experimental and theoretical investigations that shed light on electron transport dynamics in quantum wells, wires, and dots. The analysis looked into scattering mechanisms, quantum confinement effects, and the significance of material composition and structure. Results: The findings show that quantum confinement produces discrete energy states that drastically change electron mobility and conductivity. Furthermore, electron scattering by phonons, contaminants, and surfaces is shown to be heavily impacted by decreased dimensionality, which either enhances or suppresses electron transport depending on the precise configuration and size of the structures. Conclusion: Low-dimensional semiconductor structures have complex electron transport behaviours that differ significantly from their bulk counterparts. Understanding these mechanisms is critical for designing and developing future electronic devices, and this overview serves as a starting point for ongoing articles on this technologically significant topic.

Топологические изоляторы в электронных и спинтронных устройствах

Background: Topological insulators (TIs) are materials with distinctive features, including insulating interiors and conducting surface states protected by time-reversal symmetry. These features make TIs extremely promising for electrical and spintronic device applications, where manipulating electron spin without charge transfer is advantageous. Objective: This study aims to investigate of TIs to improve the performance and efficiency of electrical and spintronic devices. We look at the special qualities of TIs that may be used to improve device functionality, such as reduced power consumption and higher operational speed. Methods: To investigate electron transport behaviour on the surfaces of different TIs, we used a mix of quantum mechanical models and experimental settings. Devices based on bismuth telluride (Bi2Te3) and thallium arsenide (TlAs) were built to test their performance in real-world applications. Results: TI devices showed considerable gains in spin transport efficiency and thermal stability compared to conventional materials. Spintronic devices based on TIs demonstrated a 50% reduction in energy usage and a 30% improvement in data processing speed. Conclusion: Including topological insulators in electrical and spintronic devices offers a promising path to more efficient and speedier technologies. Future research should concentrate on the scalable integration of TIs into commercial devices and the discovery of novel materials with topological insulating characteristic.

High salinity restrains microplastic transport and increases the risk of pollution in coastal wetlands

Microplastics (MPs) pollution in coastal wetlands has attracted global attention. However, few studies have focused on the effect of soil properties and structure on MP transport in coastal wetlands. Salinity is one of the most pivotal environmental factors and varies in coastal wetlands. Here, we conducted column experiments and employed fluorescent labeling combined with Derjaguin–Landau–Verwey–Overbeek (DLVO) theoretical calculations to reveal the vertical transport behavior of MPs. Specifically, we investigated the influence of five salinity levels (0, 0.035, 0.35, 3.5, and 35 PSU) on MP transport in different coastal wetlands soils and a sand through the X-ray photoelectron spectroscopy and nondestructive computed tomography technique. The results indicated that the migration capability of MPs in soils is significantly lower than in quartz sand, and that the migration capability varies depending on the soil type. This variability may be due to soil minerals and microporous structures providing numerous attachment sites for MPs and may be explained by the DLVO energy barrier of MP-Soil (6568–7767 KT) and MP-sand (5250 KT). Salinity plays a crucial role in modifying the chemical properties of pore water (i.e., zeta potential) as well as altering the soil elemental composition and pore structure. At 0 PSU, the maximum C/C0 of MPs through the sand, Soil 1, and Soil 2 transport columns were 37.86 ± 2.36 %, 23.96 ± 1.71 %, and 3.94 ± 0.68 %, respectively. When salinity increased to 3.5 PSU, MP mobility decreased by over 20 %. Additionally, a salinity of 35 PSU may alter the soil pore distribution, thereby changing water flow paths and velocities to constrain the migration of MPs in soils. These findings could provide valuable insights into understanding the environmental behavior and transport mechanisms of MPs, and lay a solid scientific basis for accurately simulating and predicting the fate of MPs in coastal wetland water–soil systems. We highlight the effect of salinity on the fate of MPs and the corresponding priority management of MPs risks under the background of global climate change.

The Role of Interface Band Alignment in Epitaxial SrTiO3/GaAs Heterojunctions.

Correlated oxides are known to have remarkable properties, with a range of electronic, magnetic, optoelectronic, and photonic functionalities. A key ingredient in realizing these properties into practical technology is the effective and scalable integration of oxides with conventional semiconductors. Unlocking the full spectrum of functionality requires atomically abrupt oxide-semiconductor interfaces and intimate knowledge of their potential landscape and charge transport. In this study, we investigated the electrical properties of epitaxial SrTiO3/GaAs heterostructures by examining the band alignment and transport behavior at the interface. We employ X-ray photoelectron spectroscopy (XPS) to measure the barriers for electrons and holes across the interface and, through them, explain the transport behavior for junctions with n- and p-type GaAs. We further show qualitative evidence of the strong photoresponse of these structures, illustrating the potential of these structures in optoelectronic devices. These results establish the fundamental groundwork for utilizing these interfaces toward new devices and define their design space.

Ideal quadratic nodal point in half-Heusler semimetal LaPtBi

The research focus on topological states in electronic systems has recently expanded from traditional linear dispersions to encompass higher-order dispersions. These higher-order dispersions exhibit unique physical properties, including high topological charge, exotic magnetoresponse, and novel transport behaviors. In this study, we employ first-principles calculations to propose the half-Heusler material LaPtBi as an ideal quadratic nodal point semimetal. Our comprehensive analysis of the band structure reveals an ideal nodal point located precisely at the Fermi level, exhibiting quadratic dispersion in all directions. This finding is supported by symmetry analysis and effective model arguments. Moreover, when the spin-orbit coupling effect is considered, the nodal point transitions from triple to quadruple degeneracy, while maintaining its quadratic dispersion. The material also features multiple prominent arc surface states originating from the nodal point, which are distinctly separated from the bulk bands. This separation facilitates experimental verification. Overall, LaPtBi, with its quadratic nodal point and advantageous properties, serves as an ideal platform for further research. The study of this material is expected to enhance our understanding of higher-order topological states in electronic systems, potentially driving future advancements in the field.

Real-time two-dimensional visualization reveals the transport mechanisms of biochar colloids in the presence of DOM in porous media

Biochar colloids (BCs) have attracted much attention globally, and their fate and transport in the subsurface are significantly influenced by soil-dissolved organic matter (DOM) in soil. This study utilized a real-time and non-invasive visualization system to reveal the transport and retention behavior of BCs in the presence of DOM in two-dimensional porous media. Results indicated that the presence of DOM enhanced the transport of BCs, due to its increased negative charge density and increased repulsion between BCs. The change in the particle size of the porous medium was also shown to affect the BCs transport in the porous media. Additionally, the negative charge of BCs shielded by high IS, the mobility of BCs decreased by 30.37 % from 1 mM to 50 mM. When the pH was increased from 5 to 9, the oxygen-containing functional groups of BCs and DOM were dissociated, and the mobility of BCs increased by 32.41 %. Through a simplified Double-Monod model, we fitted the breakthrough curves for BCs transport in porous media (R2 > 0.94). Moreover, the mechanism of different conditions on colloid clogging behavior was further elucidated through the DLVO theory. These findings extend the understanding of the environmental behavior of BCs in the presence of DOM derived from soil, enabling us to assess better and predict their environmental risks.

XCT images-based modeling for elucidating electrochemical inert phase-dependent multiscale electrode kinetic behaviors

The electrochemically inert phase (EIP) within the electrode is formed by the combination of carbon black and binder, characterized by a highly heterogeneous spatial distribution and structural morphology. This heterogeneity impairs electrode performance under varying discharge rates and temperatures. In this study, X-ray computed tomography is employed to image the original electrode. The resulting grayscale images are digitally processed to reveal the two-dimensional (2D) and three-dimensional (3D) features of the EIP morphology, thereby providing a design window to understand the influence of EIP morphology. The physical structure characterization indicates that, compared to bulk-like EIP (B-EIP), film-like EIP (F-EIP) tends to cover the active surface of the active material (AM), exacerbating the heterogeneity of the lithiation reactions within the electrode. The reduction in the AM active surface area correlates the state of lithiation (SOL) of particles with their active specific surface area (αa). At low temperatures, the temperature sensitivity of electrodes intensifies the risk of αa loss, promoting heterogeneous reaction transfer between particles. The Biot number (Bi) is used to evaluate the competing mechanisms between interfacial reactions and bulk diffusion within particles. In electrodes with a high EIP content, the reaction rate at the particle/electrolyte interface is accelerated, causing particle performance to be dominated by interfacial reactions. Finally, the electrochemistry and heat generation from the particle-level to the electrode-level in thicker electrodes are examined. It demonstrates that ion diffusion in the pore controls interfacial reactions and heat transport behavior. Aggregated high-flux reactions and localized hot spots exacerbate the heterogeneous degradation and side reactions within the electrode.