Transparent Organic Light-emitting Diodes Research Articles

Simultaneous Multifocal Plane Fourier Ptychographic Microscopy Utilizing a Standard RGB Camera.

Fourier ptychographic microscopy (FPM) is a computational imaging technology that can acquire high-resolution large-area images for applications ranging from biology to microelectronics. In this study, we utilize multifocal plane imaging to enhance the existing FPM technology. Using an RGB light emitting diode (LED) array to illuminate the sample, raw images are captured using a color camera. Then, exploiting the basic optical principle of wavelength-dependent focal length variation, three focal plane images are extracted from the raw image through simple R, G, and B channel separation. Herein, a single aspherical lens with a numerical aperture (NA) of 0.15 was used as the objective lens, and the illumination NA used for FPM image reconstruction was 0.08. Therefore, simultaneous multifocal plane FPM with a synthetic NA of 0.23 was achieved. The multifocal imaging performance of the enhanced FPM system was then evaluated by inspecting a transparent organic light-emitting diode (OLED) sample. The FPM system was able to simultaneously inspect the individual OLED pixels as well as the surface of the encapsulating glass substrate by separating R, G, and B channel images from the raw image, which was taken in one shot.

ZnO/Ag/ZnO multilayers as an n-type transparent conducting electrode for transparent organic light-emitting diodes

Alternative transparent conducting electrodes (TCEs) have gained significant attention in recent decades in an effort to replace costly indium-tin oxide (ITO) in organic optoelectronic devices. For example, state-of-the-art top-emitting and transparent organic light-emitting diodes (OLEDs) in the display industry require a transparent or semitransparent cathode for electron injection. Current OLED display technology employs ultrathin metallic (typically Mg:Ag) layers as semitransparent cathodes. However, recent studies have shown that metal oxide/metal/metal oxide multilayers can perform better optically and offer improved stability compared to semitransparent metal cathodes. Deposition of these multilayers with minimal damage to the underlying organic emissive layer is imperative. Here, we investigate a ZnO/Ag/ZnO TCE multilayer TCE deposited under mild sputtering conditions that are safe for the emissive layer. We demonstrate ∼ 85 % transparent electrodes with a sheet resistance of 1.47 Ω/sq, which is more conductive than the industry standard, ITO. We also integrate the multilayer TCE as the cathode in a transparent OLED device built on ITO, demonstrating the compatibility of this TCE with the existing OLED technology.

Transparent Micromesh Patterned OLED Fabricated Using the In-Situ Deposition Process of an Ultrathin Mg:Ag Interconnection Layer.

TOLEDs (transparent organic light-emitting diodes) have emerged as one of the most promising ways to implement next-generation display form factors. Transparent OLEDs can provide new added value to HMDs (head mounted displays), automobiles, smart windows, mobile devices, TVs, etc. through their transparency, which allows objects to be seen from the other side. However, previous approaches using metal thin films have faced limitations in attempting to achieve high transmittance. In this study, TOLEDs were designed using a new cathode structure consisting of an interlayer and an emission pattern layer, and these layers connect the light-emitting part and the nonemitting part by themselves without requiring the use of another interconnection layer. This structure, which was intended to improve transmittance, was implemented by applying an in situ evaporation process that adds only one shadow mask without the need to use any difficult methods. Through this process, the optimal condition was found when the light-emitting part was deposited in a mesh pattern with a length of 120 μm and a width of 80 μm, in which case the transmittance of the TOLED improved by up to 83% while maintaining electro-optical performance. It was also confirmed that this new structure can be applied to flexible devices.

Flexible Embedded Metal Meshes by Sputter-Free Crack Lithography for Transparent Electrodes and Electromagnetic Interference Shielding.

A facile and novel fabrication method is demonstrated for creating flexible poly(ethylene terephthalate) (PET)-embedded silver meshes using crack lithography, reactive ion etching (RIE), and reactive silver ink. The crack width and spacing in a waterborne acrylic emulsion polymer are controlled by the thickness of the polymer and the applied stress due to heating and evaporation. Our innovative fabrication technique eliminates the need for sputtering and ensures stronger adhesion of the metal meshes to the PET substrate. Crack trench depths over 5 μm and line widths under 5 μm have been achieved. As a transparent electrode, our flexible embedded Ag meshes exhibit a visible transmission of 91.3% and sheet resistance of 0.54 Ω/sq as well as 93.7% and 1.4 Ω/sq. This performance corresponds to figures of merit (σDC/σOP) of 7500 and 4070, respectively. For transparent electromagnetic interference (EMI) shielding, the metal meshes achieve a shielding efficiency (SE) of 42 dB with 91.3% visible transmission and an EMI SE of 37.4 dB with 93.7% visible transmission. We demonstrate the highest transparent electrode performance of crack lithography approaches in the literature and the highest flexible transparent EMI shielding performance of all fabrication approaches in the literature. These metal meshes may have applications in transparent electrodes, EMI shielding, solar cells, and organic light-emitting diodes.

Highly Transparent Red Organic Light-Emitting Diodes with AZO/Ag/AZO Multilayer Electrode.

Free-form factor optoelectronics is becoming more important for various applications. Specifically, flexible and transparent optoelectronics offers the potential to be adopted in wearable devices in displays, solar cells, or biomedical applications. However, current transparent electrodes are limited in conductivity and flexibility. This study aims to address these challenges and explore potential solutions. For the next-generation transparent conductive electrode, Al-doped zinc oxide (AZO) and silver (AZO/Ag/AZO) deposited by in-line magnetron sputtering without thermal treatment was investigated, and this transparent electrode was used as a transparent organic light-emitting diode (OLED) anode to maximize the transparency characteristics. The experiment and simulation involved adjusting the thickness of Ag and AZO and OLED structure to enhance the transmittance and device performance. The AZO/Ag/AZO with Ag of 12 nm and AZO of 32 nm thickness achieved the results of the highest figure of merit (FOM) (Φ550 = 4.65 mΩ-1) and lowest roughness. The full structure of transparent OLED (TrOLED) with AZO/Ag/AZO anode and Mg:Ag cathode reached 64.84% transmittance at 550 nm, and 300 cd/m2 at about 4 V. The results demonstrate the feasibility of adopting flexible substrates, such as PET, without the need for thermal treatment. This research provides valuable insights into the development of transparent and flexible electronic devices.

Machine learning-assisted high-throughput screening of transparent organic light-emitting diode anode materials

A target-driven material design framework for the rapid work function prediction of AB-type 2D nanomaterials is proposed to accelerate the discovery of transparent OLED anode materials.

A Naturalistic Setup for Presenting Real People and Live Actions in Experimental Psychology and Cognitive Neuroscience Studies.

Perception of others' actions is crucial for survival, interaction, and communication. Despite decades of cognitive neuroscience research dedicated to understanding the perception of actions, we are still far away from developing a neurally inspired computer vision system that approaches human action perception. A major challenge is that actions in the real world consist of temporally unfolding events in space that happen "here and now" and are actable. In contrast, visual perception and cognitive neuroscience research to date have largely studied action perception through 2D displays (e.g., images or videos) that lack the presence of actors in space and time, hence these displays are limited in affording actability. Despite the growing body of knowledge in the field, these challenges must be overcome for a better understanding of the fundamental mechanisms of the perception of others' actions in the real world. The aim of this study is to introduce a novel setup to conduct naturalistic laboratory experiments with live actors in scenarios that approximate real-world settings. The core element of the setup used in this study is a transparent organic light-emitting diode (OLED) screen through which participants can watch the live actions of a physically present actor while the timing of their presentation is precisely controlled. In this work, this setup was tested in a behavioral experiment. We believe that the setup will help researchers reveal fundamental and previously inaccessible cognitive and neural mechanisms of action perception and will be a foundation for future studies investigating social perception and cognition in naturalistic settings.

Transparent and conformable organic light-emitting diodes for skin-attachable invisible displays

A skin-attachable invisible display offers a new opportunity in next-generation electronic application, such as smart contact lenses, human-machine health monitoring interfaces and soft electronic skins. In response to this trend, transparent organic light-emitting diodes (OLEDs) offer enormous advantages in future skin-attachable invisible displays, including excellent flexibility and superior efficiency. Although several approaches reported recently attempt to manufacture transparent and flexible OLEDs, it is still a tremendous challenge to simultaneously meet the desired optical and mechanical properties. Herein, we develop a feasible strategy to achieve transparent and conformable OLEDs (TC-OLEDs). Benefiting from the intrinsic high transparency and outstanding deformability of our electrodes, the whole device shows high transmittance up to 85.0% at a wavelength of 400 nm and high mechanical flexibility with skin-like conformability. More strikingly, the resulting device maintains excellent photoelectric performance with a maximum current efficiency (CE) of 56.8 cd/A and external quantum efficiency (EQE) of 17.1%. Based on the versatile TC-OLEDs, we also report an all-organic and all-conformable invisible display driven by transparent and conformable organic thin film transistors (TC-OTFTs) for the first time. This work offers a meaningful guidance for the construction of TC-OLEDs and the development of skin-attachable invisible displays.

Blue Transparent OLEDs with High Stability and Transmittance for Modulating Sleep Disorders (Adv. Mater. Interfaces 11/2023)

Blue Transparent Organic Light-Emitting Diodes In article number 2202443, Kyung-Cheol Choi and co-workers develop high-transmittance and stable blue transparent organic light-emitting diodes (TrOLEDs) using optimized dielectric-metal-dielectric (DMD) electrodes with silver, seed, and capping layers. They also demonstrated the TrOLEDs on glasses for visual stimulus devices and proposed an animal experimental protocol for modulating NREM sleep duration with blue light stimulation. The proposed blue TrOLEDs could be a practical and convenient solution for modulating sleep disorders in a wearable form factor.

Blue Transparent OLEDs with High Stability and Transmittance for Modulating Sleep Disorders

AbstractOptoelectronics devices utilizing organic light‐emitting diodes (OLEDs) are emerging as new platforms for healthcare applications. In particular, wearable optoelectronics such as visual stimulus systems offer a distinctive advantage to intervene in and improve sleep disorders. In this study, two improvements are proposed for transparent OLEDs (TrOLEDs) that will be critical for visual applications. First, zinc sulfide with high surface energy and a high refractive index is explored as a seed and capping layer. An ultra‐thin silver cathode of 8 nm is demonstrated to be feasible in TrOLEDs, and luminous transmittance of 91% is achieved. Second, in general, achieving the operational stability of TrOLEDs with high transmittance is challenging due to the vulnerability of thin electrodes. By introducing a doping process to the electron transport layer, a lifetime comparable to that of control OLEDs with thick cathodes (>90%) is secured. Last, a preclinical model using blue light is proposed to modulate sleep patterns. Melanopsin is stimulated at the highest level of sleep desire, reducing non‐rapid eye movement sleep duration in mice by up to 14%. Based on these results, the proposed TrOLEDs are promising candidates for modulating sleep disorders such as insomnia and narcolepsy–cataplexy with the convenience of wearable form factors.

Highly transparent and stretchable organic light-emitting diodes with ultrathin metal films as double electrodes

Organic light-emitting diodes (OLEDs) with both high transparency and stretchability are of importance for next-generation wearable and deformable displays, which have not been studied in depth. In this work, highly flexible and transparent OLEDs (TrOLEDs) are achieved by using ultrathin metal films as both anode and cathode to fabricate stretchable TrOLEDs (S-TrOLEDs) based on a wrinkling strategy. The TrOLEDs show a transmittance value of 73% at 550 nm and a negligible micro-cavity effect with near Lambertian emission characteristics at a wide angle of view. Furthermore, almost symmetric electroluminescent properties are obtained from the anode and cathode, which is important for dual-side display. Two-dimensional S-TrOLEDs with random wrinkles show 50% stretchability and retain 80% of their initial luminance after 200 cycles of stretching. The effect of random wrinkles on the transmittance of S-TrOLEDs is researched and the transparency losses of the device are analyzed deeply. We hope that this work is meaningful for promoting the development of S-TrOLEDs in the display industries.

Hybrid-Type Transparent Organic Light Emitting Diode with High Contrast Using Switchable Windows

Transparent organic light emitting diode (OLED) display is one of the most promising devices among next-generation information displays because of beneficial characteristics, such as self-emissive and optically clear properties. Nevertheless, in conventional transparent OLED display devices, there are serious intrinsic problems in terms of the transmittance in the dark state because of empty windows in the cell, so the contrast ratio of the transparent OLED display would be deteriorated even though it can exhibit excellent bright state. In general, the transparent mode using the OLED device applies an empty area in each pixel because an emitting device could never reveal the background image, so the transparent OLED should contain the empty area in the pixel for transparent images. This may cause the optical degradation in the dark state. To solve this problem, we propose hybrid-type transparent OLED display modes that apply a liquid crystal (LC) to the transparent window part of the empty space. In this paper, we applied two dichroic LC modes- which use an electrically controlled birefringence (ECB) mode (Heilmeier type) for the polarized mode and a cholesteric LC mode (Guest-Host mode) for the non-polarized mode-to the empty area. In each hybrid mode, we have observed optical performance, including the transmittance in the dark/bright state, contrast ratio and response time as a function of cell parameters. As a result, we confirmed that the dark state and the contrast ratio could be improved by applying the proposed modes without serious decay of the transmittance in the bright state.

RGB‐Color Textile‐Based Flexible and Transparent OLEDs Considering Aesthetics (Adv. Mater. Interfaces 2/2023)

Textile Displays In article number 2202114, Junwoo Lee, Kyung-Cheol Choi, and colleagues develop textile-based RGB-color transparent organic light-emitting diodes (trOLEDs) with high opto-electronic performance and mechanical reliability to improve the aesthetics of textile displays. In addition, by presenting a new optical analysis method that considers the special characteristics of textile-based trOLEDs, it is demonstrated that flexible optimization of textile trOLEDs in terms of aesthetic factors is possible.

Design and evaluation of thermally conductive sheet structure to enhance the thermal stability of transparent OLED displays

In transparent organic light-emitting diode (OLED) displays, both optical and thermal properties strongly affect stable performance in various environmental conditions. Though many previous studies have focused on improving the thermal conductivity of the transparent material itself, the current value of 2.5 W/mK [J. Mater. Chem. C 4, 9697 (2016)JMCCCX2050-753410.1039/C6TC03318K] may not be enough to ensure reliable performance for transparent OLED displays. In this study, we aim to introduce a novel sheet structure based on line patterned thermally conductive material embedded in a transparent polymer sheet. After designing and fabricating the optimized sheet structure, its optical and thermal characteristics were evaluated experimentally. Finally, the thermal conductivity of the developed transparent sheet was measured to be 4.35 W/mK in the louver direction with a transmittance of 75%, improved color uniformity and reduced temperature deviation in the transparent OLED displays.

Design and Evaluation of Thermal Conductive Sheet Structure for Enhancing Thermal Stability of Transparent OLED

Design and Evaluation of Thermal Conductive Sheet Structure for Enhancing Thermal Stability of Transparent OLED

Oxygen Plasma Treatment of Rear Multilayered Graphene: A Potential Top Electrode for Transparent Organic Light-Emitting Diodes.

One of the core technologies of transparent organic light-emitting diodes (TOLEDs) is to develop an optically transparent and high electrical conductivity electrode so that light generated inside the device can efficiently escape into the air through the electrodes. We recently reported in TOLED research that two flipping processes are required to dry-transfer the front multilayered graphene (MLG) to the top electrode, while the rear MLG requires one dry transfer process. As the transfer process increases, the electrical properties of graphene deteriorate due to physical damage and contamination by impurities. At the charge-injecting layer/MLG interface constituting the TOLED, the rear MLG electrode has significantly lower charge injection characteristics than the front MLG electrode, so it is very important to improve the electrical characteristics of the rear MLG. In this paper, we report that the light-emitting properties of the TOLED are improved when an oxygen plasma-treated rear MLG is used as the top electrode, as compared with untreated rear MLG. In addition, the fabricated device exhibits a transmittance of 74–75% at the maximum electroluminescence wavelength, and the uniformity of transmittance and reflectance is more constant at a wavelength of 400–700 nm than in a device with a metal electrode. Finally, near-edge X-ray absorption fine structure spectroscopic analysis proves that the MLG crystallinity is improved with the removal of impurities on the surface after oxygen plasma treatment.

Designing a solution-processable electron transport layer for transparent organic light-emitting diode

In this work, the extensively used opaque metal cathodes of the conventionally structured OLEDs were replaced with the widely used transparent electrode indium tin oxide (ITO) for solution-processed transparent organic light-emitting diode (T-OLED). A new solution-processable electron transport layer (ETL), aside from facilitating the efficient injection of electrons into the T-OLED, protected the organic emission layer (EML) of the T-OLED against the plasma damage during top ITO cathode sputter deposition. The newly designed solution-processed ETL was the composite of the zinc oxide nanoparticles (ZnO-NPs), and cesium carbonate-doped ethoxylated polyethyleneimine (d-PEIE) with the semi-hydrophilic poly (methyl methacrylate) (PMMA) interlayer coated on the EML insured the good wettability and contact of the hydrophilic ETL with the hydrophobic EML. The solution-processed T-OLED emitted the total maximum luminance of about 2417 cd/m 2 (bottom side emission at 1455 cd/m 2 and top emission at 962 cd/m 2 ), total maximum current efficiency at 3.12 cd/A (bottom and top emissions at about 1.78 and 1.34 cd/A, respectively), and total maximum power efficiency at 1.64 l m/W (bottom and top emissions at about 0.95 and 0.69 l m/W, respectively) while having a very high optical transmittance of around 85% at 550 nm light wavelength. • The solution-processed T-OLED with newly designed composite ETL was fabricated. • The electrion injection efficiency and plasma barrier effect of the composite ETL was studied. • The composite ETL had the uniform morphology with even distribution of ZnO in the PEIE matrix. • The T-OLED with composite ETL showed excellent blue light emission.

Suppressing surface plasmon losses to improve the efficiency of blue organic light-emitting diodes using the plasmonic quasi-bandgap phenomenon

It is a persistent problem in organic light-emitting diode (OLED) display devices that the efficiency of blue-light source materials is lower than that of green- or red-light source materials. To address this problem, numerous studies have investigated blue-light-emitting materials. However, ensuring the reliability of the blue-light-emitting materials has been difficult in most studies. In this study, electrodes using asymmetric dielectric/metal/dielectric structures with plasmonic quasi-bandgap characteristics were developed to achieve a highly efficient blue fluorescent OLED. The electrodes were applied in a microcavity OLED and a transparent OLED. Using the developed electrode in fabricated OLED devices not only maximized the cavity resonance effect and transparency, but also preserved the advantage of the work function of the metal in terms of electrical properties, with high device stability. The approach also minimized losses caused by surface plasmon polaritons, which is a blind spot in the optical aspect of metal electrodes, resulting in improved light extraction efficiency.

A highly transparent laminated composite cathode for organic light-emitting diodes

Transparent conductive electrodes are one of the important components of organic optoelectronic devices. Mg:Ag alloys have been widely used as a semi-transparent cathode for top-emitting organic light-emitting diodes (OLEDs) or transparent OLEDs (TrOLEDs) due to their high conductivity and relatively low work function. However, their low transmittance makes the light-extraction efficiency to be comparatively low. In this study, a highly transparent (84.6% in the visible light range), conductive, laminated cathode with the structure of ZnO/Mg:Ag/ZnO was fabricated via atomic layer deposition (ALD). ALD-deposited ZnO is used to protect the vulnerable ultrathin Mg:Ag-alloy layer, while preserving its low work function for the entire structure. In particular, the bottom ZnO layer is used as an ETL, which can provide reasonable energy alignment between the cathode layer and the emission layer and prevent metal particles from penetrating into the underlying organic layer. The top-emission OLED, which is prepared in this study by using the laminated cathode, showed an 85.8% increase in brightness, with a current density of 11.2 mA/cm3 at 4.0 V, which is an ultra-low voltage compared with devices made with Mg:Ag cathodes. In addition, the total luminance of TrOLEDs increases 34.4% compared with devices using Mg:Ag cathodes. Furthermore, the average transmittance of the device was still as high as 77.19% for visible light.

Flashlight-Induced Strong Self-Adhesive Surface on a Nanowire-Impregnated Transparent Conductive Film.

The flashlight annealing process has been widely used in the field of flexible and printed electronics because it can instantly induce chemical and structural modifications over a large area on an electronic functional layer in a subsecond time range. In this study, for the first time, we explored a straightforward method to develop strong self-adhesion on a metal nanowire-based flexible and transparent conductive film via flashlight irradiation. Nanowire interlocking, for strong mechanical bonding at the interface between the nanowires and polyamide film, was achieved by simple hot pressing. Then, by irradiating the nanowire-impregnated film with a flashlight, several events such as interdiffusion and melting of surface polymers could be induced along with morphological changes leading to an increase in the film surface area. As a result, the surface of the fabricated film exhibited strong interfacial interactions while forming intimate contact with the heterogeneous surfaces of other objects, thereby becoming strongly self-adhesive. This readily achievable, self-attachable, flexible, and transparent electrode allowed the self-interconnection of a light-emitting diode chip, and it was also compatible for various applications, such as defogging windows and transparent organic light-emitting diodes.