The presence of sulfur dioxide on the trailing hemisphere of Europa’s surface is well-established, and both its presence and its chemistry are influenced by sulfur ion implantation. Particle irradiation is known to be a significant radiolysis source, particularly on the trailing surface, which is subject to particles in Jupiter’s plasma torus. Photochemistry driven by solar ultraviolet (UV) photons is also significant. To date, most studies have investigated the effects of vacuum UV radiation, while photochemistry at longer wavelengths is less well-studied. This work investigates chemical changes in thin, cryogenic films of SO2/H2O at temperatures and pressures relevant to Europa’s surface when subjected to temperature changes and UV radiation at 147, 206, 254, and 284 nm. Spectra were collected in both the mid-infrared range and the UV range, which elucidates electronic transitions that are less diagnostic but perhaps more applicable to reflectance spectra of solar system bodies. These experiments show irreversible red shifting of the B̃ ← X̃ absorption peak upon heating likely as a result of crystallization and/or thermal chemical reactions. Further, photons with wavelengths up to 284 nm are shown to induce significant chemistry in SO2/H2O mixtures. This in conjunction with the increased solar flux compared to more energetic wavelengths and the strong C̃ ← X̃ and B̃ ← X̃ absorption bands in SO2 suggests that far-UV radiation plays a significant role in the sulfur cycle on Europa.
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