Total Suspended Particulate Concentrations Research Articles

Uptake, accumulation, and translocation of organophosphate esters and brominated flame retardants in water hyacinth (Eichhornia crassipes): A field study

Mechanisms underlying the plant uptake, accumulation, and translocation of organophosphate esters (OPEs) and brominated flame retardants (BFRs) in field environments remain ambiguous. To better understand these processes, we selected a typically polluted river with steady flow and rampant water hyacinth (Eichhornia crassipes) and investigated 25 OPEs and 23 BFRs in 24 sets of matched water–plant samples. Both OPEs and BFRs showed high or ultra-high levels in field water hyacinths, statistically positive water–plant/root concentration correlations, and dominant distributions in the roots. Passive root uptake was the dominant route for OPEs and BFRs to enter the water hyacinth. Both OPEs and BFRs in water hyacinth exhibited acropetal translocation from the root and possible basipetal translocation from the leaf. The accumulation and translocation of OPEs in water hyacinth were significantly affected by their substituents and structures, including the chlorination degree, alkyl chain length, side chain, and methylation degree of aryl-substituted OPEs. The translocation of BFRs in water hyacinth also showed close association with their bromination degree, but their accumulation in roots showed anomaly, indicating possible transformations. Overall, the enrichment and behavior of OPEs and BFRs in water hyacinth seemed to be mainly controlled by physicochemical parameters. OPE/BFR concentrations in total suspended particulate (TSP), TSP-associated organic carbon content, TSP concentration, and plant biomass all showed significant effects on their root accumulation and translocations in water hyacinth. This study provides rare field evidences and novel insights into the basipetal translocation of OPEs and BFRs in plants.

The impact of heavy metals that released from vehicles exhausts on some biochemical parameters in Eucalyptus and Ziziphus plants in street intersections of Baghdad city

The air pollution by vehicles exhaust is consider the most risk environmental problems, especially when precipitate on soil surface and transport to the plants and entering the food chain. so that, the current study was carried out to determine the impacts of air pollution on the plants growth in traffic intersections, the study was carried out in Baghdad city, identified two regions for each of the both sides of the Rusafa and Karkh by two main sites for each region, as well as, the secondary stations in each site. the heavy metals and total suspended particles concentrations were determined in the filter paper that suffer the pollution air for 30 min. in specific sites using sniffer device. The concentrations decrease of some pollutants was noticed more than to the national and global permitted limits and the summer was the highest season in pollution during study period. Eucalyptus and Ziziphus spina Christi plants was chosen to evaluating the impacts of pollution on the plants because its being of the most common and the evergreen trees in the Baghdad s' streets. Primary metabolites content in plants was measured as total chlorophyll recorded a height concentration in August(98.631mg/gm) in Eucalyptus leaves ,while the total protein content reached to maximum concentration (26.101 mg/gm) in both plants, either total carbohydrate content reached to (88ppm) in Eucalyptus leaves and (74.62ppm) in Ziziphus leaves and noticed that , the increase in concentration of pollutants affected on the protein and carbohydrate content. Seven phenolic compounds was diagnosed being one of the main secondary compounds of metabolism , the increase in total phenolic content was recorded in the region that have a high concentration of carbon dioxide was reach to (6699.88ppm) in Al-Mansour(3) samples compared to the control samples was(2388.87ppm). the heavy metals concentrations in the leaves of eucalyptus and ziziphus arranged from more to less as steady regime throughout the study period in the following order: iron > zinc > copper > lead .

Operational parameters impact on spatial and temporal distribution and multifractal characteristics of particulate matter concentration under the sink effect

The influences of different factors on spatial and temporal mass transfer mechanism and dynamic characteristics of particulate matter (PM) under the sink effect are not clear. The objective of this study was to quantitatively analyze the influences of operational parameters on spatial and temporal distribution and multifractal characteristics of indoor suspended PM concentration under the sink effect. Results showed that with the increase of the applied voltage of the purification device, the reverse increase processes of PM1 and PM2.5 concentrations were progressively attenuated, and PM10 and total suspended particulates (TSP) concentrations decreased clearly. The dynamic evolution processes of the PM concentration series all presented strong persistence and obeyed the scale-invariant power-law statistical distributions. The positive correlation of the PM concentration series between five distances increased with the increase of applied voltage. This study can provide a reference basis for further refining the PM purification theory system under the sink effect.

Factors affecting the levels and pathways of atmospheric brominated flame retardant uptake by humans in different weather conditions

The health risks posed by atmospheric brominated flame retardants (BFRs) have been widely studied, but there remains a lack of clarity about exposure differences between clear days and haze days. We sampled the total suspended particle (TSP) and gaseous BFRs on clear days in summer, clear days in winter, and haze days in winter in Harbin, China, to investigate the variations in the concentrations and intakes (dermal and inhalation) in the different weather conditions. The concentrations of atmospheric BFRs were highest on haze days in winter (185 pg/m3), followed by clear days in summer (158 pg/m3), and clear days in winter (79.2 pg/m3), and these concentrations were significantly correlated with the concentrations of TSP. The human intake in the different weather conditions followed the pattern of the BFR concentrations, and the human intake of atmospheric BFRs was dominated by inhalation. A comparison of the BFR levels showed that the human intake of gaseous and particulate BFRs varied in the three weather conditions and that the inhalation intake, but not the dermal intake, was influenced under high concentrations of gaseous BFRs with low molecular weight.

The study on influencing factors of airflow in laboratory fume hood

This study investigates the influence of the side wind flowing directly from different indoor environments on the airflow of the laboratory fume hood (LFH). When an LFH is used to discharge the harmful from the laboratory, the side wind can affect the airflow of the LFH, which is likely to cause the leakage of harmful fumes. In this study, incense was used to simulate harmful fumes, sampling and analysis of the total suspended particulate concentrations were performed in an LFH under different side wind conditions with or without air conditioning, operator, laboratory door open, and electric fan when the fume hood sash (FHS) is at the top, middle, and bottom positions, respectively. A laser pen and hot-wire anemometer are employed to demonstrate the airflow of the smoke and wind speed in different indoor environmental conditions. The experimental results reveal that the airflow field and distribution of harmful fumes in the LFH can be changed according to the different heights of the FHS and changes in the external airflow. Therefore, when using the LFH, the influence of the external airflow should be reduced, and the LFH should be operated for a few minutes before switching it off.

Longitudinal Study on the Association between Ambient Polycyclic Aromatic Hydrocarbons and Nasal Symptoms in Adult Japanese

The relationship between exposure to polycyclic aromatic hydrocarbons and nasal symptoms currently remains unclear. Therefore, we herein examine this relationship in 51 adults living in Ishikawa prefecture, Japan, and conducted a 2 month follow-up survey on these participants. All participants were asked to record daily nasal symptoms in an allergy diary during the study period between 1 April to 31 May 2020. We collected air pollutant samples during the study period and determined the concentrations of PAHs and total suspended particulates by high-performance liquid chromatography. Sulfur dioxide and nitrogen dioxide concentrations were obtained through the Atmospheric Environmental Regional Observation System. We used generalized estimating equations to analyze the association between pollutant and nasal symptoms. After adjustment for confounding factors, the B values of fluoranthene, pyrene, and Benzo[k]fluoranthene were 2.389 (p = 0.026), 3.744 (p = 0.022) and 9.604 (p = 0.041), respectively, with a one-day lag. In contrast, the B value of indeno[1,2,3-cd]pyrene was −6.664 (p = 0.013) with no lag. Collectively, these results suggest ambient PAHs such as Flt, Pyr, and BkF were associated with nasal symptoms in adults. Further studies are needed to elucidate the mechanisms contributing to the relationships between specific PAHs and nasal symptoms.

Assessment the impact of different fuels used in cement industry on pollutant emissions and ambient air quality: a case study in Egypt

This study aims to assess the impact of using different fuels in Egyptian Titan Alexandria Portland Cement Company on emissions and concentrations of pollutants (Total suspended particles (TSP), nitrogen dioxide (NO2‎), and sulfur dioxide (SO2)) and their influence on ambient air quality during the period 2014–2020 using AERMOD dispersion model. The results showed that changing the fuel from natural gas in 2014 to coal mixed with alternative fuels (Tire-Derived Fuel (TDF), Dried Sewage Sludge (DSS), and Refuse Derived Fuels (RDF)) in 2015–2020 caused fluctuating variations in pollutant emissions and concentrations. The highest and lowest maximum concentrations of TSP occurred in 2017 and 2014 respectively, where the TSP is positively correlated with coal, RDF, and DSS and negatively correlated with natural gas, diesel, and TDF. Also, the lowest and highest maximum NO2 concentrations were detected in 2020 and 2016 followed by 2017 respectively, where NO2 is positively correlated with DSS and negatively correlated with TDF and varies with diesel, coal, and RDF. Moreover, the maximum concentrations of SO2 were the lowest in 2018 and highest in 2016 followed by 2017 because of its considerable positive correlation with natural gas and DSS and negative correlation with RDF, TDF, and coal. Generally, it was found that increasing the percentage of TDF and RDF with decreasing the percentage of DSS, diesel, and coal will reduce pollutant emissions and concentrations and enhance ambient air quality.

Carbonaceous aerosol transport from the Indo-Gangetic Plain to the Himalayas: Carbon isotope evidence and light absorption characteristics

The Indo-Gangetic Plain (IGP) is a major regional and global emitter of atmospheric pollutants, which adversely affect surrounding areas such as the Himalayas. We present a comprehensive dataset on carbonaceous aerosol (CA) composition, radiocarbon (Δ14C) -based source apportionment, and light absorption of total suspended particle (TSP) samples collected over a 3-year period from high-altitude Jomsom in the central Himalayas. The 3-year mean TSP, organic carbon (OC), and elemental carbon (EC) concentrations were 92.0 ± 28.6, 9.74 ± 6.31, and 2.02 ± 1.35 μg m−3, respectively, with the highest concentrations observed during the pre-monsoon season, followed by the post-monsoon, winter, and monsoon seasons. The Δ14C analysis revealed that the contribution of fossil fuel combustion (ffossil) to EC was 47.9% ± 11.5%, which is consistent with observations in urban and remote regions in South Asia and attests that EC likely arrives in Jomsom from upwind IGP sources via long-range transport. In addition, the lowest ffossil (38.7% ± 13.3%) was observed in winter, indicating large contributions in this season from local biomass burning. The mass absorption cross-section of EC (MACEC: 8.27 ± 1.76 m2/g) and water-soluble organic carbon (MACWSOC: 0.98 ± 0.45 m2/g) were slightly higher and lower than those reported in urban regions, respectively, indicating that CA undergo an aging process. Organic aerosol coating during transport and variation of biomass burning probably led to the seasonal variation in MAC of two components. Overall, WSOC contributed considerably to the light absorption (11.1% ± 4.23%) of EC. The findings suggest that to protect glaciers of the Himalayas from pollution-related melting, it is essential to mitigate emissions from the IGP.

Seasonal Variations in Concentrations and Chemical Compositions of TSP near a Bulk Material Storage Site for a Steel Plant

The concentrations of total suspended particles (TSPs) on four buildings near a steel plant’s bulk material storage site for iron ore, coal, limestone, and sinter were evaluated for summer and winter, where the concentrations were 58 (17–55) μg m−3 and 125 (108–155) μg m−3, respectively. A multivariate regression analysis of meteorological parameters with TSP concentrations indicates that temperature, wind speed, and frequency of rainfall are potential predictors of TSP concentrations, where the respective p values for the model are p = 0.005, p = 0.049, and p = 0.046. The strong correlation between usual co-pollutants, CO, NO2, and NOX with TSP concentrations, as indicated by the Pearson correlation values of 0.87, 0.86, and 0.77, respectively, implies substantial pollution from mobile sources. The weak correlation of SO2 with TSP concentrations rules out a significant pollution contribution from power plants. The speciation of TSPs in winter showed the percentage proportions of water-soluble ions, metal elements, and carbon content in winter as 60%, 15%, and 25%, while in summer, they were 68%, 14%, and 18%, respectively. Water-soluble ions were the most significant composition for both seasons, where the predominant species in summer and winter are SO42− and NO3−, respectively. In the TSP metal elements profile, the proportion of natural origin ones exceeded those from anthropogenic sources. The health risk assessment indicates a significant cancer risk posed by chromium, while that posed by other metal elements including Co, Ni, As, and Pb are insignificant. Additionally, all metal elements’ chronic daily occupational exposure levels were below the reference doses except for Cu and Zn. Insights from this investigation can inform decisions on the design of the TSP-capturing mechanism. Specifically, water sprays to capture the water-soluble portion would substantially reduce the amplified concentrations of TSPs, especially in winter.

PAH atmospheric log(KP) values in Great Lakes samples are related to black carbon levels near each site

Many semi-volatile organic pollutants are present in the atmosphere both in the vapor and particle phases. About 50 years ago, a partition coefficient (KP) was defined as the compound's concentration in the particle phase (Cpart, in ng/m3 or pg/m3) divided by its concentration in the vapor phase (Cvapor, also in ng/m3 or pg/m3) divided by the atmospheric concentration of total suspended particles (TSP, in μg/m3) or, more recently, by the concentration of particulate matter with aerodynamic diameters less than 2.5 μm (PM2.5, also in μg/m3). The original point of this term was to account for surface adsorption of pollutants to the particles, but over the years it has become apparent that absorption, particularly to black carbon (BC, also known as elemental carbon) in the particles, may also be important. This study investigates the importance of this particle term using about 3000 polycyclic aromatic hydrocarbon (PAH) concentrations measured from 1997 to 2018 (inclusive) in 24-h samples collected once every 12 days at five sites on the shores of the North American Great Lakes and using U.S. Environmental Protection Agency PM2.5 concentrations at the same sites. Analyses of variance of the annual mean log(KP) values show significant differences for all six compounds among the five sites, which we attribute to the composition of the particles at the five sites. For example, the particles from the urban sites are likely to have higher black carbon levels compared to those from the more rural and remote sites. With an additional term for black carbon in these samples, these new ratios are similar across sites for a given compound. These results suggest that a black carbon term is useful and potentially important.

Graduation Towers Impact on the Concentration and Chemical Composition of Ambient Aerosol: A Case Study from Wieliczka Salt Mine in Poland

The aim of the research was to determine the effect of graduation towers on the aerosol concentration and its composition not only in the vicinity of the graduation tower itself, but also at a distance from it, on the example of the brine graduation tower in the Wieliczka Salt Mine health resort. Two measurement sites were selected for the research, one located inside the graduation tower and the other at the guard booth—at a considerable distance from the graduation tower. Total suspended particulate (TSP) and PM10 (particulate matter with a diameter that does not exceed 10 µm) samples were taken simultaneously using the aspiration method. The collected samples were subjected to analyses of TSP and PM10 concentrations, the content of organic carbon (OC), elemental carbon (EC) and selected ions. It was confirmed that the composition of the aerosol in the Wieliczka Salt Mine significantly differs from the typical aerosol composition in inland locations and is similar to the aerosol composition in coastal zones. The comparison of the aerosol composition at both measuring sites clearly indicates a very favorable influence of the brine graduation tower on the composition of the atmospheric aerosol, even at a certain distance from it.

The removal of atmospheric aerosols in a heavy industrial coastal city in China with frequent rainfall

Rapid urbanization and heavy industrialization generally result in serious aerosol pollution. Contrary to this conventional wisdom, Zhanjiang, one industrial city in the southernmost point of the Chinese mainland, is not accompanied by aerosol pollution and its air quality index always ranks high compared to other cities in China. To investigate this contradiction, 72-hour total suspended particles (TSPs) and water-soluble inorganic ions (WSIIs; including Mg2+, Ca2+, K+, Na+, NH4+, Cl-, NO3-, and SO42-) were collected in Zhanjiang, China, from November 2018 to November 2019. The relative humidity (RH) was higher than 80% throughout the whole year in Zhanjiang. However, the TSPs and WSIIs were not correlated with RH, indicating that RH can increase the particle size, but this had a minor impact on the dry deposition rate. The larger particles induced by RH were easily captured by wet precipitation, leading to a seasonal pattern with higher TSP and WSII mass concentrations during the dry and cool season and lower values during the hot and rainy season. This seasonal pattern and high aerosol acidity indicate that TSPs, WSIIs, and acidic gaseous precursors from the local sources were preferentially scavenged by the abundant rainfall and high precipitation frequency. Principal component analysis (PCA) results suggest that relatively clean marine emissions and secondary aerosols were the most important sources of TSPs and WSIIs. Our results indicate that the inconsistency between the heavy industrial activities and excellent air quality in Zhanjiang may be related to the high precipitation frequency (63%) and the marine dilution effect (27%).

Assessment and mapping of total suspended particulate and soil quality around brick kilns and occupational health issues among brick kilns workers in Pakistan.

Brick kilns constitute one of the major sources of environmental degradation in Pakistan. The present study was conducted to determine the soil quality and total suspended particulates (TSPs) around the brick kilns and assess the health effects on brick kiln workers. Four brick kilns were selected, two each at Sheikhupura and Pattoki city. The soil quality was assessed by analyzing pH, electrical conductivity, moisture content, nitrogen, phosphorus, potassium content, and heavy metal concentration while TSPs were measured by hand-held Microdust Pro Real time monitor. Average TSP concentration around brick kilns at Sheikhupura and Pattoki ranged between 1100 and 1200µg/m3 and between 550 and 600µg/m3 respectively which exceeded the Punjab Ambient Air Standards. The soil was slightly acidic (Sheikhupura: average pH = 6.41; Pattoki: average pH = 6.6) while all other analyzed parameters, except heavy metals, were lower than the required FAO Standards for good quality agriculture soil. Heavy metal accumulation in soil samples followed the general order zinc (Zn) > chromium (Cr) > nickel (Ni) > manganese (Mn) > cadmium (Cd) > copper (Cu). For assessment of occupational health and safety issues, all 440 brick kiln workers from the study areas were interviewed. Mostly, brick kiln workers suffered from chronic back pain (84%), skin issues (80.5%), dry cough (72.9%), common cold (46.1%), and shortness of breath (17.1%). The vulnerability risk varied with the nature of the work as workers engaged in brick baking were more vulnerable to respiratory issues than were those in molding task. The study concludes that brick kilns are a source of increased TSP, deteriorated surrounding soil quality, and impaired worker health. It is necessary to regulate these activities and implement requisite health and safety measures.

Health Exposure Assessment of Firefighters Caused by PAHs in PM4 and TSP after Firefighting Operations

Among the many different chemicals in the air, polycyclic aromatic hydrocarbons (PAHs) pose a serious threat to human health. Firefighters are exposed to them both during fire suppression and in fire vehicles and fire stations due to inhalation of the fumes from contaminated clothing and personal protective equipment. This study aimed to estimate the exposure and cancer risk caused by suspended particulate matter and PAHs present in these particles. Air samples were collected for 4 months in a garage of the fire station in a small town, located in an urban–rural area. PAH concentrations were measured using the gas chromatography method with mass spectrometry (GC/MS). The concentration of PM4 (particulate matter with a diameter below 4µm) and TSP (total suspended particulate) in the fire station garage was 7 and 9 times higher than outside, respectively. The calculated values of health hazard risks associated with the exposure to PAHs in PM4 and TSP are: a toxic equivalent (TEQ) up to 10.36 and 23.3, incremental lifetime cancer risk (ILCR) up to 3.45 and 4.65 and hazard quotient (HQ) up to 0.42 and 0.57, respectively. A significantly increased risk of cancers in the professional group of firefighters was found.

Chemical Characteristics of Water-Soluble Inorganic Ions in Different Types of Asian Dust in Wajima, a Background Site in Japan

Two Asian dust (AD) events were observed in March 2021 (AD1: 16 March 2021 00:00 UTC~17 March 2021 12:00 UTC and AD2: 28 March 2021 00:00 UTC~31 March 2021 12:00 UTC). To determine the chemical characteristics of water-soluble inorganic ions (WSIIs) in different types of Asian dust, the total suspended particulates (TSP) were collected at Kanazawa University Wajima Air Monitoring Station (KUWAMS), a background site in Japan from 27 February to 4 March, 2021. Based on the lidar observations and the backwards trajectory analysis results, AD events were divided into two types: ADN (aerosols were mainly mineral dust) and ADP (aerosols were mixtures of spherical particles). During ADs, the concentrations of the TSP and WSII increased, with the highest TSP concentration in ADN (38.6 μg/m3) and the highest WSII concentration in ADP (5.82 μg/m3). The increase in (cations)/(anions) during AD indicates that the input of AD aerosol buffered the aerosol acidity. Additionally, a significant increase in Cl depletion, along with ADN events, was found (Cl depletion = 73.8%). To comprehensively analyse the different types of ADs on WSIIs, we refer to the previous data from 2010 to 2015 at KUWAMS. As a result, the increased Cl depletion was caused by the heterogeneous reaction of HNO3 with sea salt when the air mass passed over the Japanese Sea. Additionally, the chemical form of SO42− was highly dependent on the source and pathway, while SO42− mainly came from natural soil dust in ADN and from anthropogenic emissions in ADP. The enhancement of secondary NO3− was observed in AD via the heterogeneous hydrolysis of N2O5.

Spatialized Analysis of Air Pollution Complaints in Beijing Using the BERT+CRF Model

(1) Background: To better carry out air pollution control and to assist in accurate investigations of air pollution, in this study, we fully explore the spatial distribution characteristics of air pollution complaint results and provide guidance for air pollution control by combining regional air monitoring data. (2) Methods: By selecting the air pollution complaint information in Beijing from 2019 to 2020, in this study, we extract the names and addresses of complaint points, as well as the complaint times and types by adopting the BERT (bidirectional encoder representations from transformers) + CRF (conditional random field) model deep learning method. Moreover, through further filtering and processing of the complaint points’ address information, we achieve address matching and spatial positioning of the complaint points, and realize the regional spatial representation of air pollution complaints in Beijing in the form of a heat map. (3) Results: The experimental results are compared and analyzed with the ranking data of total suspended particulate (TSP) concentration of townships (streets) in Beijing during the same period, indicating that the key areas of air pollution complaints have a high correlation with the key polluted township (street) areas. The distribution of complaints and the types of complaints in each township (street) differ according to the population density in each township (street), the level of education, and economic activity. (4) Conclusions: The results of this study show that the public, as the intuitive perceiver of air pollution, is sensitive to the air pollution situation at a smaller spatial scale; furthermore, complaints can provide guidance and reference for the direction of air pollution control and law enforcement investigations when coupled with geographical features and economic status.

Comparison of the Concentration of Suspended Particles and Their Chemical Composition near the Ground Surface and Dust Extinction Coefficient by LIDAR.

In many epidemiological studies, the dust extinction coefficient measured by light detection and ranging (LIDAR) is used as an indicator of exposure to Asian dust. However, few reports on the relationship between the distribution of total suspended particles (TSPs) near the ground surface and the dust extinction coefficient exist. In this study, we examined the relationship between the concentrations of TSPs near the ground surface, substances indicative of mineral content, and air pollutants that may be transported with Asian dust and dust extinction coefficients in two regions: Imizu and Yurihama-Matsue, from March to May in 2011 and 2013. In both years, large dust extinction coefficients were observed in Imizu and Matsue on days when the concentrations of TSPs and mineral content indicators were high near the ground surface in Imizu and Yurihama, and Asian dust was expected to be highly suspended. In both regions, the concentrations of TSPs and mineral content indicators were significantly positively correlated with the dust extinction coefficient. The concentrations of all air pollutants analyzed were significantly positively correlated with the dust extinction coefficient in each region in 2013, but not in 2011. These results suggest that the dust extinction coefficient is a useful indicator of Asian dust near the ground surface; however, as harmful air pollutants occasionally move with Asian dust, it is necessary to monitor these pollutants near the ground surface when conducting an epidemiological study on the health effect of airborne particles.

Different Transport Behaviors between Asian Dust and Polycyclic Aromatic Hydrocarbons in Urban Areas: Monitoring in Fukuoka and Kanazawa, Japan

To clarify different effects of Asian dust (AD), long-range transported from Asian continent, on total suspended particles (TSP) and polycyclic aromatic hydrocarbons (PAHs) in Japan, TSP were simultaneously collected during AD periods (from 1 March to 31 May 2020 and 2021) in Fukuoka and Kanazawa. During AD days, decided by Light Detection and Ranging and Japan Meteorological Agency, TSP concentrations increased significantly (p < 0.001) at two sampling sites. PAH concentrations increased in Kanazawa (p < 0.001) but not in Fukuoka on AD days. Correlation coefficients (r) between daily TSP and total PAHs concentrations were weak in Kanazawa: 0.521 (non-AD) and 0.526 (AD) (p < 0.01), and in Fukuoka: 0.321 (non-AD) and 0.059 (AD). However, correlation between seasonal (average monthly) TSP and total PAH concentrations were stronger: 0.680 (Kanazawa) and 0.751 (Fukuoka). The reasons might be that seasonal variations of TSP and total PAHs in two cities depend equally on planetary scale westerly, while daily TSP and total PAHs variations in each city varied by different transportation distances from AD and PAHs sources in the Asian continent to Japan. Different local sources and meteorological conditions were considered. These results are important for elucidating the causes of chronic and acute respiratory diseases.

Phthalates, non-phthalates, polychlorinated biphenyls, and phenyl phosphates in atmospheric suspended particulate matter of Dhahran City, Saudi Arabia: levels and seasonal variation

This is the first report to describe the seasonal variations, levels, and possible health effects of groups of persistent organic pollutants (POPs) as phthalates (Ps), non-phthalates (NPs), polychlorinated biphenyls (PCBs), and phenyl phosphates (PhePhs) in ambient total suspended particles (TSP) from the city of Dhahran, Saudi Arabia. The mass concentrations of TSP ranged from 88 ± 32 μg m−3 in winter to 350 ± 320 μg m−3 in summer. The total concentrations of these compounds varied from 337 ± 266 ng m−3 in summer to 469 ± 403 ng m−3 in winter. The major compounds were Ps (235 ± 199 ng m−3 in summer to 389 ± 335 ng m−3 in winter), PCBs (30.7 ± 19.3 ng m−3 in autumn to 65.6 ± 61.2 ng m−3 in summer), NPs (4.9 ± 2.3 ng m−3 in summer to 11.9 ± 12.5 ng m−3 in winter), and PhePhs (4.1 ± 4.0 ng m−3 in spring to 13.3 ± 3.2 ng m−3 in summer). The proportional fractions of these POPs relative to natural biogenic sources and petroleum-related emissions were extremely high ranging from 17% in winter to 47% in autumn. Significant correlations were found among these different POP groups and total concentrations, suggesting that they were from local sources. Principal component analysis indicated that Ps and NPs were from the same initial sources, and the PhePhs as well as PCBs were from different regional sources, where the latter were dependent on the TSP levels. In the long term, the elevated levels of these POPs in the TSP of these urban areas will affect human health by eventually developing a range of illnesses.

Carbon and Trace Element Compositions of Total Suspended Particles (TSP) and Nanoparticles (PM0.1) in Ambient Air of Southern Thailand and Characterization of Their Sources

The concentration of total suspended particles (TSP) and nanoparticles (PM0.1) over Hat Yai city, Songkhla province, southern Thailand was measured in 2019. Organic carbon (OC) and elemental carbon (EC) were evaluated by carbon aerosol analyzer (IMPROVE-TOR) method. Thirteen trace elements including Al, Ba, K, Cu, Cr, Fe, Mg, Mn, Na, Ni, Ti, Pb, and Zn were evaluated by ICP-OES. Annual average TSP and PM0.1 mass concentrations were determined to be 58.3 ± 7.8 and 10.4 ± 1.2 µg/m3, respectively. The highest levels of PM occurred in the wet season with the corresponding values for the dry seasons being lower. The averaged OC/EC ratio ranged from 3.8–4.2 (TSP) and 2.5–2.7 (PM0.1). The char to soot ratios were constantly less than 1.0 for both TSP and PM0.1, indicating that land transportation is the main emission source. A principal component analysis (PCA) revealed that road transportation, industry, and biomass burning are the key sources of these particles. However, PM arising from Indonesian peatland fires causes an increase in the carbon and trace element concentrations in southern Thailand. The findings make useful information for air quality management and strategies for controlling this problem, based on a source apportionment analysis.