Total Reflection Research Articles

Rapid polyamide membrane compatibility testing of potential anti-biofouling agents for reverse osmosis membrane systems

ABSTRACT The detrimental impacts of biofouling on reverse osmosis (RO) membrane (ROM) installations is one of the main technical barriers faced by RO technology to provide potable water. To unveil safer alternatives for biofouling prevention in ROM installations, this work assesses the ROM compatibility of three potential low-hazard anti-biofouling agents (lauroyl arginate ethyl (LAE), phenoxyethanol (PE), and sodium benzoate (SB)) via a proposed rapid membrane degradation test. This study offers a cost-effective screening tool to select biocides for extensive compatibility studies. Attenuated total reflectance – Fourier-transform infrared spectroscopy, atomic force microscopy, and scanning electron microscopy assessed ROM surface damage due to biocide exposure. LAE did not show significant morphological or chemical membrane damage at any experimental conditions (exposure time: 1, 8, and 24 h; pH: 4, 7, 9; concentration: 100 mg/L, 50 g/L, 100 g/L, and 150 g/L). However, results indicated that exposure to PE and SB led to membrane degradation. The proposed rapid membrane degradation test showed to be an excellent tool for improving current membrane compatibility testing practices. It identified two ROM-damaging biocides, SB and PE, streamlining large-scale testing efforts. Additionally, it identified a promising biocide, LAE, with the potential to address biofouling in RO systems, prompting further long-term compatibility studies.

Measuring Calcium-Sensing Receptor Agonist-Driven Insertional Signaling (ADIS) and Trafficking by TIRF Microscopy.

The calcium-sensing receptor (CaSR), which regulates parathyroid hormone secretion by sensing serum calcium concentrations, has developed unique trafficking mechanisms to respond to constant exposure to its orthosteric ligand calcium. CaSR rapidly responds to fluctuations in serum calcium by driving forward trafficking of the receptor to cell surfaces in a mechanism known as agonist-driven insertional signaling (ADIS). This increase in CaSR at cell surfaces is counterbalanced by both constitutive and agonist-driven internalization of the receptor. Deciphering these mechanisms is important to understand how mutations in the CaSR and components of its signaling and trafficking pathways cause human disorders of calcium homeostasis.This chapter describes a protocol to measure CaSR ADIS and endocytosis in parallel using total internal reflection fluorescence (TIRF) microscopy. This utilizes a mammalian expression construct comprising the full-length human CaSR with an N-terminal bungarotoxin minimal-binding site that can be labeled with commercially available fluorescent ligands to measure endocytosis, and a super-ecliptic pHluorin (SEP) to measure total cell surface expression and exocytic events. This protocol could easily be adapted to simultaneously assess forward trafficking and endocytosis of other membrane proteins by TIRF microscopy.

Laminar Flow Infrared Spectroelectrochemistry.

In this work, we advance lab-on-chip electrochemistry and spectroscopy by combining these capabilities onto a single platform, thereby achieving mid-infrared spectroelectrochemistry (SEC) for the first time. The key feature of this technique is the use of deterministic laminar flow patterns to precisely transport a reacted solution from upstream electrodes to a downstream spectral detection region. Laminar flow spectroelectrochemistry (LF-SEC) is therefore a completely new approach, which derives its distinction and advantage over traditional SEC by physically separating electrode and attenuated total reflection (ATR) elements. As such, these functional elements retain optimal properties, such as inert, highly conductive electrodes and a bare ATR element for sensitive Fourier transform infrared (FTIR) spectroscopy. By combining ATR-FTIR with a scanning aperture system, LF-SEC provides the additional advantage of spectroscopically monitoring reactions at individual electrodes. The LF-SEC system design is first optimized through a series of targeted experiments using a ferricyanide/ferrocyanide redox pair to validate electrochemical functionality, undertake spectroscopic calibration, optimize experimental parameters, and finally validate the quantitative relationship between FTIR results and the reaction rate under galvanostatic control. After optimization, we demonstrate the technique by monitoring the oxidation of the therapeutic compound ascorbic acid (vitamin C) in the presence of biomolecular interference from a molecule with an overlapping oxidation potential. We find that molecular availability causes the reaction to switch between reaction pathways, which we could finely monitor using LF-SEC. This work opens the door to future developments that take advantage of the microfluidic reactor setup, with benefits ranging from portability to high-throughput studies under precise reaction conditions.

Graphene‑vanadium dioxide ultra-wideband dual regulated absorber

In this paper, we propose a novel tunable THZ absorber consisting of a patterned graphene layer and a metal plate separated by a vanadium dioxide dielectric layer. The absorbent has a simple structure, is easy to make graphene patterns, and has a dual regulatory function. The ability to double regulate comes from the fact that the state of vanadium dioxide changes with the temperature between the insulating phase and the metal phase, resulting in a change in its conductivity. When vanadium dioxide is in the insulating phase, the total reflection characteristics of the absorber are >7 THz, and when vanadium dioxide is in the metallic phase, the absorber achieves near-perfect absorption in the ultra-wideband range of 3 THz to 12.4 THz (9.4 THz). Local surface plasmon resonance explains the perfect absorption. Compared with previous absorbers, our proposed absorbers are not only simple in structure, the graphene pattern is also easy to process, but also have double adjustment and perfect absorption in the ultra-wideband range, are not sensitive to polarized light, and have large tolerances for the Angle of incident. The further development and enrichment of terahertz metamaterials and metasurface devices will also have beneficial implications for terahertz wave applications in sensing, communications, and radar. Due to their significant application value in stealth, detection, and communication, metamaterial absorbers have become a research hotspot in the field of metamaterials.

Direct-bonded diamond membranes for heterogeneous quantum and electronic technologies

Diamond has superlative material properties for a broad range of quantum and electronic technologies. However, heteroepitaxial growth of single crystal diamond remains limited, impeding integration and evolution of diamond-based technologies. Here, we directly bond single-crystal diamond membranes to a wide variety of materials including silicon, fused silica, sapphire, thermal oxide, and lithium niobate. Our bonding process combines customized membrane synthesis, transfer, and dry surface functionalization, allowing for minimal contamination while providing pathways for near unity yield and scalability. We generate bonded crystalline membranes with thickness as low as 10 nm, sub-nm interfacial regions, and nanometer-scale thickness variability over 200 by 200 μm2 areas. We measure spin coherence times T2 for nitrogen vacancy centers in 150 nm-thick bonded membranes of up to 623 ± 21 μs, suitable for advanced quantum applications. We demonstrate multiple methods for integrating high quality factor nanophotonic cavities with the diamond heterostructures, highlighting the platform versatility in quantum photonic applications. Furthermore, we show that our ultra-thin diamond membranes are compatible with total internal reflection fluorescence (TIRF) microscopy, which enables interfacing coherent diamond quantum sensors with living cells while rejecting unwanted background luminescence. The processes demonstrated herein provide a full toolkit to synthesize heterogeneous diamond-based hybrid systems for quantum and electronic technologies.

Structural and Spectroscopic Characterization of Supported Sarcoplasmic Reticulum Membranes on Solid Substrates.

Sarcoplasmic reticulum (SR) membranes from rabbit muscle were deposited on silicon substrates and characterized by the combination of spectral ellipsometry (SE), high energy specular X-ray reflectivity (XRR), specular neutron reflectivity (NR), and attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy. Following the optimization of the preparative conditions by SE, the detailed structures in the direction perpendicular to the membrane were probed by XRR. ATR-FTIR data showed strong signals from amide I and amide II bands of the native SR membranes containing a large amount of Ca2+-ATPase, which could not be achieved by the reconstitution in artificial lipid membranes. The treatment with protease led to a significant decrease in the amide peaks, and the XRR data confirmed the modulation of the membrane structures. The obtained data show the potential of the in situ combination of reflectivity and vibrational spectroscopy of native supported membranes in order to unravel both structure and dynamics of complex biological membranes.

Infrared spectroscopy as a new approach for early fabry disease screening: a pilot study

BackgroundFabry disease (FD) is a rare X-linked lysosomal storage disorder marked by alpha-galactosidase-A (α-Gal A) deficiency, caused by pathogenic mutations in the GLA gene, resulting in the accumulation of glycosphingolipids within lysosomes. The current screening test relies on measuring α-Gal A activity. However, this approach is limited to males. Infrared (IR) spectroscopy is a technique that can generate fingerprint spectra of a biofluid’s molecular composition and has been successfully applied to screen numerous diseases. Herein, we investigate the discriminating vibration profile of plasma chemical bonds in patients with FD using attenuated total reflection Fourier-transform IR (ATR-FTIR) spectroscopy.ResultsThe Fabry disease group (n = 47) and the healthy control group (n = 52) recruited were age-matched (39.2 ± 16.9 and 36.7 ± 10.9 years, respectively), and females were predominant in both groups (59.6% and 65.4%, respectively). All patients had the classic phenotype (100%), and no late-onset phenotype was detected. A generated partial least squares discriminant analysis (PLS-DA) classification model, independent of gender, allowed differentiation of samples from FD vs. control groups, reaching 100% sensitivity, specificity and accuracy.ConclusionATR-FTIR spectroscopy harnessed to pattern recognition algorithms can distinguish between FD patients and healthy control participants, offering the potential of a fast and inexpensive screening test.

Ancient and modern bone diagnosis: Towards a better understanding of chemical and structural feature alterations

Chemical and structural alterations hold great importance in the field of diagenesis. Attenuated Total Reflectance − Fourier Transform Infrared Spectroscopy (ATR-FTIR) is a valuable method for examining bio-apatite composition changes. Infrared spectroscopy (IR) and X-ray diffraction (XRD) were employed to analyze both modern and archaeological bone specimens. Organic and mineral component changes in modern and ancient samples were investigated. Ancient bone samples were collected from two archaeological sites in Jordan, dating back to the Iron and Byzantine ages. IR results indicated that collagen cross-links and mineral maturity are higher in modern bones compared to ancient bones. Additionally, the crystallinity index is higher in modern bones than in archaeological bones, while the carbonate to phosphate ratio (C/P) is lower in modern bones than in ancient ones. Curve fitting was applied to reveal the carbonate substitution inside the hydroxyapatite lattice within the IR region from 850 to 890 cm−1. A2-type carbonates (identified as υ2 of CO32−) denote hydroxyl site substitution, and B-type carbonates represent a substitution to the phosphate site. The full width at half maximum (FWHM) of the peak at 604 cm−1 from IR spectra reveals that crystallinity is higher in modern bones, as confirmed by the FWHM of the (002)-apatite pattern in XRD. Statistical analysis was conducted to validate these findings, ensuring the robustness of the results. Finally, the results obtained in this investigation align with previous literature reports regarding ATR-FTIR ratios. This suggests that modern bones have better crystallinity compared to ancient bones. Furthermore, the ATR-FTIR ratios indicate that the hydroxyl and phosphate sites of modern bones undergo more substitution than older bones. The findings of this study not only enhance our understanding of the diagnostic processes in archaeological bone specimens but also have broader implications for fields such as archaeology, anthropology, and forensics, where the analysis of bone composition and structural changes can provide valuable insights into the history and characteristics of ancient remains.

Simulation and theoretical study of high Q gradient refractive index microresonators

Whispering gallery mode (WGM) microresonators are widely used because of their high Q factors. However, high Q factors cannot be consistently attained, as WGM cavities continue to be affected by environmental contamination and roughness. To overcome this limitation, the gradient refractive index (GRIN) has been suggested to shifting the mode field inward and preventing total internal reflection at the surface. This study proves the following two results using the simulation and potential functions. First, after ion-exchange, the refractive index fluctuations at the internal mode positions are quite small, even with roughness. As a result, the Q factor is always greater than that before ion-exchange. Second, the GRIN microresonator have a high Q factor (7.5×107) in the external high refractive index (nex=1.5) environment because the GRIN material itself creates a potential barrier, which means that it is significantly more resistant to environmental disturbances than the WGM.

Copper nanoparticles biosynthesis by Priestia megaterium and its application as antibacterial and antitumor agents

The growth of material science and technology places high importance on creating better processes for synthesizing copper nanoparticles. Thus, an easy, ecological, and benign process for producing copper nanoparticles (CuNPs) has been developed using Priestia sp. bacteria utilizing a variety of low-cost agro-industrial wastes and byproducts. The biosynthesis of CuNPs was conducted using glucose medium and copper ions salt solution, then it was replaced by utilizing low-cost agro-industrial wastes. UV–visible spectroscopy, dynamic light scattering (DLS), X-ray diffraction (XRD), High-resolution transmission electron microscope (HR-TEM), Attenuated Total Reflectance and Fourier transform infrared (ATR-FTIR), and zeta potential were used to characterize the biosynthesized CuNPs. The cytotoxicity of CuNPs using Vero -CCL-81 cell lines, and antibacterial and antitumor properties using human colon epithelial colorectal adenocarcinoma Caco-2-HTB-37 cell lines were assessed. The UV–visible and DLS studies revealed CuNPs formation, with a maximum concentration of 6.19 ppm after 48 h, as indicated by a 0.58 Surface plasmon resonance (SPR) within 450 nm and 57.73 nm particle size. The 16S rRNA gene analysis revealed that Priestia sp. isolate is closely related to Priestia megaterium and has been deposited in the NCBI GenBank with accession number AMD 2024. The biosynthesis with various agro-industrial wastes indicated blackstrap sugar cane molasses being the most effective for reducing CuNPs size to 3.12 nm owing to various reducing and stabilizing active compounds. The CuNPs were free of contaminants, with a sphere-shaped structure and a cytotoxicity assessment with an IC50 of 367.27 μg/mL. The antibacterial activity exhibited by the most susceptible bacteria were Bacillus cereus ATCC 11788 and Staphylococcus aureus ATCC 6538 with inhibition zones of 26.0 mm and 28.0 mm, respectively. The antitumor effect showed an IC50 dose of 175.36 μg/mL. Based on the findings, the current work sought to lower product costs and provide a practical solution to the environmental contamination issues brought on by the buildup of agricultural wastes. In addition, the obtained CuNPs could be applied in many fields such as pharmaceuticals, water purification, and agricultural applications as future aspects.

P-Block Aluminum Single-Atom Catalyst for Electrocatalytic CO2 Reduction with High Intrinsic Activity.

Atomically dispersed transition metal sites on nitrogen-doped carbon catalysts hold great potential for the electrochemical CO2 reduction reaction (CO2RR) to CO due to their encouraging selectivity. However, their intrinsic activity is restricted by the hurdle of the high energy barrier of either *COOH formation or *CO desorption due to the scaling relationship. Herein, we discover a p-block aluminum single-atom catalyst (Al-NC) featuring an Al-N4 site that enables disentangling this hurdle, which endows a moderate reaction kinetic barrier for *COOH formation and *CO desorption, as validated by in situ attenuated total reflection infrared spectroscopy and theoretical simulations. As a result, the developed Al-NC shows a CO Faradaic efficiency (FECO) of up to 98.76% at -0.65 V vs RHE and an intrinsic catalytic turnover frequency of 3.60 s-1 at -0.99 V vs RHE, exceeding those of the state-of-the-art Ni-NC and Fe-NC counterparts. Moreover, it also delivers a partial CO current of 309 mA·cm-2 at 93.65% FECO and 605 mA at >85% FECO in a flow cell and membrane electrode assembly (MEA), respectively. Strikingly, when using low-concentration CO2 (30%) as the feedstock, this catalyst can still deliver a partial CO current of 240 mA at >80% FECO in the MEA. Considering the earth-abundant character of the Al element and the high intrinsic activity of the Al-NC catalyst, it is a promising alternative to today's transition metal-based single-atom catalysts.

Imperskost’ from Central (Eur)Asian ethnography to the self

ABSTRACT The Russian word Imperskost’, which can be translated into English as ‘imperiality’, is a useful theoretical concept for scholarly writing in English that addresses individuals’ and countries’ imperial ambitions. In this note, I explore the meaning and relevance of this concept to our daily lives. Contrary to some existing definitions of Imperskost’ in terms of political economy, history, psychology (as an unconscious bias) and its primordial origins, I argue that this feeling is primarily personal and located in the human body. Imperskost’ is thus embodied as an emotion articulated and expressed as a sense of privilege, superiority and/or entitlement. Confronting Imperskost’ – whether one is a Russian citizen, a Russian speaker or not – is essential for overcoming it. Since scholarly works, including Central (Eur)Asian ethnography, can be sites for the formation and maintenance of Imperskost’, internal disciplinary criticism and reflection are necessary for its undoing. However, this process begins with the individual.

Unveiling the Structure and Dissociation of Interfacial Water on RuO2 for Efficient Acidic Oxygen Evolution Reaction

Understanding the structure and dynamic process of interfacial water molecules at the catalyst‐electrolyte interface on acidic oxygen evolution reaction (OER) kinetics is highly desirable for the development of proton exchange membrane water electrolyzers. Herein, we construct a series of p‐block metallic elements (Ga, In, Sn) doped RuO2 catalysts with manipulated electronic structure and Ru‐O covalency to investigate the effect of electrochemical interfacial engineering on the improvement of acidic OER activity. Associated with operando attenuated total reflectance surface‐enhanced infrared absorption spectroscopy measurements and theoretical analysis, we uncover the free‐H2O enriched local environment and dynamic evolution from 4‐coordinated hydrogen‐bonded water and 2‐coordinated hydrogen‐bonded water to free‐H2O on the surface of Ga‐RuO2, are responsible for the optimized connectivity of hydrogen bonding network in the electrical double layer by promoting solvent reorganization. In addition, the structurally ordered interfacial water molecules facilitate high‐efficiency proton‐coupled electron transfer across the interface, leading to reduced energy barrier of the follow‐up dissociation process and enhanced acidic OER performance. This work highlights the key role of structure and dynamic process of interfacial water for acidic OER, and demonstrates the electrochemical interfacial engineering as an efficient strategy to design high‐performance electrocatalysts.

Rapid Screening of Methane-Reducing Compounds for Deployment in Livestock Drinking Water Using In Vitro and FTIR-ATR Analyses

Several additives have been shown to reduce enteric methane emissions from ruminants when supplied in feed. However, utilising this method to deliver such methane-reducing compounds (MRCs) in extensive grazing systems is challenging. Use of livestock drinking water presents a novel method to deliver MRCs to animals in those systems. This work evaluated 13 MRCs for suitability to be deployed in this manner. Compounds were analysed for solubility and stability in aqueous solution using Fourier transform infrared-attenuated total reflectance (FTIR-ATR) spectroscopy. Furthermore, aqueous solutions of MRCs were subjected to variations in temperature and starting pH of water used to assess solubility and stability of the MRCs in simulated water trough conditions, also using FTIR-ATR spectroscopy. In vitro batch culture fermentations were carried out using a medium-quality tropical grass feed substrate, to simulate pastures consumed by cattle in extensive grazing systems. Measurements were made of total gas and methane production, in vitro dry matter digestibility (IVDMD), and volatile fatty acid (VFA) concentration. Of the MRCs tested, 12 were found to be soluble and stable in water using the FTIR method employed, whilst the other could not be measured. Of the 12 soluble and stable MRCs, one containing synthetic tribromomethane (Rumin8 Investigational Veterinary Product) reduced methane production by 99% (p = 0.001) when delivered aqueously in vitro, without a reduction in IVDMD (p = 0.751), with a shift towards decreased acetate and increased propionate production and decreased total VFA production (p < 0.001). Other compounds investigated also appeared suitable, and the methods developed in this study could be used to guide future research in the area.

Unveiling the Structure and Dissociation of Interfacial Water on RuO2 for Efficient Acidic Oxygen Evolution Reaction.

Understanding the structure and dynamic process of interfacial water molecules at the catalyst-electrolyte interface on acidic oxygen evolution reaction (OER) kinetics is highly desirable for the development of proton exchange membrane water electrolyzers. Herein, we construct a series of p-block metallic elements (Ga, In, Sn) doped RuO2 catalysts with manipulated electronic structure and Ru-O covalency to investigate the effect of electrochemical interfacial engineering on the improvement of acidic OER activity. Associated with operando attenuated total reflectance surface-enhanced infrared absorption spectroscopy measurements and theoretical analysis, we uncover the free-H2O enriched local environment and dynamic evolution from 4-coordinated hydrogen-bonded water and 2-coordinated hydrogen-bonded water to free-H2O on the surface of Ga-RuO2, are responsible for the optimized connectivity of hydrogen bonding network in the electrical double layer by promoting solvent reorganization. In addition, the structurally ordered interfacial water molecules facilitate high-efficiency proton-coupled electron transfer across the interface, leading to reduced energy barrier of the follow-up dissociation process and enhanced acidic OER performance. This work highlights the key role of structure and dynamic process of interfacial water for acidic OER, and demonstrates the electrochemical interfacial engineering as an efficient strategy to design high-performance electrocatalysts.

The Role of Formulations in the Ageing Process of Vinyl Acetate Based Emulsion Films: A Multivariate Approach

Vinyl acetate (VAc)-based emulsions represent one of the main media used by modern and contemporary artists. Their long-term behaviour is still not completely understood, especially due to the scarce knowledge on the influence of other compounds in the formulation, which may impact ageing over time. Besides the polymer backbone based on vinyl acetate, other co-monomers and additives can be added to the emulsion to alter the final film’s physical, chemical, and optical properties. By extension, the formulation will also impact the long-term stability of artworks and objects on which it has been applied, as well as possible current and future conservation interventions such as cleaning. For those reasons, studies shedding light on the correlation between composition and long-term stability are largely necessary. In this study, different emulsions, including homopolymers, copolymers, plasticised, and un-plasticised compositions, were gathered and artificially aged. A multivariate analyses approach based on the application of principal component analyses (PCA) and hierarchical cluster analyses (HCA) was employed for the first time on the combination of data obtained by pH, contact angle (CA), colour measurements, Fourier transform infrared spectroscopy in attenuated total reflection (FTIR-ATR), and size exclusion chromatography (SEC). This approach helped to highlight the changes that occurred during ageing and find correlations with the formulation compositions. The results further sustain the thesis that not all vinyl acetate-based emulsions are chemically the same and that their formulation deeply impacts their long-term behaviour.

Sample Preparation and Determination of Trace Elements in High-Entropy Alloys by Total Reflection X-Ray Fluorescence (TXRF)

High-entropy alloys (HEAs) have attracted significant attention in recent years owing to their exceptional material properties; however, trace impurities in these alloys can significantly affect their strength, toughness, and radiation resistance. This study employs total reflection X-ray fluorescence (TXRF) to determine the trace impurities in three common HEA powders prepared via suspension techniques. High-Z (Ca and Mn) and low-Z (Mg and Al) elements were quantified using the internal standard and calibration curve methods, respectively. The levels of high-Z elements are consistent with those determined using inductively coupled plasma – optical emission spectrometry (ICP-OES). Although the physical mechanisms exerted various effects on low-Z elements, qualitative and semi-quantitative analyses remained feasible, demonstrating the effectiveness of TXRF for impurities in HEAs. Additionally, the combination of suspension sample preparation and TXRF affords a nondestructive, rapid, and cost-effective methodology that requires minimal sample quantities. Consequently, TXRF is well suited for the rapid determination of impurities in HEAs.

Combining Infrared Refraction and Attenuated Total Reflection Spectroscopy.

We have specified and obtained a ZnSe prism with an unconventional face angle cut to 30°. This prism, with internal incidence angles ranging from 30° to 48°, allows users to record internal reflection spectra below the critical angle and attenuated total reflection (ATR) spectra above the critical angle without the need to change optics or move or replace the sample. We demonstrate its capabilities using 102 spectra of benzyl benzoate taken with s- and p-polarization at different angles of incidence. The subcritical spectra were analyzed to obtain n∞, a key parameter for correcting the ATR spectra. These corrected spectra were subsequently used to determine the complex refractive index for all ATR measurements. The averaged complex refractive index function shows excellent agreement with that obtained through ATR spectroscopic ellipsometry.

Fourier Transform Infrared Spectroscopy (FTIR) for identification of sugar adulterants in mulberry molasses (pekmez)

Fourier Transform Infrared Spectroscopy (FTIR) and chemometrics were successfully used in this research in conjunction with the Attenuated Total Reflectance (ATR) technique to determine bulberry molasses (MM) canesugar adulteration. Mulberry molasses was adultered by incorporating two fructose syrups (FS), one glucose syrup (GS), one sucrose syrup (SS), and two specific high fructose corn syrups (HFCS). Calibration sets were developed for mulberry molasses by spiking sugar syrups. The actual percentage of adulteration linked to FTIR predicted results by partial least square (PLS). The preferred spectral range was 1184-944 cm-1 for prediction of adulteration levels of F20, F30, HFCS50, HFCS55 and 1090-950 cm-1 for sucrose. This method was employed to distinguish between mulberry molasses and adulterated samples. According to the findings, the FTIR technique is an accurate and affordable method that can rapidly detect sugar adulteration in mulberry molasses.

Design and analysis of low-profile quad element wide band MIMO antenna with efficient isolation for C and X-band applications

ABSTRACT A low-profile, quad-element multiple-input/multiple-output (MIMO) antenna of 0.69 λ 0 λ 0 is presented in this study. The proposed design consists of a stub and slot-loaded partial ground plane with a quad rectangular-shaped radiator on top. The four elements are placed orthogonally to one another to reduce mutual coupling and envelope correlation coefficient (ECC). The maximum isolation of the proposed MIMO antenna is 61.5 dB at 9.94 GHz frequency. It achieved impedance bandwidth 5.56 GHz, ranging from 5.74–11.30 GHz. The peak gain of the proposed MIMO antenna is 6.18 dB at 7.3 GHz, with a maximum efficiency of 89.21% at 7.1 GHz. The minimum ECC between ports 1 and 2 over the operating band are observed as 0.0001. To achieve the best outcome, a parametric analysis of the proposed antenna is also performed. Various diversity characteristic metrics, including diversity gain (DG), mean effective gain (MEG), total active reflection coefficient (TARC), channel capacity loss (CCL), and ergodic channel capacity (CC), are thoroughly analysed to determine how well the MIMO antenna performs in terms of diversity. Over the operating band, the measured values provide good agreement with respect to simulated and equivalent circuit model results, indicating a strong candidacy for operation in the investigated bands. The proposed MIMO antenna have the potential for C and X band applications such as WLAN, radio astronomy, satellite communication, and automotive radar.