Many applications, such as photovoltaic systems, uninterruptible power supplies, and automobile headlamps, need a high step-up DC–DC converter without isolation. The conventional boost converter has the advantages of simple topology and easy control. However, it has some shortcomings, such as insufficient step-up voltage ratio and poor efficiency when operating at large duty-cycle conditions. One of the popular topologies used to overcome these problems is the coupled-inductor boost converter. It utilizes the turn ratio of the coupled inductor to realize a higher step-up voltage ratio. The drawback is that the leakage inductance of the coupled inductor causes a huge voltage spike when the power switches are turned off. Moreover, because coupled inductors are characterized by their large volume and high profile, a conventional coupled-inductor boost converter is unsuited for photovoltaic systems, such as the solar microinverter. This study proposes a novel high-step-up boost converter to solve these problems. This proposed converter uses dual coupled inductors instead of the conventional coupled-inductor boost converter. The secondary side of the coupled inductor is connected in series to increase the step-up voltage ratio. The proposed converter utilizes active clamping to achieve zero-voltage switching (ZVS) for suppressing voltage spike and improving conversion efficiency. In addition, low-profile designs can be fulfilled easily for solar microinverters. The proposed converter and its control method are introduced. The operation principle, circuit characteristics, and circuit analysis are presented. A prototype converter with 300 W output power 25–40 VDC input voltage and 200 VDC output voltage was tested. All functions, including high step-up voltage ratio, ZVS, and active clamping, were achieved, and the highest efficiency was around at 94.7%.