Time-temperature History Research Articles

A semi-analytical method of three-dimensional dual-phase-lagging heat conduction model

With the development of picosecond laser technology, the dual-phase-lagging (DPL) model is more suitable to describe the heat transfer problem with micro-scale effect and micro-time effect. In this paper, a three-dimensional dual-phase-lagging heat transfer model for picosecond laser processing is established. Then Fourier transform (FT) and Laplace transform (LT) are used to derive the frequency response functions (FRFs) of the problem in the frequency domain, and the inverse Laplace transform (ILT) and discrete-convolution fast Fourier transform (DC-FFT) algorithm are used to solve the temperature field. The calculation accuracy of this method is verified and the effect of phase lag constants on temperature field is studied. The results show that the semi-analytical method has a high accuracy for solving the dual-phase-lagging heat conduction model, and the phase lag of heat flux will affect the heating rate in the heating stage, and the phase lag of temperature gradient will delay the formation of temperature field. The effect of phase lag constants on temperature-time history is investigated and the related phenomena are explained by using the two-step heat transfer theory. This semi-analytical method provides a new approach to solve the problem of three-dimensional dual-phase-lagging heat transfer.

Inactivation of Salmonella and Shiga-toxin producing Escherichia coli on soft wheat kernels using vacuum steam pasteurization

Wheat, the raw material for flour milling, can be contaminated with enteric pathogens, leading to outbreaks linked to flour. In previous lab-scale studies, vacuum steam treatment was able to reduce Salmonella Enteritidis PT30 and Shiga-toxin producing E. coli (STEC) O121 levels on soft wheat kernels while maintaining flour quality and gluten functionality. This study used a newly designed lab-scale vacuum steam pasteurizer (VSP) to evaluate its efficacy to inactivate multiple strains of Salmonella and STEC on soft wheat by modeling the non-isothermal time-temperature history during treatment and reduction of the microbial populations. The results demonstrated that vacuum steam treatment could effectively disinfect wheat grains inoculated with enteric pathogens. In this study, Salmonella strains were less thermally resistant than STEC strains. The D75°C of Salmonella strains were 2.8 and 3.2 min, and the D75°C of STEC ranged from 3.1 to 4.6 min. E. faecium had a D75°C of 3.3 min, which indicates that it could be used as surrogate for larger scale evaluation of vacuum steam pasteurization in the future but was not conservative compared to some of the STEC strains.

Experimental Study of Inverse Heat Conduction Problem in a Kinetic Heating Facility

Estimation of unknown surface conditions using measured temperature time history inside or back wall of a solid body is known as inverse heat conduction problem. The purpose of present paper is to solve inverse heat conduction problem using iterative method in conjunction with measured thermocouple data. Exact solution of one-dimensional heat conduction equation is obtained to calculate temperature distribution inside a finite slab. An analytical expression of the sensitive coefficient is derived for constant wall heat flux. It is observed that the sensitive coefficient varies linearly with wall heat flux. Experiments were conducted in Kinetic Heating Facility to obtain temperature-time data. The facility works employing with close loop feed-back system with thyristor controlled thermac. Experimental results are compared with the estimated values and are found in good agreement. The Kinetic Heating Facility can easily be adopted to estimate the thermal diffusivity of material.

Tectonic-Thermal Evolution of the Wadi El-Dahal Area, North Eastern Desert, Egypt: Constraints on the Suez Rift Development

The Suez Rift developed as a northern extension of the Red Sea rift during the Oligocene-Miocene, whose flanks were constructed from the Neoproterozoic basement rocks of the Arabian–Nubian Shield. These basement rocks are comprised of the whole tectonic history since their formation. The Suez Rift initiation model and proposed thermal overprint role in the rifting process and flank development remain uncertain. Additionally, the amplitude of different regional tectonic events’ effects on the region is still debatable. Integration of fission-track thermochronology data with modeling of the time-temperature history has demonstrated efficiency in addressing such issues. In the context of this study, eleven representative samples were collected from the different rock units in the Wadi El-Dahal area at the northern tip of the western flank of the Suez Rift. These samples revealed Carboniferous zircon fission-track cooling ages of 353 ± 9 Ma and 344 ± 11 Ma. Meanwhile, the apatite fission-track analysis provided two spatially separated age groups: Permian-Triassic and Late Cretaceous, with average ages of 249 ± 11 Ma and ca. 86 ± 10 Ma, respectively. The time-temperature modeling revealed four possible cooling pulses representing exhumation events, which were initiated as a response to four tectonic activities: the accretion-subsequent event of erosion during the Neoproterozoic, the Hercynian (Variscan) tectonic event during the Devonian-Carboniferous, the Mid-Atlantic opening during the Cretaceous, and the Suez Rift opening during the Oligocene-Miocene. The western flank of the Suez Rift suggests a passive mechanical type with no extra thermal overprint, as indicated by the dominance of older thermochronological ages, modest rift flank elevations, and a reduction in the heat flow.

Soot nucleation in diffusion flames and the role of aromatic hydrocarbons

We perform spatially resolved measurements of light scattering of soot in atmospheric pressure counterflow diffusion flames to complement previously reported data on soot pyrometry, temperature and gaseous species up to three-ring polycyclic aromatic hydrocarbons (PAHs). We compare two flames: a baseline ethylene flame and a toluene-seeded flame in which an aliquot of ethylene in the feed stream is replaced with 3500 ppm of pre-vaporized toluene. The goal is twofold: directly adding an aromatic fuel to bypass the formation of the first aromatic ring, widely regarded as the main bottleneck to soot formation from aliphatic fuels, and assessing the impact of a common component of surrogates of transportation fuels on soot formation. The composition of the fuel and oxidizer streams are adjusted to ensure invariance of the temperature-time history, thereby decoupling the chemical effects of the fuel substitution from other factors. The doping approach enables the comparison of very similar flames with respect to combustion products, radicals and critical precursors to aromatic formation (C2–C5 species), in addition to the temperature-time history. Doping with toluene boosts the aromatic content and soot volume fraction relative to the baseline ethylene flame, but, surprisingly, the soot number density and nucleation rate are affected modestly. As a result, the observed difference in volume fraction in the toluene-doped flame is reflective of larger initial particles at the onset of soot nucleation. The nucleation rate when soot first appears near the flame is of the same order as the dimerization rate of single-ring aromatics, in contrast with the expectation that the dimerization of larger PAHs initiates the process. Even though in and of itself nucleation contributes modestly to the overall soot loading, nucleation conditions the overall soot loading by affecting the size of the initial particle, which ultimately affects subsequent growth.

Tectonic evolution of the Gabal Loman area, North Eastern Desert, Egypt: implications from low-temperature multithermochronometry on the Arabian-Nubian shield

The Neoproterozoic Arabian-Nubian Shield (ANS) in the Eastern Desert of Egypt encloses the regional thermal-tectonic history from its development till the Oligo-Miocene when the Red Sea rift system was initiated. The application of multi-thermochronometry techniques has proven to be a successful approach to revealing the influence and extent of each regional tectonic event and the recreation of the tectono-thermal development of the studied region through time. Therefore, characteristic samples from the ANS different rock suits of the Gabal Loman area at the western flank of the northern Red Sea were collected. The Zircon fission-track data reveals the Carboniferous cooling ages, while the apatite fission-track cooling ages present two differential time spans of Cretaceous and Eocene-Oligocene. The time-temperature history modeling is integrated with fission-track data to reveal three differentiated cooling events developed in response to regional tectonic events: 1) the Hercynian (Variscan) tectonic event that influenced the ANS vicinity with rock uplifts of ca. 4 km through the Devonian-Carboniferous time, 2) the Gondwana disintegration event which influenced the region with differential rock exhumations, and 3) the northern Red Sea rifting through the Oligo-Miocene which caused a regional ca. 1 km of rift flanks exhumation. This modest rift flank uplift suggests a passive rift of the northern Red Sea rifting in the region of study.

Non-Destructive Testing in Concrete Maturity Modeling and Master Curve Development

Assessing concrete quality as construction goes on provides early warnings of potential flaws and leads to timely corrections in mix proportioning and placement techniques. Compressive strength and maturity modeling are among the most common parameters used by the concrete industry. Past studies indicated that non-destructive methods, NDTs, relate well to maturity and concrete strength predictions. In this study, the hydration temperature–time history of concrete was explored in defining “master curves” for concrete maturity for the first time. Well-accepted NDTs, such as ultrasonic pulse velocity and resonant frequency, were used in this effort. The study findings indicated that the novel approach of “master curves” for the maturity of concrete can be defined and follow a generalized logarithmic form. The best fit models relating NDT response and the maturity temperature–time product provided a high coefficient of determination (i.e., in almost all cases above 0.9 and p < 0.05), thus resulting in a very good fit. The shift factors for each mixture’s maturity function in relation to the master curve were related to concrete properties. The shifted maturity functions from the concrete mixtures included in the study had a perfect transition to the master curve (i.e., all the shifted data overlap the master curve trend line with an R2 = 1). The NDTs’ ability to capture the hydration temperature-time history was assessed with impeded sensors into the concrete mixtures. This approach has provided strength prediction models with a high accuracy (i.e., good agreement between observed and predicted strength values with R2 = 0.93). The proposed NDT-based maturity modeling through “master curve” development provides significant benefits in relation to traditional maturity modeling since it offers the opportunity to: (i) predict strength without having to repeat maturity testing each time a producer adjusts mixture proportioning to fine tune mix design; (ii) save testing time and cost due to reduced maturity evaluation from the use of master curves; and (iii) be able to quickly predict without further testing what the strength gain will be due to variations in mixture proportioning. The ability to monitor concrete maturity, and thus strength, with NDTs in reinforced concrete is of particular interest since using cores is problematic due to the presence of reinforcement.

Modeling the maturation history of the stacked petroleum systems of the Williston Basin, USA

A three-dimensional petroleum systems model was built to support U.S. Geological Survey assessments of undiscovered oil and gas resources in the Williston Basin of North Dakota, Montana, and South Dakota. Numerous Paleozoic source rocks have been proven or postulated in the basin, of which five were the focus of maturation and migration modeling: the Ordovician Icebox Formation, the kukersite beds of the Ordovician Red River Formation, the shales of the Devonian–Mississippian Bakken Formation, the Mississippian Madison Group, and the Pennsylvanian Tyler Formation. Calibration of the three-dimensional model to present-day temperature data indicates the existence of a north-south trend of high heat flow in western North Dakota, along with a region of high heat flow in eastern Montana. These high heat flow trends strongly control the maturity of all studied source intervals. A Bakken-specific hydrocarbon generation kinetic model was developed to match the calibrated time-temperature history of the basin to spatial trends in hydrogen index from programmed pyrolysis data. Generation of hydrocarbons occurred in the Cretaceous through Paleogene due to increased burial. Subsequent uplift and erosion in the Neogene cooled the basin, ending hydrocarbon generation for all source rocks. The cumulative volume of hydrocarbons generated by each of the source rocks was calculated and used to compare their relative robustness. The shales of the Bakken Formation are estimated to have generated approximately 460 billion barrels of oil equivalent (BBOE), while the Red River Formation generated approximately 130 BBOE, the Tyler Formation 94 BBOE, the Madison Group 44 BBOE, and the Icebox Formation 28 BBOE. Gross migration trends were analyzed with respect to historical oil and gas production in the basin and generally indicate segregation of petroleum systems throughout the stratigraphic column. However, most modeled scenarios indicated significant loss of Bakken oil to the Madison Group, suggesting that mixing of Madison and Bakken oils may be more prevalent than has recently been recognized in the U.S. portion of the Williston Basin and is particularly likely in fractured regions of the basin.

Quantitative Evaluation of the Fracturing State of Crystalline Rocks Using Infrared Thermography

The fracturing state of rocks is a fundamental control on their hydro-mechanical properties. It can be quantified in the laboratory by non-destructive geophysical techniques that are hardly applicable in situ, where biased mapping and statistical sampling strategies are usually exploited. We explore the suitabilty of infrared thermography (IRT) to develop a quantitative, physics-based approach to predict rock fracturing starting from laboratory scales and conditions. To this aim, we performed an experimental study on the cooling behaviour of pre-fractured gneiss and mica schist samples, whose 3D fracture networks were reconstructed using Micro-CT and quantified by unbiased fracture abundance measures. We carried out cooling experiments in both controlled (laboratory) and natural (outdoor) environmental conditions and monitored temperature with a thermal camera. We extracted multi-temporal thermograms to reconstruct the spatial patterns and time histories of temperature during cooling. Their synthetic description show statistically significant correlations with fracture abundance measures. More intensely fractured rocks cool at faster rates and outdoor experiments show that differences in thermal response can be detected even in natural environmental conditions. 3D FEM models reproducing laboratory experiments outline the fundamental control of fracture pattern and convective boundary conditions on cooling dynamics. Based on a lumped capacitance approach, we provided a synthetic description of cooling curves in terms of a Curve Shape Parameter, independent on absolute thermal boundary conditions and lithology. This provides a starting point toward the development of a quantitative methodology for the contactless in situ assessment of rock mass fracturing.

Comparative response of tiled finishes and bonded fire resistive coatings for normal weight concrete tunnel liners under high-intensity one-sided heating

Experimental tests were performed to examine the relative fire resistance provided by several bonded coatings for normal weight concrete (NWC) panels that emulate a tunnel liner: ceramic tiling on mortar, spray-applied fire resistive material (SFRM), and intumescent paint (IP). Sixteen panel specimens (150-mm [6-in.] thick, 457-mm [18-in.] wide, and 610-mm [24-in.] tall) were subjected to one-sided heating using a gas-fired radiant panel, which can apply heat flux at intensities similar to hydrocarbon fuel fire. All specimens were cast from a single batch of NWC (approx. 40 MPa compressive strength) with a single curtain of steel reinforcing bars at 38-mm (1.5-in.) cover to the heated face. All specimens were vertically loaded to a service level of compressive uniaxial stress (approx. 14% of ambient specified compressive strength), which remained relatively constant during each test. Four bare concrete panel specimens were tested as a control group, and a ceramic tile finish was installed on six specimens in accordance with a current state department of transportation specification. The other six specimens were coated with fire resistive material (three each with SFRM and IP) at thicknesses corresponding to a 1-hr fire resistance rating per manufacturer specifications. Thermally-induced explosive concrete spalling was observed in 3 of 4 control specimens, 4 of 6 tiled specimens, and none of the 6 SFRM/IP coated specimens. The tiled finishes delaminated and eventually became fully detached from the concrete surface, thus providing negligible fire resistance compared to that provided by the SFRM or IP. Temperature time histories recorded within the outer 25-mm (1.0-in.) thickness of the heated concrete were used to evaluate the relative thermal resistance of each surface finish, as well as to validate a simplified thermal numerical model used for a brief parametric study. Post-fire removal of the surface finishes is also demonstrated.

Self-Destructive Structural Color Liquids for Time-Temperature Indicating.

Vaccines are undoubtedly a powerful weapon in our fight against global pandemics, as demonstrated in the recent COVID-19 case, yet they often face significant challenges in reliable cold chain transport. Despite extensive efforts to monitor their time-temperature history, current time-temperature indicators (TTIs) suffer from limited reliability and stability, such as difficulty in avoiding human intervention, inapplicable to subzero temperatures, narrow tracking temperature ranges, or susceptibility to photobleaching. Herein, we develop a class of structural color materials that harnesses dual merits of fluidic nature and structural color, enabling thermal-triggered visible color destruction based on triggering agent-diffusion-induced irreversible disassembly of liquid colloidal photonic crystals for indicating the time-temperature history of the cold chain transport. These self-destructive structural color liquids (SCLs) exhibit inherent irreversibility, superior sensitivity, tunable self-destructive time (minutes to days), and a wide tracking temperature range (-70 to +37 °C). Such self-destructive SCLs can be conveniently packaged into flexible TTIs for monitoring the storage and exposure status of diverse vaccines via naked-eye inspection or mobile phone scanning. By overcoming the shortcomings inherent in conventional TTIs and responsive photonic crystals, these self-destructive SCLs can increase their compatibility with cold chain transport and hold promise for the development and application of the next-generation intelligent TTIs and photonic crystals.

Combustion behavior of single iron particles, Part II: A theoretical analysis based on a zero-dimensional model

Following the ignition and solid-to-liquid phase transition of a fine (on the order of 10–100µm in diameter) iron particle, the self-sustained combustion of a liquid-phase droplet of iron and its oxides takes place. The objective of the current work is to develop an interpretive and explanatory model for the liquid-phase combustion of a single fine iron particle. A zero-dimensional physicochemical model is developed assuming fast internal processes, such that the combustion rate is limited by the rate of external oxygen (O2) transport. The model considers a particle covered by a shell of liquid-phase FeO enclosing a core of liquid-phase Fe. Stefan flow and diffusion are considered for the gas-transport of O2, while the gas-transport of gas-phase Fe and FeO are calculated via diffusion only. The outward gas-phase Fe and FeO consume inward-transported O2 to stoichiometrically form hematite (Fe2O3), and the remaining oxygen that reaches the particle surface is entirely consumed to form liquid-phase FeO. The time history of simulated particle temperature shows consistent overprediction of the peak particle temperature when compared to experimental temperature measurements, indicating that the assumption of fast internal kinetics may be incorrect. The model is also unable to capture the apparent slow cooling rate observed in experiments. A further analysis is performed through a heuristic model with a calibrated reaction-rate law, where the internal diffusion of reactive Fe and O ions may become rate-limiting. The calibration of the pre-exponential factor in the Arrhenius term to match the experimental peak temperature yielded good agreement of time to peak temperature, as well as the slow cooling rate. The heuristic model considering internal diffusion predicts a plateau in peak temperature with increasing oxygen concentration. Possible uncertainties of the models, as well as future work, are discussed.

Ash deposition and fine particle formation when utilizing biomass and coal fly ash in lab-, pilot- and full-scale

Fine particles were sampled at the 800 MWth Avedøre Power Station Unit 2 (AVV2) as well as at the 900 MWth Studstrup Power Station Unit 3 (SSV3), both utilizing wood pellets together with coal fly ash (CFA), for alkali capturing. In parallel, fine particle formation was quantified in the BoCTeR pilot-scale pulverized-fuel biomass combustion test-rig, at the Technical University of Munich, using the same wood pellets and CFA-additive as was applied in full-scale, to compare the impact of the CFA-addition. A comparison between fine particle formation and concentration in the BoCTeR and in full-scale, revealed a higher quantity of submicron particles (PM1) at AVV2, compared to SSV3, i.e. differences between the two full-scale boilers, while the PM1-values at BoCTeR was found to be substantially higher than what was measured in full-scale, mainly due to differences in temperature–time history between these two combustor scales.Ash deposition during wood pellets firing with CFA-addition, was quantified by an advanced deposit probe at SSV3. The results showed that with a probe surface temperature of 550 °C, and 2 %wt or 3 %wt CFA-addition, no significant amount of deposit was formed. When increasing the probe surface temperature to 650 °C, at 3 %wt CFA-addition, deposit was formed on the upstream side of the probe. No Cl was detected in the deposit samples, indicating that Cl-related corrosion can be effectively suppressed by 2 %wt or 3 %wt coal fly ash addition.Finally, deposit formation when firing different pre-treated biomasses; K- and Cl-rich wheat straw, milled wood pellets, hydrothermally carbonized (HTC)-leaves and steam exploded (SE)-bark, with and without a K-capturing additives, was also investigated in the entrained flow reactor at Technical University of Denmark (DTU-EFR). In terms of deposit formation, the K- and Cl-rich wheat straw proved to be the most problematic fuel, while milled wood pellets, HTC-leaves and SE-bark, had significantly lower deposition propensities. When applying kaolin and two types of CFA (both rich in Al and Si), as K-capturing additive, the deposition propensity of wheat straw decreased significantly, when applying a molar ratio of fuel-K/additive-Al of 1.0.This paper was originally presented at the recent 28th International Conference on Impacts of Fuel Quality on Power Production, the, Aare, Sweden, September 19–23, 2022.

Relationship between coal composition, coal facies, and desorbed methane gas content: Thermal histories and exhumation processes in the middle Magdalena Valley basin, Colombia

We analyzed a total of 25 coal samples from high volatile bituminous to medium volatile bituminous range from 2 wells drilled in the Landázuri area of the Middle Magdalena Valley Basin at the Eastern Colombia Cordillera. This study reveals the relationship between the measured gas concentration, petrographic characteristics, and coal facies. We identify that gas desorption in coal seams is related to maceral composition.Three coal seam groups were defined in Landázuri 1 based on petrographic and statistical evaluation. Two groups were identified in Landázuri 2 based on gas content.The evaluation of maceral content and preservation of reflectance vitrinite found that the highest desorbed gas values correlate with the abundance of inertinite and structured inertinite macerals, followed by the percentage of vitrinite. Structured inertinite lumens may serve as macro/mesopores which allow for higher gas desorption because they are free of mineral matter or other macerals.Using existing coal facies diagrams, two types of coal facies were differentiated: lower delta plain (fen, marsh) and back-barrier low moor developed in a humid environment, where reotrophic conditions prevail and herbaceous and aquatic/marginal vegetation predominate.The relationship of these transitional facies with gas content shows are not directly related to the higher gas values measured at Landázuri. Instead, the relationship between the high degree of destruction of organic matter in these facies (marine incursions and other flows) and the measured gas content shows the importance of quantifying the structured macerals as potential gas retainers.Using low-temperature thermochronometers apatite fission-track, and (U–Th)/He in zircon, combined with vitrinite reflectance data, we reconstructed time-Temperature histories for areas near the wells. Differences in gas content can be explained by an asynchronous behaviour of the burial-cooling processes in this part of the Colombian Eastern Cordillera. Our work shows it is possible to distinguish gas desorption in coal seams based on the maceral composition.

Reconstructing the Tectonic History of the Arabian–Nubian Shield in Sinai: Low-Temperature Thermochronology Implications on Wadi Agar Area

The Arabian–Nubian Shield envelops the entire regional tectonic history from its formation during the Ediacaran to the Red Sea/Gulf of Suez rifting in the Oligocene–Miocene. The occurrence and extent of the expected successive tectonic events on Sinai basement rocks remain uncertain. Integration of thermochronological techniques with time–temperature modelling has proven to be a powerful tool for thermal-tectonic history reconstruction. Therefore, we collected representative samples from the Arabian–Nubian Shield basement rocks of the Wadi Agar area at the eastern flank of the Suez rift. Zircon fission-track data show two cooling age possibilities of Ediacaran and Devonian ages. Meanwhile, apatite fission-track data represent three cooling age spans of Carboniferous, Triassic, and Cretaceous. The integration of these data with the modelled time–temperature histories reveals four different cooling events synchronous with the regional events; (1) the Neoproterozoic post-accretion erosional event that causes near-surface rock uplift, (2) the Devonian–Carboniferous Hercynian tectonic event which affected the region with rocks exhumation of ca. 4.2 ± 1.4 km, (3) the Triassic Gondwana breakup initiation, and (4) the Oligocene–Miocene Gulf of Suez rifting which caused flanks uplift in the studied region of ca. 1.2 ± 0.4 km. The Gulf of Suez is a passive rift with a dominant mechanical component that is divided into two differently exhumed northern and southern segments, where an additional far-field thermal overprint was restricted to the southern segment.

A Study on Creep-Fatigue Evaluation of Nuclear Cladded Components by ASME-III Division 5

In this paper, a study on creep-fatigue evaluation on the cladded nuclear component subjecting to low pressure and high temperature services is carried out. To do this, the codes and standards presented by ASME-III Division 5 are reviewed, and a detailed evaluation procedure is presented step by step for practical applications. As an example of practical design application, a molten salt reactor vessel with a cladding thickness of 10% of the base material thickness is designed and four representative operation cycle types are established. The stress cycle types based on finite element stress analysis are determined from the operation cycle types having coolant temperature and pressure time history loads, and results of the creep-fatigue evaluation are described step by step according to the evaluation procedure. From the result of the creep-fatigue evaluation, it is found that the creep-fatigue evaluation for reactors such as molten salt reactor, sodium-cooled reactor, and so on, which are operated at low pressure and high temperature, is dominated by thermal loads. In this study, the effects of the cladding material and the thermal stresses on the creep-fatigue evaluation are investigated. In addition, as one of the design options to reduce the thermal stresses, the thickness of the exampled vessel is reduced, and the calculated creep-fatigue values are compared with the acceptance creep-fatigue envelope criteria of the ASME-III Division 5.

Multilayer In Vitro Human Skin Tissue Platforms for Quantitative Burn Injury Investigation.

This study presents a multilayer in vitro human skin platform to quantitatively relate predicted spatial time-temperature history with measured tissue injury response. This information is needed to elucidate high-temperature, short-duration burn injury kinetics and enables determination of relevant input parameters for computational models to facilitate treatment planning. Multilayer in vitro skin platforms were constructed using human dermal keratinocytes and fibroblasts embedded in collagen I hydrogels. After three seconds of contact with a 50-100 °C burn tip, ablation, cell death, apoptosis, and HSP70 expression were spatially measured using immunofluorescence confocal microscopy. Finite element modeling was performed using the measured thermal characteristics of skin platforms to determine the temperature distribution within platforms over time. The process coefficients for the Arrhenius thermal injury model describing tissue ablation and cell death were determined such that the predictions calculated from the time-temperature histories fit the experimental burn results. The activation energy for thermal collagen ablation and cell death was found to be significantly lower for short-duration, high-temperature burns than those found for long-duration, low-temperature burns. Analysis of results suggests that different injury mechanisms dominate at higher temperatures, necessitating burn research in the temperature ranges of interest and demonstrating the practicality of the proposed skin platform for this purpose.

Prediction of the temperature–time history in ordinary bodies induced by surface heat flux utilizing the enhanced method of discretization in time and the finite difference method

Purpose The purpose of this paper is to address unsteady heat conduction in two subsets of ordinary bodies. One subset consists of a large plane wall, a long cylinder and a sphere in one dimension. The other subset consists of a short cylinder and a large rectangular bar in two dimensions. The prevalent assumptions in the two subsets are: constant initial temperature, uniform surface heat flux and thermo-physical properties invariant with temperature. The engineering applications of the unsteady heat conduction deal with the determination of temperature–time histories in the two subsets using electric resistance heating, radiative heating and fire pool heating. Design/methodology/approach To this end, a novel numerical procedure named the enhanced method of discretization in time (EMDT) transforms the linear one-dimensional unsteady, heat conduction equations with non-homogeneous boundary conditions into equivalent nonlinear “quasi–steady” heat conduction equations having the time variable embedded as a time parameter. The equivalent nonlinear “quasi–steady” heat conduction equations are solved with a finite difference method. Findings Based on the numerical computations, it is demonstrated that the approximate temperature–time histories in the simple subset of ordinary bodies (large plane wall, long cylinder and sphere) exhibit a perfect matching over the entire time domain 0 < t < ∞ when compared against the rigorous exact temperature–time histories expressed by classical infinite series. Furthermore, using the method of superposition of solutions in the convoluted subset (short cylinder and large rectangular crossbar), the same level of agreement in the approximate temperature–time histories in the simple subset of ordinary bodies is evident. Originality/value The performance of the proposed EMDT coupled with a finite difference method is exhaustively assessed in the solution of the unsteady, one-dimensional heat conduction equations with prescribed surface heat flux for: a subset of one-dimensional bodies (plane wall, long cylinder and spheres) and a subset of two-dimensional bodies (short cylinder and large rectangular bar).

Improving radio frequency heating uniformity in milled rice with different packaging shapes by changing temperature of forced air

Radio frequency (RF) treatment is a promising physical method for disinfesting and pasteurizing foods but the non-uniform RF heating is still a major obstacle for industrial applications. In this study, a three-dimensional model was established with COMSOL software to simulate temperature distributions in milled rice with different packaging shapes and experiments using a 6 kW, 27.12 MHz RF system were carried out to evaluate the improvement of heating uniform of sample by changing temperature of forced air. The established model was validated by temperature-time histories at three points in the sample and temperature distributions at the top and bottom surfaces. The results showed that the cold spot of the regular shape sample was found at the part with small thickness, and the RF heating uniformity was improved by increasing temperature of forced hot air. When the temperature of forced hot air increased from 40 to 60 °C, all the sample temperatures were above 50 °C, which might meet the required temperature of disinfestation, and the heating uniformity index decreased from 0.113 to 0.099. For the cuboid shape sample, the corner/edge effect was observed and the heating uniformity index firstly decreased and then increased with reduced temperature of forced cold air. When the temperature of forced air decreased to 10 °C, the best heating uniformity of the cuboid shape sample was obtained. The results of this research can help to select packaging shape and improve the heating uniformity of samples for RF treatment in large-scale applications.

Unraveling the role of chemical composition in the critical cooling rate of high-temperature CMAS slag

Centrifugal-granulation-assisted thermal energy recovery (CAGTER) emerges as a leading technology to treat the industrial CaO-MgO-Al2O3-SiO2 melts such as blast furnace slag. However, large-scale implementation of CGATER is partly limited by the lack of a thorough understanding of the crystallization dynamics of the CMAS slag. To address this issue, we carried out a systematical experimental effort to visualize the crystallization process of sixteen CMAS slags by the hot thermocouple method and measured their temperature time histories in isothermal cooling and continuous cooling processes. The slag crystallization appears in three different modes including the point growth mode, line growth mode and line-flake growth mode. Interestingly, it was found that a larger CaO/MgO ratio promotes the crystallization and thus features a larger critical cooling rate, while a larger SiO2/Al2O3 ratio suppresses the crystallization. We also assessed the correlation between the critical cooling rate and the chemical-composition-related quantities and further proposed a quantitative relationship to estimate the critical cooling rate of the CMAS-like slags with agreeable accuracy. This study sheds light on the intricate composition-specific crystallization behavior of molten slag and also enables fast yet accurate prediction of the critical cooling rate of BF slag.