Ash deposition and fine particle formation when utilizing biomass and coal fly ash in lab-, pilot- and full-scale

Abstract

Fine particles were sampled at the 800 MWth Avedøre Power Station Unit 2 (AVV2) as well as at the 900 MWth Studstrup Power Station Unit 3 (SSV3), both utilizing wood pellets together with coal fly ash (CFA), for alkali capturing. In parallel, fine particle formation was quantified in the BoCTeR pilot-scale pulverized-fuel biomass combustion test-rig, at the Technical University of Munich, using the same wood pellets and CFA-additive as was applied in full-scale, to compare the impact of the CFA-addition. A comparison between fine particle formation and concentration in the BoCTeR and in full-scale, revealed a higher quantity of submicron particles (PM1) at AVV2, compared to SSV3, i.e. differences between the two full-scale boilers, while the PM1-values at BoCTeR was found to be substantially higher than what was measured in full-scale, mainly due to differences in temperature–time history between these two combustor scales.Ash deposition during wood pellets firing with CFA-addition, was quantified by an advanced deposit probe at SSV3. The results showed that with a probe surface temperature of 550 °C, and 2 %wt or 3 %wt CFA-addition, no significant amount of deposit was formed. When increasing the probe surface temperature to 650 °C, at 3 %wt CFA-addition, deposit was formed on the upstream side of the probe. No Cl was detected in the deposit samples, indicating that Cl-related corrosion can be effectively suppressed by 2 %wt or 3 %wt coal fly ash addition.Finally, deposit formation when firing different pre-treated biomasses; K- and Cl-rich wheat straw, milled wood pellets, hydrothermally carbonized (HTC)-leaves and steam exploded (SE)-bark, with and without a K-capturing additives, was also investigated in the entrained flow reactor at Technical University of Denmark (DTU-EFR). In terms of deposit formation, the K- and Cl-rich wheat straw proved to be the most problematic fuel, while milled wood pellets, HTC-leaves and SE-bark, had significantly lower deposition propensities. When applying kaolin and two types of CFA (both rich in Al and Si), as K-capturing additive, the deposition propensity of wheat straw decreased significantly, when applying a molar ratio of fuel-K/additive-Al of 1.0.This paper was originally presented at the recent 28th International Conference on Impacts of Fuel Quality on Power Production, the, Aare, Sweden, September 19–23, 2022.