The role of gas-to-wall temperature ratio on bypass transition along a highly loaded turbine guide vane is investigated through time-resolved heat flux measurements for different flow conditions. The tests are conducted in the von Karman Institute (VKI) isentropic compression tube (CT-2) facility. High response thin films mounted on the vane (VKI LS89 airfoil) coupled with analog circuits are used for the heat flux measurements. The first detectable wall heat flux fluctuations denote the onset of transition which is also evaluated by both the heat transfer coefficient and the intermittency factor distributions along the suction side. The exit Mach number is kept constant during each test by means of a downstream sonic throat while the gas-to-wall temperature ratio is varied from 1.14 to 1.51 by changing the inlet gas temperature. Four test cases are considered for different exit Mach numbers (0.52 and 0.86) and freestream turbulence intensity levels (0.8% and 5.3%) while the isentropic exit chord Reynolds number is maintained at 106. In the present test campaign, the length and the evolution of the phenomenon indicate a measurable effect of the gas-to-wall temperature ratio for test cases with mild pressure gradients.