Heating Time Research Articles

Sodium salicylate as a green fluorescent probe for ultrasensitive determination of vonoprazan fumarate via fluorescence switch off strategy; greenness assessment

A green, simple and sensitive spectrofluorometric approach for determining vonoprazan fumarate in bulk and pharmaceutical dosage form by turning off the fluorescence of sodium salicylate is developed. The addition of vonoprazan fumarate reduced linearly the fluorescence intensity of 0.4mM sodium salicylate at λem 408nm and at λex 330nm. The approach was found to be linear in the 50.0-3000.0ng/mL range. The limits of detection and quantification were 10.97 and 33.23ng/mL, respectively. The presented method proved its suitability in determination of vonoprazan fumarate in its pure and pharmaceutical dosage form. This method employs water as the exclusive solvent and utilizes safe reagents, evaluated using the Analytical Eco Scale, Green Analytical Procedure Index (GAPI), and carbon footprint. In contrast, previous methods relied on toxic reagents and required extended heating times, resulting in higher environmental impact. The novel method not only enhances analytical efficiency but also aligns with green chemistry principles, offering a sustainable solution for routine pharmaceutical analysis.

Enhanced pyrophosphate detection: Utilizing oPD-derived carbon dots and Fe3+ interactions in a paper strip biosensor

The development of portable, cost-effective, and straightforward DNA biosensors holds immense importance in various fields, including healthcare, environmental monitoring, and food safety. This study contributes to the objective by introducing an innovative approach for synthesizing carbon dots (Cdots) with high quantum yield (QY) and remarkable selectivity for Fe3+ ions. Utilizing o-phenylenediamine as a precursor, the study achieved a straightforward and environmentally friendly synthesis method, enabling the efficient detachment of metal ions from the Cdot surface upon introducing pyrophosphate (PPi). The presence of surface hydroxyl and amino groups facilitated specific Fe3+ recognition. Employing D-optimal response surface methodology, the study optimized Cdot synthesis parameters, identifying temperature and heating time as critical factors influencing QY. Statistical analysis confirmed the model's reliability, predicting maximum QY of 48.8 % with minimal deviation from experimental results. Characterization studies revealed the amorphous nature of Cdots through HR-TEM, XRD, and FTIR analysis. Furthermore, the proposed LAMP/PPi biosensing technique demonstrated higher sensitivity, specificity, and repeatability, with negligible interference from common anions and efficacy across varying pH levels. The limit of detection (LOD) of 0.079 (±0.01) μM and the detection range of 0.1μM-2mM underscore the biosensor's practical utility. This study highlights a promising direction for developing paper-based LAMP/PPi biosensors with potential diagnostics and environmental monitoring applications. Significantly, the biosensing technique is applicable to any DNA amplification method generating pyrophosphate (PPi) as a by-product.

Relationship between Texture, Hydrogen Content, Residual Stress and Corrosion Resistance of Electrodeposited Chromium Coating: Influence of Heat Treatment.

Electrodeposited chromium plating continues to be widely used in a number of specialized areas, such as weapons, transport, aerospace, etc. However, the formation of texture, hydrogen content and residual stress can degrade the serviceability and lead to material failure. The effect of post heat treatment processes on the relationship of texture, hydrogen content, residual stress and corrosion resistance of hexavalent [Cr(VI)] chromium coatings deposited on Cr-Ni-Mo-V steel substrates was investigated. Macrotexture was measured by XRD. Microtexture, dislocation density and grain size were studied by EBSD. With the increase of the heat treatment temperature, it was found that the fiber texture strength of the (222) plane tended to increase and subsequently decrease. Below 600 °C, the increase in the (222) plane texture carried a decrease in the hydrogen content, residual stress, microhardness and an increase in the corrosion resistance. In addition, crack density and texture strength were less affected by the heat treatment time. Notably, relatively fewer crack densities of 219/cm2, a lower corrosion current density of 1.798 × 10-6 A/dm2 and a higher microhardness of 865 HV were found under the preferred heat treatment temperature and time of 380 °C and 4 h, respectively. The hydrogen content and residual stress were 7.63 ppm and 61 MPa, with 86% and 75% reduction rates compared to the as-plated state, respectively. In conclusion, in our future judgement of the influence of heat treatment on coating properties, we can screen or determine to a certain extent whether the heat treatment process is reasonable or not by measuring only the macrotexture.

Use of optical absorption and scattering properties to monitor the change of chemical characteristics, particle structure and viscoelasticity during apple puree processing

This work explored the optical absorption (μa) and reduced scattering (μs') properties at 400-1050nm (Vis-NIR) and 900-1650nm (SWIR) of apple puree at different heating times to evaluate their changes in composition and structure. The optical absorption and scattering coefficients of μa and μs' decreased with increasing heating time. The specific μs' coefficients at 432nm, 455nm, 1183nm and 1304nm were related to particle structural changes. The partial least squares regression (PLSR) models based on μs' coefficients in the combined Vis-NIR and SWIR regions provided satisfactory estimations of puree particle area (Rp2=0.90) and particle perimeter (Rp2=0.85), whereas the μs' coefficients in the Vis-NIR region predicted puree viscosity (Rp2=0.83), elasticity modulus (Rp2=0.81) and viscous modulus (Rp2=0.78). Consequently, optical properties can be a potential tool to determine structural and rheological changes of apple puree.

Investigation of the effects of heat treatment on medium density fiberboard (MDF)

In particular, materials such as medium density fiberboard (MDF) have advantages such as high strength, homogeneous structure and easy processability, but disadvantages such as sensitivity to water and formaldehyde emission. To minimize these disadvantages and increase the durability of the material, methods such as heat treatment are used. This study was carried out to determine the effect of heat treatment at different temperatures on water swelling and formaldehyde emission values of MDF samples. Fiberboards with a thickness of 18 mm were used in the experiments. The fiberboard samples used in this study were kept at 120 °C, 150 °C and 180 °C for 2, 4 and 6 hours respectively. It was observed that water swelling and formaldehyde emission values decreased with increasing time and temperature in heat treatment.

A study of capacity demands for heat pumps intermittent heating of China’s residences

A study of capacity demands for heat pumps intermittent heating of China’s residences

Study of Effects of Post-Weld Heat Treatment Time on Corrosion Behavior and Manufacturing Processes of Super Duplex Stainless SAF 2507 for Advanced Li-Ion Battery Cases.

Lithium-ion batteries are superior energy storage devices that are widely utilized in various fields, from electric cars to small portable electric devices. However, their susceptibility to thermal runaway necessitates improvements in battery case materials to improve their safety. This study used electrochemical analyses, including open-circuit potential (OCP), potentiodynamic polarization, and critical pitting temperature (CPT) analyses, to investigate the corrosion resistance of super duplex stainless steel (SAF 2507) applied to battery cases in relation to post-weld heat treatment (PWHT) time. The microstructure during the manufacture, laser welding, and PWHT was analyzed using field-emission scanning electron microscopy, X-ray diffraction, and electron backscatter diffraction, and the chemical composition was analyzed using dispersive X-ray spectroscopy and electron probe micro-analysis. The PWHT increased the volume fraction of austenite from 5% to 50% over 3 min at 1200 °C; this increased the OCP from -0.21 V to +0.03 V, and increased the CPT from 56 °C to 73 °C. The PWHT effectively improved the corrosion resistance, laying the groundwork for utilizing SAF 2507 in battery case materials. But the alloy segregation and heterogeneous grain morphology after PWHT needs improvement.

Influence of temperature and heating duration on the thermal stability and flow characteristics of oil extracted from undersized crawfish (Procambarus clarkii) using non‐solvent method

AbstractUndersized crawfish (UC) have less economic value for sale in live or processed tail meat markets. Therefore, this study's objectives were to extract crawfish oil (CO) from UC and determine the impact of temperature and heating duration on CO's thermal stability and flow properties. However, extracting oil from these undersized specimens could potentially add value to the crawfish industry. Crawfish minced meat (CMM) was obtained by passing cooked and chilled UC through a pilot scale deboning machine. CO was extracted by agitating CMM at 70°C for 30 min, followed by centrifugation at 10,000×g. CO was analyzed for inherent physicochemical characteristics, heating time (0–8 h), temperature (45–85°C) effects on peroxide value (PV) and astaxanthin (ASX) content, and flow properties at 5–35°C. ASX content, PV, water activity, bulk density, specific gravity, and free fatty acid values in CO were found to be 1.52 ± 0.06 mg/g oil, 0.22 ± 0.07 meq/kg, 0.56 ± 0.02, 0.88 ± 0.00, 0.90 ± 0.00 g/mL, and 0.11 ± 0.04%, respectively. ASX content in CO showed no significant change within or between same‐temperature and different‐temperature heated samples after 8 h. PV increased significantly from 0 to 8 h of heating at all tested temperatures (45, 65, and 85°C; Δ = 0.31, 0.51, and 10.76 meq/kg, respectively). CO had pseudoplastic characteristics below 30°C and Newtonian flow from 30 to 35°C. The Arrhenius equation suitably described the relationship between temperature and apparent viscosity of CO. This study characterized a seldom‐researched oil (CO containing ASX) and provided insight into its ability to resist thermal degradation.

Numerical optimization of drying of white button mushroom (Agaricus bisporus) employing microwave and fluidized bed drying for preparing value added product

Numerical optimization of drying of white button mushroom (Agaricus bisporus) employing microwave and fluidized bed drying for preparing value added product

Oil in water emulsion stabilized by glycated rice bran protein aggregates: Effect on interfacial behavior and in vitro digestion of emulsion

Oil in water emulsion stabilized by glycated rice bran protein aggregates: Effect on interfacial behavior and in vitro digestion of emulsion

Microwave-assisted rapid synthesis of ZnO multipod-BiOBr heterojunction on recycled PET plastic waste for photocatalytic degradation of oily wastewater

Microwave-assisted rapid synthesis of ZnO multipod-BiOBr heterojunction on recycled PET plastic waste for photocatalytic degradation of oily wastewater

Broad emission in Bi-doped GeGaSe chalcogenide glass and glass-ceramic

Broad emission in Bi-doped GeGaSe chalcogenide glass and glass-ceramic

Effects of magnetic field heat treatment on magnetic properties and microstructure of Sm2Co17-type sintered magnets

Effects of magnetic field heat treatment on magnetic properties and microstructure of Sm2Co17-type sintered magnets

Comparative analysis of charging and discharging characteristics in novel cold and hot simultaneous energy storage tanks

Comparative analysis of charging and discharging characteristics in novel cold and hot simultaneous energy storage tanks

Reconstruction of Mars 2020 Backshell Radiative Heating via Infrared Emission Spectroscopy of CO2/N2/Ar Shockwaves

A test series was performed in the Electric Arc Shock Tube (EAST) facility with the aim of reproducing flight conditions encountered during the Mars 2020 mission entry into the Mars atmosphere. For this test series, the EAST facility was instrumented with two spectrometers for optical emission spectroscopy (OES) measurements and three mid-infrared lasers for tunable diode laser absorption spectroscopy (TDLAS). This paper focuses on the spectrally and spatially resolved radiance measured with OES. Conditions were chosen to achieve similarity to backshell radiative heating measured with the MEDLI2 heat flux gauges near and after the time of peak heating. Comparisons were made against two candidate kinetic models for Mars entry. Below 2.7 km/s, the chemistry is effectively frozen, with measurements being above both models and CEA predictions. It is shown that taking into account shock deceleration in the tube explains most of the discrepancy between measured and frozen radiance. For velocities above 2.7 km/s, the data lies between the two models. However, adjusting for shock deceleration indicates that one of the models may be preferred for predicting CO2 dissociation. Finally, comparisons between OES and TDLAS data are made and show a good agreement on the measured temperature and CO2 number density profiles, typically within 10 and 5%, respectively. A good agreement is also observed for the radiance that would be inferred based upon the quantities measured by TDLAS.

4D printing of Pickering emulsion: Temperature-driven color changes

4D printing of Pickering emulsion: Temperature-driven color changes

Advanced Bioceramics: Properties, Fabrication and Applications

Bioceramics are engineered materials that achieve their applications in the medical field. Bioceramics are promising inorganic materials to create scaffolds for bone regeneration due to their desirable properties, such as biocompatibility, osteoconduction, and their similarity with bone composition. Bioceramics can operate as tissue replacement and can be used for coating metal implants to increase their biocompatibility. Bioceramics are classified into three types: bioinert ceramics, bioactive bioceramics, and biodegradable ceramics. There are different methods for the fabrication of bioceramics, they can be prepared by conventional powder processing methods or by some new unconventional methods. Bioceramics can be fabricated by a sintering process, which takes place through the hardening of the green bodies at a relatively high temperature lower than their melting point. Nowadays, microwave sintering is excellent in both heating efficiency, saving energy and time, and the concomitant processing cost. There are other methods used to obtain bioceramics; such as sol-gel, gas-foaming, gel-casting, and freeze-casting techniques. Recently, the CAD/CAM technique (computer-aided design/manufacture) was used in the fabrication of bioceramics and is applied in the dentistry field. The application of bioceramics connects to the repair of the skeletal system, which consists of joints, bones, and teeth, as well as both soft and hard tissues. Bioceramics can be used to replace parts of the cardiovascular system, especially heart valves.

Examining Shape Dependence on Small Mild Steel Specimens during Heating Processes.

With regard to the heating technology of small test specimens (D < 1 inch, i.e., 25.4 mm), only a limited amount of data and literature are available for making adequate technological decisions. Heating time of small geometric shapes is influenced by the technological parameters of the furnace, the temperature, the disposition technique in the furnace and the geometric characteristics of the workpiece. How to shorten heating time to achieve a suitable material structure is a vital question, while considerable energy is saved at the same time. Among the geometric characteristics, shape dependence is one of the important aspects that must be taken into account in terms of heating technology. Shape dependence is usually taken into account with empirically produced correction factors, which can result in significant oversizing of heating time, energy-wasting technology and material structure of insufficient fineness. In the course of our work, we investigated and compared the shape dependence of cylindrical and prismatic specimens with the same surface-to-volume ratios, which were combined with surface heat transfer analyses and geometric effect tests to formulate new approximate equations for determining heating time. As a result, we could mathematically derive a relationship between heating time, size and shape of the active surfaces, the correlation of which can shorten heating time by 20%. In addition, a shape factor (1.125) between cylinder and prismatic-shaped specimens was determined, which can be used with the new equation to calculate heating time for similar specimens. At last, a relationship is developed between the amount of heat that can be stored in the body during heat equalization and the complexity of the shape, which can be characterized through ratios depending on heating times and active surfaces in the function of total surface/volume ratio. Based on this relationship it can be determined more precisely when heat equalization occurs; therefore, shorter heating time can be achieved. In conclusion, with the help of this new method, optimal heating time for structural steel components, in the case of small cross-section and weight, can be determined.

Improved Design and Fabrication of a Compression Moulding Machine with Performance Evaluation

This study explores the advancements in the design and performance of an improved compression moulding machine aimed at efficiently recycling various plastic wastes, with an emphasis on Polyethylene Terephthalate (PET). With global plastic waste accumulation posing severe environmental challenges, enhancing recycling technologies is imperative. The re-designed machine was tested at operating temperatures of 200°C, 250°C, and 300°C, highlighting the critical role of temperature and processing duration in determining product quality. Theoretical heating times were found to be shorter than actual times due to real-world inefficiencies such as heat loss and thermal conductivity variations. Weight loss during heating, attributed to the evaporation of volatile components and thermal degradation, was observed. The formation of air pores in samples with extended heating times underscored the necessity for precise process control. The PET melting process initiated effectively at approximately 250°C. The improved machine demonstrated significant potential in enhancing recycling efficiency and versatility.

Interfacial microstructure and mechanical properties of CBN brazed in a continuous tunnel furnace with low-temperature Sn-Cu-Ti filler alloy

Interfacial microstructure and mechanical properties of CBN brazed in a continuous tunnel furnace with low-temperature Sn-Cu-Ti filler alloy